CN109627964A - 一种不锈钢丝双涂层金刚纱网及其制作方法 - Google Patents

一种不锈钢丝双涂层金刚纱网及其制作方法 Download PDF

Info

Publication number
CN109627964A
CN109627964A CN201811556749.9A CN201811556749A CN109627964A CN 109627964 A CN109627964 A CN 109627964A CN 201811556749 A CN201811556749 A CN 201811556749A CN 109627964 A CN109627964 A CN 109627964A
Authority
CN
China
Prior art keywords
stainless steel
steel wire
warrior attendant
buddha
double coating
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201811556749.9A
Other languages
English (en)
Inventor
林兆材
林兆欣
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Xiaoxian Jinke Electric Wire Co Ltd
Original Assignee
Xiaoxian Jinke Electric Wire Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Xiaoxian Jinke Electric Wire Co Ltd filed Critical Xiaoxian Jinke Electric Wire Co Ltd
Priority to CN201811556749.9A priority Critical patent/CN109627964A/zh
Publication of CN109627964A publication Critical patent/CN109627964A/zh
Withdrawn legal-status Critical Current

Links

Classifications

    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D3/00—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials
    • B05D3/10—Pretreatment of surfaces to which liquids or other fluent materials are to be applied; After-treatment of applied coatings, e.g. intermediate treating of an applied coating preparatory to subsequent applications of liquids or other fluent materials by other chemical means
    • B05D3/102—Pretreatment of metallic substrates
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00—Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50—Multilayers
    • B05D7/52—Two layers
    • B05D7/54—No clear coat specified
    • B05D7/544—No clear coat specified the first layer is let to dry at least partially before applying the second layer
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04—Polyurethanes
    • C09D175/14—Polyurethanes having carbon-to-carbon unsaturated bonds
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08—Anti-corrosive paints
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/61—Additives non-macromolecular inorganic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/60—Additives non-macromolecular
    • C09D7/63—Additives non-macromolecular organic
    • C—CHEMISTRY; METALLURGY
    • C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40—Additives
    • C09D7/65—Additives macromolecular
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C22/00—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals
    • C23C22/05—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions
    • C23C22/06—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6
    • C23C22/34—Chemical surface treatment of metallic material by reaction of the surface with a reactive liquid, leaving reaction products of surface material in the coating, e.g. conversion coatings, passivation of metals using aqueous solutions using aqueous acidic solutions with pH less than 6 containing fluorides or complex fluorides
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23F—NON-MECHANICAL REMOVAL OF METALLIC MATERIAL FROM SURFACE; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL; MULTI-STEP PROCESSES FOR SURFACE TREATMENT OF METALLIC MATERIAL INVOLVING AT LEAST ONE PROCESS PROVIDED FOR IN CLASS C23 AND AT LEAST ONE PROCESS COVERED BY SUBCLASS C21D OR C22F OR CLASS C25
    • C23F1/00—Etching metallic material by chemical means
    • C23F1/10—Etching compositions
    • C23F1/14—Aqueous compositions
    • C23F1/16—Acidic compositions
    • C23F1/28—Acidic compositions for etching iron group metals
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2202/00—Metallic substrate
    • B05D2202/10—Metallic substrate based on Fe
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2502/00—Acrylic polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2504/00—Epoxy polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D—PROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2508/00—Polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2217—Oxides; Hydroxides of metals of magnesium
    • C08K2003/2224—Magnesium hydroxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20—Oxides; Hydroxides
    • C08K3/22—Oxides; Hydroxides of metals
    • C08K2003/2237—Oxides; Hydroxides of metals of titanium
    • C08K2003/2241—Titanium dioxide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00—Use of inorganic substances as compounding ingredients
    • C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24—Acids; Salts thereof
    • C08K3/26—Carbonates; Bicarbonates
    • C08K2003/265—Calcium, strontium or barium carbonate
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00—Specific properties of additives
    • C08K2201/011—Nanostructured additives
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C—CHEMISTRY; METALLURGY
    • C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
    • C23C—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
    • C23C2222/00—Aspects relating to chemical surface treatment of metallic material by reaction of the surface with a reactive medium
    • C23C2222/10—Use of solutions containing trivalent chromium but free of hexavalent chromium

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Mechanical Engineering (AREA)
  • Metallurgy (AREA)
  • Inorganic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Chemical Treatment Of Metals (AREA)

