CN109659798A - A kind of device generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray - Google Patents

A kind of device generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray Download PDF

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Publication number
CN109659798A
CN109659798A CN201910013953.4A CN201910013953A CN109659798A CN 109659798 A CN109659798 A CN 109659798A CN 201910013953 A CN201910013953 A CN 201910013953A CN 109659798 A CN109659798 A CN 109659798A
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CN
China
Prior art keywords
repetition rate
vacuum
ultraviolet ray
extreme ultraviolet
laser
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Pending
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CN201910013953.4A
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Chinese (zh)
Inventor
徐永兵
聂忠辉
黎遥
何亮
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Nanjing University
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Nanjing University
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Priority to CN201910013953.4A priority Critical patent/CN109659798A/en
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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01SDEVICES USING THE PROCESS OF LIGHT AMPLIFICATION BY STIMULATED EMISSION OF RADIATION [LASER] TO AMPLIFY OR GENERATE LIGHT; DEVICES USING STIMULATED EMISSION OF ELECTROMAGNETIC RADIATION IN WAVE RANGES OTHER THAN OPTICAL
    • H01S3/00Lasers, i.e. devices using stimulated emission of electromagnetic radiation in the infrared, visible or ultraviolet wave range
    • H01S3/005Optical devices external to the laser cavity, specially adapted for lasers, e.g. for homogenisation of the beam or for manipulating laser pulses, e.g. pulse shaping
    • H01S3/0092Nonlinear frequency conversion, e.g. second harmonic generation [SHG] or sum- or difference-frequency generation outside the laser cavity
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/35Non-linear optics
    • G02F1/3501Constructional details or arrangements of non-linear optical devices, e.g. shape of non-linear crystals
    • GPHYSICS
    • G02OPTICS
    • G02FOPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS
    • G02F1/00Devices or arrangements for the control of the intensity, colour, phase, polarisation or direction of light arriving from an independent light source, e.g. switching, gating or modulating; Non-linear optics
    • G02F1/35Non-linear optics
    • G02F1/353Frequency conversion, i.e. wherein a light beam is generated with frequency components different from those of the incident light beams

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  • Physics & Mathematics (AREA)
  • Nonlinear Science (AREA)
  • Optics & Photonics (AREA)
  • Electromagnetism (AREA)
  • General Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Plasma & Fusion (AREA)
  • Chemical & Material Sciences (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • X-Ray Techniques (AREA)

Abstract

The invention discloses a kind of devices for generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray, comprising: the femto-second laser of the Superhigh repetition rate is used to export the laser pulse of femtosecond magnitude, and repetition rate reaches as high as MHz;The focusing optic by laser pulse for guiding and focusing in the intracorporal continuity gas device of vacuum chamber;The continuity gas device is used to discharge gas and generates femtosecond extreme ultraviolet ray after interacting with the laser pulse after focusing;The vacuum system is for absorbing excessive gas in gas device, it is ensured that the vacuum degree in device;The monitoring system is used to monitor the interaction of laser and gas device, and avoiding device is by laser breakdown.The configuration of the present invention is simple, it is convenient to operate, and being formed by high-throughput and Superhigh repetition rate extreme ultraviolet ray has the other pulse width of femtosecond, can provide high-quality light source for the scientific instrument application such as photoelectron spectroscopy, measurement efficiency is greatly improved, ultrafast area research is facilitated.

