CN109651845A - A kind of Environmentally-friecomposite composite disperse yellow dye composition and dyestuff - Google Patents
A kind of Environmentally-friecomposite composite disperse yellow dye composition and dyestuff Download PDFInfo
- Publication number
- CN109651845A CN109651845A CN201910065423.4A CN201910065423A CN109651845A CN 109651845 A CN109651845 A CN 109651845A CN 201910065423 A CN201910065423 A CN 201910065423A CN 109651845 A CN109651845 A CN 109651845A
- Authority
- CN
- China
- Prior art keywords
- component
- friecomposite
- environmentally
- yellow dye
- disperse yellow
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B67/00—Influencing the physical, e.g. the dyeing or printing properties of dyestuffs without chemical reactions, e.g. by treating with solvents grinding or grinding assistants, coating of pigments or dyes; Process features in the making of dyestuff preparations; Dyestuff preparations of a special physical nature, e.g. tablets, films
- C09B67/0033—Blends of pigments; Mixtured crystals; Solid solutions
- C09B67/0046—Mixtures of two or more azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/18—Azo dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/16—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using dispersed, e.g. acetate, dyestuffs
- D06P1/19—Nitro dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P3/00—Special processes of dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form, classified according to the material treated
- D06P3/34—Material containing ester groups
- D06P3/52—Polyesters
- D06P3/54—Polyesters using dispersed dyestuffs
Landscapes
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Organic Chemistry (AREA)
- Coloring (AREA)
Abstract
The invention discloses a kind of Environmentally-friecomposite composite disperse yellow dye composition and dyestuff, mainly consist of the following components: the auxiliary agent that component C that component B that component A that mass fraction is 10%~65%, mass fraction are 0%~35%, mass fraction are 0.5%~35%, surplus are 20%~85%.Disperse dye composition items color fastness of the present invention is excellent, and tinting power is high, bright in color light, with good level-dyeing property and enhancing, both it can make monochromatic kind to use, and colorant match can also have been carried out by the disperse dyes such as blue, 3B is red, SE-GFL carbuncle, SE-2R indigo plant with 2BLN, compatibility is splendid.
Description
Technical field
The present invention relates to dyestuff preparation technical field, it is specifically related to a kind of print and dye for polyester material and vinegar fiber material
Environmentally-friecomposite composite disperse yellow dye composition and the dyestuff being prepared by the composition.
Background technique
With the rapid development of synthetic fibers especially polyester fiber, dedicated dye of the disperse dyes as polyester fiber,
It is increasingly becoming one of dyestuff with fastest developing speed.In order to improve the application performance of disperse dyes, and the requirement of environmental protection is adapted to, developed
While disperse dyes new varieties, processing technology and compounded technology, which is commercialized, also becomes the emphasis of research.
Disperse dyeing is many with weld type, and (structure is simple, and raw material is easy to get, synthesis letter for disperse yellow 23 before
Just, cheap) it is very big as shallow three former market dosages, but its synthesis material 4- aminoazabenzol is carcinogenic intermediate, therefore its
Substitute is widely studied.Patent CN1580133A (a kind of low-temperature environment-friendly type disperse dyes) discloses a kind of low form yellow dye
Feed composition, but by producer gradually using discovery, this golden yellow sublimation reliability is poor, and light fastness is undesirable, and not alkaline-resisting,
Chromatic light deviation is larger under alkaline condition, and feux rouges glows obviously.A kind of patent CN103740135A (low-temperature environment-friendly type disperse yellow dye
Composition) disclose a kind of low form yellow dye composition, in component A, Acetoxyethyl is introduced, is introduced in component C
The disperse yellow of pyridone structure, this alkali resistance for allowing for composition are extremely restricted.Patent CN101143973A is (a kind of low
Warm environmental protection disperse yellow dye composition) a kind of low form yellow dye composition is disclosed, component dye monomer (2) is medium temperature
Type disperse orange, washing solarization is general, while composition and 3B is red, 2BLN is blue compatibility being made to have certain influence.Therefore, it finds
The problem of disperse yellow of the high light fastness of alkali resistant is still urgent need to resolve.
Summary of the invention
The present invention provides a kind of Environmentally-friecomposite composite disperse yellow dye composition and the dyestuff being prepared by the composition,
The composite disperse yellow dye lifting force is high, and depth is strong, and light fastness and sublimation reliability are good, is particularly suitable for contaminating under alkaline condition
Color.
