CN109629039A - A kind of manufacturing method of coloured anti-bacterial zein fiber long filament - Google Patents
A kind of manufacturing method of coloured anti-bacterial zein fiber long filament Download PDFInfo
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- CN109629039A CN109629039A CN201811576776.2A CN201811576776A CN109629039A CN 109629039 A CN109629039 A CN 109629039A CN 201811576776 A CN201811576776 A CN 201811576776A CN 109629039 A CN109629039 A CN 109629039A
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- CN
- China
- Prior art keywords
- zein fiber
- long filament
- bacterial
- polylactic acid
- heat radiation
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- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F6/00—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
- D01F6/88—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
- D01F6/92—Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/07—Addition of substances to the spinning solution or to the melt for making fire- or flame-proof filaments
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
- D01F1/103—Agents inhibiting growth of microorganisms
Abstract
The present invention relates to the technical field of synthetic textile fibre, specifically a kind of manufacturing method of coloured anti-bacterial zein fiber long filament.Drying, spinning plus three steps of bullet including particle, wherein adding play step by the preorientation fibre bundle that spinning process obtains pass sequentially through high temperature heat radiation pipeline, scroll tube, formed pipe low-temperature heat radiation be formed pipeline, obtain can weaving coloured anti-bacterial zein fiber long filament.The zein fiber long filament elastic force of production method production is big, it is beautiful in colour it is colour-fast, with soft feel, good comfort and crease recovery.It is provided simultaneously with advantage of both natural fiber and chemical fibre.It is degradable, non-environmental-pollution problem;Elasticity is good, and not vulnerable to the influence of ultraviolet light;Anti pilling, easy dyeing, anti-flammability good hydrophilic property;Raw material comes from plant, the renewable circulation of resource.
Description
Technical field
The present invention relates to the technical field of synthetic textile fibre, specifically a kind of system of coloured anti-bacterial zein fiber long filament
Make method.
Background technique
Polylactic acid is also referred to as polylactide, belongs to polyester family.Polylactic acid is obtained with the main polymerizable raw material of lactic acid
Polymer, raw material sources are abundant and can regenerate.The production process of polylactic acid is pollution-free, and product can be biodegradable,
It realizes circulation in nature, therefore is ideal Green Polymer Material.Acid fiber by polylactic is as a kind of fibre that comparison is new
Type is tieed up, there are many product advantage, but fail largely to apply always, and main cause is to produce and still having much using upper
Problem to be solved.Such as the elastic force problem of fabric.Zein fiber is also known as acid fiber by polylactic (PLA), is with corn, wheat etc.
Starch is raw material, fermented to be converted to that lactic acid is aggregated again to be spinned, and belongs to very environmentally friendly biodegradable fiber, by
In zein fiber fusing point at 165 ~ 170 DEG C, far below the fusing point of fusing point (252 DEG C or so) and nylon fibre of polyester fiber
(220 DEG C or so), production and the melting completely if more than 170 DEG C zein fibers in use process, but fabric will have biggish bullet
Power must use spandex, and the setting temperature of spandex just can ensure that the dimensional stability of finished textile product at 170 DEG C or more.Corn is fine
The low melting point of dimension causes to be difficult to produce all preferable zein fiber elastic fabric of elastic force and dimensional stability at present;In addition at present
The anti-fluffing and anti-pilling performance of zein fiber fabric is mostly poor, and generally only 2.5 ~ 3 grades, this is the inadequate natural endowment of zein fiber
It causes, still fails to reach 3 grades or more of pilling resistance index so far, but for consumers, product is just using with regard to rising
Hair pilling, this is the hard defects of product;And the color of zein fiber fabric is also not gorgeous enough, dyeing in production process
Compare difficult grasp.These problems always affect the fast development of zein fiber industry.
Summary of the invention
That the object of the present invention is to provide a kind of elastic force is big, beautiful in colour, with soft feel, good comfort and folding
The manufacturing method of the coloured anti-bacterial deodorization zein fiber long filament of wrinkle recovery.
