CN109609214A - A kind of preparation method for the environmentally friendly auxiliary agent preventing low temperature diesel oil wax deposition - Google Patents

A kind of preparation method for the environmentally friendly auxiliary agent preventing low temperature diesel oil wax deposition Download PDF

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Publication number
CN109609214A
CN109609214A CN201910004516.6A CN201910004516A CN109609214A CN 109609214 A CN109609214 A CN 109609214A CN 201910004516 A CN201910004516 A CN 201910004516A CN 109609214 A CN109609214 A CN 109609214A
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mixture
auxiliary agent
diesel oil
environmentally friendly
low temperature
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CN201910004516.6A
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Chinese (zh)
Inventor
闫海龙
张振秀
李文超
张东民
张秦怡
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Shaanxi He He Chemical Industry Science Co Ltd
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Shaanxi He He Chemical Industry Science Co Ltd
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Priority to CN201910004516.6A priority Critical patent/CN109609214A/en
Publication of CN109609214A publication Critical patent/CN109609214A/en
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    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/143Organic compounds mixtures of organic macromolecular compounds with organic non-macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/182Organic compounds containing oxygen containing hydroxy groups; Salts thereof
    • C10L1/1822Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms
    • C10L1/1826Organic compounds containing oxygen containing hydroxy groups; Salts thereof hydroxy group directly attached to (cyclo)aliphatic carbon atoms poly-hydroxy
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/188Carboxylic acids; metal salts thereof
    • C10L1/1881Carboxylic acids; metal salts thereof carboxylic group attached to an aliphatic carbon atom
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/192Macromolecular compounds
    • C10L1/195Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds
    • C10L1/196Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof
    • C10L1/1963Macromolecular compounds obtained by reactions involving only carbon-to-carbon unsaturated bonds derived from monomers containing a carbon-to-carbon unsaturated bond and a carboxyl group or salts, anhydrides or esters thereof homo- or copolymers of compounds having one or more unsaturated aliphatic radicals each having one carbon bond to carbon double bond, and at least one being terminated by a carboxyl radical or of salts, anhydrides or esters thereof mono-carboxylic
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10LFUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G, C10K; LIQUEFIED PETROLEUM GAS; ADDING MATERIALS TO FUELS OR FIRES TO REDUCE SMOKE OR UNDESIRABLE DEPOSITS OR TO FACILITATE SOOT REMOVAL; FIRELIGHTERS
    • C10L1/00Liquid carbonaceous fuels
    • C10L1/10Liquid carbonaceous fuels containing additives
    • C10L1/14Organic compounds
    • C10L1/18Organic compounds containing oxygen
    • C10L1/192Macromolecular compounds
    • C10L1/198Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid
    • C10L1/1985Macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds homo- or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon to carbon double bond, and at least one being terminated by an acyloxy radical of a saturated carboxylic acid, of carbonic acid polyethers, e.g. di- polygylcols and derivatives; ethers - esters

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  • Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Lubricants (AREA)
  • Liquid Carbonaceous Fuels (AREA)

Abstract

The invention discloses a kind of preparation methods of environmentally friendly auxiliary agent for preventing low temperature diesel oil wax deposition, comprising the following steps: ethylene glycol and polyethylene glycol S1, are mixed and made into mixed solution A;S2, it takes plastic of poly vinyl acetate and Polystearylmethacrylate to be dissolved separately in the mixed solution A that temperature is 30~50 DEG C, mixture B and mixture C is respectively obtained after being cooled to room temperature;S3, it oleic acid is dissolved in mixed solution A obtains mixture D, stir evenly and be placed in microwave reactor, power setting 600W, time 5min take out after heating reaction;S4, it is mixed under fast stirring with mixture B and mixture C after mixture D is cooled to room temperature to get to environmentally friendly auxiliary agent.The environmentally friendly auxiliary agent that the method for the present invention is produced is deployed by the multipolymer containing chain alkyl and highly polar group with active material, it is suitble to the diesel oil of various different crude oils processings, refinery's diesel and gasoline ratio can be improved in it, improves low temperature diesel quality and other indexs.

