CN109629244A - A kind of coating material of PVC Antistatic Fabric - Google Patents
A kind of coating material of PVC Antistatic Fabric Download PDFInfo
- Publication number
- CN109629244A CN109629244A CN201811544344.3A CN201811544344A CN109629244A CN 109629244 A CN109629244 A CN 109629244A CN 201811544344 A CN201811544344 A CN 201811544344A CN 109629244 A CN109629244 A CN 109629244A
- Authority
- CN
- China
- Prior art keywords
- parts
- pvc
- agent
- coating material
- antistatic
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/06—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyvinylchloride or its copolymerisation products
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0056—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the compounding ingredients of the macro-molecular coating
- D06N3/0059—Organic ingredients with special effects, e.g. oil- or water-repellent, antimicrobial, flame-resistant, magnetic, bactericidal, odour-influencing agents; perfumes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/04—Properties of the materials having electrical or magnetic properties
- D06N2209/046—Anti-static
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/10—Properties of the materials having mechanical properties
- D06N2209/103—Resistant to mechanical forces, e.g. shock, impact, puncture, flexion, shear, compression, tear
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Paints Or Removers (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention provides a kind of coating materials of PVC Antistatic Fabric, raw material composition including following parts by weight: 30-40 parts of PVC paste resin, 40-60 parts of PVC blending resin, 0.1-1.0 parts of composite antistatic agent, 1-3 parts of compound base amount method agent, 1-5 parts of filler, 60-70 parts of plasticizer, 0.1-1.5 parts of fire retardant, 3-5 parts of heat stabilizer, 0.1-0.5 parts of coupling agent, the present invention operates that simpler, finished product antistatic effect is more preferable by the way that antistatic agent is added in PVC formula, and the product surface resistance Rs of preparation can achieve 107‑109；And the product tensile strength and elongation at break, sheet resistance of preparation all have excellent performance.
Description
Technical field
The present invention relates to PVC Antistatic Fabric field, in particular to a kind of coating material of PVC Antistatic Fabric.
Background technique
PVC polyester fiber clamp wire side material has been widely used in all trades and professions at present, and some purposes have antistatic to fabric
It is required that such as ventilation duct, shield and rolling screen door.It either squeezes out, roll, fitting or coating process, traditional PVC resist quiet
Electric fabric plus material producing method is all that directly antistatic agent is added in PVC formula.There are two drawbacks for this method: being on the one hand
The bad control of production process, and surface often has the exception such as pin hole, bubble.Another aspect antistatic agent PVC material in not
Good dispersion, influences whole antistatic effect.
Summary of the invention
In order to solve above-mentioned insufficient defect, the present invention provides a kind of coating material of PVC Antistatic Fabric, the present invention is logical
It crosses antistatic agent to be added in PVC formula and operates that simpler, finished product antistatic effect is more preferable, the product surface resistance Rs of preparation can
To reach 107-109；And the product tensile strength and elongation at break, sheet resistance of preparation all have excellent performance.
The present invention provides a kind of coating materials of PVC Antistatic Fabric, the raw material composition including following parts by weight: PVC paste
30-40 parts of resin, 40-60 parts of PVC blending resin, 0.1-1.0 parts of composite antistatic agent, 1-3 parts of compound base amount method agent, filling
1-5 parts of agent, 60-70 parts of plasticizer, 0.1-1.5 parts of fire retardant, 3-5 parts of heat stabilizer, 0.1-0.5 parts of coupling agent.
The coating material of above-mentioned a kind of PVC Antistatic Fabric, wherein the composite antistatic agent is alkylphenol polyoxy second
Alkene ether sulfuric ester and polyester polyether, wherein alkylphenol polyoxyethylene ether sulfate and polyester polyether are in composite antistatic agent
In weight ratio be 1:1.
A kind of coating material of above-mentioned PVC Antistatic Fabric, wherein the compound base amount method agent be Kynoar and
The mixture of poly-methyl methacrylate base.
The coating material of above-mentioned a kind of PVC Antistatic Fabric, wherein the Kynoar and poly-methyl methacrylate base
Weight ratio in compound base amount method agent is 1:2.
