CN1096276A - With iron, black glaze preparing by industrial offscum that titanium content is high - Google Patents
With iron, black glaze preparing by industrial offscum that titanium content is high Download PDFInfo
- Publication number
- CN1096276A CN1096276A CN94104510A CN94104510A CN1096276A CN 1096276 A CN1096276 A CN 1096276A CN 94104510 A CN94104510 A CN 94104510A CN 94104510 A CN94104510 A CN 94104510A CN 1096276 A CN1096276 A CN 1096276A
- Authority
- CN
- China
- Prior art keywords
- glaze
- iron
- content
- black glaze
- black
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
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Classifications
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02W—CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
- Y02W30/00—Technologies for solid waste management
- Y02W30/50—Reuse, recycling or recovery technologies
- Y02W30/91—Use of waste materials as fillers for mortars or concrete
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- Glass Compositions (AREA)
Abstract
The invention belongs to the glaze technology.
The present invention discloses with iron content, titanium and other transition metal oxide content sum greater than 40% industrial residue with the high black glaze preparing by industrial offscum of ferrotitanium content, mixes additive preparation black glaze formulation.Glaze of the present invention can replace a large amount of at present black glaze that use, and reduces cost: impose on the ceramic surface, can obtain the excellent decoration effect after burning till.
Description
The invention belongs to the glaze technology.
Black glaze always is famous and precious color glaze.Ancient Times in China adopts the high clay of iron-holder to prepare glaze more, burns till under reducing atmosphere.Grasp but firing process is difficult, colour generation is also unstable.In recent years people to have developed and adopted multiple transition metal oxide be the black glaze of tinting material, as Fe
2O
3-Cr
2O
3-Mn
2O
3-Co
2O
3-NiO system, NiO-Mn
2O
3-Fe
2O
3-Cr
2O
3-V
2O
5-Al
2O
3System.Wherein metal oxide is an industrial chemicals, and add-on generally is no less than 10%.Because adopt industrial chemicals, thus glaze cost height, thus limited its use.And the firing temperature of black glaze is also higher, for reducing firing temperature, improves glossiness, adds PbO in the prescription of being everlasting, thereby has limited outlet, and workman's operating environment is degenerated.
The objective of the invention is to develop a kind of cheapness, lead-free black glaze.Glaze of the present invention adopts iron, and the industrial waste that titanium content is high is mixed general clay and other additive, adopts conventional glaze preparation method, preferably makes fritted glaze, can make the black glaze that is colour-stable.Glaze of the present invention is formed: SiO
240%-70%, Al
2O
33.0%-15%, Fe
2O
34.5%-20%, TiO
21.0%-5.0%, Na
2O 7.0%-13%, K
2O 0-10%, CaO 3.0%-7.0%, Cr
2O
30.1%-1.5%, V
2O
50.1%-1.0%, Mn
2O
30.5%-3%, MgO 0-0.5%.
Advantage of the present invention is:
(1) production cost is low, and can remove the environmental pollution that the industrial residue of a large amount of dischargings causes.
(2) firing temperature is low, can burn till fast, saves the energy.
(3) unleaded, solved plumbous volatilization in the sintering process infringement problem and many ceramics of workman's health contacted the lead poisoning problem that causes with food.
Example: tailings: 43%, kaolin: 24%, cullet: 33%.Cullet is crushed to＜powdery of 0.5mm, together enters ball mill with other raw material then, pulp is crossed 100 mesh sieves, press filtration, drying.Dried feed is dropped in the tubular type continuous melting stove, found under 1210 ℃ temperature, glaze makes fritted glaze thus through fully directly falling into the tank quenching after the fusing.100 parts of fritted glazes are packed in the ball mill, add 0.5 part of methylcellulose gum simultaneously, make glaze slip.Glaze slip is imposed on billet surface, under 1090 ℃-1130 ℃, burn till, finally obtain light, pitch-dark glaze.