Abstract

本发明公开了一种不锈钢丝双涂层金刚纱网的制作方法，先用钢丝织造机对不锈钢丝进行织造，将得到的不锈钢丝网经过除油、清洗、刻蚀、钝化后，用硅烷偶联剂进行改性处理，再先后将防锈底漆、涂胶涂料均匀喷涂在改性处理后的不锈钢丝网上，通过烘烤固化，在不锈钢丝网表面形成不同厚度的双层涂膜，最后得到不锈钢丝双涂层金刚纱网。本发明的制作方法能有效改善纱网表面涂膜的防腐性能以及附着性，使得到的金刚纱网具有优良的防腐效果以及长效防腐性能，使用寿命长。

Description

一种不锈钢丝双涂层金刚纱网及其制作方法
技术领域
本发明涉及金刚纱网技术领域，尤其涉及一种不锈钢丝双涂层金刚纱网的制作方法。
背景技术
纱窗是安装在窗户上面的一种产品，可以起到防盗、防尘、防昆虫，阻挡阳光等作用，在居家装饰领域得到广泛的应用。金刚网纱窗是防盗纱窗中的一种，指的是纱窗采用金刚网作为纱网的防盗纱窗，是目前市场上流行的纱窗产品。金刚网采用高强度不锈钢丝编织而成，具有强度高、抗撞击等优质性能，采用金刚网加工而成的防盗纱窗，其不仅能起到优良的安全防护效果，而且无阻隔感、遮挡感和压抑感，室内随时保持明亮自然，是高档家居的首选，受到消费者的喜爱，具有非常广阔的市场前景。
金刚网虽然是由不锈钢丝编织而出名，但是不锈钢丝长时间暴露在空气中，有可能因为外界因素导致生锈，从而影响金刚网的使用寿命。为了防止这种情况发生，需要对不锈钢的表面进行喷涂处理，阻止不锈钢丝与外界接触，这样就能起到非常好的防锈作用，使其能够长期抵御各种严峻天气或环境腐蚀因素如酸雨的损害。喷涂处理通常采用聚酯树脂，其与金属基体的化学键合力非常低，在金刚纱网表面的长效附着力很差，长期使用后局部或整体涂层容易出现起鼓、脱落等现象。目前的金刚纱网制作方法主要是先对不锈钢丝网表面进行钝化处理，使金属表面生成一层几微米的钝化膜，其表面粗糙具有多孔性，使涂料等可以渗透到这些孔隙之中，与钝化膜紧密结合，能起到增强防锈以及增强涂层和底材附着力的作用。但是，由于钝化膜本身较薄，所起到的改善附着力效果有限，所得金刚网的长期防腐性能、耐候性较差。因此，有必要对现有的金刚纱网的制作方法作出改进。
发明内容
本发明目的就是为了弥补已有技术的缺陷，提供一种不锈钢丝双涂层金刚纱网的制作方法，该方法能有效改善纱网表面涂膜的防腐性能以及附着性，使得到的金刚纱网具有优良的防腐效果以及长效防腐性能，使用寿命长。
本发明是通过以下技术方案实现的：
一种不锈钢丝双涂层金刚纱网的制作方法，其特征在于，包括以下步骤：
(1)用钢丝织造机对不锈钢丝进行织造，得到不锈钢丝网；
(2)将步骤(1)得到的不锈钢丝网经过除油、清洗，然后浸泡在刻蚀液中于30-60℃刻蚀15-30min，取出后用水清洗干净，烘干；
(3)将步骤(2)处理后的不锈钢丝网浸泡在钝化液中于常温钝化10-15min，取出后用水洗净、烘干；
(4)将步骤(3)处理后的不锈钢丝网浸泡在硅烷偶联剂的乙醇溶液中于常温改性处理5-10min，取出后于110-120℃保温处理10-15min；
(5)将防锈底漆分4-5次均匀喷涂在步骤(4)处理后的不锈钢丝网上，然后送入烘烤室中于140-160℃烘烤20-30min，取出后冷却，在不锈钢丝网表面形成厚度为10-20μm的漆膜；
(6)将涂胶涂料分2-3次均匀喷涂在步骤(5)处理后的不锈钢丝网上，然后送入烘烤室中于130-140℃烘烤15-25min，取出后冷却，在不锈钢丝网表面形成厚度为30-50μm的涂膜，得到不锈钢丝双涂层金刚纱网。
所述刻蚀液由下述重量份的原料配制而成：三氯化铁10-15，盐酸5-10，水1000-1500。
所述钝化液由下述重量份的原料配制而成：柠檬酸10-15，双氧水5-10，氟化钠5-10，硫脲1-2，硝酸铈1-2，水1000-1500。
