CN113707370A - Self-adhesive enameled wire and production process thereof - Google Patents
Self-adhesive enameled wire and production process thereof Download PDFInfo
- Publication number
- CN113707370A CN113707370A CN202110972385.8A CN202110972385A CN113707370A CN 113707370 A CN113707370 A CN 113707370A CN 202110972385 A CN202110972385 A CN 202110972385A CN 113707370 A CN113707370 A CN 113707370A
- Authority
- CN
- China
- Prior art keywords
- parts
- self
- adhesive
- enameled wire
- wire
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Images
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/02—Disposition of insulation
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D161/00—Coating compositions based on condensation polymers of aldehydes or ketones; Coating compositions based on derivatives of such polymers
- C09D161/04—Condensation polymers of aldehydes or ketones with phenols only
- C09D161/06—Condensation polymers of aldehydes or ketones with phenols only of aldehydes with phenols
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D191/00—Coating compositions based on oils, fats or waxes; Coating compositions based on derivatives thereof
- C09D191/005—Drying oils
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
- H01B13/06—Insulating conductors or cables
- H01B13/065—Insulating conductors with lacquers or enamels
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
- H01B13/06—Insulating conductors or cables
- H01B13/16—Insulating conductors or cables by passing through or dipping in a liquid bath; by spraying
- H01B13/165—Insulating conductors or cables by passing through or dipping in a liquid bath; by spraying by spraying
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B13/00—Apparatus or processes specially adapted for manufacturing conductors or cables
- H01B13/30—Drying; Impregnating
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/28—Protection against damage caused by moisture, corrosion, chemical attack or weather
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2296—Oxides; Hydroxides of metals of zinc
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02A—TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
- Y02A30/00—Adapting or protecting infrastructure or their operation
- Y02A30/14—Extreme weather resilient electric power supply systems, e.g. strengthening power lines or underground power cables
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Manufacturing & Machinery (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a self-adhesive enameled wire, wherein a self-adhesive paint layer is arranged on the surface of a conductor wire core, and the self-adhesive paint layer comprises the following components in parts by mass: phenolic resin, m-cresol, glycerol, carbon black, polyamide resin, dimethylbenzene, polymethacrylate, No. 200 solvent gasoline and the like, and also provides a production process of the self-adhesive enameled wire. The self-adhesive paint provided by the invention has good insulativity and oil resistance, has good adhesive force to copper wires, enriches the functions of paint, and has stronger scratch resistance and better smoothness on the surface compared with the existing common self-adhesive enameled wire, so that the self-adhesive enameled wire is closer to the requirements of the modern motor industry on the enameled wire; in addition, the steps of paying off, annealing, painting and the like are provided, and the surface of the conductor wire core is coated with a plurality of layers of self-adhesive paints through repeating the steps of painting, baking, cooling and the like, so that the enameled wire with better performance is obtained.
Description
Technical Field
The invention belongs to the technical field of self-adhesive enameled wires, and particularly relates to a self-adhesive enameled wire and a production process thereof.
Background
The enameled wire is a main variety of winding wires and consists of a conductor and an insulating layer, and a bare wire is annealed and softened and then is subjected to painting and baking for multiple times. However, it is not easy to produce a product which meets both the standard requirements and the customer requirements, and it is influenced by the quality of raw materials, process parameters, production equipment, environment and other factors, so that the quality characteristics of various enameled wires are different, but the enameled wires have four properties of mechanical properties, chemical properties, electrical properties and thermal properties. The enameled wire is a main raw material of products such as motors, electric appliances, household electric appliances and the like, particularly, the continuous and rapid growth of the power industry is realized in recent years, the rapid development of the household electric appliances brings a wider field for the application of the enameled wire, and along with the realization, higher requirements are put forward on the enameled wire. Therefore, the product structure of the enameled wire is inevitably adjusted, and the raw materials (copper and paint), the enameled process, the process equipment, the detection means and the like matched with the enameled wire are also urgently needed to be developed and researched.