Description

A kind of preparation method for the environmentally friendly auxiliary agent preventing low temperature diesel oil wax deposition
Technical field
The present invention relates to additive agent field more particularly to a kind of preparation sides for the environmentally friendly auxiliary agent for preventing low temperature diesel oil wax deposition Method.
Background technique
Diesel oil is the midbarrel in petroleum refining process, and general boiling range is a kind of multiple groups between 170 DEG C~380 DEG C The complicated hydrocarbon mixture divided, contains n-alkane, cycloalkane, alkene and aromatic hydrocarbon.Wax is the n-alkane in diesel oil, works as temperature When degree reduces, the wax crystalline substance in diesel oil can be gradually precipitated, and the wax crystalline substance of the lower precipitation of temperature is more, forms three-dimensional netted crystallization, makes bavin Oil loses flowability, and influences the normal use and transport of diesel oil.In order to improve the low temperature fluidity of diesel oil, it is necessary to take certain Measure reduce diesel oil condensation point, keep it in the standard limited value of use for diesel engine oil.
Solve diesel oil at low-temperature crystallisation problems and be mainly the following method: (1) by adjusting process units operating parameter or Change processing route, such as using be hydrocracked, delay coking process, but the problems such as there are investment cost and big operating costs, Therefore it is subject to certain restrictions.(2) by adjusting the cut point of fractionating column, shorten diesel oil boiling range, reduce heavy constituent in diesel oil, it can Reduce diesel oil at low-temperature crystallization temperature.But with the reduction of heavy constituent, necessarily affect the device capbility of diesel oil.(3) in long distillate In diesel oil, improve the low temperature crystallization problem of diesel oil by the way that chemical assistant is added.This is a kind of flexible, easy, economical and effective Method.
Summary of the invention
Object of the present invention is to solve the above problems, a kind of environmentally friendly auxiliary agent that low temperature diesel oil wax deposition can be effectively prevented is provided Preparation method.
To achieve the goals above, the technical scheme is that
A kind of preparation method for the environmentally friendly auxiliary agent preventing low temperature diesel oil wax deposition, comprising the following steps:
S1, ethylene glycol and polyethylene glycol are mixed and made into mixed solution A;
S2, to take plastic of poly vinyl acetate and Polystearylmethacrylate to be dissolved separately in temperature be 30~50 DEG C mixed It closes in solution A, mixture B and mixture C is respectively obtained after being cooled to room temperature;
S3, it oleic acid is dissolved in mixed solution A obtains mixture D, stir evenly and be placed in microwave reactor, power is set It is set to 500~600W, the time is 5~7min, is taken out after heating reaction;
S4, it is mixed under fast stirring with mixture B and mixture C after mixture D is cooled to room temperature to get to environmental protection Auxiliary agent.
Further, the mass ratio of ethylene glycol and polyethylene glycol is 0.5~1:1 in the mixed solution A.
Further, in the mixture B in the step S2, the mass ratio of plastic of poly vinyl acetate and mixed solution A For 1:0.5~1.5;In mixture C, the mass ratio of Polystearylmethacrylate and mixed solution A is 1:0.5~1.5.
Further, in the mixture D in the step S3, the mass ratio of oleic acid and mixed solution A is 1:0.5~1.
Further, catalyst is added in the mixture D in the step S3.
Further, the catalyst is the hydrochloric acid that concentration is 0.1mol/L.
Further, in the mixture D in the step S3, the mass ratio of oleic acid and catalyst is 60:1.
Compared with prior art, the advantages and positive effects of the present invention are:
The environmentally friendly auxiliary agent that the method for the present invention is produced by containing chain alkyl and highly polar group multipolymer with Active material is deployed, and is suitble to the diesel oil of various different crude oils processings, refinery's diesel and gasoline ratio can be improved, improve low temperature Diesel quality and other indexs, and the auxiliary agent raw material is cheap, reaction is simple, save the cost while, have the function of resistive connection wax; On the other hand, the auxiliary agent is free from environmental pollution, with environment protecting, the mixture after reaction in component containing oleic acid and oleate, With anti-wear lubricating effect, increase with the mixed stability of diesel oil, to improve the using effect of diesel oil.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical solution in the embodiment of the present invention is clearly and completely retouched It states, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the present invention In embodiment, every other implementation obtained by those of ordinary skill in the art without making creative efforts Example, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention.
Embodiment 1, a kind of preparation method for the environmentally friendly auxiliary agent for preventing low temperature diesel oil wax deposition, comprising the following steps:
S1, ethylene glycol and polyethylene glycol are mixed and made into mixed solution A;Ethylene glycol and polyethylene glycol in mixed solution A Mass ratio is 0.5:1.