所述硅烷偶联剂的乙醇溶液的浓度为5-10g/L。
所述防锈底漆由下述重量份的原料配制而成：脂肪族聚氨酯丙烯酸酯20-30，甲基丙烯酸酯10-15，异氰酸酯类固化剂0.5-1，纳米二氧化钛0.1-0.2。
所述涂胶涂料由下述重量份的原料配制而成：环氧树脂40-50，聚酯树脂30-40，环氧大豆油2-4，T105固化剂1-2，炭黑1-2，氢氧化镁0.3-0.5，纳米碳酸钙0.2-0.4，降粘剂0.2-0.4，亚甲基二萘硫磺钠0.1-0.2。
所述的不锈钢丝为304不锈钢丝。
本发明的制作方法制作的双涂层金刚纱网。
本发明的优点是：
(1)本发明采用化学刻蚀与钝化相结合对不锈钢丝网进行前处理，先通过化学刻蚀在不锈钢丝网表面形成较大的孔隙，然后通过钝化在其表面形成钝化膜，从而增加钝化膜的粗糙度，使钝化膜孔隙变得更大、更深，从而使涂料更好地渗透进钝化膜中；再辅以硅烷偶联剂对钝化膜进行改性处理，增加钝化膜与涂料的亲和结合力，使涂料固化后与钝化膜形成更紧密的结合，达到改善纱网表面涂膜附着性的效果，使涂膜不易起鼓、脱落，提高金刚纱网的长效防腐性能；
(2)本发明采用双层涂层的加工方式，能更好地起到防腐的防护性能，保护金刚纱网不易发生腐蚀，同时具有很好的耐候性，使得到的金刚纱网具有更优良的防腐耐候效果。
具体实施方式
实施例1
一种不锈钢丝双涂层金刚纱网的制作方法，包括以下步骤：
(1)用钢丝织造机对不锈钢丝进行织造，得到不锈钢丝网；
(2)将步骤(1)得到的不锈钢丝网经过除油、清洗，然后浸泡在刻蚀液中于30℃刻蚀15min，取出后用水清洗干净，烘干；
(3)将步骤(2)处理后的不锈钢丝网浸泡在钝化液中于常温钝化10min，取出后用水洗净、烘干；
(4)将步骤(3)处理后的不锈钢丝网浸泡在硅烷偶联剂的乙醇溶液中于常温改性处理5min，取出后于110℃保温处理10min；
(5)将防锈底漆分4次均匀喷涂在步骤(4)处理后的不锈钢丝网上，然后送入烘烤室中于140℃烘烤20min，取出后冷却，在不锈钢丝网表面形成厚度为10μm的漆膜；
(6)将涂胶涂料分2次均匀喷涂在步骤(5)处理后的不锈钢丝网上，然后送入烘烤室中于130℃烘烤15min，取出后冷却，在不锈钢丝网表面形成厚度为30μm的涂膜，得到不锈钢丝双涂层金刚纱网。
所述刻蚀液由下述重量份的原料配制而成：三氯化铁10，盐酸5，水1000。
所述钝化液由下述重量份的原料配制而成：柠檬酸10，双氧水5，氟化钠5，硫脲1，硝酸铈1，水1000。
所述硅烷偶联剂的乙醇溶液的浓度为5g/L。
所述防锈底漆由下述重量份的原料配制而成：脂肪族聚氨酯丙烯酸酯20，甲基丙烯酸酯10，异氰酸酯类固化剂0.5，纳米二氧化钛0.1。
所述涂胶涂料由下述重量份的原料配制而成：环氧树脂40，聚酯树脂30，环氧大豆油2，T105固化剂1，炭黑1，氢氧化镁0.3，纳米碳酸钙0.2，降粘剂0.3，亚甲基二萘硫磺钠0.1。
所述的不锈钢丝为304不锈钢丝。
实施例2
一种不锈钢丝双涂层金刚纱网的制作方法，包括以下步骤：
(1)用钢丝织造机对不锈钢丝进行织造，得到不锈钢丝网；
(2)将步骤(1)得到的不锈钢丝网经过除油、清洗，然后浸泡在刻蚀液中于30℃刻蚀30min，取出后用水清洗干净，烘干；
(3)将步骤(2)处理后的不锈钢丝网浸泡在钝化液中于常温钝化15min，取出后用水洗净、烘干；
(4)将步骤(3)处理后的不锈钢丝网浸泡在硅烷偶联剂的乙醇溶液中于常温改性处理10min，取出后于120℃保温处理10min；
(5)将防锈底漆分5次均匀喷涂在步骤(4)处理后的不锈钢丝网上，然后送入烘烤室中于160℃烘烤20-30min，取出后冷却，在不锈钢丝网表面形成厚度为20μm的漆膜；