Description

A kind of device generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray
Technical field
The present invention relates to a kind of device for generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray, belong to extremely purple Outer ray field.
Background technique
Being constantly progressive and develop with science and technology, extreme ultraviolet ray even X-ray are obtained in numerous areas It is widely applied, such as photoelectron spectroscopy, extreme ultraviolet photolithographic etc..Past extreme ultraviolet ray can only by synchrotron radiation light source or again The equipment such as frequency crystal generate.Synchrotron radiation light source can satisfy the requirement of many scientific experiments, but its equipment is huge, and when machine is tight , and pulse width is longer, therefore has many limitations in practical applications.Although in addition can by the way of frequency-doubling crystal Overcome the problems, such as pulse width, but wave-length coverage is relatively narrow, is difficult to meet the requirement of wide range in scientific experiment.
Appearance and higher hamonic wave progress of research with femto-second laser, light laser and inert gas interaction generate The wide range extreme ultraviolet ray of femtosecond is possibly realized.But at present experimental facilities mostly use greatly impulse jet nozzle release inert gas and Laser interaction, although this impulse jet nozzle can control the vacuum degree of vacuum cavity well, efficiency is very low, therefore This extreme ultraviolet ray is mostly low-repetition-frequency, the lesser extreme ultraviolet ray of luminous flux, and which greatly limits in scientific experiment Efficiency is also unable to satisfy the requirement of photoetching technique center high pass amount.
Summary of the invention
Goal of the invention: in order to overcome the deficiencies in the prior art, it is high-throughput that the present invention provides a kind of generation femtosecond With the device of Superhigh repetition rate extreme ultraviolet ray, there are the spies such as structure is simple, operation is convenient, occupies little space, is cheap Point greatly improves the measurement efficiency of scientific instrument, helps to carry out the research topic in ultrafast field.
Technical solution: to achieve the above object, the technical solution adopted by the present invention are as follows:
A kind of device generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray, including Superhigh repetition rate Femto-second laser, focusing optic, continuity gas device, vacuum cavity, vacuum system and monitoring system;
Wherein, the femto-second laser of the Superhigh repetition rate repeats frequency for exporting the other laser pulse of femtosecond Rate reaches as high as MHz;
The focusing optic by laser pulse for guiding and focusing to the intracorporal continuity gas device of vacuum chamber In;
The continuity gas device, which is used to discharge gas, flies it with generation after the laser pulse interaction after focusing Second grade extreme ultraviolet ray;
The vacuum system is used to absorb the excessive gas of continuity gas device release, it is ensured that the intracorporal vacuum of vacuum chamber Degree;
Relative position and laser pulse of the monitoring system for monitoring laser pulse and continuity gas device are saturating Penetrated the facula position and shape of continuity gas device.
Preferably, the focusing optic includes off axis paraboloidal mirror or short focus plano-convex lens.
Preferably, the continuity gas device includes outer layer protection cavity and to be connected to outer layer protection chamber intracorporal continuous Gas nozzle.
Preferably, the continuity gas nozzle uses needle point formula nozzle or hole drilling type nozzle.
Preferably, the calibrating installation passed through completely for ensuring laser is provided on the outer layer protection cavity.
Preferably, the vacuum system includes that vacuum pump and vibration isolation hose, vacuum pump are inhaled by vibration isolation hose Receive the excessive gas discharged in continuity gas device.
Preferably, the monitoring system includes CCD imaging system, computer and the form being arranged on vacuum cavity, is led to It crosses the CCD imaging system being connected with computer and acquires the intracorporal image of vacuum chamber through form.
Preferably, the vacuum cavity includes the anti-reflection window on vacuum reaction chamber and vacuum reaction chamber, laser pulse It is intracavitary to enter vacuum reaction by anti-reflection window, to guarantee that pulse width does not broaden, and most of energy enters inside cavity.
The utility model has the advantages that a kind of dress for generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray provided by the invention It sets, compared with the existing technology, has the advantage that 1, structure is simple, it is convenient to operate, and occupies little space, and it is cheap, it provides super The extreme ultraviolet ray of high repetition frequency, substantially increases the measurement efficiency of the scientific instrument such as electron spectrum;2, it is high to provide femtosecond The extreme ultraviolet ray of flux meets the application that all multipair flux require, such as ultraviolet photolithographic;3, femtosecond pulse width is provided Extreme ultraviolet ray, improve the temporal resolution of scientific instrument, help to carry out the research topic in ultrafast field.
Detailed description of the invention
Fig. 1 is the overall structure diagram in the present invention;
Fig. 2 is the structural schematic diagram of the embodiment of the present invention;
It include: the femto-second laser of 1- Superhigh repetition rate in figure,
2- focusing optic, the plane mirror of 2.1- high reflectance, 2.2- off axis paraboloidal mirror,
3- continuity gas device, 3.1- outer layer protection cavity, 3.2- continuous gas nozzle,
4- vacuum system, 4.1- vacuum pump, 4.2- vibration isolation hose,
5- monitoring system, 5.1- form, 5.2-CCD imaging system, 5.3- computer,
6- vacuum cavity, 6.1- vacuum reaction chamber, 6.2- is anti-reflection window.
Specific embodiment
The present invention will be further explained with reference to the accompanying drawings and embodiments.
It is as shown in Figure 1 a kind of device for generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray, including super The femto-second laser 1 of high repetition frequency, focusing optic 2, continuity gas device 3, vacuum system 4, monitoring system 5 and true Cavity body 6;
Wherein, the femto-second laser 1 of the Superhigh repetition rate repeats frequency for exporting the other laser pulse of femtosecond Rate reaches as high as MHz;
Laser pulse for being guided and being focused to the dress of the continuity gas in vacuum cavity 6 by the focusing optic 2 It sets in 3;
The continuity gas device 3, which is used to discharge gas, flies it with generation after the laser pulse interaction after focusing Second grade extreme ultraviolet ray;
The vacuum system 4 is used to absorb the excessive gas of the release of continuity gas device 3, it is ensured that in vacuum cavity 6 Vacuum degree;
The monitoring system 5 is used to monitor relative position and the laser pulse of laser pulse and continuity gas device 3 Transmitted through the facula position and shape of continuity gas device 3.
In preferred embodiment as shown in Figure 2, the plane mirror 2.1 of the focusing optic 2 including high reflectance and from Axis paraboloidal mirror 2.2;
The continuity gas device 3 includes outer layer protection cavity 3.1 and is connected to continuous in outer layer protection cavity 3.1 Gas nozzle 3.2;
The vacuum system 4 includes vacuum pump 4.1 and vibration isolation hose 4.2, and vacuum pump 4.1 passes through vibration isolation hose The excessive gas discharged in 4.2 absorption continuity gas devices 3;
The monitoring system 5 includes the form 5.1 on CCD imaging system 5.2, computer 5.3 and vacuum cavity 6, is passed through The CCD imaging system 5.2 being connected with computer 5.3 acquires the image in vacuum cavity 6 through form 5.1;
The vacuum cavity 6 includes vacuum reaction chamber 6.1 and the anti-reflection window 6.2 being arranged on vacuum reaction chamber 6.1, Laser pulse is entered in vacuum reaction chamber 6.1 by anti-reflection window 6.2.
In the present embodiment, the continuous gas nozzle 3.2 uses needle point formula nozzle or hole drilling type nozzle;The outer layer is protected The calibrating installation passed through completely for ensuring laser is provided on shield cavity 3.1.
A specific embodiment of the invention is as follows:
The central wavelength of femto-second laser is 1030nm, repetition rate 1MHz, after being compressed by hollow optical fiber, arteries and veins Width is rushed less than 40fs, single pulse energy can reach 0.7mJ.The femtosecond laser of Superhigh repetition rate is by the flat of high reflectance Face mirror 2.1 reflects, and minimum hot spot is focused into using off axis paraboloidal mirror 2.2, the mean intensity of focal zone laser is big In 1014W/cm2.Laser is needed when entering vacuum reaction chamber 6.1 through anti-reflection window 6.2, and guarantee pulse width does not broaden, and Most of energy enters inside cavity.After femtosecond laser enters cavity, the calibrating installation in continuity gas device 3 is adjusted, is made It obtains femtosecond laser and passes through outer layer protection cavity 3.1 like clockwork, the gas then released with continuous gas nozzle 3.2 is mutual Effect generates femtosecond extreme ultraviolet ray.
It should be noted that monitoring whether laser completely passes through by monitoring system 5 when adjusting continuity gas device Continuity gas device 3, the interior metal without bombarding device.Through form 5.1, CCD imaging system can be observed constantly To the laser position and light spot shape through gas device.Excessive gas is ceaselessly absorbed additionally by vacuum system, it can not only It is enough that extra gas is prevented to absorb extreme ultraviolet ray in time, and can guarantee the intracorporal vacuum degree of vacuum chamber.
It is measured through experiment, in the present embodiment, apparatus of the present invention can generate pulse less than 40fs, and repetition rate is up to 1MHz, luminous flux is up to 1013-1014The extreme ultraviolet ray of photons/second.
In above-mentioned apparatus, used optical element and its quantity are only schematical, and use can play phase same-action Other art-recognized components the purpose of the present invention equally may be implemented.For example, laser used can be by superpower Other femto-second lasers commonly used by laser field are substituted.The conditions such as wavelength, frequency for laser, do not limit strictly System, those of ordinary skill in the art can select as the case may be under the enlightenment of the present embodiment.In addition, off-axis paraboloidal mirror It can also be substituted by other focusing optics such as spherical surface focusing mirror, long focus lens, they can carry out laser It focuses, but off-axis paraboloidal mirror can eliminate the aberration during laser transmission, and be able to bear higher less laser energy value of threshold, Therefore as preferred.CCD imaging system needs to pay attention to damage of the laser for CCD when monitoring laser position, has to infuse Meaning decaying.
In conclusion the device of the extreme ultraviolet ray of femtosecond high throughput proposed by the present invention and Superhigh repetition rate, knot Structure is simple, and it is convenient to operate, and occupies little space, cheap, compared with synchrotron radiation source, X-ray tube etc., has significantly excellent.To the greatest extent Pipe has made specific descriptions to the present invention referring to the above embodiments, but for those of ordinary skill in the art, it answers The understanding can be modified or be improved based on present disclosure within spirit and scope of the invention not departing from.
The above is only a preferred embodiment of the present invention, it should be pointed out that: for the ordinary skill people of the art For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (8)

