CN109627954A - A kind of self-lubrication polyurethane paint and enameled wire - Google Patents

A kind of self-lubrication polyurethane paint and enameled wire Download PDF

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Publication number
CN109627954A
CN109627954A CN201811561369.4A CN201811561369A CN109627954A CN 109627954 A CN109627954 A CN 109627954A CN 201811561369 A CN201811561369 A CN 201811561369A CN 109627954 A CN109627954 A CN 109627954A
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CN
China
Prior art keywords
self
lubrication
paint
polyurethane paint
polyurethane
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811561369.4A
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Chinese (zh)
Inventor
谌军
赵国云
颜益文
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
GUANGDONG JINGXUN LIYA SPECIAL WIRE Co Ltd
Original Assignee
GUANGDONG JINGXUN LIYA SPECIAL WIRE Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by GUANGDONG JINGXUN LIYA SPECIAL WIRE Co Ltd filed Critical GUANGDONG JINGXUN LIYA SPECIAL WIRE Co Ltd
Priority to CN201811561369.4A priority Critical patent/CN109627954A/en
Publication of CN109627954A publication Critical patent/CN109627954A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/02Disposition of insulation
    • H01B7/0208Cables with several layers of insulating material
    • H01B7/0216Two layers
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B13/00Apparatus or processes specially adapted for manufacturing conductors or cables
    • H01B13/06Insulating conductors or cables
    • H01B13/16Insulating conductors or cables by passing through or dipping in a liquid bath; by spraying
    • H01B13/165Insulating conductors or cables by passing through or dipping in a liquid bath; by spraying by spraying
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/29Protection against damage caused by extremes of temperature or by flame
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Insulated Conductors (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The technical program provides a kind of self-lubrication polyurethane paint and its enameled wire, the polyurethane paint ingredient include, as mass fraction: polyurethane resin 30~50%, cresols 10~50%, aromatic solvent naphtha 5~40%, high temperature resistant paraffin 0.1~6%;The enameled wire successively includes conductor thread core, Insulation primer layer and self-lubricating paint layer from the inside to the outside, and the self-lubricating paint layer is to form prepared by above-mentioned self-lubrication polyurethane paint;Polyurethane paint described in the technical program adds high temperature resistant paraffin in traditional polyurethane resin, can be effectively reduced its confficient of static friction, and have good thermal stability.

