CN109622332A - A kind of anticorrosion process of steel construction - Google Patents

A kind of anticorrosion process of steel construction Download PDF

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Publication number
CN109622332A
CN109622332A CN201811395820.XA CN201811395820A CN109622332A CN 109622332 A CN109622332 A CN 109622332A CN 201811395820 A CN201811395820 A CN 201811395820A CN 109622332 A CN109622332 A CN 109622332A
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coating
emulsion
steel construction
polyaniline
steel
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刘永飞
马敏
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Huaibei Philippine Environmental Protection Technology Co Ltd
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Huaibei Philippine Environmental Protection Technology Co Ltd
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Priority to CN201811395820.XA priority Critical patent/CN109622332A/en
Publication of CN109622332A publication Critical patent/CN109622332A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D5/00Processes for applying liquids or other fluent materials to surfaces to obtain special surface effects, finishes or structures
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/14Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials to metal, e.g. car bodies
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/24Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials for applying particular liquids or other fluent materials
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D7/00Processes, other than flocking, specially adapted for applying liquids or other fluent materials to particular surfaces or for applying particular liquids or other fluent materials
    • B05D7/50Multilayers
    • B05D7/56Three layers or more
    • B05D7/58No clear coat specified
    • B05D7/584No clear coat specified at least some layers being let to dry, at least partially, before applying the next layer
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D163/00Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/002Priming paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/60Additives non-macromolecular
    • C09D7/61Additives non-macromolecular inorganic
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/65Additives macromolecular
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D7/00Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
    • C09D7/40Additives
    • C09D7/70Additives characterised by shape, e.g. fibres, flakes or microspheres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2202/00Metallic substrate
    • B05D2202/10Metallic substrate based on Fe
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2451/00Type of carrier, type of coating (Multilayers)
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2502/00Acrylic polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2504/00Epoxy polymers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2601/00Inorganic fillers
    • B05D2601/20Inorganic fillers used for non-pigmentation effect
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2601/00Inorganic fillers
    • B05D2601/20Inorganic fillers used for non-pigmentation effect
    • B05D2601/24Titanium dioxide, e.g. rutile
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B05SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05DPROCESSES FOR APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
    • B05D2602/00Organic fillers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2265Oxides; Hydroxides of metals of iron
    • C08K2003/2272Ferric oxide (Fe2O3)
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Wood Science & Technology (AREA)
  • Materials Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Application Of Or Painting With Fluid Materials (AREA)
  • Preventing Corrosion Or Incrustation Of Metals (AREA)
  • Paints Or Removers (AREA)

Abstract

The present invention settles sth. according to policy or law the anticorrosion process of steel construction a kind of, comprising the following steps: the surface preparation of S1, steel construction;S2, steel surface derusting;S3, steel structure aqueous corrosion resisting paint without need of cleaning rust is prepared;The preparation of S4, priming paint;The coating of S5, steel construction;S6, oil paint coating quality inspection and examination.The present invention combines epoxy emulsion with the characteristic of acrylic emulsion, improve the comprehensive performance of coating, Polyaniline emulsion is added directly into coating, solves the problems, such as the stability problem of polyaniline and compatible and preparation the anticorrosive paint of other macromolecule emulsions, the antiseptic property of coating is improved, the acid and active hydrogen in conversion fluid, polyaniline can promote the solidification of epoxy resin, the curing agent as epoxy emulsion, simple process and low cost.The anticorrosion process of steel construction is simple, not only has good antiseptic property, but also easy construction, can mitigate significantly the labor intensity of coating, while having stronger weatherability, can be realized the digital preservation for steel construction.

Description

A kind of anticorrosion process of steel construction
Technical field
The invention belongs to steel structure technology fields, and in particular to a kind of anticorrosion process of steel construction.