Claims (4)
1, adds additive and make the black glaze with iron content, titanium industry waste slag, it is characterized in that the percentage composition content of this glaze is: SiO
240%-70%, Al
2O
33.0-15%, Fe
2O
34.5%-20%, TiO
21.0%-5.0%, Na
2O 7.0%-13%, K
2O 0-10%, CaO 3.0%-7.0%, Cr
2O
30.1%-1.5%, V
2O
50.1%-1%, Mn
2O
30.5%-3%, MgO
20-0.5%.
2, as claim 1 described glaze, it is characterized in that its percentage composition content of described industrial residue is: iron, titanium, chromium, manganese, content of vanadium sum are greater than 40%.
3, black glaze as claimed in claim 1 is characterized in that described additive refers to: unselected clay, china clay, potter's clay, refractory mortar, shale, red mud, borax, cullet, water glass, natural mineral or certain industrial residue.
4, as claim 1 described black glaze, it is characterized in that: can be used for making pottery, the decoration of porcelain, coloured glaze, clay, brick and tile, also can be used as frit for porcelain enamel and solar energy absorbing coating.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94104510A CN1096276A (en) | 1994-04-26 | 1994-04-26 | With iron, black glaze preparing by industrial offscum that titanium content is high |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN94104510A CN1096276A (en) | 1994-04-26 | 1994-04-26 | With iron, black glaze preparing by industrial offscum that titanium content is high |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1096276A true CN1096276A (en) | 1994-12-14 |
Family
ID=5031631
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN94104510A Pending CN1096276A (en) | 1994-04-26 | 1994-04-26 | With iron, black glaze preparing by industrial offscum that titanium content is high |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1096276A (en) |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104817270A (en) * | 2015-05-26 | 2015-08-05 | 攀枝花学院 | Enamel black glaze and preparation method thereof |
| CN104909567A (en) * | 2015-05-26 | 2015-09-16 | 攀枝花学院 | Vanadium-titanium enamel glaze material, and preparation method thereof |
| CN104961501A (en) * | 2015-07-29 | 2015-10-07 | 陈文源 | Black glaze prepared by utilizing manganese ore tailing residue as main raw material |
| CN106746669A (en) * | 2016-12-28 | 2017-05-31 | 湖南陶润会文化传播有限公司 | Plus the single-layer back of grain answers glaze and preparation method thereof |
| CN108558360A (en) * | 2018-01-30 | 2018-09-21 | 山东理工大学 | Black Antique Imitation Tiles and preparation method thereof |
| CN114804628A (en) * | 2022-05-09 | 2022-07-29 | 佛山市新亮剑陶瓷科技有限公司 | Black glaze material utilizing vanadium extraction tailings, preparation method and application thereof |
-
1994
- 1994-04-26 CN CN94104510A patent/CN1096276A/en active Pending
Cited By (9)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104817270A (en) * | 2015-05-26 | 2015-08-05 | 攀枝花学院 | Enamel black glaze and preparation method thereof |
| CN104909567A (en) * | 2015-05-26 | 2015-09-16 | 攀枝花学院 | Vanadium-titanium enamel glaze material, and preparation method thereof |
| CN104817270B (en) * | 2015-05-26 | 2017-05-17 | 攀枝花学院 | Enamel black glaze and preparation method thereof |
| CN104909567B (en) * | 2015-05-26 | 2017-10-27 | 攀枝花学院 | Vanadium titanium frit for porcelain enamel and preparation method thereof |
| CN104961501A (en) * | 2015-07-29 | 2015-10-07 | 陈文源 | Black glaze prepared by utilizing manganese ore tailing residue as main raw material |
| CN106746669A (en) * | 2016-12-28 | 2017-05-31 | 湖南陶润会文化传播有限公司 | Plus the single-layer back of grain answers glaze and preparation method thereof |
| CN108558360A (en) * | 2018-01-30 | 2018-09-21 | 山东理工大学 | Black Antique Imitation Tiles and preparation method thereof |
| CN108558360B (en) * | 2018-01-30 | 2021-03-09 | 山东理工大学 | Black archaized brick and preparation method thereof |
| CN114804628A (en) * | 2022-05-09 | 2022-07-29 | 佛山市新亮剑陶瓷科技有限公司 | Black glaze material utilizing vanadium extraction tailings, preparation method and application thereof |
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| C06 | Publication | ||
| PB01 | Publication |