CN109621589A - A kind of novel haze remover - Google Patents

A kind of novel haze remover Download PDF

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Publication number
CN109621589A
CN109621589A CN201811404078.4A CN201811404078A CN109621589A CN 109621589 A CN109621589 A CN 109621589A CN 201811404078 A CN201811404078 A CN 201811404078A CN 109621589 A CN109621589 A CN 109621589A
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CN
China
Prior art keywords
haze
parts
organic silicon
jfc
agent
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811404078.4A
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Chinese (zh)
Inventor
赵冬梅
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Beijing Lianyan Zhuochuang Technology Co Ltd
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Beijing Lianyan Zhuochuang Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Beijing Lianyan Zhuochuang Technology Co Ltd filed Critical Beijing Lianyan Zhuochuang Technology Co Ltd
Priority to CN201811404078.4A priority Critical patent/CN109621589A/en
Publication of CN109621589A publication Critical patent/CN109621589A/en
Pending legal-status Critical Current

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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D47/00Separating dispersed particles from gases, air or vapours by liquid as separating agent
    • B01D47/06Spray cleaning
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D50/00Combinations of methods or devices for separating particles from gases or vapours
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/06Polluted air

Abstract

The invention discloses a kind of novel haze removers, and by 20-60 parts of organic silicon surfactant, 30-70 parts of bleeding agent, 5-20 parts of hygroscopic agent, 5-40 parts of water are formed.The organic silicon surfactant is nonionic surfactant, is the one or more of the organic silicon surfactant obtained with polyether-modified containing hydrogen silicone oils such as polyoxyethylene ether, polyethenoxy ether alkene, propyl alcohol polyoxyalkyl ether, dimethylamine polyethers, amino-polyether, urine polyethers;The bleeding agent is the one or more of JFC, JFC-1, JFC-E, AEO-9, NP-10;The hygroscopic agent be ethylene glycol, glycerine, diethylene glycol, PEG400, PEG60 it is one or more.Novel haze remover of the invention has many advantages, such as ultra-low surface tension, superpower infiltration wellability, permanent moisture absorbability and moisture retentivity.