Background technique
Anticorrosion with coat is one of important channel of anti-corrosion of metal, in order to obtain excellent anticorrosion ability, is needed to be coated Decorations surface handled, this not only time-consuming, effort, reduce production efficiency, improve construction cost, but also rust dirt can also endanger Human health.Nonetheless, the result of surface treatment may still can not meet coating specification.And on rust paint then just makes up This defect, on rust paint are exactly the antirusting paint that can directly brush on the surface without derusting or simply derusted, the painting Material construction pre-treatment is simple, reduces construction cost, has biggish practical value, on rust paint can be divided by the principle of antirust For osmosis type, four class of transformant, stable type and functional form.Rust-converter coating contains and can chemically react with iron rust Rust transformation can be substance that is stable or having protective effect, so that corrosion layer is become solid and can preferably be attached to by ingredient The substance of steel surface.In the environmentally friendly spring tide that coating industry oil changes water, anticorrosive paint is to be difficult the field captured.Anti-corrosion row Majority is all oil paint in industry, is even more the oil paint almost selected entirely, traditional oiliness anti-corrosion in heavy antisepsis field Coating process is complicated, operating condition is severe, large labor intensity.
For this purpose, it is proposed that a kind of simple process and low cost, so that the water resistance of steel construction coating significantly improves, anti-corrosion The anticorrosion process for the steel construction that performance improves solves the above problems.
Summary of the invention
The purpose of the present invention is to provide a kind of anticorrosion process of steel construction, to solve mentioned above in the background art ask Topic.
To achieve the above object, the invention provides the following technical scheme: a kind of anticorrosion process of steel construction, including following step It is rapid:
The surface preparation of S1, steel construction: use mechanical treatment or chemically treated method, by the burr of steel surface, Welding agent, overlap, splash, dust, loose scale and thicker rusty scale are cleaned out, using lye or organic solvent by steel Greasy dirt, the grease of body structure surface clean up, and after caustic dip, rinse 2-3 times using with clean water, and empty with oil free compression Gas dries up the surface of steel construction;
S2, steel surface derusting: Shot Blasting, derusting grade Sa2.5, roughness are used to the surface of steel structure member It is 40-75 μm;
S3, it prepares steel structure aqueous corrosion resisting paint without need of cleaning rust: taking a certain amount of converting agent of iron rust and Polyaniline emulsion, addition is stirred It mixes and 30-45min is mixed in device, stir evenly, the temperature of stirring is controlled at 50-60 DEG C, is added slowly to a certain amount of It is stirred evenly in epoxy emulsion, acrylic acid composite emulsion and organic solvent ethyl alcohol, then is separately added into coalescing agent, stably dispersing Agent, converting agent of iron rust, defoaming agent and thickener, temperature are controlled at 65-80 DEG C, up on rust paint after stirring 30-50min;
The preparation of S4, priming paint: sequentially added into high speed disperser water, acrylic acid elastic water-proof lotion, styrene-acrylic emulsion with And chlorine partial emulsion, under 3000r/min mixing speed, aluminosilicate fiber cotton and hydroxyethyl ether cellulose dispersion is added in dispersion 30-50min adjusts pH=8 with ammonium hydroxide, adds anticorrosive packing, mica powder, iron oxide red and divided titanium dioxide after mixing evenly Dissipate 40-60min, slurry coating obtained mixed with gypsum slag cement after to get fire safe type anticorrosion of steel structure priming paint;
The coating of S5, steel construction: the steel construction after spraying ball blast passed examination carries out the primer painting in step S4 and makees Industry, primer painting operation are completed in Painting Shop, then carry out the finishing coat coating of on rust paint in step S3, by the spray of steel construction Painting dead angle position just can be carried out large area painting operation after should being first preliminarily sprayed, and apply in primer painting, intermediate coat coating and finishing coat In the technique of dress, when carrying out the coating process of next step, need to dry step by 2-6h before coating process;
S6, oil paint coating quality inspection and examination: after painting layer is dry, reply film thickness measures inspection and closes Lattice, coating surface should uniformly, and color is consistent, the defects of without obvious elephant skin, trickling, blistering, crackle, component surface do not answer holiday, It accidentally applies, coating should not peel, return rust.
Preferably, the clean water used in the step S1 is hot water, and the temperature of the hot water is 40-50 DEG C, to remove Remove the acid, alkali and salt of steel surface.