The self-adhesive enameled wire is a special enameled wire, and the manufacturing of the coil is simple and convenient due to the special processing performance of the self-adhesive enameled wire. Wound coils are heat treated or solvent treated to form a coil by adhesion, and are therefore favored for use in the manufacture of various electromagnetic coils of complex shape or without a bobbin. The application of the self-adhesive enameled wire brings remarkable social and economic benefits, can simplify coil forming process, improve work efficiency, save energy, improve environmental pollution and is beneficial to industrial production. At present, the motor manufacturing industry generally adopts high-speed automatic winding equipment to wind a motor coil, so that high requirements are provided for various mechanical properties of an enameled wire, and the high-speed automatic winding equipment requires that the enameled wire has certain mechanical strength, and the surface of the enameled wire has high wear resistance, high scraping resistance and high smoothness. The conventional enameled wire can not meet the requirement, and a self-adhesive enameled wire and a production process thereof are provided for solving the problems in the prior art.
Disclosure of Invention
The invention aims to provide a self-adhesive enameled wire and a production process thereof, which aim to solve the problems in the prior art in the background technology.
In order to achieve the purpose, the invention adopts the following technical scheme: the self-adhesive enameled wire comprises a conductor wire core, wherein a self-adhesive paint layer is arranged on the surface of the conductor wire core, and the self-adhesive paint layer comprises the following components in parts by mass:
14.5 to 15.5 portions of phenolic resin, 9.5 to 10.5 portions of m-cresol, 4.5 to 5.5 portions of glycerol, 4.5 to 5.5 portions of carbon black, 4.5 to 5.5 portions of polyamide resin, 9.5 to 10.5 portions of dimethylbenzene, 1.5 to 2.5 portions of polymethacrylate, 0.5 to 1.5 portions of methyl silicone oil, 0.5 to 1.5 portions of diaminodiphenyl ether, 14.5 to 15.5 portions of tung oil, 49.5 to 50.5 portions of No. 200 solvent gasoline and 2.5 to 3.5 portions of zinc oxide.
Preferably, the conductor wire core is set to have the purity of more than 99.95 percent,The conductivity is more than 98 percent, and the resistivity of the hard copper is not more than 0.01796 omega mm2The resistivity of the soft copper is not more than 0.017241 omega mm2The wire is an industrial pure copper wire with the elongation of soft copper being not less than 30%, and the diameter of the conductor wire core is 0.3-0.4 mm.
Preferably, the surface of the conductor wire core is provided with at least one self-adhesive paint layer, and the thickness of one self-adhesive paint layer is 0.01mm-0.015 mm.
Preferably, the formula of the self-adhesive paint layer comprises the following components in parts by mass: 14.5 parts of phenolic resin, 9.5 parts of m-cresol, 4.5 parts of glycerol, 4.5 parts of carbon black, 4.5 parts of polyamide resin, 9.5 parts of xylene, 1.5 parts of polymethacrylate, 0.5 part of methyl silicone oil, 0.5 part of diaminodiphenyl ether, 14.5 parts of tung oil, 49.5 parts of No. 200 solvent gasoline and 2.5 parts of zinc oxide.
Preferably, the formula of the self-adhesive paint layer comprises the following components in parts by mass: 15 parts of phenolic resin, 15 parts of m-cresol, 50 parts of glycerol, 3 parts of carbon black, 5 parts of polyamide resin, 5 parts of dimethylbenzene, 10 parts of polymethacrylate, 5 parts of methyl silicone oil, 10 parts of diaminodiphenyl ether, 2 parts of tung oil, 1 part of No. 200 solvent gasoline and 1 part of zinc oxide.
Preferably, the formula of the self-adhesive paint layer comprises the following components in parts by mass: 15.5 parts of phenolic resin, 10.5 parts of m-cresol, 5.5 parts of glycerol, 5.5 parts of carbon black, 5.5 parts of polyamide resin, 10.5 parts of dimethylbenzene, 2.5 parts of polymethacrylate, 1.5 parts of methyl silicone oil, 1.5 parts of diaminodiphenyl ether, 15.5 parts of tung oil, 50.5 parts of No. 200 solvent gasoline and 3.5 parts of zinc oxide.
