CN109633734B - Device and method for detecting neutron content in ion implantation cavity - Google Patents
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Abstract
本发明公开了一种检测离子注入腔中中子含量的装置,包括离子注入腔、离子源、数据收集模块和处理模块,所述离子注入腔中放置表面涂有光刻胶的衬底,所述离子源对所述衬底中的光刻胶进行离子注入,离子注入过程中产生的中子与光刻胶中C、H、O元素的原子核相互作用,产生γ射线,所述数据收集模块用于测量所述离子注入腔中γ射线的强度,并将该强度传输至所述处理模块,所述处理模块根据γ射线的强度计算出离子注入过程中产生的中子含量。本发明提供的一种检测离子注入腔中中子含量的装置和方法,通过测量Υ射线的强度,进而可以测量出高能离子注入过程中产生的中子含量。
The invention discloses a device for detecting neutron content in an ion implantation cavity, which comprises an ion injection cavity, an ion source, a data collection module and a processing module. A substrate coated with photoresist is placed in the ion injection cavity, and the ion implantation cavity The source performs ion implantation on the photoresist in the substrate, and the neutrons generated during the ion implantation interact with the atomic nuclei of C, H, and O elements in the photoresist to generate gamma rays. The data collection module is used for The intensity of the gamma rays in the ion implantation chamber is measured, and the intensity is transmitted to the processing module, and the processing module calculates the content of neutrons generated during the ion implantation process according to the intensity of the gamma rays. The present invention provides a device and method for detecting neutron content in an ion implantation chamber. By measuring the intensity of gamma rays, the neutron content generated during high-energy ion implantation can be measured.
Description
技术领域technical field
本发明涉及集成电路工艺设计,具体涉及一种检测离子注入腔中中子含量的装置和方法。The invention relates to integrated circuit process design, in particular to a device and method for detecting neutron content in an ion implantation chamber.
背景技术Background technique
随着半导体技术的不断发展,离子注入技术在集成电路制造中的作用越来越重要。离子注入机是集成电路制造前工序中的关键设备,离子注入是对半导体表面附近区域进行掺杂的技术,其目的是改变半导体的载流子浓度和导电类型,其中高能离子注入机是进行深掺杂的最好方法。高能离子注入机的粒子加速器主要包括射频加速和静电加速,离子在系统中实现加速的同时对外发射对人身和环境产生危害的射线,如射线等。所以日常都要对注入机的χ射线的进行检测,但对于超高能注入机来说,需要产生2价,3价甚至4价的离子,在这过程中在产生χ射线的同时会产生中子,然而中子不带电荷,因此在穿透物体时,与原子的核外电子不发生电子库仑力的作用,从而可轻易地穿过电子层,直接击中原子核而发生核反应,从而制作注入机的一些金属材料如铝,铅很容易就被击穿,从而造成伤害;同时由于中子本身不带电,不会引起电离等作用,不能产生直接的可观察效果,很难用常规的手段来检测。With the continuous development of semiconductor technology, the role of ion implantation technology in the manufacture of integrated circuits is becoming more and more important. Ion implanter is the key equipment in the pre-process of integrated circuit manufacturing. Ion implantation is a technology for doping the area near the semiconductor surface. Its purpose is to change the carrier concentration and conductivity type of the semiconductor. The best way to dope. The particle accelerator of the high-energy ion implanter mainly includes radio frequency acceleration and electrostatic acceleration. The ions are accelerated in the system and at the same time emit radiation that is harmful to the human body and the environment, such as radiation. Therefore, the x-rays of the implanter must be detected daily, but for ultra-high-energy implanters, it is necessary to generate 2-, 3-, and even 4-valent ions. In this process, neutrons will be generated while x-rays are produced. However, neutrons have no charge, so when they penetrate objects, there is no electron Coulomb force with the electrons outside the nucleus of the atom, so they can easily pass through the electron layer and directly hit the nucleus to cause a nuclear reaction, thus making the injection machine Some metal materials such as aluminum and lead are easily broken down, causing damage; at the same time, because the neutron itself is not charged, it will not cause ionization and other effects, and cannot produce direct observable effects, so it is difficult to use conventional means to detect .