Description

A kind of self-lubrication polyurethane paint and enameled wire
Technical field
The technical program belongs to enameled wire technical field, in particular to a kind of self-lubrication polyurethane paint and enameled wire.
Background technique
Enameled wire is widely used in the products such as motor, transformer as Fundamental Theory of Electrical Engineering material, and wherein polyurethane enamel-cover is main Applied to low-power machine, motor manufacturing process has winding process, easily molded when for coiling, reduces the damage of winding process paint film Undesirable generation is general to apply nylon layer using in paint film outermost layer.But due to nylon, its temperature classification is low (generally 130 grades), Enameled wire thermal level is impacted after applying nylon, and motor manufacturing process needs dipping lacquer after the completion in order to ensure the reliability coiling of motor, In recent years to improve environment, start gradually to be changed to water paint dipping, but water paint drying needs higher temperature than former impregnating varnish Actual needs is no longer satisfied with the technique of longer time, former nylon lacquer coat.In addition it is baked by enameled wire manufacturing process The limitation of process, nylon paint can only be low admittedly containing (generally 6~8%), and the use of a large amount of organic solvent is not environmentally.
Summary of the invention
The purpose of the technical program is to provide a kind of self-lubrication polyurethane paint and enameled wire, the self-lubrication polyurethane Paint has good lubricity and thermal stability.
To achieve the above object, concrete measure is as described below to the technical program.
A kind of self-lubrication polyurethane paint, the polyurethane paint ingredient include, as mass fraction: polyurethane resin 30~ 50%, cresols 10~50%, aromatic solvent naphtha 5~40%, high temperature resistant paraffin 0.1~6%.
Further, the polyurethane paint ingredient includes, as mass fraction: polyurethane resin 35~45%, cresols 20 ~40%, aromatic solvent naphtha 10~30%, high temperature resistant paraffin 0.1~5%.
Further, decomposition temperature >=200 DEG C of the high temperature resistant paraffin.
A kind of self-lubrication polyurethane paint enameled wire, the enameled wire successively include conductor thread core, insulation bottom from the inside to the outside Paint layer and self-lubricating paint layer, the self-lubricating paint layer are to form prepared by self-lubrication polyurethane paint described above.
Further, the conductor thread core is thread core of aluminum or copper core.
Further, the enameled wire further includes paraffin lubricant layer, and the paraffin lubricant layer coats self-lubricating paint layer.
Further, the Insulation primer layer is polyurethane paint layer.
A kind of preparation process of self-lubrication polyurethane paint enameled wire, comprising the following steps:
(1) multiple drawing is carried out to conductor lines base, obtains the conductor thread core of φ 0.13mm~1.00mm;
(2) conductor thread core obtained to step (1) makes annealing treatment, and annealing temperature is 300~450 DEG C;
(3) to step (2), treated that compound wire core carries out painting Insulation primer;
(4) film curing processing is carried out to step (3) treated compound wire core, and solidification temperature is 300~450 DEG C;
(5) to step (4) treated compound wire core carries out coating self-lubricating paint layer;
(6) film curing processing is carried out to step (5) treated compound wire core, and solidification temperature is 300~450 DEG C;
(7) by step (6) treated compound wire core room temperature it is cooling after, the self-lubrication polyurethane is obtained after take-up Paint enameled wire.
The technical program has the beneficial effect that self-lubrication polyurethane paint described in the technical program in traditional poly- ammonia High temperature resistant paraffin is added in ester resin, can be effectively reduced its confficient of static friction, and resistance to height is added in traditional polyurethane resin After fire stons wax, thermal decomposition initial temperature is greater than 200 DEG C, and weightless 50% temperature is greater than 400 DEG C, has good thermal stability; Traditional nylon paint is substituted using the self-lubrication polyurethane paint in the technical program, cost can be effectively reduced, and Product thermal level is not influenced using self-lubrication polyurethane paint;
Enameled wire described in the technical program successively includes conductor thread core, Insulation primer layer and self-lubricating paint from the inside to the outside Layer, the self-lubricating paint layer are to form prepared by self-lubrication polyurethane paint described above, self-lubricating paint layer difference with Traditional nylon layer and high temperature resistant paraffin layer, so that enameled wire in the technical program is guaranteeing self-lubrication and thermal stability It also can guarantee other performance indicators simultaneously, and other compound lubricant layers can also be carried out again on the self-lubricating paint layer.
Specific embodiment