S2, take plastic of poly vinyl acetate and Polystearylmethacrylate be dissolved separately in temperature be 30 DEG C mixing it is molten In liquid A, mixture B and mixture C are respectively obtained after being cooled to room temperature;In mixture B, plastic of poly vinyl acetate with mix it is molten The mass ratio of liquid A is 1:0.5;In mixture C, the mass ratio of Polystearylmethacrylate and mixed solution A is 1:0.5.
S3, it oleic acid is dissolved in mixed solution A obtains mixture D, and it is 0.1mol/L's that concentration is added in the mixture Hydrochloric acid, in mixture D, the mass ratio of oleic acid and mixed solution A is 1:0.5;The mass ratio of oleic acid and hydrochloric acid is 60:1;Stirring is equal Even to be placed in microwave reactor, power setting 500W, time 7min take out after heating reaction;
S4, it is mixed under fast stirring with mixture B and mixture C after mixture D is cooled to room temperature to get to environmental protection Auxiliary agent.
Embodiment 2, a kind of preparation method for the environmentally friendly auxiliary agent for preventing low temperature diesel oil wax deposition, comprising the following steps:
S1, ethylene glycol and polyethylene glycol are mixed and made into mixed solution A;Ethylene glycol and polyethylene glycol in mixed solution A Mass ratio is 0.8:1.
S2, take plastic of poly vinyl acetate and Polystearylmethacrylate be dissolved separately in temperature be 40 DEG C mixing it is molten In liquid A, mixture B and mixture C are respectively obtained after being cooled to room temperature;In mixture B, plastic of poly vinyl acetate with mix it is molten The mass ratio of liquid A is 1:1;In mixture C, the mass ratio of Polystearylmethacrylate and mixed solution A is 1:1.
S3, it oleic acid is dissolved in mixed solution A obtains mixture D, and it is 0.1mol/L's that concentration is added in the mixture Hydrochloric acid, in mixture D, the mass ratio of oleic acid and mixed solution A is 1:0.8;The mass ratio of oleic acid and hydrochloric acid is 60:1;Stirring is equal Even to be placed in microwave reactor, power setting 550W, time 6min take out after heating reaction;
S4, it is mixed under fast stirring with mixture B and mixture C after mixture D is cooled to room temperature to get to environmental protection Auxiliary agent.
Embodiment 3, a kind of preparation method for the environmentally friendly auxiliary agent for preventing low temperature diesel oil wax deposition, comprising the following steps:
S1, ethylene glycol and polyethylene glycol are mixed and made into mixed solution A;Ethylene glycol and polyethylene glycol in mixed solution A Mass ratio is 1:1.
S2, take plastic of poly vinyl acetate and Polystearylmethacrylate be dissolved separately in temperature be 50 DEG C mixing it is molten In liquid A, mixture B and mixture C are respectively obtained after being cooled to room temperature;In mixture B, plastic of poly vinyl acetate with mix it is molten The mass ratio of liquid A is 1:1.5;In mixture C, the mass ratio of Polystearylmethacrylate and mixed solution A is 1:1.5.
S3, it oleic acid is dissolved in mixed solution A obtains mixture D, and it is 0.1mol/L's that concentration is added in the mixture Hydrochloric acid, in mixture D, the mass ratio of oleic acid and mixed solution A is 1:1;The mass ratio of oleic acid and hydrochloric acid is 60:1;It stirs evenly It is placed in microwave reactor, power setting 600W, time 5min, is taken out after heating reaction;
S4, it is mixed under fast stirring with mixture B and mixture C after mixture D is cooled to room temperature to get to environmental protection Auxiliary agent.
Embodiment 4
A kind of preparation method for the environmentally friendly auxiliary agent preventing low temperature diesel oil wax deposition, comprising the following steps:
S1, ethylene glycol and polyethylene glycol are mixed and made into mixed solution A;Ethylene glycol and polyethylene glycol in mixed solution A Mass ratio is 1:1.
S2, take plastic of poly vinyl acetate and Polystearylmethacrylate be dissolved separately in temperature be 50 DEG C mixing it is molten In liquid A, mixture B and mixture C are respectively obtained after being cooled to room temperature;In mixture B, plastic of poly vinyl acetate with mix it is molten The mass ratio of liquid A is 1:1;In mixture C, the mass ratio of Polystearylmethacrylate and mixed solution A is 1:1.
S3, it oleic acid is dissolved in mixed solution A obtains mixture D, and it is 0.1mol/L's that concentration is added in the mixture Hydrochloric acid, in mixture D, the mass ratio of oleic acid and mixed solution A is 1:1;The mass ratio of oleic acid and hydrochloric acid is 60:1;It stirs evenly It is placed in microwave reactor, power setting 600W, time 5min, is taken out after heating reaction;
S4, it is mixed under fast stirring with mixture B and mixture C after mixture D is cooled to room temperature to get to environmental protection Auxiliary agent.
Produce four kinds of environmentally friendly auxiliary agents according to the method for the present invention, model is respectively HH-01, HH-02, HH-03, HH-04, Effect and preferred best product for the identification environmentally friendly auxiliary agent of the invention produced, by comparative experiments in-No. 35 diesel oil After middle tetra- kinds of samples of addition 200ppm, the cold filter plugging point (cold filter plugging point is the important indicator for measuring diesel oil resistive connection wax performance) and mill of diesel oil Trace diameter change, experimental result are as follows:
(1) cold filter plugging point test result
(2) grinding defect diameter test result
By the above experimental result, choose that HH-04 effect is good, and cold filter point of diesel oil is substantially reduced after addition, and grinding defect diameter It is minimum.

