CN104651962A - Double-component hollow high-moisture-absorption curly composite fiber and preparation method thereof - Google Patents
Double-component hollow high-moisture-absorption curly composite fiber and preparation method thereof Download PDFInfo
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- CN104651962A CN104651962A CN201510028723.7A CN201510028723A CN104651962A CN 104651962 A CN104651962 A CN 104651962A CN 201510028723 A CN201510028723 A CN 201510028723A CN 104651962 A CN104651962 A CN 104651962A
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- Prior art keywords
- spinneret orifice
- component
- outage
- moisture absorption
- composite fibre
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Classifications
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- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/28—Formation of filaments, threads, or the like while mixing different spinning solutions or melts during the spinning operation; Spinnerette packs therefor
- D01D5/30—Conjugate filaments; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/24—Formation of filaments, threads, or the like with a hollow structure; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01D—MECHANICAL METHODS OR APPARATUS IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS
- D01D5/00—Formation of filaments, threads, or the like
- D01D5/253—Formation of filaments, threads, or the like with a non-circular cross section; Spinnerette packs therefor
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Multicomponent Fibers (AREA)
Abstract
The invention relates to a double-component hollow high-moisture-absorption curly composite fiber and a preparation method thereof. The double-component hollow high-moisture-absorption curly composite fiber is prepared by adopting Dacron, bio-based chinlon 56 and adhesive in a mass ratio of 50: (50-70): 30 by virtue of a circular hollow 2C spinning hole. The double-component hollow high-moisture-absorption curly composite fiber is good in wool-like effect and good in moisture absorption property, ventilation property and electrostatic resistance, after the dyeing and finishing heat-moisture treatment and dry-heat rotating fleece treatment, a fabric has a high-imitation wool-like curly tufting attractive structure and is comfortable to wear; the preparation method is only modified on the basis of the existing equipment, the application property of the Dacron can be greatly improved, the application range can be enlarged, the clothing fabric can be enriched and optimized, and the economic benefit and social benefit are remarkable.
Description
Technical field
The invention belongs to terylene composite fibre field, particularly curling composite fibre of outage moisture absorption and preparation method thereof in a kind of bi-component.
Background technology
Terylene is the very many a kind of chemical fiber garment raw material of fabric in daily life, the maximum advantage of its fabric is that wrinkle resistance and conformality are fine, but its sucting wet air permeability is poor, and it is airtight, non-hygroscopic that fabric makes garment material, and easily because friction produces electrostatic, wear sultry especially uncomfortable.In recent years, along with the development of demand of articles for use is spun by family, consumption increases rapidly, and China has become the maximum production of terylene chemical fibre and demand country, to produce and the development of demand and people pursue and wear pursuit that is attractive in appearance, comfort level and there is great paradox, govern further developing of terylene chemical fibre.
Summary of the invention
Technical problem to be solved by this invention is to provide curling composite fibre of outage moisture absorption and preparation method thereof in a kind of bi-component, and this composite fibre has good simulate wool effect, and has that good moisture absorption is ventilative, antistatic behaviour; Preparation method only need transform at existing equipment, greatly can improve the application performance of terylene, expand its application space, enrich and optimize garment material, have significant economic benefit and social benefit.
The curling composite fibre of outage moisture absorption in a kind of bi-component of the present invention, described composite fibre is adopted the terylene of mass ratio 50:50-70:30 and bio-based polyamide fibre 56 and adds adhesive and obtained by circle hollow 2C spinneret orifice.
Xeothermic, the boiling water shrinkage difference of described terylene and bio-based polyamide fibre 56 are all greater than 10%.In process, because of generation difference in shrinkage of being heated, finished product strand produces large waveform three-dimensional crimp construction fabric and shakes grain process through dyeing and finishing humid heat treatment and xeothermic rotation, produces curling tufting structure attractive in appearance.
The addition of described adhesive is the 2-6% of gross mass.Adhesive is blended in terylene and the section of full bio-based polyamide fibre 56 according to the ratio of 2-6% respectively, be melted into blend melt together, adhesive is with the group reacted with polyamide fibre 56 and terylene, in two component contacts faces two component good bond, avoid because of terylene and polyamide fibre poor compatibility, fiber stretches at aft-loaded airfoil, by hyther time, because bi-component difference in shrinkage interface produces shearing force two-phase laminated flow, thus fiber properties can be deteriorated or disappear.
