CN109626845A - A kind of enhancing textile size of alkali-free glass fibre - Google Patents
A kind of enhancing textile size of alkali-free glass fibre Download PDFInfo
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- CN109626845A CN109626845A CN201910048479.9A CN201910048479A CN109626845A CN 109626845 A CN109626845 A CN 109626845A CN 201910048479 A CN201910048479 A CN 201910048479A CN 109626845 A CN109626845 A CN 109626845A
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- alkali
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- free glass
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C25/00—Surface treatment of fibres or filaments made from glass, minerals or slags
- C03C25/10—Coating
- C03C25/465—Coatings containing composite materials
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
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- Life Sciences & Earth Sciences (AREA)
- Composite Materials (AREA)
- General Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Organic Chemistry (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of enhancing textile size of alkali-free glass fibre, the component including following parts by weight: cornstarch: 3-5 parts, 1-3 parts of three acidic group glyceride, 0.3-0.8 parts of fatty acid ester, 0.05-0.1 parts of polyoxyethylene poly-oxygen propylene aether, 0.05-0.1 parts of aliphatic acid polyethenoxy amide, 0.1-0.8 parts of softening agent, 0.1-0.4 parts of antistatic agent, 0.2-0.6 parts of modified epoxy, 0.05-0.12 parts of preservative, 0.0005-0.002 parts of defoaming agent, 0.1-0.5 parts of silane coupling agent, 0.08-0.2 parts of PVA.The size has the characteristics that intensity is high, wearability is good and resin impregnated is fast, line density is uniform, filoplume lacks good physical and chemical.
Description
Technical field
The present invention relates to size technical field, in particular to the enhancing Weave type of a kind of alkali-free glass fibre infiltrates
Agent.
Background technique
Enhance Weave type glass fiber infiltration agent continuous glass fibre produced be suitable for enhancing unsaturated polyester resin,
The resins for universal use such as vinylite, epoxy resin.Such continuous glass fibre product has that intensity is high, corrosion-resistant, high temperature resistant, resistance to
Mill property is good, with the features such as resin impregnated is fast, moisture absorption is few, line density is uniform, filoplume is few, heat-resisting, good physical and chemical, therefore have excellent
Good manufacturing property can be used for producing various fiberglass products.Therefore enhancing Weave type glass fiber yarn has wide city
Prospect, can increase the capacity to earn foreign exchange through exports of our company, bring huge economic benefit to enterprise, at the same also make it is domestic this
The processing enterprise of class product enhances the market competitiveness.But the performances such as intensity, the wearability of existing size are not ideal enough.
Summary of the invention
Goal of the invention: it is an object of the present invention to provide a kind of enhancing textile size of alkali-free glass fibre, the present invention
Film forming agent used is converted starch, and the starch granules and slurry viscosity by chemical modification can be effectively controlled,
Function admirable, and starch is nontoxic, thermal decomposition temperature is low, remaining carbon is few after burning, environmental sound.
Technical solution: the present invention provides a kind of enhancing textile size of alkali-free glass fibre, including following weight
The component of number: cornstarch: 3-5 parts, 1-3 parts of three acidic group glyceride, 0.3-0.8 parts of fatty acid ester, polyoxyethylene polyoxy third
0.05-0.1 parts of alkene ether, 0.05-0.1 parts of aliphatic acid polyethenoxy amide, 0.1-0.8 parts of softening agent, antistatic agent 0.1-0.4
Part, 0.2-0.6 parts of modified epoxy, 0.05-0.12 parts of preservative, 0.0005-0.002 parts of defoaming agent, silane coupling agent
0.1-0.5 parts, PVA0.08-0.2 parts.
Further, the enhancing textile size of the alkali-free glass fibre, the component including following parts by weight:
0.9 part of cornstarch, 1.04 parts of three acidic group glyceride, 0.56 part of fatty acid ester, 0.08 part of polyoxyethylene poly-oxygen propylene aether, fat
0.08 part of sour polyoxyethylate amide, 0.4 part of softening agent, 0.24 part of antistatic agent, 0.48 part of modified epoxy, preservative 0.08
Part, 0.001 part of defoaming agent, 0.3 part, PVA0.1 parts of silane coupling agent.
Further, the cornstarch is etherificate amylomaize or cross-linked corn starch.
Further, the softening agent is the reaction product of fatty acid and polyethylene polyamine.
Further, the antistatic agent is cationic/nonionic surfactant.
Further, the preservative is organic nitrogen sulfur compound, formaldehyde.
Further, the defoaming agent is organosiloxane, polyethers and amides.