The invention also provides a production process of the self-adhesive enameled wire, which comprises the following steps:
step S1, paying off, namely, uniformly paying off the copper materials from the iron shaft, providing raw materials and ensuring the stability of painting, and paying off by a combined wire stretcher on a high-speed machine platform;
step S2, annealing, softening the bare copper wire, removing internal stress in the stretching process, rearranging molecular lattices, and enhancing flexibility and conductivity;
step S3, painting, namely, uniformly painting the insulating paint on the bare copper wire by using a mould or a felt as a medium;
s4, baking, namely evaporating the solvent in the coating to solidify the binder into a film to form an insulating layer; after the solvent is evaporated, the solvent is catalyzed by a catalyst and is converted into carbon dioxide and water, and a large amount of heat is released, so that the effects of environmental protection and energy conservation are achieved;
step S5, cooling, wherein after the wire is baked from the furnace, the wire needs to be cooled when the temperature is high;
step S6, lubricating, namely, a layer of lubricating liquid is required to be added to the cooled enameled wire before large coiling, so that friction of wire operation is reduced when a customer uses the enameled wire, and paying-off is convenient;
and step S7, taking up, wherein after the previous working procedures are finished, the enameled wire is formed and is wound on a plastic shaft.
Preferably, the catalyst used in step S4 includes active components (platinum, palladium and compounds thereof) and a carrier (metal mesh, ceramic).
Preferably, the cooling manner of step S5 is air cooling, and the enameled wire baked from the furnace is cooled by blowing with cold air.
Preferably, the painting of step S3 further includes a step of preparing the self-adhesive paint layer according to the formula of each component of the self-adhesive paint layer.
The invention has the technical effects and advantages that: compared with the prior art, the self-adhesive enameled wire and the production process thereof provided by the invention have the following advantages:
the self-adhesive enameled wire provided by the invention is a self-adhesive paint layer prepared from phenolic resin, m-cresol, glycerol, carbon black, polyamide resin and the like, has good insulativity and oil resistance, has good adhesive force on a copper wire, and enriches the function of paint, and compared with the existing common self-adhesive enameled wire, the surface of the self-adhesive enameled wire provided by the invention has stronger scratch resistance and better slip property, so that the self-adhesive enameled wire is closer to the higher requirement of the modern motor industry on the mechanical property of the enameled wire;
in addition, the method comprises the steps of paying off, annealing, painting, baking, cooling, lubricating and taking up, and the multi-layer self-adhesive paint is coated on the surface of the conductor wire core by repeating the steps of painting, baking, cooling and the like, so that the enameled wire with better performance is obtained.
Additional features and advantages of the invention will be set forth in the description which follows, and in part will be obvious from the description, or may be learned by practice of the invention. The objectives and other advantages of the invention will be realized and attained by the structure particularly pointed out in the written description and claims hereof as well as the appended drawings.
Drawings
FIG. 1 is a schematic structural diagram of a self-adhesive enameled wire according to the present invention;
FIG. 2 is a process flow diagram of the self-adhesive enameled wire production process of the present invention.
Detailed Description
The technical solutions in the embodiments of the present invention will be clearly and completely described below with reference to the drawings in the embodiments of the present invention, and it is obvious that the described embodiments are only a part of the embodiments of the present invention, and not all of the embodiments. The specific embodiments described herein are merely illustrative of the invention and do not delimit the invention. All other embodiments, which can be derived by a person skilled in the art from the embodiments given herein without making any creative effort, shall fall within the protection scope of the present invention.
The present invention provides embodiments as shown in figures 1 and 2:
example 1
The self-adhesive enameled wire comprises a conductor wire core, wherein a self-adhesive paint layer is arranged on the surface of the conductor wire core, and the self-adhesive paint layer comprises the following components in parts by mass:
15 parts of phenolic resin, 15 parts of m-cresol, 50 parts of glycerol, 3 parts of carbon black, 5 parts of polyamide resin, 5 parts of dimethylbenzene, 10 parts of polymethacrylate, 5 parts of methyl silicone oil, 10 parts of diaminodiphenyl ether, 2 parts of tung oil, 1 part of No. 200 solvent gasoline and 1 part of zinc oxide.
The conductor wire core is set to have the purity of more than 99.95 percent, the conductivity of more than 98 percent and the resistivity of hard copper of not more than 0.01796 omega mm2M, resistivity of soft copperGreater than 0.017241 omega mm2The wire is an industrial pure copper wire with the elongation of soft copper being not less than 30%, and the diameter of the conductor wire core is 0.3-0.4 mm.