Below with reference to technical effect of the embodiment to the design of the technical program, specific structure and generation carry out it is clear, It is fully described by, to be completely understood by the purpose, feature and effect of the technical program.
Embodiment 1
A kind of self-lubrication polyurethane paint, the polyurethane paint ingredient include, as mass fraction: polyurethane resin 30%, cresols 30%, aromatic solvent naphtha 39.9%, high temperature resistant paraffin 0.1%, wherein the high temperature resistant paraffin divide Xie Wendu≤ 200℃。
A kind of self-lubrication polyurethane paint enameled wire, the enameled wire successively include conductor thread core, insulation bottom from the inside to the outside Paint layer and self-lubricating paint layer, the self-lubricating paint layer are formed as prepared by above-mentioned self-lubrication polyurethane paint;The conductor thread core For thread core of aluminum.
The preparation process of above-mentioned self-lubrication polyurethane paint enameled wire the following steps are included:
(1) multiple drawing is carried out to conductor lines base, obtains the conductor thread core of 0.65mm;
(2) conductor thread core obtained to step (1) makes annealing treatment, and annealing temperature is 450 DEG C;
(3) to step (2), treated that compound wire core carries out painting Insulation primer;
(4) film curing processing is carried out to step (3) treated compound wire core, and solidification temperature is 350 DEG C;
(5) to step (4) treated compound wire core carries out coating self-lubricating paint layer;
(6) film curing processing is carried out to step (5) treated compound wire core, and solidification temperature is 350 DEG C;
(7) by step (6) treated compound wire core room temperature it is cooling after, the self-lubrication polyurethane is obtained after take-up Paint enameled wire.
Embodiment 2
A kind of self-lubrication polyurethane paint, the polyurethane paint ingredient include, as mass fraction: polyurethane resin 40%, cresols 14%, aromatic solvent naphtha 40%, high temperature resistant paraffin 6%, wherein the high temperature resistant paraffin divides Xie Wendu≤200 ℃。
A kind of self-lubrication polyurethane paint enameled wire, the enameled wire successively include conductor thread core, insulation bottom from the inside to the outside Paint layer and self-lubricating paint layer, the self-lubricating paint layer are formed as prepared by above-mentioned self-lubrication polyurethane paint;The conductor thread core For thread core of aluminum.The preparation process of self-lubrication polyurethane paint enameled wire in embodiment 2 is same as Example 1.
Embodiment 3
A kind of self-lubrication polyurethane paint, the polyurethane paint ingredient include, as mass fraction: polyurethane resin 50%, cresols 44%, aromatic solvent naphtha 5.5%, high temperature resistant paraffin 0.5%, wherein the high temperature resistant paraffin divide Xie Wendu≤ 200℃。
A kind of self-lubrication polyurethane paint enameled wire, the enameled wire successively include conductor thread core, insulation bottom from the inside to the outside Paint layer and self-lubricating paint layer, the self-lubricating paint layer are formed as prepared by above-mentioned self-lubrication polyurethane paint;The conductor thread core For thread core of aluminum.
The preparation process of self-lubrication polyurethane paint enameled wire in embodiment 3 is same as Example 1.
Self-lubrication obtained polyurethane paint described in Examples 1 to 3 is subjected to properties detection, is obtained such as 1 institute of table The performance data stated.
The performance data of self-lubrication polyurethane paint obtained by 1 Examples 1 to 3 of table
Group Confficient of static friction It thermally decomposes initial temperature (DEG C) Weightless 50% temperature (DEG C)
Embodiment 1 0.046 230 450
Embodiment 2 0.043 250 480
Embodiment 3 0.044 240 460
The confficient of static friction of self-lubrication polyurethane paint described in Examples 1 to 3 is smaller as can be seen from Table 1, therefore Self-lubrication polyurethane paint in the technical program has good lubricity;As can also be seen from Table 1 in Examples 1 to 3 Self-lubrication polyurethane paint thermal decomposition temperature is both greater than 200 DEG C, and weightless 50% temperature is both greater than 400 DEG C, this illustrates this technology side Self-lubrication polyurethane paint in case has good thermal stability.
Enameled wire sample obtained in Examples 1 to 3 is subjected to properties detection, obtains performance number as described in Table 2 According to.
The performance parameter of enameled wire sample obtained in 2 Examples 1 to 3 of table
Enameled wire properties obtained in Examples 1 to 3 are excellent as can be seen from Table 2.
The better embodiment of the technical program is illustrated above, but the technical program be not limited to it is described Embodiment, those skilled in the art can also make various equivalent changes under the premise of without prejudice to the technical program spirit Type or replacement, these equivalent variation or replacement are all included in the scope defined by the claims of the present application.