A kind of Environmentally-friecomposite composite disperse yellow dye composition, according to mass percent meter, comprising:
Component A 10%~65%
Component B 0%~35%
Component C 0.5%~35%
The component A is compound shown in lower formula (I):
The component B is compound shown in lower formula (II):
The component C is compound shown in lower formula (III):
As further preferred, according to mass percent meter, the Environmentally-friecomposite composite disperse yellow dye composition includes:
Component A 25%~55%
Component B 0%~25%
Component C 1%~25%
As further preferred, according to mass percent meter, the Environmentally-friecomposite composite disperse yellow dye composition includes:
Component A 32%~45%
Component B 3%~18%
Component C 3%~18%
By adopting the above technical scheme, the component that can adjust component A, component B, component C according to actual needs, meets different fields
The requirement of conjunction.
As further preferred, according to mass percent meter, the Environmentally-friecomposite composite disperse yellow dye composition includes:
Component A 38%~43%
Component B 8%~15%
Component C 7%~13%
Experiment shows dye composite by adopting the above technical scheme, and light fastness and sublimation reliability are higher, is 5
Grade or 5 grades or more.
Yellow disperse dye composition of the present invention, when application, are generally needed to be added auxiliary agent.The auxiliary agent is point
Dissipate common dispersing agent, diffusant and other surfactants etc. when dyestuff compounding.It preferably includes or mixtures thereof one of following:
Naphthalene sulfonic acid-formaldehyde condensation product, lignosulfonates, alkyl naphthalene sulfonic acid formaldehyde condensation products.As methyl naphthalene sulfonic acid and formaldehyde contracts
Close object (Dispersant MF), naphthalene sulfonic acid-formaldehyde condensation product (dispersing agent NNO), benzyl naphthalene sulfonic acid-formaldehyde condensation product (dispersing agent CNF), wood
Quality sodium sulfonate (lignin 85A, 83A) etc..In general, auxiliary agent and former dyestuff weight ratio are 0.25~2.8:1.
Above-mentioned yellow disperse dye composition can be prepared by the following method: above-mentioned dye component is mixed by a certain percentage
After conjunction, particlized is carried out with pulverizers such as sand mill or grinders in the presence of auxiliary agent, water, is then spray-dried.Above-mentioned dyestuff
Commercial product can be used in component.Above-mentioned yellow disperse dye composition can be liquid after corpusculed, can be after spray drying
Powdery, graininess.
Yellow disperse dye composition of the present invention, dye-uptake is high, and depth is good, fastness to rubbing, resistance to distillation jail
Every fastness such as degree is excellent, and especially washing fastness, sunlight fastness are significantly improved, and are resistant to highly basic, be suitable for terylene and
The dyeing of its blended fabric and stamp are the disperse yellow dyes of a high washing haveing excellent performance, high light fastness, have fine
Market prospects.
Detailed description of the invention
Fig. 1 is that the flow chart that terylene is contaminated on Yellow disperse dye is prepared in embodiment.
Specific embodiment
The invention will be further described combined with specific embodiments below, but the scope of protection of the present invention is not limited thereto.
Examples 1 to 20
According to data shown in table 1, by dye component A, dye component B, dye component C and auxiliary agent (Dispersant MF, diffusant
CNF, sodium lignin sulfonate), after adding water blending, grinding distribution is carried out with sand mill, is then spray-dried.
Wherein, commercial product, the disperse yellow 54# of Zhejiang mountain valley Science and Technology Co., Ltd. production can be used in component A；
The disperse orange 25 # of Zhejiang mountain valley Science and Technology Co., Ltd. production can be used in component B；
The disperse orange 29# of Zhejiang double crown Dye Co., Ltd production can be used in component C；
Table 1 (unit of weight: g)
Comparative example 1~3
Comparative example 1: by the l as a comparison case of embodiment 3 disclosed in patent CN1580133A.
Comparative example 2: by embodiment 4 disclosed in patent CN103740135A as a comparison case 2.
Comparative example 3: by embodiment 11 disclosed in patent CN101143973A as a comparison case 3.
Embodiment 19
Yellow disperse dye composition made from above-described embodiment is tested for the property, test method is as follows:
According to the similar method of GB/T2394-2003, the dispersion obtained of 0.5 gram of embodiment 1~18, comparative example 1~3 is respectively taken
Dyestuff and the contrast sample of comparative example 1-3 preparation are configured to the disperse dyes that concentration is 0.5g/500ml respectively with water and suspend
Liquid takes 20ml to mix with the water of 80ml, adjusts Value in Dyeing Process to 5 with acetic acid/sodium acetate, is then warming up to 60 DEG C, simultaneously respectively
It is put into 2g dacron fabric, high-temperature pressure dyeing is carried out by Fig. 1, is cooled to 80 DEG C of samplings.