因此,必须采取可靠的高能离子注入机中中子的检测方法,防止系统工作时对周围的工作人员造成伤害,对环境形成污染。Therefore, a reliable neutron detection method in the high-energy ion implanter must be adopted to prevent the system from causing harm to the surrounding staff and polluting the environment.
发明内容Contents of the invention
本发明的目的是提供一种检测离子注入腔中中子含量的装置和方法,通过在高能离子轰击光刻胶,其中,中子和光刻胶中C,H,O等元素的原子核相互作用产生大量的Υ射线,通过测量这些Υ射线的强度,进而可以测量出高能离子注入过程中产生的中子含量。The object of the present invention is to provide a device and method for detecting the content of neutrons in the ion implantation chamber, by bombarding the photoresist with high-energy ions, wherein the neutrons interact with the nuclei of C, H, O and other elements in the photoresist A large number of γ-rays are generated, and by measuring the intensity of these γ-rays, the content of neutrons generated during high-energy ion implantation can be measured.
为了实现上述目的,本发明采用如下技术方案:一种检测离子注入腔中中子含量的装置,包括离子注入腔、离子源、数据收集模块和处理模块,所述离子源用于对所述离子注入腔进行离子注入,所述数据收集模块同时连接所述离子注入腔、处理模块和离子源;In order to achieve the above object, the present invention adopts the following technical solution: a device for detecting neutron content in an ion implantation chamber, including an ion implantation chamber, an ion source, a data collection module and a processing module, the ion source is used for The implantation chamber performs ion implantation, and the data collection module is connected to the ion implantation chamber, the processing module and the ion source at the same time;
所述离子注入腔中放置表面涂有光刻胶的衬底,所述离子源发射离子束,对所述衬底中的光刻胶进行离子注入,离子注入过程中产生的中子与光刻胶中C、 H、O元素的原子核相互作用,产生Υ射线,所述数据收集模块用于测量所述离子注入腔中Υ射线的强度,并将Υ射线的强度传输至所述处理模块,所述处理模块根据Υ射线的强度计算出离子注入过程中产生的中子含量。A substrate coated with photoresist is placed in the ion implantation chamber, and the ion source emits an ion beam to perform ion implantation on the photoresist in the substrate. The neutrons generated in the ion implantation process are mixed with the photoresist The nuclei of C, H, and O elements interact to generate γ-rays, and the data collection module is used to measure the intensity of γ-rays in the ion implantation cavity, and transmit the intensity of γ-rays to the processing module, and the processing The module calculates the neutron content produced in the ion implantation process according to the intensity of the γ-ray.
进一步地,所述光刻胶的厚度为6-10微米。Further, the thickness of the photoresist is 6-10 microns.
进一步地,所述离子源对光刻胶进行离子注入时所采用的离子束的能量大于3MeV。Further, when the ion source performs ion implantation on the photoresist, the energy of the ion beam used is greater than 3 MeV.
本发明提供的一种检测离子注入腔中中子含量的方法,包括如下步骤:A method for detecting neutron content in an ion implantation cavity provided by the present invention comprises the following steps:
S01:在衬底上涂一层光刻胶,并将该衬底放入离子注入腔中;S01: coating a layer of photoresist on the substrate, and putting the substrate into the ion implantation chamber;
S02:利用离子源对所述离子注入腔中衬底表面的光刻胶进行离子注入,离子注入过程中产生的中子与光刻胶中C、H、O元素的原子核相互作用,产生Υ射线;S02: Using an ion source to perform ion implantation on the photoresist on the substrate surface in the ion implantation chamber, the neutrons generated during the ion implantation process interact with the nuclei of C, H, and O elements in the photoresist to generate γ-rays ;
S03:利用数据收集模块测量所述离子注入腔中Υ射线的强度,并将该强度传输至处理模块;S03: Use the data collection module to measure the intensity of the γ-ray in the ion implantation chamber, and transmit the intensity to the processing module;
S04:所述处理模块根据上述Υ射线的强度计算出离子注入过程中产生的中子含量。S04: The processing module calculates the content of neutrons generated during the ion implantation process according to the intensity of the above-mentioned γ-rays.