Preferably, epoxy emulsion described in the step S3 is aqueous epoxy resins, and the Polyaniline emulsion adds for anti-corrosion Add agent, after Polyaniline emulsion is added, the acid in the hydrogen and Polyaniline emulsion in polyaniline can promote epoxy emulsion to solidify, and take on The curing agent of epoxy emulsion increases in addition, the wetting and permeance property of coating can be improved in the emulsifier contained in Polyaniline emulsion The permeance property of coating not only can be improved in the adhesion of strong coating and substrate, the assistant for emulsifying agent ethyl alcohol contained in polyaniline, also Can reduce the drying time of film, polyaniline in coating also mainly rise antisepsis, it metal surface can with passive metal, Mask erosion environment hinders electron transmission, forms hydrophobic adsorbent layer, prevents dirt from adhering to, and it is excellent that this has polyaniline Anti-corrosion effect.
Preferably, epoxy emulsion in the step S3, acrylic acid composite emulsion, Polyaniline emulsion, converting agent of iron rust and The percentage composition of ethyl alcohol is respectively 35%, 25%, 1.2%, 2%, 35%.
Preferably, defoaming agent is silicon oil foam killer in the step S1, and the dispersion stabilizer is polycarboxylic acids metal salt, institute Stating coalescing agent is at least one of alcohol ester and alcohol ether, and the thickener is polyacrylate.
Preferably, in the step S4 when steel surface coating, it should be noted that steel surface situation and atmospheric environment, coating are applied Work must surface temperature be higher than 3 DEG C of dew-point temperature or more, relative humidity carries out in 85% condition below, when steel surface by When rainwater influences, then it not can be carried out coating, oil paint coating place should hang temperature and humidity recorder, for detecting record spraying process In temperature and humidity numerical value.
Preferably, acrylic acid elastic water-proof lotion, mica powder, styrene-acrylic emulsion, titanium dioxide, chlorine are partially newborn in the step S4 Liquid, iron oxide red, aluminosilicate fiber cotton, hydroxyethyl ether cellulose, anticorrosive packing, water and gypsum slag cement mass ratio be 10:10:5:5:4:5:5:5:1:50:66.
Technical effect and advantage of the invention: the anticorrosion process of the steel construction prepares steel structure aqueous corrosion resisting paint without need of cleaning rust It is good with the crosslinking ability of steel construction, have it is nontoxic, tasteless, without organic volatile discharge, pollution-free, without firing risk, construct Safe ready, environmentally protective advantage use aqueous epoxy resins and acrylic emulsion for the main film forming substance of coating, with poly- Aniline lotion is anticorrosive additive, and the water resistance of the addition of polyaniline, coating significantly improves, and antiseptic property improves, which will Epoxy emulsion combines with the characteristic of acrylic emulsion, improves the comprehensive performance of coating, and Polyaniline emulsion is added directly into Coating solves the problems, such as the stability problem of polyaniline and compatible and preparation the anticorrosive paint of other macromolecule emulsions, improves The antiseptic property of coating, acid and active hydrogen in conversion fluid, polyaniline can promote the solidification of epoxy resin, as epoxy cream The curing agent of liquid, simple process and low cost.The anticorrosion process of steel construction is simple, not only has good antiseptic property, Er Qieshi Work is easy, can mitigate significantly the labor intensity of coating, while having stronger weatherability, can be realized the length for steel construction Phase protection, polyaniline, which is used for Corrosion resisting paint without need of cleaning rust as anticorrosive additive, both can be improved anti-corrosion effect, delay corrosion of metal Speed, and cost can be reduced, priming paint is mixed to prepare using dispersing agent, auxiliary agent, emulsifier and gypsum slag cement, is had good Fire resistance and antiseptic property.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects It encloses.