(6)将涂胶涂料分3次均匀喷涂在步骤(5)处理后的不锈钢丝网上，然后送入烘烤室中于140℃烘烤5min，取出后冷却，在不锈钢丝网表面形成厚度为30μm的涂膜，得到不锈钢丝双涂层金刚纱网。
所述刻蚀液由下述重量份的原料配制而成：三氯化铁10，盐酸5，水1000。
所述钝化液由下述重量份的原料配制而成：柠檬酸10，双氧水5，氟化钠5，硫脲1，硝酸铈1，水1000。
所述硅烷偶联剂的乙醇溶液的浓度为5g/L。
所述防锈底漆由下述重量份的原料配制而成：脂肪族聚氨酯丙烯酸酯20，甲基丙烯酸酯10，异氰酸酯类固化剂0.5，纳米二氧化钛0.1。
所述涂胶涂料由下述重量份的原料配制而成：环氧树脂40，聚酯树脂30，环氧大豆油2，T105固化剂1，炭黑1，氢氧化镁0.3，纳米碳酸钙0.2，降粘剂0.2，亚甲基二萘硫磺钠0.1。
所述的不锈钢丝为304不锈钢丝。
实施例3
一种不锈钢丝双涂层金刚纱网的制作方法，包括以下步骤：
(1)用钢丝织造机对不锈钢丝进行织造，得到不锈钢丝网；
(2)将步骤(1)得到的不锈钢丝网经过除油、清洗，然后浸泡在刻蚀液中于60℃刻蚀30min，取出后用水清洗干净，烘干；
(3)将步骤(2)处理后的不锈钢丝网浸泡在钝化液中于常温钝化15min，取出后用水洗净、烘干；
(4)将步骤(3)处理后的不锈钢丝网浸泡在硅烷偶联剂的乙醇溶液中于常温改性处理10min，取出后于120℃保温处理15min；
(5)将防锈底漆分5次均匀喷涂在步骤(4)处理后的不锈钢丝网上，然后送入烘烤室中于160℃烘烤30min，取出后冷却，在不锈钢丝网表面形成厚度为20μm的漆膜；
(6)将涂胶涂料分3次均匀喷涂在步骤(5)处理后的不锈钢丝网上，然后送入烘烤室中于140℃烘烤25min，取出后冷却，在不锈钢丝网表面形成厚度为50μm的涂膜，得到不锈钢丝双涂层金刚纱网。
所述刻蚀液由下述重量份的原料配制而成：三氯化铁15，盐酸10，水1500。
所述钝化液由下述重量份的原料配制而成：柠檬酸15，双氧水10，氟化钠10，硫脲2，硝酸铈2，水1500。
所述硅烷偶联剂的乙醇溶液的浓度为10g/L。
所述防锈底漆由下述重量份的原料配制而成：脂肪族聚氨酯丙烯酸酯20，甲基丙烯酸酯10，异氰酸酯类固化剂0.5，纳米二氧化钛0.1。
所述涂胶涂料由下述重量份的原料配制而成：环氧树脂40，聚酯树脂30，环氧大豆油2，T105固化剂1，炭黑1，氢氧化镁0.3，纳米碳酸钙0.2，降粘剂0.2，亚甲基二萘硫磺钠0.1。
所述的不锈钢丝为304不锈钢丝。
对比例1
一种304不锈钢丝双涂层金刚纱网的制作方法，先用钢丝织造机对不锈钢丝进行织造，得到不锈钢丝网，然后经过常规除油、清洗、钝化，先喷涂防锈底漆，烘烤、冷却，形成厚度为10μm的漆膜，然后喷涂涂胶涂料，烘烤、冷却，形成厚度为30μm的涂膜，得到不锈钢丝双涂层金刚纱网。
所述防锈底漆由下述重量份的原料配制而成：脂肪族聚氨酯丙烯酸酯20，甲基丙烯酸酯10，异氰酸酯类固化剂0.5，纳米二氧化钛0.1。
所述涂胶涂料由下述重量份的原料配制而成：环氧树脂40，聚酯树脂30，环氧大豆油2，T105固化剂1，炭黑1，氢氧化镁0.3，纳米碳酸钙0.2，降粘剂0.3，亚甲基二萘硫磺钠0.1。
上述制作的样品的耐腐蚀性能测试方法：
将上述制得的样品置于质量浓度为20％的FeCl3溶液中，浸泡温度为30℃，浸泡时间为3h，测试腐蚀率，腐蚀率(％)＝(腐蚀前重量-腐蚀后重量)/腐蚀前重量×100％，同时按照GB/T1865-2009测试方法对上述制得的样品进行人工加速耐候性(II)检测。
测试结果如下：
通过上述实施例1-3与对比例的耐盐雾测试、人工加速耐候性(II)检测结果可知，在涂层成分相同的情况下，经过本发明工艺进行处理的不锈钢网，其耐腐蚀性、人工加速耐候性(II)能远高于常规处理的不锈钢网，由此可见本发明的工艺制作的不锈钢丝金刚纱网具有很好耐腐蚀性和耐候性。