进一步地,所述Υ射线的强度小于等于0.6uSv/h。Further, the intensity of the gamma rays is less than or equal to 0.6uSv/h.
进一步地,所述步骤S02中离子源对所述离子注入腔中衬底表面的光刻胶进行离子注入时所采用的离子束的能量大于3MeV。Further, in the step S02, the energy of the ion beam used by the ion source to implant the photoresist on the surface of the substrate in the ion implantation chamber is greater than 3 MeV.
进一步地,所述光刻胶的厚度为6-10微米。Further, the thickness of the photoresist is 6-10 microns.
本发明的有益效果为:本发明利用在高能离子注入过程中,大量粒子轰击光刻胶,其中中子对C,H,O等元素的吸收系数大,而质子等粒子不吸收,当中子和C,H,O等元素的原子核相互作用时,会发生非弹性散射,产生大量的Υ射线,这些Υ射线能量高,产生截面较大,易于测量,且强度和C,H,O的含量成正比。通过测量这些Υ射线的强度,进而可以测量出高能离子注入过程中产生的中子含量。本发明解决了其他方法无法测量高能离子注入产生中子的问题,而且这套装置结构简单,测量系统组成仪器简单,成本较低。The beneficial effects of the present invention are: the present invention uses a large number of particles bombarding the photoresist during the high-energy ion implantation process, wherein neutrons have a large absorption coefficient for elements such as C, H, and O, while protons and other particles do not absorb, neutrons and When the nuclei of C, H, O and other elements interact, inelastic scattering will occur and a large number of γ-rays will be generated. These γ-rays have high energy and produce large cross-sections, which are easy to measure, and their intensity is proportional to the content of C, H, and O. Proportional. By measuring the intensity of these γ-rays, the content of neutrons generated during high-energy ion implantation can be measured. The invention solves the problem that other methods cannot measure the neutrons produced by high-energy ion implantation, and the device has simple structure, simple components of the measuring system and low cost.
附图说明Description of drawings
附图1为本发明一种检测离子注入腔中中子含量装置的结构示意图。Accompanying drawing 1 is a schematic structural diagram of a device for detecting neutron content in an ion implantation chamber according to the present invention.
图中:100衬底,102光刻胶,200离子注入腔。In the figure: 100 substrate, 102 photoresist, 200 ion implantation chamber.
具体实施方式Detailed ways
为使本发明的目的、技术方案和优点更加清楚,下面结合附图对本发明的具体实施方式做进一步的详细说明。In order to make the purpose, technical solution and advantages of the present invention clearer, the specific implementation manners of the present invention will be further described in detail below in conjunction with the accompanying drawings.
如附图1所示,本发明提供的一种检测离子注入腔中中子含量的装置,包括离子注入腔200、离子源、数据收集模块和处理模块,离子源用于对离子注入腔 200进行离子注入,数据收集模块同时连接离子注入腔和处理模块。其中,衬底可以为硅衬底,硅衬底上涂覆的光刻胶层的厚度为6-10微米;离子源对光刻胶进行离子注入时所采用的离子束的能量大于3MeV。As shown in Figure 1, a device for detecting neutron content in an ion implantation chamber provided by the present invention includes an
离子注入腔200中放置表面涂有光刻胶101的衬底100,离子源发射离子束,对衬底中的光刻胶101进行离子注入,离子注入过程中产生的中子与光刻胶中C、H、O元素的原子核相互作用,产生Υ射线,数据收集模块用于测量离子注入腔中Υ射线的强度,并将该强度传输至处理模块,处理模块根据Υ射线的强度计算出离子注入过程中产生的中子含量。A
其中,中子对C,H,O等元素的吸收系数大,而质子等粒子不吸收,当中子和C,H,O等元素的原子核相互作用时,会发生非弹性散射,产生大量的Υ射线,这些Υ射线能量高,产生截面较大,易于测量,且强度和C,H,O的含量成正比。本发明中数据收集模块测量到的Υ射线的强度包括Υ射线的强度,由于该强度与C,H,O的含量以及中子的含量均成正比,处理模块可以根据Υ射线的强度计算出离子注入腔中中子的含量。Among them, neutrons have a large absorption coefficient for elements such as C, H, and O, while particles such as protons do not absorb them. When neutrons interact with the nuclei of elements such as C, H, and O, inelastic scattering will occur, resulting in a large amount of γ Rays, these γ-rays have high energy, produce larger cross-sections, are easy to measure, and their intensity is proportional to the content of C, H, and O. The intensity of the gamma-ray measured by the data collection module in the present invention comprises the intensity of the gamma-ray, because this intensity is proportional to C, H, the content of O and the content of neutrons, the processing module can calculate the ion according to the intensity of the gamma-ray The content of neutrons in the injected cavity.