A kind of anticorrosion process of steel construction, comprising the following steps:
The surface preparation of S1, steel construction: use mechanical treatment or chemically treated method, by the burr of steel surface, Welding agent, overlap, splash, dust, loose scale and thicker rusty scale are cleaned out, using lye or organic solvent by steel Greasy dirt, the grease of body structure surface clean up, and after caustic dip, rinse 2-3 times using with clean water, and empty with oil free compression Gas dries up the surface of steel construction;
S2, steel surface derusting: Shot Blasting, derusting grade Sa2.5, roughness are used to the surface of steel structure member It is 40-75 μm;
S3, it prepares steel structure aqueous corrosion resisting paint without need of cleaning rust: taking a certain amount of converting agent of iron rust and Polyaniline emulsion, addition is stirred It mixes and 30-45min is mixed in device, stir evenly, the temperature of stirring is controlled at 50-60 DEG C, is added slowly to a certain amount of It is stirred evenly in epoxy emulsion, acrylic acid composite emulsion and organic solvent ethyl alcohol, then is separately added into coalescing agent, stably dispersing Agent, converting agent of iron rust, defoaming agent and thickener, temperature are controlled at 65-80 DEG C, up on rust paint after stirring 30-50min;
The preparation of S4, priming paint: sequentially added into high speed disperser water, acrylic acid elastic water-proof lotion, styrene-acrylic emulsion with And chlorine partial emulsion, under 3000r/min mixing speed, aluminosilicate fiber cotton and hydroxyethyl ether cellulose dispersion is added in dispersion 30-50min adjusts pH=8 with ammonium hydroxide, adds anticorrosive packing, mica powder, iron oxide red and divided titanium dioxide after mixing evenly Dissipate 40-60min, slurry coating obtained mixed with gypsum slag cement after to get fire safe type anticorrosion of steel structure priming paint;
The coating of S5, steel construction: the steel construction after spraying ball blast passed examination carries out the primer painting in step S4 and makees Industry, primer painting operation are completed in Painting Shop, then carry out the finishing coat coating of on rust paint in step S3, by the spray of steel construction Painting dead angle position just can be carried out large area painting operation after should being first preliminarily sprayed, and apply in primer painting, intermediate coat coating and finishing coat In the technique of dress, when carrying out the coating process of next step, need to dry step by 2-6h before coating process;
S6, oil paint coating quality inspection and examination: after painting layer is dry, reply film thickness measures inspection and closes Lattice, coating surface should uniformly, and color is consistent, the defects of without obvious elephant skin, trickling, blistering, crackle, component surface do not answer holiday, It accidentally applies, coating should not peel, return rust.
Specifically, the clean water used in the step S1 is hot water, the temperature of the hot water is 40-50 DEG C, to remove Remove the acid, alkali and salt of steel surface.
Specifically, epoxy emulsion described in the step S3 is aqueous epoxy resins, the Polyaniline emulsion adds for anti-corrosion Add agent, after Polyaniline emulsion is added, the acid in the hydrogen and Polyaniline emulsion in polyaniline can promote epoxy emulsion to solidify, and take on The curing agent of epoxy emulsion increases in addition, the wetting and permeance property of coating can be improved in the emulsifier contained in Polyaniline emulsion The permeance property of coating not only can be improved in the adhesion of strong coating and substrate, the assistant for emulsifying agent ethyl alcohol contained in polyaniline, also Can reduce the drying time of film, polyaniline in coating also mainly rise antisepsis, it metal surface can with passive metal, Mask erosion environment hinders electron transmission, forms hydrophobic adsorbent layer, prevents dirt from adhering to, and it is excellent that this has polyaniline Anti-corrosion effect.
Specifically, epoxy emulsion in the step S3, acrylic acid composite emulsion, Polyaniline emulsion, converting agent of iron rust and The percentage composition of ethyl alcohol is respectively 35%, 25%, 1.2%, 2%, 35%.
Specifically, defoaming agent is silicon oil foam killer in the step S1, the dispersion stabilizer is polycarboxylic acids metal salt, institute Stating coalescing agent is at least one of alcohol ester and alcohol ether, and the thickener is polyacrylate.
Specifically, in the step S4 when steel surface coating, it should be noted that steel surface situation and atmospheric environment, coating are applied Work must surface temperature be higher than 3 DEG C of dew-point temperature or more, relative humidity carries out in 85% condition below, when steel surface by When rainwater influences, then it not can be carried out coating, oil paint coating place should hang temperature and humidity recorder, for detecting record spraying process In temperature and humidity numerical value.