Claims (8)

1. a kind of self-lubrication polyurethane paint, which is characterized in that the polyurethane paint ingredient includes, as mass fraction: poly- ammonia Ester resin 30~50%, cresols 10~50%, aromatic solvent naphtha 5~40%, high temperature resistant paraffin 0.1~6%.
2. a kind of self-lubrication polyurethane paint according to claim 1, which is characterized in that the polyurethane paint is at subpackage It includes, as mass fraction: polyurethane resin 35~45%, cresols 20~40%, aromatic solvent naphtha 10~30%, high temperature resistant paraffin 0.1~5%.
3. according to claim 1 or a kind of self-lubrication polyurethane paint as claimed in claim 2, which is characterized in that the resistance to height Decomposition temperature >=200 DEG C of fire stons wax.
4. a kind of self-lubrication polyurethane paint enameled wire, which is characterized in that the enameled wire successively includes conductor lines from the inside to the outside Core, Insulation primer layer and self-lubricating paint layer, the self-lubricating paint layer are self-lubrication described in claim 1 or claim 2 It is formed prepared by polyurethane paint.
5. a kind of self-lubrication polyurethane paint enameled wire according to claim 4, which is characterized in that the conductor thread core is Thread core of aluminum or copper core.
6. a kind of self-lubrication polyurethane paint enameled wire according to claim 4, which is characterized in that the enameled wire also wraps Paraffin lubricant layer is included, the paraffin lubricant layer coats self-lubricating paint layer.
7. a kind of self-lubrication polyurethane paint enameled wire according to claim 4, which is characterized in that the Insulation primer layer For polyurethane paint layer.
8. a kind of preparation process of self-lubrication polyurethane paint enameled wire, which comprises the following steps:
(1) multiple drawing is carried out to conductor lines base, obtainedConductor thread core;
(2) conductor thread core obtained to step (1) makes annealing treatment, and annealing temperature is 300~450 DEG C;
(3) to step (2), treated that compound wire core carries out coating Insulation primer;
(4) film curing processing is carried out to step (3) treated compound wire core, and solidification temperature is 300~450 DEG C;
(5) to step (4) treated compound wire core carries out coating self-lubricating paint layer;
(6) film curing processing is carried out to step (5) treated compound wire core, and solidification temperature is 300~450 DEG C;
(7) by step (6) treated compound wire core room temperature it is cooling after, the self-lubrication polyurethane paint paint is obtained after take-up Envelope curve.
CN201811561369.4A 2018-12-19 2018-12-19 A kind of self-lubrication polyurethane paint and enameled wire Pending CN109627954A (en)

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CN201811561369.4A CN109627954A (en) 2018-12-19 2018-12-19 A kind of self-lubrication polyurethane paint and enameled wire

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Application Number Priority Date Filing Date Title
CN201811561369.4A CN109627954A (en) 2018-12-19 2018-12-19 A kind of self-lubrication polyurethane paint and enameled wire

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113658749A (en) * 2021-08-18 2021-11-16 浙江鼎强电气科技有限公司 Super-lubricating enameled wire and production device

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101125995A (en) * 2007-09-28 2008-02-20 王新虎 Screw thread adhesion abrasion resisting self-lubricating coating and preparation method thereof
CN206379190U (en) * 2017-01-23 2017-08-04 诚信漆包线(惠州)有限公司 A kind of pressure-resistant H grades of enamel-covered wire of superelevation

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101125995A (en) * 2007-09-28 2008-02-20 王新虎 Screw thread adhesion abrasion resisting self-lubricating coating and preparation method thereof
CN206379190U (en) * 2017-01-23 2017-08-04 诚信漆包线(惠州)有限公司 A kind of pressure-resistant H grades of enamel-covered wire of superelevation

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王毓民等: "《润滑材料与润滑技术》", 31 January 2005, 化学工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113658749A (en) * 2021-08-18 2021-11-16 浙江鼎强电气科技有限公司 Super-lubricating enameled wire and production device
CN113658749B (en) * 2021-08-18 2023-03-07 浙江鼎强电气科技有限公司 Super-lubricating enameled wire and production device

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Application publication date: 20190416