A kind of coating material of above-mentioned PVC Antistatic Fabric, wherein the filler be calcium carbonate and magnesium carbonate, wherein
Calcium carbonate and magnesium carbonate are modified by silane coupling agent and the mesh number of calcium carbonate is 800-1250 mesh, the mesh of magnesium carbonate
Number is 500-800 mesh.
The coating material of above-mentioned a kind of PVC Antistatic Fabric, wherein the coupling agent is the coupling agent of isobutyl functionality
With the compound composition of isobutyl ethyl triethoxy silicane.
A kind of coating material of above-mentioned PVC Antistatic Fabric, wherein the raw material composition including following parts by weight: PVC paste tree
30 parts of rouge, 50 parts of PVC blending resin, 0.2 part of alkylphenol polyoxyethylene ether sulfate, 0.2 part of polyester polyether, polyvinylidene fluoride
0.5 part of alkene, 1.0 parts of plasticizer, 0.5 part of fire retardant, 2 parts of calcium carbonate, 3 parts of magnesium carbonate, increases 1.0 parts of poly-methyl methacrylate base
Mould 65 parts of agent, 0.5 part of fire retardant, 3 parts of heat stabilizer, 0.3 part of coupling agent.
The invention has the following advantages: the 1, present invention by antistatic agent is added in PVC formula operate it is simpler,
Finished product antistatic effect is more preferable, and the product surface resistance Rs of preparation can achieve 107-109；And the product tensile strength of preparation
All there is excellent performance with elongation at break, sheet resistance.
Specific embodiment
In the following description, a large amount of concrete details are given so as to provide a more thorough understanding of the present invention.So
And it is obvious to the skilled person that the present invention may not need one or more of these details and be able to
Implement.In other examples, in order to avoid confusion with the present invention, for some technical characteristics well known in the art not into
Row description.
In order to thoroughly understand the present invention, detailed step and detailed structure will be proposed in following description, so as to
Illustrate technical solution of the present invention.Presently preferred embodiments of the present invention is described in detail as follows, however other than these detailed descriptions, this
Invention can also have other embodiments.
The present invention provides a kind of coating materials of PVC Antistatic Fabric, the raw material composition including following parts by weight: PVC paste
30-40 parts of resin, 40-60 parts of PVC blending resin, 0.1-1.0 parts of composite antistatic agent, 1-3 parts of compound base amount method agent, filling
1-5 parts of agent, 60-70 parts of plasticizer, 0.1-1.5 parts of fire retardant, 3-5 parts of heat stabilizer, 0.1-0.5 parts of coupling agent.
In a preferred but unrestricted embodiment of the invention, composite antistatic agent is polyoxyethylene alkylphenol ether sulfuric acid
Ester and polyester polyether, the wherein weight of alkylphenol polyoxyethylene ether sulfate and polyester polyether in composite antistatic agent
Than for 1:1, operate that simpler, finished product antistatic effect is more preferable, the product table of preparation by the way that antistatic agent is added in PVC formula
Surface resistance Rs can achieve 107-109。
In a preferred but unrestricted embodiment of the invention, compound base amount method agent is Kynoar and poly- methyl-prop
The mixture of olefin(e) acid methyl.
In a preferred but unrestricted embodiment of the invention, Kynoar and poly-methyl methacrylate base are in composite table
Weight ratio in surface treatment agent is 1:2.
In an of the invention preferred but unrestricted embodiment, filler is calcium carbonate and magnesium carbonate, wherein calcium carbonate and
Magnesium carbonate is modified by silane coupling agent and the mesh number of calcium carbonate is 800-1250 mesh, and the mesh number of magnesium carbonate is 500-
800 mesh.
In a preferred but unrestricted embodiment of the invention, coupling agent is the coupling agent and isobutyl group of isobutyl functionality
The compound composition of triethoxysilicane can improve dispersibility and bonding force of the filler in resin, and improve inorganic filler and tree
Compatibility between rouge, and after cooperating suitable filler material, may be implemented that product draws high intensity and extension at break is forthright
The promotion of energy.