Described round hollow 2C spinneret orifice is made up of the first spinneret orifice of two C word structures and the second spinneret orifice, first spinneret orifice and the distribution of the second spinneret orifice opposed juxtaposition, first contact interface of contact position is identical with the second contact interface, the first spinneret orifice and the second spinneret orifice respectively with the corresponding connection of pod apertures in the pod apertures on the polyester derivative chute on melt distribution plate and polyamide fibre 56 guiding gutter.Ensure to wash brocade and the polyamide fibre 56 single C part distributing binder arranged side by side respectively by spinneret orifice.Adopt lateral blowing cooling spinning during spinning, as shown in Figure 2, ensure that blowing direction is vertical with the symmetry axis of 2C spinneret orifice, terylene component Parts is near blowing window in the installation of spinnerets.Make bi-component Asymmetrical cooling, terylene cooling velocity is fast, increases xeothermic, the damp and hot inotropic difference of bi-component, increases thread crimping performance and curling stability.The ratio of the width of the first spinneret orifice and the second spinneret orifice vertical direction and the width of horizontal direction is 2:3-1:2, two single C spinneret orifice walls can be identical, also can be different curve, said structure ensure that strand is subject to easily occur curling and just have the effect keeping curly form stability by humid heat treatment.
The area ratio of described first spinneret orifice and the second spinneret orifice is 50:50-70:30.
The preparation method of the curling composite fibre of outage moisture absorption in a kind of bi-component of the present invention, comprising:
On two component combined spinning machine, adopt circle hollow 2C spinneret orifice, adopt the terylene of mass ratio 50:50-70:30 and bio-based polyamide fibre 56 and add adhesive, carrying out spinning and namely obtain the curling composite fibre of outage moisture absorption in bi-component; Wherein, the screw rod melting of bio-based polyamide fibre 56 component system and spinning temperature are than the temperature height 5-10 DEG C of terylene system, and polyamide fibre 56 fusing point, a little more than terylene, improves spinning temperature, to ensure its rheological property.
Full-drawn yarn FDY, draw false twisting textured filament DTY or short fiber are made in described spinning.
The described technological parameter making full-drawn yarn FDY or short fiber is: stretcher strain temperature 100-120 DEG C, setting temperature 120-140 DEG C; The technological parameter making draw false twisting textured filament DTY is: total drawing ratio draw ratio 3.2-4.0, draw false twisting distortion speed ratio 1.2-1.4, false twist texturing temperature 180-200 DEG C, false twisting setting temperature 130-150 DEG C.
beneficial effect
The present invention has good simulate wool effect, and has that good moisture absorption is ventilative, antistatic behaviour, and fabric shakes grain process through dyeing and finishing humid heat treatment and xeothermic rotation, has the curling tufting structure attractive in appearance of high imitative wool, and has fine snugness of fit; Preparation method only need transform at existing equipment, greatly can improve the application performance of terylene, expand its application space, enrich and optimize garment material, have significant economic benefit and social benefit.
Accompanying drawing explanation
Fig. 1 is the schematic diagram of round hollow 2C spinneret orifice of the present invention;
Fig. 2 is the schematic diagram in blowing direction and spinneret orifice direction;
Fig. 3 is the different component two-part corresponding relation schematic diagram with spinneret orifice respectively;
Fig. 4 is the large wave-like curls schematic diagram of strand;
Fig. 5 is that fabric imitates wool tufting coiled structure schematic diagram.
Detailed description of the invention
Below in conjunction with specific embodiment, set forth the present invention further.Should be understood that these embodiments are only not used in for illustration of the present invention to limit the scope of the invention.In addition should be understood that those skilled in the art can make various changes or modifications the present invention, and these equivalent form of values fall within the application's appended claims limited range equally after the content of having read the present invention's instruction.
Embodiment 1
On original bi-component composite spinning equipment on machine, the design of transformation spinnerets spinneret orifice, and ensure that blowing direction is vertical with the symmetry axis of 2C spinneret orifice, terylene component Parts is near blowing window, make bi-component Asymmetrical cooling, terylene cooling velocity is fast, increase bi-component xeothermic, damp and hot inotropic difference, increase thread crimping performance and curling stability, terylene melt arrives the C1 region of spinneret orifice respectively by the thread eye 9 on the guiding gutter A on distribution plate 8, the melt of polyamide fibre 56 component arrives the C2 region of spinneret orifice by the thread eye 10 on guiding gutter B on distribution plate 8, then two components column distribution, contact surface 2 and 6 is integrated by the effect good bond of adhesive, form the as-spun fibre of the curling composite fibre of outage moisture absorption in bi-component, as-spun fibre can be produced into FDY by full drawing process or be produced into POY or DTY by preorientation spinning technique or be spun into short fiber.Adding adhesive in two components is because adhesive is with the group reacted with polyamide fibre 56 and terylene, in two component contacts faces two component good bond, avoid because of terylene and polyamide fibre poor compatibility, fiber aft-loaded airfoil stretch, by hyther time, because bi-component difference in shrinkage interface produces shearing force two-phase laminated flow, thus fiber properties can be deteriorated or disappear, ensure end properties and effect.