The surface of the conductor wire core is provided with at least one self-adhesive paint layer, and the thickness of one self-adhesive paint layer is 0.01mm-0.015 mm.
The invention also provides a production process of the self-adhesive enameled wire, which comprises the following steps:
step S1, paying off, namely, uniformly paying off the copper materials from the iron shaft, providing raw materials and ensuring the stability of painting, and paying off by a combined wire stretcher on a high-speed machine platform;
step S2, annealing, softening the bare copper wire, removing internal stress in the stretching process, rearranging molecular lattices, and enhancing flexibility and conductivity;
step S3, painting, namely, uniformly painting the insulating paint on the bare copper wire by using a mould or a felt as a medium;
s4, baking, namely evaporating the solvent in the coating to solidify the binder into a film to form an insulating layer; after the solvent is evaporated, the solvent is catalyzed by a catalyst and is converted into carbon dioxide and water, and a large amount of heat is released, so that the effects of environmental protection and energy conservation are achieved;
step S5, cooling, wherein after the wire is baked from the furnace, the wire needs to be cooled when the temperature is high;
step S6, lubricating, namely, a layer of lubricating liquid is required to be added to the cooled enameled wire before large coiling, so that friction of wire operation is reduced when a customer uses the enameled wire, and paying-off is convenient;
and step S7, taking up, wherein after the previous working procedures are finished, the enameled wire is formed and is wound on a plastic shaft.
The catalyst used in step S4 includes active components (platinum, palladium and compounds thereof) and a carrier (metal mesh, ceramic); the cooling mode of the step S5 adopts air cooling, and the enameled wire baked from the furnace is cooled by blowing cold air; the step S3 includes, before painting, a step of preparing the self-adhesive paint layer, which is performed according to the formula of each component of the self-adhesive paint layer.
After the production of the enamel of the enameled wire is finished, the enamel can be measured in different modes, the enameled wire is one of cables, and the specification of the enameled wire is expressed according to the diameter of a bare copper wire (the unit is mm). The measurement of the specification of the enameled wire is actually the measurement of the diameter of the bare copper wire, and is generally used for measuring a micrometer, the accuracy of the micrometer can reach 0.01mm, and the measurement of the specification (wire diameter) of the enameled wire has a direct measurement method and an indirect measurement method.
Direct measurement: the direct measurement method is to directly measure the diameter of a bare copper wire, and needs to burn off the coat of the enameled wire and adopt a fire burning method. The wire diameter of the enameled wire used by the rotor of the series motor for the electric tool is very small, and the enameled wire needs to be burnt for a plurality of times in a short time when burnt by fire, otherwise the enameled wire can be burnt out and the efficiency is influenced. Wiping the burnt enamel leather clean by cloth after burning, and measuring the diameter of a bare copper wire by a micrometer, wherein the diameter of the bare copper wire is the specification of the enameled wire; the enamel coating of the enameled wire can be an alcohol lamp or a candle.
Indirect measurement method: the indirect measurement method is to measure the diameter of the outer circle of the enameled copper wire (containing the enamel coating) and then obtain data according to the diameter of the outer circle of the enameled copper wire (containing the enamel coating). The method does not need to burn the enamel coating of the enameled wire, and has high efficiency. If the specific type of the enameled copper wire can be known, the specification (wire diameter) of the enameled wire is checked more accurately.
No matter which method is adopted, the wire is straightened before measurement and then measurement is carried out, so that the measurement accuracy is ensured. When the difference of the 3 times of measurement data is large, the wire may not be straightened; direct measurement is generally used for measurement of old wires (removed from burnt windings), and indirect measurement is generally used for measurement of new windings, which is convenient and fast.
Example 2
Different from the embodiment 1, the formula of the self-adhesive paint layer comprises the following components in parts by weight: 14.5 parts of phenolic resin, 9.5 parts of m-cresol, 4.5 parts of glycerol, 4.5 parts of carbon black, 4.5 parts of polyamide resin, 9.5 parts of xylene, 1.5 parts of polymethacrylate, 0.5 part of methyl silicone oil, 0.5 part of diaminodiphenyl ether, 14.5 parts of tung oil, 49.5 parts of No. 200 solvent gasoline and 2.5 parts of zinc oxide.