It observes cloth specimen coloured light and uses GB/T2397-2012 (lifting force), GB/T8427-2008 (light fastness), GB/
T3921-2008 (washing fastness), GB/T3920-2008 (crock fastness), GB/T5718-1997 (sublimation reliability) measure its dye
Color fastness, measurement result are shown in Table 2.
Comparative example 4
0.5 gram of 23 dyestuff of disperse yellow is taken, repeats embodiment 19, test result is shown in Table 2.
Alkali resistance comparison
It chooses embodiment 3,7,13,15,17,18 and repeats embodiment 19, before dyeing, pH value acetic acid/sodium acetate of dye liquor
It is adjusted to 7,8,9,10 respectively, compares coloured light, the intensity of cloth specimen, test result is shown in Table 3.
Table 2 (unit: grade)
| Embodiment title | Light fastness | Washing fastness | Crock fastness | Sublimation reliability (180 DEG C) |
| Embodiment 1 | 6 | 5 | 5 | 5 |
| Embodiment 2 | 6-7 | 5 | 4-5 | 4-5 |
| Embodiment 3 | 7 | 5 | 5 | 5 |
| Embodiment 4 | 6 | 5 | 5 | 5 |
| Embodiment 5 | 6-7 | 4-5 | 4-5 | 4-5 |
| Embodiment 6 | 6-7 | 5 | 5 | 5 |
| Embodiment 7 | 7 | 5 | 5 | 5 |
| Embodiment 8 | 6 | 5 | 5 | 5 |
| Embodiment 9 | 6 | 5 | 5 | 5 |
| Embodiment 10 | 6 | 5 | 5 | 5 |
| Embodiment 11 | 6-7 | 4-5 | 4-5 | 4-5 |
| Embodiment 12 | 6-7 | 5 | 5 | 5 |
| Embodiment 13 | 7 | 5 | 5 | 5 |
| Embodiment 14 | 6-7 | 5 | 5 | 5 |
| Embodiment 15 | 7 | 5 | 5 | 5 |
| Embodiment 16 | 6-7 | 5 | 5 | 5 |
| Embodiment 17 | 7 | 5 | 5 | 5 |
| Embodiment 18 | 7 | 5 | 5 | 5 |
| Comparative example 1 | 5 | 4 | 4-5 | 4-5 |
| Comparative example 2 | 5 | 4-5 | 4-5 | 4-5 |
| Comparative example 3 | 5 | 4 | 4-5 | 4-5 |
| Comparative example 4 | 6 | 3-4 | 3-4 | 3 |
By the test result of table 2 it is found that yellow disperse dye composition light fastness of the present invention, crock fastness,
The items fastness such as sublimation reliability is excellent.
Using the colour examining result under the conditions of pH=5 as standard coloured light, power part, when pH is respectively 6,7,8,9,10, embodiment
Alkali resistance comparing result, is shown in Table 3.
Table 3
Remarks: the total color difference of Δ E expression cloth specimen.
By the test result of table 3 it is found that its alkali resistance of yellow disperse dye composition of the present invention is obviously improved.
Claims (8)
1. a kind of Environmentally-friecomposite composite disperse yellow dye composition, which is characterized in that be made of following component:
Structure component A as shown in chemical formula (I) that mass fraction is 10%~65%；
Structure component B as shown in chemical formula (II) that mass fraction is 0%~35%；
Structure component C as shown in chemical formula (III) that mass fraction is 0.5%~35%；
The auxiliary agent that surplus is 20%~85%.
2. Environmentally-friecomposite composite disperse yellow dye composition as described in claim 1, which is characterized in that according to mass percent,
Include:
Component A 25%~55%
Component B 0%~25%
Component C 1%~25%.
3. Environmentally-friecomposite composite disperse yellow dye composition as described in claim 1, which is characterized in that according to mass percent,
Include:
Component A 32%~45%
Component B 3%~18%
Component C 3%~18%.
4. Environmentally-friecomposite composite disperse yellow dye composition as described in claim 1, which is characterized in that according to mass percent,
Include:
Component A 38%~43%
Component B 8%~15%
Component C 7%~13%.
5. a kind of Environmentally-friecomposite composite disperse yellow dye, which is characterized in that including group described in claim 1-4 any claim
Close object and auxiliary material.
6. Environmentally-friecomposite composite disperse yellow dye according to claim 5, which is characterized in that the auxiliary material includes water and helps
Agent.
7. Environmentally-friecomposite composite disperse yellow dye composition as claimed in claim 6, it is characterised in that the auxiliary agent is following
One or more of mixture: naphthalene sulfonic acid-formaldehyde condensation product, alkyl naphthalene sulfonic acid formaldehyde condensation products, lignosulfonates.