In a preferred but unrestricted embodiment of the invention, a kind of coating material of PVC Antistatic Fabric, including it is following heavy
Measure the raw material composition of part: 30 parts of PVC paste resin, 0.2 part of alkylphenol polyoxyethylene ether sulfate, gathers 50 parts of PVC blending resin
0.2 part of ester polyether class, 0.5 part of Kynoar, 1.0 parts of poly-methyl methacrylate base, 1.0 parts of plasticizer, 0.5 part of fire retardant,
2 parts of calcium carbonate, 3 parts of magnesium carbonate, 65 parts of plasticizer, 0.5 part of fire retardant, 3 parts of heat stabilizer, 0.3 part of coupling agent.
A specific embodiment presented below
Embodiment 1
A kind of coating material of PVC Antistatic Fabric, the raw material composition including following parts by weight: 30 parts of PVC paste resin, PVC
50 parts of blending resin, 0.2 part of polyester polyether, 0.5 part of Kynoar, gathers at 0.2 part of alkylphenol polyoxyethylene ether sulfate
1.0 parts of methacrylic acid methyl, 1.0 parts of plasticizer, 0.5 part of fire retardant, 2 parts of calcium carbonate, 3 parts of magnesium carbonate, 65 parts of plasticizer, resistance
Fire 0.5 part of agent, 3 parts of heat stabilizer, 0.3 part of coupling agent.
Embodiment 2
A kind of coating material of PVC Antistatic Fabric, the raw material composition including following parts by weight: 30 parts of PVC paste resin, PVC
50 parts of blending resin, 0.2 part of polyester polyether, 0.5 part of Kynoar, gathers at 0.2 part of alkylphenol polyoxyethylene ether sulfate
1.0 parts of methacrylic acid methyl, 1.0 parts of plasticizer, 0.5 part of fire retardant, 2 parts of calcium carbonate, 3 parts of magnesium carbonate, 65 parts of plasticizer, resistance
Fire 0.5 part of agent, 3 parts of heat stabilizer.
Embodiment 3
A kind of coating material of PVC Antistatic Fabric, the raw material composition including following parts by weight: 30 parts of PVC paste resin, PVC
50 parts of blending resin, 0.2 part of polyester polyether, 0.5 part of Kynoar, gathers at 0.2 part of alkylphenol polyoxyethylene ether sulfate
1.0 parts of methacrylic acid methyl, 1.0 parts of plasticizer, 0.5 part of fire retardant, 5 parts of calcium carbonate, 65 parts of plasticizer, 0.5 part of fire retardant,
3 parts of heat stabilizer, 0.3 part of coupling agent.
Embodiment 4
A kind of coating material of PVC Antistatic Fabric, the raw material composition including following parts by weight: 30 parts of PVC paste resin, PVC
50 parts of blending resin, 0.4 part of alkylphenol polyoxyethylene ether sulfate, 0.5 part of Kynoar, poly-methyl methacrylate base
1.0 parts, 1.0 parts of plasticizer, 0.5 part of fire retardant, 2 parts of calcium carbonate, 3 parts of magnesium carbonate, 65 parts of plasticizer, 0.5 part of fire retardant, heat it is steady
Determine 3 parts of agent, 0.3 part of coupling agent.
Embodiment 5
A kind of coating material of PVC Antistatic Fabric, the raw material composition including following parts by weight: 30 parts of PVC paste resin, PVC
50 parts of blending resin, 0.2 part of polyester polyether, 1.5 parts of Kynoar, increases 0.2 part of alkylphenol polyoxyethylene ether sulfate
Mould 65 parts of agent, 0.5 part of fire retardant, 2 parts of calcium carbonate, 3 parts of magnesium carbonate, 1.0 parts of plasticizer, 0.5 part of fire retardant, 3 parts of heat stabilizer,
0.3 part of coupling agent.
The following are the performance data for preparing product of 1- of embodiment of the present invention embodiment 5, table 1 as shown in table 1
Referring to shown in table 1, embodiment 1 is highly preferred embodiment of the present invention, can make the product surface resistance Rs of preparation can
To reach 107-109；And the product tensile strength and elongation at break, sheet resistance of preparation all have excellent performance.