Specifically, acrylic acid elastic water-proof lotion, mica powder, styrene-acrylic emulsion, titanium dioxide, chlorine are partially newborn in the step S4 Liquid, iron oxide red, aluminosilicate fiber cotton, hydroxyethyl ether cellulose, anticorrosive packing, water and gypsum slag cement mass ratio be 10:10:5:5:4:5:5:5:1:50:66.
The anticorrosion process of the steel construction, the crosslinking ability for preparing steel structure aqueous corrosion resisting paint without need of cleaning rust and steel construction is good, With it is nontoxic, tasteless, without organic volatile discharge, pollution-free, without risk is fired, construction safety is convenient, environmentally protective advantage, It uses aqueous epoxy resins and acrylic emulsion for the main film forming substance of coating, using Polyaniline emulsion as anticorrosive additive, gathers The water resistance of the addition of aniline, coating significantly improves, and antiseptic property improves, and the coating is by the spy of epoxy emulsion and acrylic emulsion Property combine, improve the comprehensive performance of coating, Polyaniline emulsion is added directly into coating, solves polyaniline and other are high The stability problem of the anticorrosive paint of the compatible problem and preparation of molecule lotion, improves the antiseptic property of coating.Conversion fluid gathers Acid and active hydrogen in aniline can promote the solidification of epoxy resin, as the curing agent of epoxy emulsion, simple process, cost Low, the anticorrosion process of steel construction is simple, not only has good antiseptic property, but also easy construction, can mitigate coating significantly Labor intensity, while there is stronger weatherability, can be realized the digital preservation for steel construction, using polyaniline as anti-corrosion Anti-corrosion effect both can be improved for Corrosion resisting paint without need of cleaning rust in additive, delays corrosion of metal speed, and can reduce cost, priming paint is adopted It is mixed to prepare with dispersing agent, auxiliary agent, emulsifier and gypsum slag cement, there is good fire resistance and antiseptic property.
Finally, it should be noted that the foregoing is only a preferred embodiment of the present invention, it is not intended to restrict the invention, Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used To modify the technical solutions described in the foregoing embodiments or equivalent replacement of some of the technical features, All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in of the invention Within protection scope.

Claims (7)

1. a kind of anticorrosion process of steel construction, which comprises the following steps:
The surface preparation of S1, steel construction: use mechanical treatment or chemically treated method, by the burr of steel surface, welding agent, Overlap, splash, dust, loose scale and thicker rusty scale are cleaned out, using lye or organic solvent by steel construction Greasy dirt, the grease on surface clean up, and after caustic dip, rinse 2-3 times using with clean water, and will with oil-free compressed air The surface of steel construction dries up;
S2, steel surface derusting: Shot Blasting, derusting grade Sa2.5 are used to the surface of steel structure member, roughness is 40-75μm;
S3, it prepares steel structure aqueous corrosion resisting paint without need of cleaning rust: taking a certain amount of converting agent of iron rust and Polyaniline emulsion, blender is added Middle mixing 30-45min, stirs evenly, and the temperature of stirring is controlled at 50-60 DEG C, is added slowly to a certain amount of epoxy Stirred evenly in lotion, acrylic acid composite emulsion and organic solvent ethyl alcohol, then be separately added into coalescing agent, dispersion stabilizer, Converting agent of iron rust, defoaming agent and thickener, temperature are controlled at 65-80 DEG C, up on rust paint after stirring 30-50min;
The preparation of S4, priming paint: water, acrylic acid elastic water-proof lotion, styrene-acrylic emulsion and chlorine are sequentially added into high speed disperser Meta-latex emulsion, under 3000r/min mixing speed, aluminosilicate fiber cotton is added in dispersion and hydroxyethyl ether cellulose disperses 30- 50min adjusts pH=8 with ammonium hydroxide after mixing evenly, adds anticorrosive packing, mica powder, iron oxide red and titanium dioxide dispersion 40-60min, slurry coating obtained mixed with gypsum slag cement after to get fire safe type anticorrosion of steel structure priming paint;
The coating of S5, steel construction: the steel construction after spraying ball blast passed examination carries out the primer painting operation in step S4, bottom Paint painting operation is completed in Painting Shop, then carries out the finishing coat coating of on rust paint in step S3, and the spraying of steel construction is dead Angular position just can be carried out large area painting operation after should being first preliminarily sprayed, in primer painting, intermediate coat coating and finishing coat coating In technique, when carrying out the coating process of next step, need to dry step by 2-6h before coating process;
S6, oil paint coating quality inspection and examination: after painting layer is dry, reply film thickness, which measures, examines qualified, painting Layer surface should uniformly, and color is consistent, and the defects of without obvious elephant skin, trickling, blistering, crackle, component surface is not answered holiday, accidentally applied, Coating should not peel, return rust.
