CN109608931A - A kind of environmental protection coating material and preparation method thereof of green building wall - Google Patents
A kind of environmental protection coating material and preparation method thereof of green building wall Download PDFInfo
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- CN109608931A CN109608931A CN201811471838.3A CN201811471838A CN109608931A CN 109608931 A CN109608931 A CN 109608931A CN 201811471838 A CN201811471838 A CN 201811471838A CN 109608931 A CN109608931 A CN 109608931A
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- environmental protection
- protection coating
- green building
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- 239000000463 material Substances 0.000 title claims abstract description 69
- 239000011248 coating agent Substances 0.000 title claims abstract description 56
- 238000000576 coating method Methods 0.000 title claims abstract description 56
- 230000007613 environmental effect Effects 0.000 title claims abstract description 38
- 238000002360 preparation method Methods 0.000 title claims abstract description 11
- CDBYLPFSWZWCQE-UHFFFAOYSA-L Sodium Carbonate Chemical compound [Na+].[Na+].[O-]C([O-])=O CDBYLPFSWZWCQE-UHFFFAOYSA-L 0.000 claims abstract description 40
- 239000003292 glue Substances 0.000 claims abstract description 33
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 31
- 230000001681 protective effect Effects 0.000 claims abstract description 26
- 229910000029 sodium carbonate Inorganic materials 0.000 claims abstract description 20
- 239000002904 solvent Substances 0.000 claims abstract description 20
- 239000000049 pigment Substances 0.000 claims abstract description 19
- 239000002994 raw material Substances 0.000 claims abstract description 17
- 238000003756 stirring Methods 0.000 claims abstract description 9
- 238000000034 method Methods 0.000 claims abstract description 7
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 18
- 239000002253 acid Substances 0.000 claims description 9
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 9
- 238000002156 mixing Methods 0.000 claims description 4
- 108010010803 Gelatin Proteins 0.000 claims description 2
- 229920000159 gelatin Polymers 0.000 claims description 2
- 239000008273 gelatin Substances 0.000 claims description 2
- 235000019322 gelatine Nutrition 0.000 claims description 2
- 235000011852 gelatine desserts Nutrition 0.000 claims description 2
- BVKZGUZCCUSVTD-UHFFFAOYSA-N carbonic acid Chemical compound OC(O)=O BVKZGUZCCUSVTD-UHFFFAOYSA-N 0.000 claims 2
- 230000000505 pernicious effect Effects 0.000 abstract description 3
- 238000010521 absorption reaction Methods 0.000 abstract description 2
- 239000011253 protective coating Substances 0.000 abstract description 2
- 230000000052 comparative effect Effects 0.000 description 14
- CURLTUGMZLYLDI-UHFFFAOYSA-N Carbon dioxide Chemical compound O=C=O CURLTUGMZLYLDI-UHFFFAOYSA-N 0.000 description 9
- WSFSSNUMVMOOMR-UHFFFAOYSA-N Formaldehyde Chemical compound O=C WSFSSNUMVMOOMR-UHFFFAOYSA-N 0.000 description 9
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 6
- 239000003973 paint Substances 0.000 description 4
- 239000000126 substance Substances 0.000 description 4
- 238000010276 construction Methods 0.000 description 3
- 230000000694 effects Effects 0.000 description 3
- MKYBYDHXWVHEJW-UHFFFAOYSA-N N-[1-oxo-1-(2,4,6,7-tetrahydrotriazolo[4,5-c]pyridin-5-yl)propan-2-yl]-2-[[3-(trifluoromethoxy)phenyl]methylamino]pyrimidine-5-carboxamide Chemical compound O=C(C(C)NC(=O)C=1C=NC(=NC=1)NCC1=CC(=CC=C1)OC(F)(F)F)N1CC2=C(CC1)NN=N2 MKYBYDHXWVHEJW-UHFFFAOYSA-N 0.000 description 2
- 238000005034 decoration Methods 0.000 description 2
- 239000004615 ingredient Substances 0.000 description 2
- 239000007788 liquid Substances 0.000 description 2
- 235000015112 vegetable and seed oil Nutrition 0.000 description 2
- 239000008158 vegetable oil Substances 0.000 description 2
- 238000004887 air purification Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000001569 carbon dioxide Substances 0.000 description 1
- 229910002092 carbon dioxide Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000002939 deleterious effect Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 239000012847 fine chemical Substances 0.000 description 1
- 238000009413 insulation Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000011343 solid material Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
- 229920003002 synthetic resin Polymers 0.000 description 1
- 239000000057 synthetic resin Substances 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of environmental protection coating materials of green building wall, including following raw material by weight: 80-130 parts of base-material, 40-60 parts of pigment, 30-50 parts of sodium carbonate, triggering agent 60-85 parts, 20-35 parts of protective glue, 50-65 parts of solvent;Preparation method, comprising the following steps: base-material and pigment are poured into and stirred together with the revolving speed of 50-60r/min, solvent is at the uniform velocity added in whipping process again, continues to stir after solvent is added completely into, obtains initial material;After initial material is carried out first time ultrasonic vibration, sodium carbonate and protective glue are added into initial material, continues to stir, then stand 2.8h after carrying out second of ultrasonic vibration, obtains quasi- coating;Into quasi- coating, stirring stands 1.2h after triggering agent is added, and the environmental protection coating material of green building wall is made.The environmental protection coating material of green building wall of the present invention, the micropore that inside is formed are conducive to the pernicious gas and suspended particulate of the outside outside absorption;Coating integrally glues viscosity height, is conducive to the micropore inside protective coating;The preparation method of environmental protection coating material, it is simply, at low cost.