Example 3
Different from the embodiment 1, the formula of the self-adhesive paint layer comprises the following components in parts by weight: 15.5 parts of phenolic resin, 10.5 parts of m-cresol, 5.5 parts of glycerol, 5.5 parts of carbon black, 5.5 parts of polyamide resin, 10.5 parts of dimethylbenzene, 2.5 parts of polymethacrylate, 1.5 parts of methyl silicone oil, 1.5 parts of diaminodiphenyl ether, 15.5 parts of tung oil, 50.5 parts of No. 200 solvent gasoline and 3.5 parts of zinc oxide.
The component proportions for examples 1-3 are shown in the following table:
in summary, the following steps: the self-adhesive enameled wire provided by the invention is a self-adhesive paint layer prepared from phenolic resin, m-cresol, glycerol, carbon black, polyamide resin and the like, has good insulativity and oil resistance, has good adhesive force on a copper wire, and enriches the function of paint, and compared with the existing common self-adhesive enameled wire, the surface of the self-adhesive enameled wire provided by the invention has stronger scratch resistance and better slip property, so that the self-adhesive enameled wire is closer to the higher requirement of the modern motor industry on the mechanical property of the enameled wire; in addition, the method comprises the steps of paying off, annealing, painting, baking, cooling, lubricating and taking up, and the multi-layer self-adhesive paint is coated on the surface of the conductor wire core by repeating the steps of painting, baking, cooling and the like, so that the enameled wire with better performance is obtained.
Finally, it should be noted that: although the present invention has been described in detail with reference to the foregoing embodiments, it will be apparent to those skilled in the art that modifications may be made to the embodiments or portions thereof without departing from the spirit and scope of the invention.
Claims (10)
1. The self-adhesive enameled wire comprises a conductor wire core and is characterized in that a self-adhesive paint layer is arranged on the surface of the conductor wire core, and the self-adhesive paint layer comprises the following components in parts by mass:
14.5 to 15.5 portions of phenolic resin, 9.5 to 10.5 portions of m-cresol, 4.5 to 5.5 portions of glycerol, 4.5 to 5.5 portions of carbon black, 4.5 to 5.5 portions of polyamide resin, 9.5 to 10.5 portions of dimethylbenzene, 1.5 to 2.5 portions of polymethacrylate, 0.5 to 1.5 portions of methyl silicone oil, 0.5 to 1.5 portions of diaminodiphenyl ether, 14.5 to 15.5 portions of tung oil, 49.5 to 50.5 portions of No. 200 solvent gasoline and 2.5 to 3.5 portions of zinc oxide.
2. The self-adhesive enameled wire according to claim 1, characterized in that: the conductor wire core is set to have the purity of more than 99.95 percent, the conductivity of more than 98 percent and the resistivity of hard copper of not more than 0.01796 omega mm2The resistivity of the soft copper is not more than 0.017241 omega mm2The wire is an industrial pure copper wire with the elongation of soft copper being not less than 30%, and the diameter of the conductor wire core is 0.3-0.4 mm.
3. The self-adhesive enameled wire according to claim 2, characterized in that: the surface of the conductor wire core is provided with at least one self-adhesive paint layer, and the thickness of one self-adhesive paint layer is 0.01mm-0.015 mm.
4. The self-adhesive enameled wire according to claim 1, characterized in that: the formula of the self-adhesive paint layer comprises the following components in parts by mass: 14.5 parts of phenolic resin, 9.5 parts of m-cresol, 4.5 parts of glycerol, 4.5 parts of carbon black, 4.5 parts of polyamide resin, 9.5 parts of xylene, 1.5 parts of polymethacrylate, 0.5 part of methyl silicone oil, 0.5 part of diaminodiphenyl ether, 14.5 parts of tung oil, 49.5 parts of No. 200 solvent gasoline and 2.5 parts of zinc oxide.