2. a kind of anticorrosion process of steel construction according to claim 1, it is characterised in that: used in the step S1 clean Water purification is hot water, and the temperature of the hot water is 40-50 DEG C, to remove the acid, alkali and salt of steel surface.
3. a kind of anticorrosion process of steel construction according to claim 1, it is characterised in that: epoxy described in the step S3 Lotion is aqueous epoxy resins, and the Polyaniline emulsion is anticorrosive additive, after Polyaniline emulsion is added, hydrogen in polyaniline and Acid in Polyaniline emulsion can promote epoxy emulsion to solidify, and take on the curing agent of epoxy emulsion, in addition, containing in Polyaniline emulsion The wetting and permeance property of coating can be improved in some emulsifiers, enhances the adhesion of coating and substrate, contains in polyaniline The permeance property of coating not only can be improved in assistant for emulsifying agent ethyl alcohol, can also reduce the drying time of film, polyaniline is in coating Antisepsis is also mainly played, it can be hydrophobic with passive metal, mask erosion environment, obstruction electron transmission, formation in metal surface Adsorption layer prevents dirt from adhering to, this makes polyaniline have excellent anti-corrosion effect.
4. a kind of anticorrosion process of steel construction according to claim 1, it is characterised in that: epoxy cream in the step S3 Liquid, acrylic acid composite emulsion, Polyaniline emulsion, converting agent of iron rust and ethyl alcohol percentage composition be respectively 35%, 25%, 1.2%, 2%, 35%.
5. a kind of anticorrosion process of steel construction according to claim 1, it is characterised in that: defoaming agent is in the step S3 Silicon oil foam killer, the dispersion stabilizer be polycarboxylic acids metal salt, the coalescing agent be at least one of alcohol ester and alcohol ether, The thickener is polyacrylate.
6. a kind of anticorrosion process of steel construction according to claim 1, it is characterised in that: steel surface in the step S5 When coating, it should be noted that steel surface situation and atmospheric environment, coating decoration must be higher than 3 DEG C of dew-point temperature or more in surface temperature, Relative humidity carries out in 85% condition below, when steel surface is influenced by rainwater, then not can be carried out coating, oil paint coating Place should hang temperature and humidity recorder, for detecting the temperature and humidity numerical value in record spraying process.
7. a kind of anticorrosion process of steel construction according to claim 1, it is characterised in that: acrylic acid bullet in the step S4 Property water-proof emulsion, mica powder, styrene-acrylic emulsion, titanium dioxide, chlorine partial emulsion, iron oxide red, aluminosilicate fiber cotton, hydroxyethyl cellulose Ether, anticorrosive packing, water and gypsum slag cement mass ratio be 10:10:5:5:4:5:5:5:1:50:66.
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CN111589668A (en) * 2020-06-02 2020-08-28 天津市昊航复合管业有限公司 Construction method of DEP modified silicon elastic coating
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CN114058239A (en) * 2021-11-25 2022-02-18 深圳安盾海洋新材料有限公司 Cement-based anti-permeability anticorrosive multilayer coating and application method thereof
CN114058239B (en) * 2021-11-25 2023-01-10 深圳安盾海洋新材料有限公司 Cement-based anti-permeability anticorrosive multilayer coating and application method thereof

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