Claims (7)

1. a kind of preparation method for the environmentally friendly auxiliary agent for preventing low temperature diesel oil wax deposition, it is characterised in that: the following steps are included:
S1, ethylene glycol and polyethylene glycol are mixed and made into mixed solution A;
S2, take plastic of poly vinyl acetate and Polystearylmethacrylate be dissolved separately in temperature be 30~50 DEG C mixing it is molten In liquid A, mixture B and mixture C are respectively obtained after being cooled to room temperature;
S3, it oleic acid is dissolved in mixed solution A obtains mixture D, stir evenly and be placed in microwave reactor, power setting is 500~600W, time are 5~7min, are taken out after heating reaction;
S4, it mixes after mixture D is cooled to room temperature with mixture B and mixture C and is helped to get to environmental protection under fast stirring Agent.
2. preventing the preparation method of the environmentally friendly auxiliary agent of low temperature diesel oil wax deposition as described in claim 1, it is characterised in that: described mixed Closing the mass ratio of ethylene glycol and polyethylene glycol in solution A is 0.5~1:1.
3. the preparation method of the environmentally friendly auxiliary agent as described in claim 1 or 2 is any for preventing low temperature diesel oil wax deposition, feature exist In: in the mixture B in the step S2, the mass ratio of plastic of poly vinyl acetate and mixed solution A is 1:0.5~1.5;It is mixed It closes in object C, the mass ratio of Polystearylmethacrylate and mixed solution A is 1:0.5~1.5.
4. the preparation method of the environmentally friendly auxiliary agent as described in claim 1 or 2 is any for preventing low temperature diesel oil wax deposition, feature exist In: in the mixture D in the step S3, the mass ratio of oleic acid and mixed solution A is 1:0.5~1.
5. preventing the preparation method of the environmentally friendly auxiliary agent of low temperature diesel oil wax deposition as claimed in claim 4, it is characterised in that: the step Catalyst is added in mixture D in rapid S3.
6. preventing the preparation method of the environmentally friendly auxiliary agent of low temperature diesel oil wax deposition as claimed in claim 5, it is characterised in that: described to urge Agent concentration is the hydrochloric acid of 0.1mol/L.
7. preventing the preparation method of the environmentally friendly auxiliary agent of low temperature diesel oil wax deposition as claimed in claim 5, it is characterised in that: the step In mixture D in rapid S3, the mass ratio of oleic acid and catalyst is 60:1.
CN201910004516.6A 2019-01-03 2019-01-03 A kind of preparation method for the environmentally friendly auxiliary agent preventing low temperature diesel oil wax deposition Pending CN109609214A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111635792A (en) * 2020-05-27 2020-09-08 上海中太行之光能源有限公司 Environment-friendly antifreeze agent for diesel oil and preparation method thereof

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1091152A (en) * 1994-01-06 1994-08-24 王学绍 A kind of method for preparing energy-saving lubricant oil
CN101709233A (en) * 2009-10-28 2010-05-19 上海应用技术学院 Diesel fuel pour-point depressant dispersant and preparation method thereof
CN103642546A (en) * 2013-11-19 2014-03-19 济南开发区星火科学技术研究院 Diesel oil pour-point and viscosity reducer, and preparation method thereof
CN104910977A (en) * 2015-05-29 2015-09-16 马健 Diesel oil pour point depressant
CN107964433A (en) * 2017-12-12 2018-04-27 天津大远科技有限公司 A kind of diesel pour inhibitor and preparation method thereof

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1091152A (en) * 1994-01-06 1994-08-24 王学绍 A kind of method for preparing energy-saving lubricant oil
CN101709233A (en) * 2009-10-28 2010-05-19 上海应用技术学院 Diesel fuel pour-point depressant dispersant and preparation method thereof
CN103642546A (en) * 2013-11-19 2014-03-19 济南开发区星火科学技术研究院 Diesel oil pour-point and viscosity reducer, and preparation method thereof
CN104910977A (en) * 2015-05-29 2015-09-16 马健 Diesel oil pour point depressant
CN107964433A (en) * 2017-12-12 2018-04-27 天津大远科技有限公司 A kind of diesel pour inhibitor and preparation method thereof

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111635792A (en) * 2020-05-27 2020-09-08 上海中太行之光能源有限公司 Environment-friendly antifreeze agent for diesel oil and preparation method thereof

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