本发明提供的一种检测离子注入腔中中子含量的方法,包括如下步骤:A method for detecting neutron content in an ion implantation cavity provided by the present invention comprises the following steps:
S01:在衬底上涂一层光刻胶,并将该衬底放入离子注入腔中。其中,衬底可以为硅衬底,硅衬底上涂覆的光刻胶层的厚度为6-10微米。S01: Coating a layer of photoresist on the substrate, and putting the substrate into the ion implantation chamber. Wherein, the substrate may be a silicon substrate, and the photoresist layer coated on the silicon substrate has a thickness of 6-10 microns.
S02:利用离子源对离子注入腔中衬底表面的光刻胶进行离子注入,离子注入过程中产生的中子与光刻胶中C、H、O元素的原子核相互作用,产生Υ射线。其中,离子源对光刻胶进行离子注入时所采用的离子束的能量大于3MeV,Υ射线能量高,产生截面较大,易于测量,且强度和C,H,O的含量成正比。S02: Use an ion source to perform ion implantation on the photoresist on the surface of the substrate in the ion implantation chamber. The neutrons generated during the ion implantation interact with the nuclei of C, H, and O elements in the photoresist to generate γ-rays. Among them, the energy of the ion beam used by the ion source for ion implantation of the photoresist is greater than 3MeV, and the energy of the γ-ray is high, resulting in a large cross-section, which is easy to measure, and the intensity is proportional to the content of C, H, and O.
S03:利用数据收集模块测量离子注入腔中Υ射线的强度,并将该强度传输至处理模块。S03: Use the data collection module to measure the intensity of the γ-ray in the ion implantation chamber, and transmit the intensity to the processing module.
本发明中所测量的Υ射线的强度小于等于0.6uSv/h,当Υ射线的强度大于该数值的时候,说明该注入机出现问题,已经不满足SEMI标准,需要检修后再重新检测是否满足使用标准。The intensity of the measured γ-ray in the present invention is less than or equal to 0.6uSv/h, when the intensity of the γ-ray is greater than this value, it indicates that the injection machine has a problem, and the SEMI standard has not been met, and it needs to be overhauled and then re-examined to see if it can be used standard.
具体地,在离子注入过程中,提前确定一个设定阈值,当数据收集模块测量到的Υ射线的强度大于等于设定阈值时,离子源停止离子注入,设定阈值的范围为0.4-0.6uSv/h。当测量到的Υ射线的强度大于等于设定阈值时,收据收集模块发出报警信号或者停止信号,使得离子源停止注入工作。Specifically, in the ion implantation process, a set threshold is determined in advance, and when the intensity of the gamma rays measured by the data collection module is greater than or equal to the set threshold, the ion source stops ion implantation, and the range of the set threshold is 0.4-0.6uSv /h. When the intensity of the measured γ-ray is greater than or equal to the set threshold, the receipt collection module sends an alarm signal or a stop signal, so that the ion source stops the implantation work.
S04:处理模块根据上述Υ射线的强度计算出离子注入过程中产生的中子含量。其中,由于Υ射线的强度与C,H,O的含量以及中子的含量均成正比,处理模块可以根据Υ射线的强度计算出离子注入腔中中子的含量。S04: The processing module calculates the content of neutrons generated during the ion implantation process according to the intensity of the above-mentioned γ-rays. Wherein, since the intensity of the γ-ray is proportional to the content of C, H, O and the content of the neutron, the processing module can calculate the content of the neutron in the ion implantation cavity according to the intensity of the γ-ray.