Claims (8)

1.一种不锈钢丝双涂层金刚纱网的制作方法，其特征在于，包括以下步骤：
(1)用钢丝织造机对不锈钢丝进行织造，得到不锈钢丝网；
(2)将步骤(1)得到的不锈钢丝网经过除油、清洗，然后浸泡在刻蚀液中于30-60℃刻蚀15-30min，取出后用水清洗干净，烘干；
(3)将步骤(2)处理后的不锈钢丝网浸泡在钝化液中于常温钝化10-15min，取出后用水洗净、烘干；
(4)将步骤(3)处理后的不锈钢丝网浸泡在硅烷偶联剂的乙醇溶液中于常温改性处理5-10min，取出后于110-120℃保温处理10-15min；
(5)将防锈底漆分4-6次均匀喷涂在步骤(4)处理后的不锈钢丝网上，然后送入烘烤室中于140-160℃烘烤20-30min，取出后冷却，在不锈钢丝网表面形成厚度为10-20μm的漆膜；
(6)将涂胶涂料分2-3次均匀喷涂在步骤(5)处理后的不锈钢丝网上，然后送入烘烤室中于130-140℃烘烤15-25min，取出后冷却，在不锈钢丝网表面形成厚度为30-50μm的涂膜，得到不锈钢丝双涂层金刚纱网。
2.根据权利要求1所述的一种不锈钢丝双涂层金刚纱网的制作方法，其特征在于，所述刻蚀液由下述重量份的原料配制而成：三氯化铁10-15，盐酸5-10，水1000-1500。
3.根据权利要求1所述的一种不锈钢丝双涂层金刚纱网的制作方法，其特征在于，所述钝化液由下述重量份的原料配制而成：柠檬酸10-15，双氧水5-10，氟化钠5-10，硫脲1-2，硝酸铈1-2，水1000-1500。
4.根据权利要求1所述的一种不锈钢丝双涂层金刚纱网的制作方法，其特征在于，所述硅烷偶联剂的乙醇溶液的浓度为5-10g/L。
5.根据权利要求1所述的一种不锈钢丝双涂层金刚纱网的制作方法，其特征在于，所述防锈底漆由下述重量份的原料配制而成：脂肪族聚氨酯丙烯酸酯20-30，甲基丙烯酸酯10-15，异氰酸酯类固化剂0.5-1，纳米二氧化钛0.1-0.2。
6.根据权利要求1所述的一种不锈钢丝双涂层金刚纱网的制作方法，其特征在于，所述涂胶涂料由下述重量份的原料配制而成：环氧树脂40-50，聚酯树脂30-40，环氧大豆油2-4，T105固化剂1-2，炭黑1-2，氢氧化镁0.3-0.5，纳米碳酸钙0.2-0.4，降粘剂0.2-0.4，亚甲基二萘硫磺钠0.1-0.2。
7.根据权利要求1所述的一种不锈钢丝双涂层金刚纱网的制作方法，其特征在于：所述的不锈钢丝为304不锈钢丝。
8.权利要求1-7任一项所述的不锈钢丝双涂层金刚纱网的制作方法制作的双涂层金刚纱网。
CN201811556749.9A 2018-12-19 2018-12-19 一种不锈钢丝双涂层金刚纱网及其制作方法 Withdrawn CN109627964A (zh)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811556749.9A CN109627964A (zh) 2018-12-19 2018-12-19 一种不锈钢丝双涂层金刚纱网及其制作方法

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811556749.9A CN109627964A (zh) 2018-12-19 2018-12-19 一种不锈钢丝双涂层金刚纱网及其制作方法