Presently preferred embodiments of the present invention is described above.It is to be appreciated that the invention is not limited to above-mentioned
Particular implementation, devices and structures not described in detail herein should be understood as gives reality with the common mode in this field
It applies；Anyone skilled in the art, without departing from the scope of the technical proposal of the invention, all using the disclosure above
Methods and technical content many possible changes and modifications are made to technical solution of the present invention, or be revised as equivalent variations etc.
Embodiment is imitated, this is not affected the essence of the present invention.Therefore, anything that does not depart from the technical scheme of the invention, foundation
Technical spirit of the invention any simple modifications, equivalents, and modifications made to the above embodiment, still fall within the present invention
In the range of technical solution protection.
Claims (7)
1. a kind of coating material of PVC Antistatic Fabric, which is characterized in that the raw material composition including following parts by weight: PVC paste resin
30-40 parts, 40-60 parts of PVC blending resin, 0.1-1.0 parts of composite antistatic agent, 1-3 parts of compound base amount method agent, filler 1-
5 parts, 60-70 parts of plasticizer, 0.1-1.5 parts of fire retardant, 3-5 parts of heat stabilizer, 0.1-0.5 parts of coupling agent.
2. a kind of coating material of PVC Antistatic Fabric as described in claim 1, which is characterized in that the composite antistatic agent
For alkylphenol polyoxyethylene ether sulfate and polyester polyether, wherein alkylphenol polyoxyethylene ether sulfate and polyester polyethers
Weight ratio of the class in composite antistatic agent is 1:1.
3. a kind of coating material of PVC Antistatic Fabric as claimed in claim 2, which is characterized in that the compound base amount method
Agent is the mixture of Kynoar and poly-methyl methacrylate base.
4. a kind of coating material of PVC Antistatic Fabric as claimed in claim 3, which is characterized in that the Kynoar and
Weight ratio of the poly-methyl methacrylate base in compound base amount method agent is 1:2.
5. a kind of coating material of PVC Antistatic Fabric as claimed in claim 4, which is characterized in that the filler is carbonic acid
Calcium and magnesium carbonate, wherein calcium carbonate and magnesium carbonate are modified by silane coupling agent and the mesh number of calcium carbonate is 800-
1250 mesh, the mesh number of magnesium carbonate are 500-800 mesh.
6. a kind of coating material of PVC Antistatic Fabric as claimed in claim 5, which is characterized in that the coupling agent is isobutyl
The coupling agent of base functional group and the compound composition of isobutyl ethyl triethoxy silicane.
7. a kind of coating material of PVC Antistatic Fabric as claimed in claim 6, which is characterized in that including following parts by weight
Raw material composition: 30 parts of PVC paste resin, 50 parts of PVC blending resin, 0.2 part of alkylphenol polyoxyethylene ether sulfate, polyester polyethers
0.2 part of class, 0.5 part of Kynoar, 1.0 parts of poly-methyl methacrylate base, 1.0 parts of plasticizer, 0.5 part of fire retardant, calcium carbonate 2
Part, 3 parts of magnesium carbonate, 65 parts of plasticizer, 0.5 part of fire retardant, 3 parts of heat stabilizer, 0.3 part of coupling agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811544344.3A CN109629244A (en) | 2018-12-17 | 2018-12-17 | A kind of coating material of PVC Antistatic Fabric |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811544344.3A CN109629244A (en) | 2018-12-17 | 2018-12-17 | A kind of coating material of PVC Antistatic Fabric |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109629244A true CN109629244A (en) | 2019-04-16 |
Family
ID=66074788
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811544344.3A Pending CN109629244A (en) | 2018-12-17 | 2018-12-17 | A kind of coating material of PVC Antistatic Fabric |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109629244A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116377732A (en) * | 2023-03-14 | 2023-07-04 | 思嘉环保材料科技（上海）有限公司 | Antistatic coating material and PVC clip net |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101757774A (en) * | 2009-12-30 | 2010-06-30 | 上海永利带业股份有限公司 | Ultra-silent treadmill belt and manufacture method thereof |