Further, the silane coupling agent is vinyltriethoxysilane, vinyl trimethylsilane or vinyl
Three (beta-methoxy ethyoxyl) silane.
The utility model has the advantages that the continuous glass fibre that the present invention enhances textile size production has, intensity is high, wearability is good,
With the features such as resin impregnated is fast, line density is uniform, filoplume lacks good physical and chemical, therefore have excellent manufacturing property, and enhance
Weave type glass fiber yarn has vast market prospect.
Specific embodiment
Embodiment 1
The component including following parts by weight: the enhancing textile size of the alkali-free glass fibre of the present embodiment is handed over
Join 0.8 part of cornstarch, 1.04 parts of three acidic group glyceride, 0.56 part of fatty acid ester, 0.08 part of polyoxyethylene poly-oxygen propylene aether, rouge
0.08 part of fat acid polyoxyethylate amide, 0.4 part of softening agent, 0.24 part of cationic surfactant, 0.48 part of modified epoxy,
0.08 part of organic nitrogen sulfur compound, 0.001 part of organosiloxane, 0.3 part, PVA0.1 parts of vinyltriethoxysilane.
Size is prepared by conventional method in above-mentioned formula material, and the size intensity is high, wearability is good and tree
Rouge is impregnated with the features such as fast, line density is uniform, filoplume lacks good physical and chemical.
Embodiment 2
The enhancing textile size of the alkali-free glass fibre of the present embodiment, the component including following parts by weight: ether
Change 3.6 parts of amylomaize, 1.04 parts of three acidic group glyceride, 0.56 part of fatty acid ester, polyoxyethylene poly-oxygen propylene aether
0.08 part, 0.08 part of aliphatic acid polyethenoxy amide, 0.4 part of softening agent, 0.24 part of nonionic surfactant, modified epoxy tree
0.48 part of rouge, 0.08 part of formaldehyde, 0.001 part of organosiloxane, 0.3 part, PVA0.1 parts of vinyltriethoxysilane.
Size is prepared by conventional method in above-mentioned formula material, and the size intensity is high, wearability is good and tree
Rouge is impregnated with the features such as fast, line density is uniform, filoplume lacks good physical and chemical.
Embodiment 3
The component including following parts by weight: the enhancing textile size of the alkali-free glass fibre of the present embodiment is handed over
Join 1 part of cornstarch, 1.04 parts of three acidic group glyceride, 0.56 part of fatty acid ester, 0.08 part of polyoxyethylene poly-oxygen propylene aether, fat
0.08 part of sour polyoxyethylate amide, 0.24 part of cationic surfactant, 0.48 part of modified epoxy, has 0.4 part of softening agent
0.08 part of machine nitrogen sulfur compound, 0.001 part of amides, 0.3 part, PVA0.1 parts of silane coupling agent.
Size is prepared by conventional method in above-mentioned formula material, and the size intensity is high, wearability is good and tree
Rouge is impregnated with the features such as fast, line density is uniform, filoplume lacks good physical and chemical.
Embodiment 4
The enhancing textile size of the alkali-free glass fibre of the present embodiment, the component including following parts by weight: beautiful
Rice starch: 5 parts, 3 parts of three acidic group glyceride, 0.8 part of fatty acid ester, 0.1 part of polyoxyethylene poly-oxygen propylene aether, fatty acid polyoxy second
0.1 part of acrylamide, 0.8 part of softening agent, 0.4 part of cationic surfactant, 0.6 part of modified epoxy, 0.12 part of formaldehyde, acyl
0.002 part of amine, 0.5 part, PVA0.2 parts of vinyl trimethylsilane.
Size is prepared by conventional method in above-mentioned formula material, and the size intensity is high, wearability is good and tree
Rouge is impregnated with the features such as fast, line density is uniform, filoplume lacks good physical and chemical.
Embodiment 5
The enhancing textile size of the alkali-free glass fibre of the present embodiment, the component including following parts by weight: beautiful
Rice starch: 3 parts, 1 part of three acidic group glyceride, 0.3 part of fatty acid ester, 0.05 part of polyoxyethylene poly-oxygen propylene aether, fatty acid polyoxy
0.05 part of ethernamine, 0.1 part of softening agent, 0.1 part of nonionic surfactant, 0.2 part of modified epoxy, organic nitrogen vulcanization
Close 0.05 part of object, 0.0005 part of amides, 0.1 part of vinyl trimethylsilane, 0.08 part of PVA.
Size is prepared by conventional method in above-mentioned formula material, and the size intensity is high, wearability is good and tree
Rouge is impregnated with the features such as fast, line density is uniform, filoplume lacks good physical and chemical.