In order to achieve the above objectives, the present invention adopts the following technical scheme that:
A kind of manufacturing method of coloured anti-bacterial zein fiber long filament of the present invention, using following steps:
A) the drying of particle is put particles of polylactic acid, antibacterial matrices and Masterbatch into sufficiently dry in drying machine respectively;Wherein
Particles of polylactic acid is dry using drum dryer;Antibacterial matrices and Masterbatch are put hot air type baking oven into and are dried;Contained
Water is lower than the dry particle of 30ppm.
B) spinning, by after above-mentioned drying Masterbatch and antibacterial matrices respectively with the ratio of 1%-5% extruder type spinning machine spiral shell
Melt spinning is carried out in particles of polylactic acid after being mixed into drying before bar, between 200-220 degrees Celsius, spinning specification is temperature
75D-300D, spinneret hole count are -288 hole of 36 hole, obtain preorientation fibre bundle.
C) add bullet, it is 105-115 that above-mentioned preorientation fibre bundle, which is passed through temperature with 400-500 meters of speed per minute,
Degree Celsius high temperature heat radiation pipeline center, the length of high temperature heat radiation pipeline bringing-up section is 1.5-2 meter, utilizes high warm spoke
The different rotating speeds for penetrating the conducting wire roller of pipeline rear and front end guidance preorientation fibre bundle draw the preorientation fibre bundle of heating
It is 1.5-1.6 times long;It handled after fibre bundle cooling after elongation by scroll tube, assign its certain bulkiness and elasticity, obtained
To elastomeric fiber strands;The subsequent elastomeric fiber strands are imported into and by the centers of formed pipe, by being mounted on formed pipe side wall
On air current spray nozzle under certain air pressure to elastomeric fiber strands injection pulse air-flow, interval setting is formed on tow
Fluffy section and close section, last elastomeric fiber strands are imported into and pass through temperature as 100-110 degrees Celsius of low-temperature heat radiation
Be formed the center of pipeline, give the certain contraction of tow and internal stresses release, make tow have certain dimensional stability and by
Thermal stability, obtain can weaving coloured anti-bacterial zein fiber long filament.
Above-mentioned particles of polylactic acid is corn plant base polylactic acid particle, the antibacterial matrices be nano silver, nano zine oxide,
The particle of the mixture of one of nano cupric oxide, nano-titanium dioxide or several substances.
After adopting the above technical scheme, the production method production zein fiber long filament elastic force it is big, it is beautiful in colour it is colour-fast,
With soft feel, good comfort and crease recovery.It is provided simultaneously with excellent of both natural fiber and chemical fibre
Point.It is degradable, non-environmental-pollution problem;Elasticity is good, and not vulnerable to the influence of ultraviolet light;Anti pilling, easy dyeing, anti-flammability are hydrophilic
Property is good;Raw material comes from plant, the renewable circulation of resource.
Detailed description of the invention
Fig. 1 is the present invention plus the process flow chart for playing step.
Specific embodiment
Embodiment 1
A kind of manufacturing method of coloured anti-bacterial zein fiber long filament of the present invention, using following steps:
A) the drying of particle is put particles of polylactic acid, antibacterial matrices and Masterbatch into sufficiently dry in drying machine respectively, wherein
The particles of polylactic acid is corn plant base polylactic acid particle, and the antibacterial matrices are nano silvers, nano zine oxide, nano oxidized
The particle of the mixture of one of copper, nano-titanium dioxide or several substances.Particles of polylactic acid uses drum dryer
Dry, 120 degrees Celsius of temperature, pressure is lower than 50 pas, and the time 20 hours;Antibacterial matrices and Masterbatch put into hot air type baking oven into
Row drying, 120 degree of temperature, the time 6 hours;Obtain the dry particle that water content is lower than 30PPm.The running parameter of above-mentioned drying machine
It can according to need and do adjustment appropriate, to meet the requirement that the dry particle water content after drying is lower than 30ppm.In equipment item
In the case that part allows, dry particle water content is as low as possible, and preferred water content range is 20-30ppm.