8. according to Environmentally-friecomposite composite disperse yellow dye described in claim 6-7, which is characterized in that the auxiliary agent and compound point
Dissipating the ratio between total weight of xanthochromia feed composition is 0.25~2.8:1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910065423.4A CN109651845A (en) | 2019-01-24 | 2019-01-24 | A kind of Environmentally-friecomposite composite disperse yellow dye composition and dyestuff |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910065423.4A CN109651845A (en) | 2019-01-24 | 2019-01-24 | A kind of Environmentally-friecomposite composite disperse yellow dye composition and dyestuff |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109651845A true CN109651845A (en) | 2019-04-19 |
Family
ID=66120997
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910065423.4A Pending CN109651845A (en) | 2019-01-24 | 2019-01-24 | A kind of Environmentally-friecomposite composite disperse yellow dye composition and dyestuff |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109651845A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111500088A (en) * | 2020-04-24 | 2020-08-07 | 王羽蘅 | Disperse yellow dye composition, dye product and application |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006188595A (en) * | 2005-01-06 | 2006-07-20 | Sumitomo Chemical Co Ltd | Disperse dye composition and application to hydrophobic fiber material |
| CN101143973A (en) * | 2007-10-26 | 2008-03-19 | 浙江闰土股份有限公司 | Low-temperature environment-friendly disperse yellow dye composition |
| CN104744968A (en) * | 2015-02-12 | 2015-07-01 | 太湖亚太精化有限公司 | Disperse yellow dye composition, dye product and application thereof |
-
2019
- 2019-01-24 CN CN201910065423.4A patent/CN109651845A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006188595A (en) * | 2005-01-06 | 2006-07-20 | Sumitomo Chemical Co Ltd | Disperse dye composition and application to hydrophobic fiber material |
| CN101143973A (en) * | 2007-10-26 | 2008-03-19 | 浙江闰土股份有限公司 | Low-temperature environment-friendly disperse yellow dye composition |
| CN104744968A (en) * | 2015-02-12 | 2015-07-01 | 太湖亚太精化有限公司 | Disperse yellow dye composition, dye product and application thereof |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111500088A (en) * | 2020-04-24 | 2020-08-07 | 王羽蘅 | Disperse yellow dye composition, dye product and application |
| CN111500088B (en) * | 2020-04-24 | 2021-08-17 | 王羽蘅 | Disperse yellow dye composition, dye product and application |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN100577744C (en) | Black and blue series environment-friendly disperse dye composition | |
| CN102206430B (en) | Environment-friendly type yellow disperse dyestuff composition | |
| CN104088166B (en) | A kind of navy or the application of black disperse dye | |
| CN104087018B (en) | A kind of navy or the preparation method of black disperse dye | |
| CN103589190B (en) | A kind of dispersion red dye composition | |
| CN100374511C (en) | Mixed black and blue series combined disperse dye | |
| CN106833018B (en) | A kind of dispersed black dye mixture and its dye preparations | |
| CN106479221B (en) | It is a kind of dark blue to black disperse dye mixture | |
| CN101629026A (en) | Black-blue disperse dye composition | |
| CN105602284B (en) | A kind of blue disperse dye composition, blue disperse dye and its production and use | |
| CN100393817C (en) | Combined blue disperse dye | |
| CN104650621B (en) | Disperse dye composition, disperse dyes and its production and use | |
| EP3147333B1 (en) | Disperse dye composition, disperse dye and preparation method and use thereof | |
| CN107805409A (en) | A kind of Yellow environment-friendly disperse dye composition | |
| CN105670341B (en) | A kind of blue disperse dye composition, blue disperse dye and its preparation method and application | |
| CN109651845A (en) | A kind of Environmentally-friecomposite composite disperse yellow dye composition and dyestuff | |
| CN110204923B (en) | Disperse grey dye composition, dye product, preparation method and application thereof, and colored product | |
| CN108530947B (en) | Environment-friendly economical disperse red dye mixture | |
| CN107057403A (en) | A kind of golden yellow disperse dye composition, disperse dyes product and its application | |
| CN106700648A (en) | Black disperse dye composition | |
| CN104087011B (en) | Azo disperse dye goods | |
| CN107312358B (en) | A kind of disperse dye composition, preparation method and application | |
| CN107722668B (en) | A kind of azo dye composition and its application | |
| CN109705620A (en) | A kind of alkali resistant yellow disperse dye composition | |
| CN101948633B (en) | Environment-friendly quick dyeing disperse dye composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20190419 |