5. The self-adhesive enameled wire according to claim 1, characterized in that: the formula of the self-adhesive paint layer comprises the following components in parts by mass: 15 parts of phenolic resin, 15 parts of m-cresol, 50 parts of glycerol, 3 parts of carbon black, 5 parts of polyamide resin, 5 parts of dimethylbenzene, 10 parts of polymethacrylate, 5 parts of methyl silicone oil, 10 parts of diaminodiphenyl ether, 2 parts of tung oil, 1 part of No. 200 solvent gasoline and 1 part of zinc oxide.
6. The self-adhesive enameled wire according to claim 1, characterized in that: the formula of the self-adhesive paint layer comprises the following components in parts by mass: 15.5 parts of phenolic resin, 10.5 parts of m-cresol, 5.5 parts of glycerol, 5.5 parts of carbon black, 5.5 parts of polyamide resin, 10.5 parts of dimethylbenzene, 2.5 parts of polymethacrylate, 1.5 parts of methyl silicone oil, 1.5 parts of diaminodiphenyl ether, 15.5 parts of tung oil, 50.5 parts of No. 200 solvent gasoline and 3.5 parts of zinc oxide.
7. The production process of the self-adhesive enameled wire according to claim 1, characterized in that: the method comprises the following steps:
step S1, paying off, namely, uniformly paying off the copper materials from the iron shaft, providing raw materials and ensuring the stability of painting, and paying off by a combined wire stretcher on a high-speed machine platform;
step S2, annealing, softening the bare copper wire, removing internal stress in the stretching process, rearranging molecular lattices, and enhancing flexibility and conductivity;
step S3, painting, namely, uniformly painting the insulating paint on the bare copper wire by using a mould or a felt as a medium;
s4, baking, namely evaporating the solvent in the coating to solidify the binder into a film to form an insulating layer; after the solvent is evaporated, the solvent is catalyzed by a catalyst and is converted into carbon dioxide and water, and a large amount of heat is released, so that the effects of environmental protection and energy conservation are achieved;
step S5, cooling, wherein after the wire is baked from the furnace, the wire needs to be cooled when the temperature is high;
step S6, lubricating, namely, a layer of lubricating liquid is required to be added to the cooled enameled wire before large coiling, so that friction of wire operation is reduced when a customer uses the enameled wire, and paying-off is convenient;
and step S7, taking up, wherein after the previous working procedures are finished, the enameled wire is formed and is wound on a plastic shaft.
8. The production process of the self-adhesive enameled wire according to claim 7, characterized in that: the catalyst used in step S4 includes active components (platinum, palladium, and compounds thereof) and a carrier (metal mesh, ceramic).
9. The production process of the self-adhesive enameled wire according to claim 7, characterized in that: the cooling manner of the step S5 is air cooling, and the enameled wire baked from the furnace is cooled by blowing cold air.
10. The production process of the self-adhesive enameled wire according to claim 7, characterized in that: the step S3 includes, before painting, a step of preparing the self-adhesive paint layer, which is performed according to the formula of each component of the self-adhesive paint layer.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110972385.8A CN113707370B (en) | 2021-08-24 | 2021-08-24 | Self-adhesive enameled wire and production process thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN202110972385.8A CN113707370B (en) | 2021-08-24 | 2021-08-24 | Self-adhesive enameled wire and production process thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN113707370A true CN113707370A (en) | 2021-11-26 |
| CN113707370B CN113707370B (en) | 2023-10-10 |
Family
ID=78654209
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN202110972385.8A Active CN113707370B (en) | 2021-08-24 | 2021-08-24 | Self-adhesive enameled wire and production process thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN113707370B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116665973A (en) * | 2023-07-27 | 2023-08-29 | 佳腾电业(赣州)股份有限公司 | Self-adhesive insulating ultrafine wire, coil and electric and electronic equipment |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20020058171A (en) * | 2000-12-29 | 2002-07-12 | 조병우 | Vanish compositon and selfbonding enameled copper wire using the same |