Description

A kind of novel haze remover
Technical field
The present invention relates to a kind of haze remover, in particular to it is a kind of have ultra-low surface tension, superpower infiltration wellability, The novel haze remover of permanent moisture absorbability and moisture retentivity.
Background technique
Haze is the portmanteau word of mist and haze.The source of haze is varied, for example vehicle exhaust, industrial discharge, building are raised Dirt, waste incineration or even volcanic eruption etc., haze weather are usually that a variety of pollution sources immixtures are formed.Haze is special Determine the result of weather conditions and mankind's activity interaction.The economy of high density population and social activities will necessarily discharge a large amount of thin Particulate matter (PM 2.5), once discharge is more than atmospheric air circulation ability and carrying degree, fine particle concentration is by continued accumulation, at this time such as Fruit is influenced by quiet steady weather etc., large-scale haze easily occurs.The distribution of haze particle in haze is relatively uniform, and haze grain The scale of son is smaller, and from 0.001 micron to 10 micron, for average diameter about in 1~2 microns, haze particle is to influence people Body health, traffic safety, ecological environment key factor.How control atmosphere pollution, be whole mankind's urgent problem it One.
The administering method of atmospheric haze is to reduce discharge, afforestation and water spray except haze etc. at present.Reducing energy use is It is unpractical, and clean energy resource is at present also far from meet demand.Although planting trees for regulating the climate, water conservation, subtracting Light atmosphere pollution is of great significance, but heavy workload, need to consume a large amount of manpower and material resources, and except haze required time is long.Water spray Except haze method to have the function that agglomerated particles, but is sprayed water by soaking the particles such as particle, dust, aerosol in atmosphere Method removes the low efficiency of haze, cannot fundamentally remove haze.Therefore it develops a kind of except haze effect is good, high-efficient, required Time it is short remove haze method, have important social effect.
Report is mixed by water, salt, glycerol and modified acrylic polymer in existing patent CN 105642048A, Vehicular atomization is then charged into except being sprayed in haze spraying device, is administered for atmospheric haze.Modified acrylic polymer system Standby process is more complicated, while the surfactant for playing and reducing surface tension is had no in system, not can guarantee mixing except haze body System can capture the haze particle with ultra-low surface tension;The infiltration infiltration of infiltration immersional wetting is not played in system yet Agent, mixing also can not quickly play the role of wet, bonding, condensation except haze system.
Summary of the invention
In view of this, the present invention for haze administering method in current atmosphere except haze the time required to it is long, except haze low efficiency, remove The drawback of haze effect difference, provide it is a kind of with ultra-low surface tension, it is superpower infiltration wellability, permanent moisture absorbability and moisture retentivity it is novel Haze remover.
The present invention is solved the above problems by following technological means:
A kind of novel haze remover, by one or more organic silicon surfactants of following component, one or more infiltrations Agent, one or more hygroscopic agents, water composition:
20-60 parts of organic silicon surfactant, 30-70 parts of bleeding agent, 5-20 parts of hygroscopic agent, 5-40 parts of water.
Preferably, the organic silicon surfactant is nonionic surfactant, is with polyoxyethylene ether, polyoxy third The polyether-modified containing hydrogen silicone oils such as alkene ether, allyl alcohol polyoxyalkyl ether, dimethylamine polyethers, amino-polyether, urine polyethers obtain organic Silicon surface active agent it is one or more.
Preferably, the bleeding agent is the one or more of JFC, JFC-1, JFC-E, AEO-9, NP-10.
Preferably, the hygroscopic agent be ethylene glycol, glycerine, diethylene glycol, PEG400, PEG60 it is one or more.
Due to using above-mentioned technological means, the beneficial effects of the present invention are:
The haze remover of the invention patent can reduce the surface tension of water within 20mN/m, while 200 mesh coal dusts exist Sedimentation time in haze remover, partial size was sedimentation time of the diatomite of 10um in haze remover in 9s in 5s Interior, partial size is sedimentation time of the diatomite of 2.5um in haze remover in 20s, illustrates that the present invention has more except haze agent High dust capturing efficiency.Meanwhile the present invention uses compound hygroscopic agent, can keep the dust for having sprayed haze remover for a long time The hygroscopicity on surface, moisture retention, and then improve the wind resistance of dust.
Specific embodiment
In order to keep the purposes, technical schemes and advantages of the embodiment of the present invention clearer, implement below in conjunction with the present invention Example, technical solution in the embodiment of the present invention are explicitly described.
Embodiment 1
A kind of novel haze remover, by one or more organic silicon surfactants of following component, one or more infiltrations Agent, one or more hygroscopic agents, water composition:
20 parts of organic silicon surfactant, 30 parts of bleeding agent, 5 parts of hygroscopic agent, 5 parts of water.
Preferably, the organic silicon surfactant is nonionic surfactant, is with polyoxyethylene ether, polyoxy third The polyether-modified containing hydrogen silicone oils such as alkene ether, allyl alcohol polyoxyalkyl ether, dimethylamine polyethers, amino-polyether, urine polyethers obtain organic Silicon surface active agent it is one or more.
Preferably, the bleeding agent is the one or more of JFC, JFC-1, JFC-E, AEO-9, NP-10.
Preferably, the hygroscopic agent be ethylene glycol, glycerine, diethylene glycol, PEG400, PEG60 it is one or more.
Embodiment 2
A kind of novel haze remover, by one or more organic silicon surfactants of following component, one or more infiltrations Agent, one or more hygroscopic agents, water composition:
40 parts of organic silicon surfactant, 50 parts of bleeding agent, 15 parts of hygroscopic agent, 25 parts of water.
Preferably, the organic silicon surfactant is nonionic surfactant, is with polyoxyethylene ether, polyoxy third The polyether-modified containing hydrogen silicone oils such as alkene ether, allyl alcohol polyoxyalkyl ether, dimethylamine polyethers, amino-polyether, urine polyethers obtain organic Silicon surface active agent it is one or more.
Preferably, the bleeding agent is the one or more of JFC, JFC-1, JFC-E, AEO-9, NP-10.
Preferably, the hygroscopic agent be ethylene glycol, glycerine, diethylene glycol, PEG400, PEG60 it is one or more.
Embodiment 3
A kind of novel haze remover, by one or more organic silicon surfactants of following component, one or more infiltrations Agent, one or more hygroscopic agents, water composition:
60 parts of organic silicon surfactant, 70 parts of bleeding agent, 20 parts of hygroscopic agent, 40 parts of water.
Preferably, the organic silicon surfactant is nonionic surfactant, is with polyoxyethylene ether, polyoxy third The polyether-modified containing hydrogen silicone oils such as alkene ether, allyl alcohol polyoxyalkyl ether, dimethylamine polyethers, amino-polyether, urine polyethers obtain organic Silicon surface active agent it is one or more.
Preferably, the bleeding agent is the one or more of JFC, JFC-1, JFC-E, AEO-9, NP-10.
Preferably, the hygroscopic agent be ethylene glycol, glycerine, diethylene glycol, PEG400, PEG60 it is one or more.
In above-mentioned technical proposal, organic silicon surfactant is using permethylated siloxanes as hydrophobic main chain, wherein Meta position or end position connect one or more polar organic groups and a kind of surfactant for constituting, and organic silicon surfactant is because of it Low-surface-energy with high surface and methyl, while siloxane main chain is particularly soft makes methyl in surface dense arrangement, So that organic group is farthest utilized, therefore the surface tension of aqueous solution can be down to by organic silicon surfactant 20~30 mN m-1, ultralow surface tension can make its effective wetting haze dust surface, and then capture, absorption, reunion powder Dirt particle, is rigidly fastened within reticular structure, and haze particle agglomeration is settled, to achieve the effect that remove haze.
Bleeding agent can be cooperateed with organic silicon surfactant with rapid osmotic to haze particle surface and be played increase haze powder The moistened surface of dirt acts on.
Compared with prior art, haze remover of the invention is unique in component selection, in performance indicator With superiority.
1, in component selection:
Organosilicon nonionic surfactant is because it can effectively soak with ultralow surface tension, capture small size first Haze particle plays the role of reunion, coalescence, depositing dust.Bleeding agent can be with rapid osmotic to haze particle surface, with organosilicon table Activating agent collaboration in face plays the role of increasing the moistened surface of haze dust.
2, in technical indicator:
1) haze remover of the invention and water match in the case where 100-300 times, its surface tension can be made to be reduced to 20mN/m is hereinafter, this solution can quickly capture the haze dust of different-grain diameter, and haze remover dosage is few, and the dosage of water is few, It is high-efficient;
2) haze remover of the invention and water match in the case where 100-300 times, can quickly infiltrate haze dust, simultaneously Sedimentation time of the 200 mesh coal dusts in haze remover, partial size was that the diatomite of 10um is heavy in haze remover in 5s Drop in 9s the time, partial size is sedimentation time of the diatomite of 2.5um in haze remover in 20s;
3) haze remover of the invention and water match in the case where 100-300 times, and in haze environment, haze removal rate exists 95% or more.
Finally, it is stated that the above examples are only used to illustrate the technical scheme of the present invention and are not limiting, although referring to compared with Good embodiment describes the invention in detail, those skilled in the art should understand that, it can be to skill of the invention Art scheme is modified or replaced equivalently, and without departing from the objective and range of technical solution of the present invention, should all be covered at this In the scope of the claims of invention.