本发明利用在高能离子注入过程中,大量粒子轰击光刻胶,其中中子对C, H,O等元素的吸收系数大,而质子等粒子不吸收,当中子和C,H,O等元素的原子核相互作用时,会发生非弹性散射,产生大量的Υ射线,这些Υ射线能量高,产生截面较大,易于测量,且强度和C,H,O的含量成正比。通过测量这些Υ射线的强度,进而可以测量出高能离子注入过程中产生的中子含量。本发明解决了其他方法无法测量高能离子注入产生中子的问题,而且这套装置结构简单,测量系统组成仪器简单,成本较低。The present invention utilizes that during the high-energy ion implantation process, a large number of particles bombard the photoresist, wherein neutrons have a large absorption coefficient for elements such as C, H, and O, while particles such as protons do not absorb, neutrons and elements such as C, H, and O When the atomic nuclei interact with each other, inelastic scattering will occur, and a large number of γ-rays will be generated. These γ-rays have high energy, large cross-section, easy to measure, and the intensity is proportional to the content of C, H, and O. By measuring the intensity of these γ-rays, the content of neutrons generated during high-energy ion implantation can be measured. The invention solves the problem that other methods cannot measure the neutrons produced by high-energy ion implantation, and the device has simple structure, simple components of the measuring system and low cost.
以上所述仅为本发明的优选实施例,所述实施例并非用于限制本发明的专利保护范围,因此凡是运用本发明的说明书及附图内容所作的等同结构变化,同理均应包含在本发明所附权利要求的保护范围内。The above are only preferred embodiments of the present invention, and the embodiments are not intended to limit the scope of patent protection of the present invention, so all equivalent structural changes made by using the description and drawings of the present invention should be included in the same reason Within the protection scope of the appended claims of the present invention.
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GB201003674D0 (en) * | 2009-10-26 | 2010-04-21 | Finphys Oy | Neutron detector with neutron converter, method for manufacturing the neutron detector and neutron imaging apparatus |
CN102162857A (en) * | 2011-01-11 | 2011-08-24 | 长沙开元仪器股份有限公司 | Method and system for detecting neutron yield |
JP2011196739A (en) * | 2010-03-18 | 2011-10-06 | Hitachi Aloka Medical Ltd | Radiation measuring device |
CN102386121A (en) * | 2010-09-01 | 2012-03-21 | 无锡华润上华半导体有限公司 | Manufacturing method of semiconductor device and semiconductor buried layer |
CN106898546A (en) * | 2017-03-13 | 2017-06-27 | 上海华力微电子有限公司 | A kind of method of monitoring Ge ion implanting quality |
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CN107247286B (en) * | 2017-05-16 | 2019-06-07 | 北京大学 | A kind of fast neutron spectrum measuring system and method |
JP6785189B2 (en) * | 2017-05-31 | 2020-11-18 | 住友重機械イオンテクノロジー株式会社 | Ion implantation device and ion implantation method |
CN107884809B (en) * | 2017-11-10 | 2020-09-15 | 中国科学院高能物理研究所 | Neutron detector and neutron detection method |
CN109633734B (en) * | 2018-12-24 | 2023-01-31 | 上海集成电路研发中心有限公司 | Device and method for detecting neutron content in ion implantation cavity |
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GB201003674D0 (en) * | 2009-10-26 | 2010-04-21 | Finphys Oy | Neutron detector with neutron converter, method for manufacturing the neutron detector and neutron imaging apparatus |
JP2011196739A (en) * | 2010-03-18 | 2011-10-06 | Hitachi Aloka Medical Ltd | Radiation measuring device |
CN102386121A (en) * | 2010-09-01 | 2012-03-21 | 无锡华润上华半导体有限公司 | Manufacturing method of semiconductor device and semiconductor buried layer |
CN102162857A (en) * | 2011-01-11 | 2011-08-24 | 长沙开元仪器股份有限公司 | Method and system for detecting neutron yield |
CN106898546A (en) * | 2017-03-13 | 2017-06-27 | 上海华力微电子有限公司 | A kind of method of monitoring Ge ion implanting quality |
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