1. a kind of device for generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray, which is characterized in that including superelevation The femto-second laser (1) of repetition rate, focusing optic (2), continuity gas device (3), vacuum system (4), monitoring system System (5) and vacuum cavity (6);
Wherein, the femto-second laser (1) of the Superhigh repetition rate is for exporting the other laser pulse of femtosecond, repetition rate Up to MHz;
Laser pulse for being guided and being focused to the dress of the continuity gas in vacuum cavity (6) by the focusing optic (2) It sets in (3);
The continuity gas device (3), which is used to discharge gas, to be made it and generates femtosecond after the laser pulse interaction after focusing Grade extreme ultraviolet ray;
The vacuum system (4) is used to absorb the excessive gas of continuity gas device (3) release, it is ensured that in vacuum cavity (6) Vacuum degree;
The monitoring system (5) is used to monitor relative position and the laser pulse of laser pulse and continuity gas device (3) Transmitted through the facula position and shape of continuity gas device (3).
2. a kind of device for generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray according to claim 1, It is characterized in that, the focusing optic (2) includes off axis paraboloidal mirror (2.2) or short focus plano-convex lens.
3. a kind of device for generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray according to claim 1, It is characterized in that, the continuity gas device (3) includes outer layer protection cavity (3.1) and is connected to outer layer protection cavity (3.1) the continuous gas nozzle (3.2) in.
4. a kind of device for generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray according to claim 3, It is characterized in that, the continuous gas nozzle (3.2) uses needle point formula nozzle or hole drilling type nozzle.
5. a kind of device for generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray according to claim 3, It is characterized in that, being provided with the calibrating installation passed through completely for ensuring laser on the outer layer protection cavity (3.1).
6. a kind of device for generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray according to claim 1, It is characterized in that, the vacuum system (4) includes vacuum pump (4.1) and vibration isolation hose (4.2), vacuum pump (4.1) passes through Vibration isolation hose (4.2) absorbs the excessive gas discharged in continuity gas device (3).
7. a kind of device for generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray according to claim 1, It is characterized in that, the monitoring system (5) includes CCD imaging system (5.2), computer (5.3) and is arranged in vacuum cavity (6) On form (5.1), vacuum chamber is acquired through form (5.1) by the CCD imaging system (5.2) that is connected with computer (5.3) Image in body (6).
8. a kind of device for generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray according to claim 1, It is characterized in that, the vacuum cavity (6) includes vacuum reaction chamber (6.1) and the increasing that is arranged on vacuum reaction chamber (6.1) Saturating window (6.2), laser pulse are entered in vacuum reaction chamber (6.1) by anti-reflection window (6.2).
CN201910013953.4A 2019-01-08 2019-01-08 A kind of device generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray Pending CN109659798A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114221203A (en) * 2021-09-30 2022-03-22 南京大学 Extreme ultraviolet pulse light source device with long-time stable output