Publications (1)

Publication Number Publication Date
CN109627964A true CN109627964A (zh) 2019-04-16

Family

ID=66075496

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811556749.9A Withdrawn CN109627964A (zh) 2018-12-19 2018-12-19 一种不锈钢丝双涂层金刚纱网及其制作方法

Country Status (1)

Country Link
CN (1) CN109627964A (zh)

Cited By (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110923882A (zh) * 2019-12-06 2020-03-27 利辛县富亚纱网有限公司 一种纱窗用金属纱线及其生产设备
CN111229996A (zh) * 2020-03-09 2020-06-05 萧县金科电工线材有限公司 一种双涂层不锈钢金钢网及其制作方法
CN111455366A (zh) * 2020-04-03 2020-07-28 贵州水钢同鑫晟金属制品有限公司 一种改性无磷无硼镀膜剂及其制备方法
CN112295878A (zh) * 2020-09-11 2021-02-02 安徽和邦纺织科技有限公司 一种纱网生产工艺
CN113231289A (zh) * 2021-05-12 2021-08-10 浦江三思光电技术有限公司 用于灯具结构件的喷塑方法及系统
CN114054646A (zh) * 2021-11-08 2022-02-18 河北艾林建材有限公司 高透光丝网的织造系统和工艺及丝网
CN115627468A (zh) * 2022-10-14 2023-01-20 广东冀安筛网有限公司 一种不锈钢丝网的制备方法

Cited By (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110923882A (zh) * 2019-12-06 2020-03-27 利辛县富亚纱网有限公司 一种纱窗用金属纱线及其生产设备
CN111229996A (zh) * 2020-03-09 2020-06-05 萧县金科电工线材有限公司 一种双涂层不锈钢金钢网及其制作方法
CN111455366A (zh) * 2020-04-03 2020-07-28 贵州水钢同鑫晟金属制品有限公司 一种改性无磷无硼镀膜剂及其制备方法
CN112295878A (zh) * 2020-09-11 2021-02-02 安徽和邦纺织科技有限公司 一种纱网生产工艺
CN113231289A (zh) * 2021-05-12 2021-08-10 浦江三思光电技术有限公司 用于灯具结构件的喷塑方法及系统
CN114054646A (zh) * 2021-11-08 2022-02-18 河北艾林建材有限公司 高透光丝网的织造系统和工艺及丝网
CN114054646B (zh) * 2021-11-08 2024-03-26 河北艾林建材有限公司 高透光丝网的织造系统和工艺及丝网
CN115627468A (zh) * 2022-10-14 2023-01-20 广东冀安筛网有限公司 一种不锈钢丝网的制备方法

Similar Documents

Publication Publication Date Title
CN109627964A (zh) 一种不锈钢丝双涂层金刚纱网及其制作方法
CN107755228A (zh) 一种在铝合金基体表面上制备超疏水和疏油表面的方法
CN111229996A (zh) 一种双涂层不锈钢金钢网及其制作方法
CN102942845A (zh) 金属表面的防腐流程
CN101736348B (zh) 一种对耐海洋气候的工程零件进行表面活化处理的方法
CN105296910A (zh) 一种输变电角钢塔的角钢表面喷涂工艺
CN102964994A (zh) 防腐涂料的涂覆方案
CN102942858A (zh) 一种金属表面的防腐流程
CN102965007A (zh) 金属表面的防腐方案
CN103013330A (zh) 金属结构无芳烃防腐方法
CN102964992A (zh) 防腐涂料涂覆方案
CN102964991A (zh) 金属表面无芳烃防腐流程
CN103214938A (zh) 一种防腐涂料的涂覆方法
CN103214884A (zh) 防腐涂料的涂覆工艺
CN102993801A (zh) 一种防腐涂料的涂覆方法
CN102965001A (zh) 金属表面防腐流程
CN102964995A (zh) 金属结构防腐方案
CN102964999A (zh) 金属表面防腐方案
CN114752927A (zh) 一种耐候漆膜保护层铝制品及其表面处理方法
CN112916359A (zh) 一种铁艺护栏纳米喷涂工艺
CN102993944A (zh) 无芳烃防腐涂料涂覆方法
CN102964984A (zh) 一种金属表面防腐流程
CN102993957A (zh) 一种金属结构的无芳烃防腐方案
CN103045087A (zh) 防腐涂料的涂覆过程
CN102965009A (zh) 一种金属结构的无芳烃防腐流程

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20190416