Embodiment 6
The enhancing textile size of the alkali-free glass fibre of the present embodiment, the component including following parts by weight: beautiful
0.9 part of rice starch, 1.04 parts of three acidic group glyceride, 0.56 part of fatty acid ester, 0.08 part of polyoxyethylene poly-oxygen propylene aether, fatty acid
0.08 part of polyoxyethylate amide, 0.4 part of softening agent, 0.24 part of cationic surfactant, 0.48 part of modified epoxy, formaldehyde
0.08 part, 0.001 part of amides, 0.3 part, PVA0.1 parts of silane of vinyl three (beta-methoxy ethyoxyl).
Size is prepared by conventional method in above-mentioned formula material, and the size intensity is high, wearability is good and tree
Rouge is impregnated with the features such as fast, line density is uniform, filoplume lacks good physical and chemical.
Claims (8)
1. a kind of enhancing textile size of alkali-free glass fibre, it is characterised in that: the component including following parts by weight:
Cornstarch: 3-5 parts, 1-3 parts of three acidic group glyceride, 0.3-0.8 parts of fatty acid ester, polyoxyethylene poly-oxygen propylene aether 0.05-0.1
Part, 0.05-0.1 parts of aliphatic acid polyethenoxy amide, 0.1-0.8 parts of softening agent, 0.1-0.4 parts of antistatic agent, modified epoxy tree
0.2-0.6 parts of rouge, 0.05-0.12 parts of preservative, 0.0005-0.002 parts of defoaming agent, 0.1-0.5 parts of silane coupling agent,
PVA0.08-0.2 parts.
2. the enhancing textile size of alkali-free glass fibre according to claim 1, it is characterised in that: including as follows
The component of parts by weight: 0.9 part of cornstarch, 1.04 parts of three acidic group glyceride, 0.56 part of fatty acid ester, polyoxyethylene polyoxy third
0.08 part of alkene ether, 0.08 part of aliphatic acid polyethenoxy amide, 0.4 part of softening agent, 0.24 part of antistatic agent, modified epoxy
0.48 part, 0.08 part of preservative, 0.001 part of defoaming agent, 0.3 part, PVA0.1 parts of silane coupling agent.
3. the enhancing textile size of alkali-free glass fibre according to claim 1, it is characterised in that: the corn
Starch is etherificate amylomaize or cross-linked corn starch.
4. the enhancing textile size of alkali-free glass fibre according to claim 1, it is characterised in that: the softness
Agent is the reaction product of fatty acid and polyethylene polyamine.
5. the enhancing textile size of alkali-free glass fibre according to claim 1, it is characterised in that: it is described resist it is quiet
Electric agent is cationic/nonionic surfactant.
6. the enhancing textile size of alkali-free glass fibre according to claim 1, it is characterised in that: the anti-corrosion
Agent is organic nitrogen sulfur compound, formaldehyde.
7. the enhancing textile size of alkali-free glass fibre according to claim 1, it is characterised in that: the defoaming
Agent is organosiloxane, polyethers and amides.
8. the enhancing textile size of alkali-free glass fibre according to claim 1, it is characterised in that: the silane
Coupling agent is vinyltriethoxysilane, vinyl trimethylsilane or vinyl three (beta-methoxy ethyoxyl) silane.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910048479.9A CN109626845A (en) | 2019-01-18 | 2019-01-18 | A kind of enhancing textile size of alkali-free glass fibre |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201910048479.9A CN109626845A (en) | 2019-01-18 | 2019-01-18 | A kind of enhancing textile size of alkali-free glass fibre |
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| Publication Number | Publication Date |
|---|---|
| CN109626845A true CN109626845A (en) | 2019-04-16 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201910048479.9A Withdrawn CN109626845A (en) | 2019-01-18 | 2019-01-18 | A kind of enhancing textile size of alkali-free glass fibre |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110305464A (en) * | 2019-07-05 | 2019-10-08 | 天津工业大学 | A kind of continuous nitride silica fibre reinforced resin base composite wire and preparation method thereof |
| CN114592351A (en) * | 2022-03-15 | 2022-06-07 | 无锡市百丝丽纺织有限公司 | Special antistatic cleaning cloth for laboratory |
-
2019
- 2019-01-18 CN CN201910048479.9A patent/CN109626845A/en not_active Withdrawn
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110305464A (en) * | 2019-07-05 | 2019-10-08 | 天津工业大学 | A kind of continuous nitride silica fibre reinforced resin base composite wire and preparation method thereof |
| CN114592351A (en) * | 2022-03-15 | 2022-06-07 | 无锡市百丝丽纺织有限公司 | Special antistatic cleaning cloth for laboratory |
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Application publication date: 20190416 |
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