| CN102926199A (en) * | 2012-11-28 | 2013-02-13 | 福建思嘉环保材料科技有限公司 | PVC (polyvinyl chloride) coated fabric paste and preparation method thereof |
| CN104258535A (en) * | 2014-10-14 | 2015-01-07 | 上海永利带业股份有限公司 | Anti-static fabric and manufacturing method of anti-static treadmill belt |
| CN105064024A (en) * | 2015-08-17 | 2015-11-18 | 海宁经达布业有限公司 | High-modulus flame-retardant antistatic safe protection belt and preparation method thereof |
| CN106012578A (en) * | 2016-06-27 | 2016-10-12 | 江阴龙盛塑胶有限公司 | Antistatic environmental protection artificial leather |
-
2018
- 2018-12-17 CN CN201811544344.3A patent/CN109629244A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101757774A (en) * | 2009-12-30 | 2010-06-30 | 上海永利带业股份有限公司 | Ultra-silent treadmill belt and manufacture method thereof |
| CN102926199A (en) * | 2012-11-28 | 2013-02-13 | 福建思嘉环保材料科技有限公司 | PVC (polyvinyl chloride) coated fabric paste and preparation method thereof |
| CN104258535A (en) * | 2014-10-14 | 2015-01-07 | 上海永利带业股份有限公司 | Anti-static fabric and manufacturing method of anti-static treadmill belt |
| CN105064024A (en) * | 2015-08-17 | 2015-11-18 | 海宁经达布业有限公司 | High-modulus flame-retardant antistatic safe protection belt and preparation method thereof |
| CN106012578A (en) * | 2016-06-27 | 2016-10-12 | 江阴龙盛塑胶有限公司 | Antistatic environmental protection artificial leather |
Non-Patent Citations (3)
| Title |
|---|
| 白晓艳: "《PVC木塑复合材料》", 30 April 2014 * |
| 邓舜扬: "《纺织化学品》", 31 August 2001 * |
| 邢凤兰: "《印染助剂》", 31 August 2002 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116377732A (en) * | 2023-03-14 | 2023-07-04 | 思嘉环保材料科技（上海）有限公司 | Antistatic coating material and PVC clip net |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN104073107B (en) | A kind of texture paint | |
| CN102206395B (en) | Preparation method and application of nano-montmorillonite/polyacrylate composite material | |
| CN103524653B (en) | The preparation of polymeric hollow microsphere | |
| CN104073047B (en) | A kind of exterior wall putty | |
| CN104672702B (en) | PVC (Polyvinyl Chloride) paste for PVC suede wallpaper and preparation method thereof | |
| CN104446271A (en) | Efforescence resistant colored wall finishing mortar | |
| CN105178138A (en) | Semi-gloss artificial grass and preparation method thereof | |
| CN108004798B (en) | Preparation method of coating wall cloth | |
| CN109972401B (en) | Preparation method of super-amphiphobic flame-retardant high-conductivity fabric | |
| CN103224648B (en) | Surface modified nano calcium carbonate and preparation method thereof | |
| CN103602194A (en) | Acrylate waterproof coating material | |
| CN109629244A (en) | A kind of coating material of PVC Antistatic Fabric | |
| CN103937335B (en) | A kind of water base damping pulp and preparation method thereof | |
| CN115108775B (en) | High-strength concrete and preparation method thereof | |
| CN103408949B (en) | Ultrahigh hardness rubber unvulcanizate and preparation method thereof | |
| CN102911469B (en) | Acid and alkali resistant peel-resistant mobile electric power cable material and preparation method thereof | |
| CN107814848B (en) | Microcrystalline cellulose, microcrystalline cellulose trielement composite material and preparation method thereof | |
| CN104530656A (en) | Antistatic PBT material and preparation method thereof | |
| CN109610185A (en) | A kind of preparation method of PVC fabric | |
| CN108912527A (en) | A kind of polyvinyl chloride antibiosis layered board material | |
| CN114702769B (en) | Reinforced flame-retardant microcapsule composite material and preparation method thereof | |
| CN108219404A (en) | A kind of preparation method of the 3D printing material of nano micro crystal cellulose enhancing | |
| CN106832085A (en) | A kind of high temperature resistant, high rigidity acrylate and vinyl acetate emulsion of color inhibition and preparation method thereof | |
| CN108276624A (en) | A kind of preparation that graphene adulterates anti-impact modifier and the application in PVC matrix | |
| CN107903612A (en) | A kind of antifatigue environment-friendly materials and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190416 |