Production method is as follows:
On bi-component compound FDY spinning machine, adopt circle hollow 2C spinneret orifice, C1 is terylene component, C2 is bio-based polyamide fibre 56 component, the area ratio of C1:C2 is 50:50, the ratio of C font spinneret orifice width 3 and width 2 and width 7 and width 6 is 2:3, spinneret orifice wall 4 is identical with 5, spinnerets is installed according to shown in Fig. 2, and adhesive addition is 4%, draw ratio 3.3, one hot-rolling stretcher strain temperature 105 DEG C, two hot-rolling drawing and setting temperature 125 DEG C, spinning speed 4600m/min, the curling composite fibre FDY of outage moisture absorption in obtained 75D/36F bi-component.
Embodiment 2
On bi-component compound POY spinning machine, adopt circle hollow 2C spinneret orifice, C1 is terylene component, and C2 is bio-based polyamide fibre 56 component, the area ratio of C1:C2 is 70:30, the ratio of C font spinneret orifice width 3 and width 2 and width 7 and width 6 is 2:1, and spinneret orifice wall 4 and 5 is different, and spinnerets is installed according to shown in Fig. 2, adhesive addition is 3.5%, spinning speed 3200m/min, spinneret draft ratio 2.1, the curling composite fibre POY of outage moisture absorption in the bi-component of obtained compositely proportional 70:30.
In bi-component, the curling composite fibre POY of outage moisture absorption is on Ba Mage false twist texturing machine, draw ratio 1.72 (stretches 2.1 with POY, amount to total stretching 3.61), one hot case stretcher strain temperature 190 DEG C, two hot case setting temperatures 140 DEG C, speed of production 700m/min, the curling composite fibre DTY of outage moisture absorption in the 70:30 bi-component of obtained 100D/48F.
Embodiment 3
On bi-component compound short fiber spinning machine, adopt circle hollow 2C spinneret orifice, C1 is terylene component, C2 is bio-based polyamide fibre 56 component, the area ratio of C1:C2 is 60:40, the ratio of C font spinneret orifice width 3 and width 2 and width 7 and width 6 is 2:3, spinneret orifice wall 4 and 5 is different, spinnerets is installed according to shown in Fig. 2, adhesive addition is 4%, total drawing ratio 4.0, short fiber hot-rolling stretcher strain temperature 120 DEG C, short fiber setting temperature 140 DEG C, through curling, oil and cut off fibre, the compositely proportional of obtained 1.3D*38mm is the curling composite fibre short fiber of outage moisture absorption in 60:40 bi-component.
Embodiment 4
On bi-component compound FDY spinning machine, adopt circle hollow 2C spinneret orifice, C1 is terylene component, C2 is bio-based polyamide fibre 56 component, the area ratio of C1:C2 is 50:50, the ratio of C font spinneret orifice width 3 and width 2 and width 7 and width 6 is 2:1, spinneret orifice wall 4 is identical with 5, spinnerets is installed according to shown in Fig. 2, adhesive addition is 6%, draw ratio 3.8, one hot-rolling stretcher strain temperature 120 DEG C, two hot-rolling drawing and setting temperature 140 DEG C, spinning speed 4600m/min, the curling composite fibre FDY of outage moisture absorption in the 300D/96F bi-component of obtained compositely proportional 50:50.
Claims (9)
1. the curling composite fibre of outage moisture absorption in bi-component, is characterized in that: described composite fibre is adopted the terylene of mass ratio 50:50-70:30 and bio-based polyamide fibre 56 and adds adhesive and obtained by circle hollow 2C spinneret orifice.
2. the curling composite fibre of outage moisture absorption in a kind of bi-component according to claim 1, is characterized in that: xeothermic, the boiling water shrinkage difference of described terylene and bio-based polyamide fibre 56 are all greater than 10%.
3. the curling composite fibre of outage moisture absorption in a kind of bi-component according to claim 1, is characterized in that: the addition of described adhesive is the 2-6% of gross mass.
4. the curling composite fibre of outage moisture absorption in a kind of bi-component according to claim 1, it is characterized in that: described round hollow 2C spinneret orifice is made up of first spinneret orifice (C1) of two C word structures and the second spinneret orifice (C2), first spinneret orifice (C1) and the distribution of the second spinneret orifice (C2) opposed juxtaposition, first contact interface (2) of contact position is identical with the second contact interface (6), first spinneret orifice (C1) and the second spinneret orifice (C2) respectively with the pod apertures (9) on the polyester derivative chute (A) on melt distribution plate (8) and pod apertures (10) the corresponding connection on polyamide fibre 56 guiding gutter (B).
5. the curling composite fibre of outage moisture absorption in a kind of bi-component according to claim 4, is characterized in that: the area ratio of described first spinneret orifice (C1) and the second spinneret orifice (C2) is 50:50-70:30.