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102185250A (en) * 2010-12-02 2011-09-14 中国科学院物理研究所 Device and method for generating femtosecond time-resolved X-ray source
CN104638505A (en) * 2015-02-10 2015-05-20 华中科技大学 Method and device for generating broadband continuously tunable coherent extreme ultraviolet source
CN209266823U (en) * 2019-01-08 2019-08-16 南京大学 A kind of device generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102185250A (en) * 2010-12-02 2011-09-14 中国科学院物理研究所 Device and method for generating femtosecond time-resolved X-ray source
CN104638505A (en) * 2015-02-10 2015-05-20 华中科技大学 Method and device for generating broadband continuously tunable coherent extreme ultraviolet source
CN209266823U (en) * 2019-01-08 2019-08-16 南京大学 A kind of device generating femtosecond high throughput and Superhigh repetition rate extreme ultraviolet ray

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
A CABASSE 等: "Collection and spectral control of high-order harmonics generated with a 50W high-repetition rate Ytterbium femtosecond laser system", 《JOURNAL OF PHYSICS B: ATOMIC, MOLECULAR AND OPTICAL PHYSICS》, pages 1 - 4 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114221203A (en) * 2021-09-30 2022-03-22 南京大学 Extreme ultraviolet pulse light source device with long-time stable output
CN114221203B (en) * 2021-09-30 2023-11-03 南京大学 Extreme ultraviolet pulse light source device capable of outputting long-time stability

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