| CN102876227A (en) * | 2012-09-18 | 2013-01-16 | 南通东泰新能源设备有限公司 | Wire enamel |
| CN103725185A (en) * | 2013-11-25 | 2014-04-16 | 铜陵天河特种电磁线有限公司 | Wire enamel and preparation method thereof |
| CN103996466A (en) * | 2014-06-05 | 2014-08-20 | 珠海市一致电工有限公司 | Enamel covering method of fine enamel covered wires |
| CN104087153A (en) * | 2014-07-18 | 2014-10-08 | 上海晟然绝缘材料有限公司 | Polyamide enameled wire varnishes with excellent lubricity and preparation method of polyamide enameled wire varnishes |
-
2021
- 2021-08-24 CN CN202110972385.8A patent/CN113707370B/en active Active
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| KR20020058171A (en) * | 2000-12-29 | 2002-07-12 | 조병우 | Vanish compositon and selfbonding enameled copper wire using the same |
| CN102876227A (en) * | 2012-09-18 | 2013-01-16 | 南通东泰新能源设备有限公司 | Wire enamel |
| CN103725185A (en) * | 2013-11-25 | 2014-04-16 | 铜陵天河特种电磁线有限公司 | Wire enamel and preparation method thereof |
| CN103996466A (en) * | 2014-06-05 | 2014-08-20 | 珠海市一致电工有限公司 | Enamel covering method of fine enamel covered wires |
| CN104087153A (en) * | 2014-07-18 | 2014-10-08 | 上海晟然绝缘材料有限公司 | Polyamide enameled wire varnishes with excellent lubricity and preparation method of polyamide enameled wire varnishes |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN116665973A (en) * | 2023-07-27 | 2023-08-29 | 佳腾电业(赣州)股份有限公司 | Self-adhesive insulating ultrafine wire, coil and electric and electronic equipment |
| CN116665973B (en) * | 2023-07-27 | 2023-11-17 | 佳腾电业(赣州)股份有限公司 | Self-adhesive insulating ultrafine wire, coil and electric and electronic equipment |
Also Published As
| Publication number | Publication date |
|---|---|
| CN113707370B (en) | 2023-10-10 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102034570B (en) | Preparation method of glass fiber covered corona-resistant enameled rectangular wire | |
| CN102623084B (en) | Production process of glass-fiber covered enameled rectangular copper wire for electric excitation coil | |
| CN100440387C (en) | Compound paint copper-in-aluminum enameled wire and its manufacturing method | |
| CN108666023A (en) | Flat copper magnet wire of Inverter fed motor and preparation method thereof | |
| CN103514989A (en) | High heat resistance type weldable polyesterimide enameled wire and production method thereof | |
| CN113707370A (en) | Self-adhesive enameled wire and production process thereof | |
| CN111627618B (en) | Production and processing technology of enameled wire for automobile oil-cooled driving motor | |
| CN104112550A (en) | Manufacturing method for aluminum copper alloy enameled wire | |
| CN201336166Y (en) | Polyimide fiberglass enamelled flat wire for stator coil of 10kv high-voltage motor | |
| CN103515031A (en) | Double-coated self-lubricating polyurethane enameled wire production process | |
| CN201611583U (en) | Porous insulating paper belt acetal self-adhesive transposed conductor | |
| CN109637742B (en) | Production process of tensile polyimide coil enameled wire | |
| CN201084473Y (en) | A thermal-bonding composite copper-coated aluminum paint covered wire | |
| CN201378453Y (en) | Self-bonding polyurethane/polyamideimide composite Litz enameled wire | |
| CN111462938B (en) | Copper-coated carbon nano composite flat wire and preparation method thereof | |
| CN203760104U (en) | Glass fiber-covered polyimide film reinforcing mica tape lapped wire | |
| CN202839145U (en) | Enameling machine guide wheel mechanism coated by using heat resistant insulating paper and heat resistant insulating films | |
| CN201413651Y (en) | Self-lubricating double-layer paint film frequency conversion enameled round copper wire | |
| CN110675989A (en) | Preparation method of winding wire for high-performance extra-high voltage power transmission and transformation product | |
| CN218123014U (en) | Corona-resistant enameled rectangular copper wire | |
| CN218957446U (en) | Polyesterimine composite enamelled wire for stator | |
| CN212208949U (en) | 180-grade polyester-imide enameled round copper wire | |
| CN104637580A (en) | High temperature-resisting aluminum electromagnetic wire and manufacturing method thereof | |
| CN203150204U (en) | Polyamide-imide enameled flat copper wire coated with DuPont double-layer paint film | |
| CN219979205U (en) | High-temperature-resistant American gauge enameled wire |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| GR01 | Patent grant |