B) spinning, by after above-mentioned drying Masterbatch and antibacterial matrices respectively with 1% ratio before the screw rod of extruder type spinning machine
Melt spinning is carried out in particles of polylactic acid after being mixed into drying, for temperature between 200-220 degrees Celsius, spinning specification is 75D-
300D, spinneret hole count are -288 hole of 36 hole, obtain preorientation fibre bundle 9.
C) add bullet, as shown in Figure 1, above-mentioned preorientation fibre bundle 9 is passed through temperature with 400-500 meters of speed per minute
For the center of 105-115 degrees Celsius of high temperature heat radiation pipeline 1, the length of 1 bringing-up section of high temperature heat radiation pipeline is 1.5-2 meters,
The heating of preorientation fibre bundle is allowed in stretchable molten by the temperature of 1 tube wall of high temperature heat radiation pipeline by heat radiation
State, while will using the different rotating speeds of the conducting wire roller 2,3 of high temperature heat radiation pipeline rear and front end guidance preorientation fibre bundle
The preorientation fibre bundle of heating elongates 1.5-1.6 times, the conducting wire roller 2 positioned at 9 direction of motion front end of preorientation fibre bundle
The linear velocity of rotation is 1.5-1.6 times of rear end conducting wire roller 3, can thus make preorientation fibre bundle by conducting wire sieve
1.5-1.6 times is elongated after drawing 2.
It handled after fibre bundle cooling after elongation by scroll tube 4, assign its certain bulkiness and elasticity, obtain height
Elastic fibre tow 10,4 field of textile machinery of scroll tube are used for false twist texturized common parts, and structure and working principle are existing
Well-known technique, herein no longer narration in detail.Treated that high-elasticity fiber tow is then directed into and passes through formed pipe 6 for scroll tube 4
Center, from the air current spray nozzle 7 being mounted on 6 side wall of formed pipe under 0.5-2.5 kilograms of air pressure to high-elasticity fiber silk
Beam 10 sprays lateral air pulse, and high pressure draught can dispel tow, is allowed to become more fluffy, the arteries and veins of intermittence injection
Qi of chong channel ascending adversely stream forms spaced fluffy section 8 and close section 9 on tow, and the density of fluffy section 8 and close section 9 is every meter of 100-
200.
The low-temperature heat radiation that temperature is 100-110 degrees Celsius is imported into and passed through by the later tow of formed pipe 6 to be formed
Give tow certain contraction using the heat tow of low-temperature heat radiation sizing 5 tube wall of pipeline radiation in the center of pipeline 5
And internal stresses release, make tow that there is certain dimensional stability and by thermal stability, finally obtain can weaving it is coloured
Antibacterial zein fiber long filament.
Above-mentioned high temperature heat radiation pipeline 1 and low-temperature heat radiation sizing pipeline 5 can use electrically heated mode or adopt
Its tube wall is heated with the mode that medium heats.
Embodiment 2
With embodiment 1, wherein in spinning process, by after drying Masterbatch and antibacterial matrices respectively spun with 5% ratio in screw rod
Melt spinning is carried out in particles of polylactic acid after being mixed into drying before the screw rod of silk machine.
Embodiment 3
With embodiment 1, wherein in spinning process, by after drying Masterbatch and antibacterial matrices respectively with 3% ratio in screw spinning
Melt spinning is carried out in particles of polylactic acid after being mixed into drying before the screw rod of machine.
Embodiment 4
With embodiment 1, wherein in spinning process, by the Masterbatch after drying with 1% ratio, antibacterial matrices with 2.5% ratio
Melt spinning is carried out in particles of polylactic acid after being mixed into drying before the screw rod of extruder type spinning machine.
Embodiment 5
With embodiment 1, wherein adding bullet step, preorientation fibre bundle pass through high temperature heat radiation pipeline 1 after, into scroll tube
Room temperature is cooled to by natural cooling or by coldplate before 4;Elastomeric fiber strands pass through low-temperature heat radiation sizing pipeline 5
After, by natural cooling before molding 6 or by coldplate cool to room temperature.