6. the curling composite fibre of outage moisture absorption in a kind of bi-component according to claim 4, it is characterized in that: adopt lateral blowing cooling spinning, blowing direction is vertical with the symmetry axis of spinneret orifice, first spinneret orifice (C1) is near blowing window, and the ratio of the width of the first spinneret orifice (C1) and the second spinneret orifice (C2) vertical direction and the width of horizontal direction is 2:3-1:2.
7. the preparation method of the curling composite fibre of outage moisture absorption in bi-component, comprising:
On two component combined spinning machine, adopt circle hollow 2C spinneret orifice, adopt the terylene of mass ratio 50:50-70:30 and bio-based polyamide fibre 56 and add adhesive, carrying out spinning and namely obtain the curling composite fibre of outage moisture absorption in bi-component; Wherein, the screw rod melting of bio-based polyamide fibre 56 component system and spinning temperature are than the temperature height 5-10 DEG C of terylene system.
8. the preparation method of the curling composite fibre of outage moisture absorption in a kind of bi-component according to claim 7, is characterized in that: full-drawn yarn FDY, draw false twisting textured filament DTY or short fiber are made in described spinning.
9. the preparation method of the curling composite fibre of outage moisture absorption in a kind of bi-component according to claim 8, is characterized in that: described in make full-drawn yarn FDY or short fiber technological parameter be: stretcher strain temperature 100-120 DEG C, setting temperature 120-140 DEG C; The technological parameter making draw false twisting textured filament DTY is: total drawing ratio draw ratio 3.2-4.0, draw false twisting distortion speed ratio 1.2-1.4, false twist texturing temperature 180-200 DEG C, false twisting setting temperature 130-150 DEG C.
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105177740A (en) * | 2015-08-10 | 2015-12-23 | 东华大学 | A two-component abnormity hollow high moisture absorption curling composite fiber and a preparation method thereof |
CN109957856A (en) * | 2017-12-25 | 2019-07-02 | 上海凯赛生物技术研发中心有限公司 | A kind of parallel composite fiber and preparation method thereof |
CN111733470A (en) * | 2020-06-12 | 2020-10-02 | 温州大学 | Self-crimping composite moisture absorption fiber, preparation method and fabric |
CN112760749A (en) * | 2020-12-29 | 2021-05-07 | 嘉兴市凯邦锦纶科技股份有限公司 | Manufacturing method of parallel superfine denier modified polyester fancy spun yarn |
CN115559014A (en) * | 2022-09-15 | 2023-01-03 | 浙江盛元化纤有限公司 | Preparation method of antistatic wool-like polyester filament yarn |
CN116575182A (en) * | 2023-07-14 | 2023-08-11 | 江苏富之岛美安纺织品科技有限公司 | PLA (polylactic acid) bi-component super-expansion super-elastic pearl cotton ball, processing equipment and manufacturing method thereof |
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Cited By (10)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105177740A (en) * | 2015-08-10 | 2015-12-23 | 东华大学 | A two-component abnormity hollow high moisture absorption curling composite fiber and a preparation method thereof |
CN109957856A (en) * | 2017-12-25 | 2019-07-02 | 上海凯赛生物技术研发中心有限公司 | A kind of parallel composite fiber and preparation method thereof |
CN109957856B (en) * | 2017-12-25 | 2022-07-19 | 上海凯赛生物技术股份有限公司 | Parallel composite fiber and preparation method thereof |
CN111733470A (en) * | 2020-06-12 | 2020-10-02 | 温州大学 | Self-crimping composite moisture absorption fiber, preparation method and fabric |
CN111733470B (en) * | 2020-06-12 | 2022-11-08 | 温州大学 | Self-crimping composite moisture absorption fiber, preparation method and fabric |
CN112760749A (en) * | 2020-12-29 | 2021-05-07 | 嘉兴市凯邦锦纶科技股份有限公司 | Manufacturing method of parallel superfine denier modified polyester fancy spun yarn |
CN115559014A (en) * | 2022-09-15 | 2023-01-03 | 浙江盛元化纤有限公司 | Preparation method of antistatic wool-like polyester filament yarn |
CN115559014B (en) * | 2022-09-15 | 2024-03-08 | 浙江盛元化纤有限公司 | Preparation method of antistatic wool-like polyester filaments |
CN116575182A (en) * | 2023-07-14 | 2023-08-11 | 江苏富之岛美安纺织品科技有限公司 | PLA (polylactic acid) bi-component super-expansion super-elastic pearl cotton ball, processing equipment and manufacturing method thereof |
CN116575182B (en) * | 2023-07-14 | 2023-09-19 | 江苏富之岛美安纺织品科技有限公司 | PLA (polylactic acid) bi-component super-expansion super-elastic pearl cotton ball processing equipment and manufacturing method thereof |
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