Claims (4)

1. a kind of novel haze remover, it is characterised in that: by one or more organic silicon surfactants of following component, one Kind or a variety of bleeding agents, one or more hygroscopic agents, water composition:
20-60 parts of organic silicon surfactant, 30-70 parts of bleeding agent, 5-20 parts of hygroscopic agent, 5-40 parts of water.
2. haze remover according to claim 1, it is characterised in that: the organic silicon surfactant is nonionic Surfactant is with polyoxyethylene ether, polyethenoxy ether, allyl alcohol polyoxyalkyl ether, dimethylamine polyethers, amino-polyether, urine The organic silicon surfactant that the polyether-modified containing hydrogen silicone oil such as polyethers obtains it is one or more.
3. haze remover according to claim 1, it is characterised in that: the bleeding agent be JFC, JFC-1, JFC-E, AEO-9, NP-10's is one or more.
4. haze remover according to claim 1, it is characterised in that: the hygroscopic agent is ethylene glycol, glycerine, two Ethylene glycol, PEG400, PEG60 it is one or more.
CN201811404078.4A 2018-11-23 2018-11-23 A kind of novel haze remover Pending CN109621589A (en)

Priority Applications (1)

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Application Number Priority Date Filing Date Title
CN201811404078.4A CN109621589A (en) 2018-11-23 2018-11-23 A kind of novel haze remover

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Publication Number Publication Date
CN109621589A true CN109621589A (en) 2019-04-16

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Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2007216923A1 (en) * 2006-09-21 2008-04-10 Complete Liquid Transport Pty Ltd Dust suppressant
US20100229756A1 (en) * 2009-03-10 2010-09-16 Japan Corn Starch Co., Ltd. Additive composition for spraying water to prevent dust scattering
CN105062424A (en) * 2015-08-03 2015-11-18 舒新前 Antifoaming dust suppressant and preparation method thereof
CN108276962A (en) * 2018-01-10 2018-07-13 北京国电富通科技发展有限责任公司 A kind of efficient moisture-retention moist type dust suppressant and its preparation and application
CN108395879A (en) * 2018-01-18 2018-08-14 北京国电富通科技发展有限责任公司 A kind of improvement dust efficient moist type dust suppressant and its preparation and application

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
AU2007216923A1 (en) * 2006-09-21 2008-04-10 Complete Liquid Transport Pty Ltd Dust suppressant
US20100229756A1 (en) * 2009-03-10 2010-09-16 Japan Corn Starch Co., Ltd. Additive composition for spraying water to prevent dust scattering
CN105062424A (en) * 2015-08-03 2015-11-18 舒新前 Antifoaming dust suppressant and preparation method thereof
CN108276962A (en) * 2018-01-10 2018-07-13 北京国电富通科技发展有限责任公司 A kind of efficient moisture-retention moist type dust suppressant and its preparation and application
CN108395879A (en) * 2018-01-18 2018-08-14 北京国电富通科技发展有限责任公司 A kind of improvement dust efficient moist type dust suppressant and its preparation and application

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Application publication date: 20190416

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