The dosage of above-mentioned Masterbatch and antibacterial matrices is weight percentage.
Product testing result
Table one
Performance class | Terylene | Cotton | Silk | Zein fiber |
It is antibacterial anti-mite | Difference | Difference | Generally | It is fabulous |
Gas permeability | Difference | Generally | Difference | It is fabulous |
Degradability | It is very poor | It is good | It is good | It is fabulous |
Drapability | Generally | Difference | It is good | It is fabulous |
Wrinkle resistance | Generally | Generally | Difference | It is fabulous |
Warmth retention property | Generally | It is good | Difference | It is good |
Summer cool property | Generally | It is good | Difference | It is fabulous |
Anti-flammability | 20 | 16 | 17 | 26-30 |
PH value | - | - | 7 | 6-6.3 |
Raw material | Petroleum | Cotton | Silk | Corn |
Processing pollution | Chemical pollution | Pesticide residue | Nothing | Nothing |
As shown in above-mentioned table one, zein fiber commonly uses one of the performance comparison of textile fabrics with other, and zein fiber therein is
The product produced using the manufacturing method of coloured anti-bacterial zein fiber long filament of the present invention.The water contact angle of the zein fiber is
76, between the 82 of terylene and the 70 of polyamide fibre, its hydrophily compared with terylene, capillary effect and water diffusivity all compared with
It is good.Therefore terylene is better than in terms of snugness of fit using the garment material of zein fiber production, antibacterial anti-mite, breathed freely
Property, drapability, wrinkle resistance, warmth retention property and Xia Liangxing etc. very advantageous.In addition, the degradability of the zein fiber is fabulous
, its raw starch be it is reproducible, the degradative phase of product in the soil after use is limited to 1 to 2 years, and the terylene that compares makes
It is manufactured with non-renewable petroleum and up to 100 years degradative phases, there is zein fiber unmatched environmentally protective regeneration to follow
Ring utility will have great potentiality in terms of substitution terylene will solve pollution in future.
Table two
Kinds of fibers | Anaclasis angle | Water contact angle | Spinning process | Uviolresistance |
Terylene | 1.54 | 82 | Melt spinning | Generally |
Polyamide fibre | 1.52 | 70 | Melt spinning | Difference |
Zein fiber | 1.35-1.45 | 76 | Melt spinning | It is good |
Cotton | 1.53 | - | - | It is poor |
Silk | 1.54 | - | - | It is poor |
Wool | 1.54 | - | - | Generally |
As shown in above-mentioned table two, the two of the performance comparison of zein fiber and other common textile fabrics.Zein fiber therein is
The product produced using the manufacturing method of coloured anti-bacterial zein fiber long filament of the present invention.The uvioresistant performance of the zein fiber
It is outstanding, it is better than cotton, silk, hair and terylene, polyamide fibre.Anaclasis angle is 1.35-1.45 simultaneously, than cotton, silk, and hair, terylene, polyamide fibre
Anaclasis angle is all small, illustrates that the refractive index of zein fiber is low, and dyeability is good, help to obtain deep dyed color.
Table three
Kinds of fibers | The combustion heat (mj/kg) | Flammability | Limit oxygen index (%) |
Terylene | 25-30 | Thickness | 20-22 |
Polyamide fibre | 31 | Middle cigarette | 20-24 |
Zein fiber | 19 | Few cigarette | 28 |
Cotton | 17 | Burning | 16-17 |
Wool | 21 | It burns (slow) | 24-25 |
As shown in above-mentioned table three, the three of the performance comparison of zein fiber and other common textile fabrics.Zein fiber therein is
The product produced using the manufacturing method of coloured anti-bacterial zein fiber long filament of the present invention.The limit oxygen index of the zein fiber
It is 28, higher than the 20-22 of the terylene and 20-24 of polyamide fibre, illustrates that zein fiber has preferable flame retardant property.
Table four
Kinds of fibers | Relative density | Fusing point (DEG C) | Strongly (g/d) | Restore (elongation 5%) |
Terylene | 1.38 | 255 | 4-4.5 | 65 |
Polyamide fibre | 1.14 | 205 | 4.5 | 89 |
Zein fiber | 1.27 | 175 | 3.5-4.2 | 93 |
Cotton | 1.52 | - | 1.9-3.1 | 52 |
Silk | 1.3-1.45 | - | 4 | 52 |
Wool | 1.32 | - | 1.6 | 69 |
As shown in above-mentioned table four, the four of the performance comparison of zein fiber and other common textile fabrics.Zein fiber therein is
The product produced using the manufacturing method of coloured anti-bacterial zein fiber long filament of the present invention.The strength 3.5- of the zein fiber
4.2 is close with terylene 4-4.5, is higher than cotton and hair, has good tensile resistance, and the elastic restoration ratio 93 of zein fiber
Be it is highest, it is fine greater than with the elasticity polyamide fibre 89 claimed, significantly larger than the 65 of terylene, therefore 100% zein fiber or corn
Dimension and wool, garment material made of cotton blend have good snugness of fit, are well suited for making gym suit and fashion dress ornament,
In addition, zein fiber is soft, it is beautiful in colour to be particularly suitable for making women's dress.
Claims (2)
1. a kind of manufacturing method of coloured anti-bacterial zein fiber long filament, it is characterised in that use following steps:
A) the drying of particle is put particles of polylactic acid, antibacterial matrices and Masterbatch into sufficiently dry in drying machine respectively;Wherein
Particles of polylactic acid is dry using drum dryer;Antibacterial matrices and Masterbatch are put hot air type baking oven into and are dried;Contained
Water is lower than the dry particle of 30ppm;
B) spinning, by after above-mentioned drying Masterbatch and antibacterial matrices respectively with the ratio of 1%-5% before the screw rod of extruder type spinning machine
Melt spinning is carried out in particles of polylactic acid after being mixed into drying, for temperature between 200-220 degrees Celsius, spinning specification is 75D-
300D, spinneret hole count are -288 hole of 36 hole, obtain preorientation fibre bundle;
C) add bullet, above-mentioned preorientation fibre bundle is passed through into temperature with 400-500 meters of speed per minute as 105-115 degrees Celsius
High temperature heat radiation pipeline (1) center, the length of high temperature heat radiation pipeline (1) bringing-up section is 1.5-2 meter, utilizes high warm spoke
The different rotating speeds of the conducting wire roller (2,3) of pipeline rear and front end guidance preorientation fibre bundle are penetrated by the preorientation fiber filament of heating
Shu Lachang 1.5-1.6 times;After fibre bundle after elongation is cooling by scroll tube (4) processing, assign its certain bulkiness and
Elasticity obtains elastomeric fiber strands;The subsequent elastomeric fiber strands are imported into and pass through the center of formed pipe (6), by being mounted on
Air current spray nozzle (7) on formed pipe (6) side wall under certain air pressure to elastomeric fiber strands injection pulse air-flow, in silk
Spaced fluffy section (8) and close section (9) are formed on beam, it is 100- that last elastomeric fiber strands, which are imported into and pass through temperature,
The center of 110 degrees Celsius of low-temperature heat radiation sizing pipeline (5), gives the certain contraction of tow and internal stresses release, makes tow
With certain dimensional stability and by thermal stability, finally again by the tow obtain can weaving coloured anti-bacterial corn it is fine
Tie up long filament.
2. a kind of manufacturing method of coloured anti-bacterial deodorization zein fiber long filament according to claim 1, it is characterised in that: described
Particles of polylactic acid is corn plant base polylactic acid particle, the antibacterial matrices be nano silver, nano zine oxide, nano cupric oxide,
The particle of the mixture of one of nano-titanium dioxide or several substances.
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CN102260925A (en) * | 2011-06-22 | 2011-11-30 | 绍兴文理学院 | Method for producing flat metachromatic superbright DTY (draw texturing yarn) fibers |
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