Description
Technical field
The present invention relates to a kind of environmental protection coating material, the environmental protection coating material of specifically a kind of green building wall and its preparation side
Method.
Background technique
Coating (paint), our usually described paint are only one such.Finger is coated on body surface certain
Under the conditions of can form film and play a class I liquid I of protection, decoration or other specific functions (insulation, antirust, mould proof, heat-resisting etc.)
Or solid material.Because the coating of early stage is mostly using vegetable oil as primary raw material, therefore also referred to as paint.Present synthetic resin has replaced
Vegetable oil, therefore referred to as coating.Coating is simultaneously non-liquid, and powdery paints is one major class of coating variety.Coating belongs to organic chemical industry's height
Molecular material is formed by film and belongs to high-molecular compound type.According to the classification for the chemical products that the modern times pass through, coating category
In fine chemical product.Modern coating gradually becomes a kind of multi-functional engineering material, is one in chemical industry
A important industry.Effect mainly has at 4 points: protection, decoration, covers up the defect and other special roles of product, promotes the valence of product
Value.
It is outer due to being chronically exposed at present applied to the coating outside construction wall, panoramic air can be faced, by
It is indoor first of guard wire in wall, after wall can not handle pernicious gas and suspended particulate, these harmful substances are just
It can enter the room.
Summary of the invention
The purpose of the present invention is to provide a kind of environmental protection coating materials and preparation method thereof of green building wall, on solving
State the problem of proposing in background technique.
To achieve the above object, the invention provides the following technical scheme:
A kind of environmental protection coating material of green building wall, including following raw material by weight: 80-130 parts of base-material, pigment
40-60 parts, 30-50 parts of sodium carbonate, triggering agent 60-85 parts, 20-35 parts of protective glue, 50-65 parts of solvent.
As a further solution of the present invention: the environmental protection coating material of the green building wall, including it is following by weight
Raw material: it is 95-120 parts of base-material, 45-57 parts of pigment, 37-45 parts of sodium carbonate, agent 70-80 parts of triggering, 25-30 parts of protective glue, molten
55-62 parts of agent.
As the present invention further scheme: the environmental protection coating material of the green building wall, including it is following by weight
The raw material of part: 100 parts of base-material, 50 parts of pigment, 40 parts of sodium carbonate, triggering 76 parts of agent, 28 parts of protective glue, 58 parts of solvent.
As further scheme of the invention: the triggering agent is that carbonic acid and phosphoric acid are added by the mass ratio of 1-3:2-5
Mixed acid.
As further scheme of the invention: the triggering agent is that carbonic acid and phosphoric acid are mixed as what the mass ratio of 2:3 was added
Close acid.
As further scheme of the invention: the protective glue is gelatin.
As it is a further object to provide a kind of preparation method of the environmental protection coating material of green building wall, packets
Include following steps:
1), base-material and pigment are poured into and stirred together with the revolving speed of 50-60r/min, is at the uniform velocity added again in whipping process molten
Agent continues to stir 30-40min after solvent is added completely into, obtains initial material;
2) after initial material, is carried out first time ultrasonic vibration, sodium carbonate and protective glue is added into initial material, continues to stir
30min, then 2.8h is stood after carrying out second of ultrasonic vibration, obtain quasi- coating;
3), into quasi- coating, stirring stands 1.2h after triggering agent is added, and the environmental protection coating material of green building wall is made.
As further scheme of the invention: the first time mixing speed in the step 1) is 58r/min.
As further scheme of the invention: second of mixing time in the step 1) is 25min.
Compared with prior art, the beneficial effects of the present invention are:
1, sodium carbonate of the present invention and the carbon dioxide gas of triggering agent effect release form numerous micropore by coating inside,
Be conducive to the pernicious gas of the outside outside absorption and the deleterious particle of suspension;
2, the viscous viscosity of coating entirety can be improved in protective glue of the present invention, is conducive to the micropore inside protective coating;
3, the preparation method of environmental protection coating material of the present invention, it is simply, at low cost.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment 1
In the embodiment of the present invention, a kind of environmental protection coating material of green building wall, including following raw material by weight: base
80 parts of material, 40 parts of pigment, 30 parts of sodium carbonate, triggering 60 parts of agent, 20 parts of protective glue, 50 parts of solvent.
Wherein, the triggering agent is the mixed acid that carbonic acid and phosphoric acid are added by the mass ratio of 1:2;The protective glue is bright
Glue.
Embodiment 2
In the embodiment of the present invention, a kind of environmental protection coating material of green building wall, including following raw material by weight: base
130 parts of material, 60 parts of pigment, 50 parts of sodium carbonate, triggering 85 parts of agent, 35 parts of protective glue, 65 parts of solvent.
Wherein, the triggering agent is the mixed acid that carbonic acid and phosphoric acid are added by the mass ratio of 3:5;The protective glue is bright
Glue.
Embodiment 3
In the embodiment of the present invention, a kind of environmental protection coating material of green building wall, including following raw material by weight: base
95 parts of material, 45 parts of pigment, 37 parts of sodium carbonate, triggering 70 parts of agent, 25 parts of protective glue, 55 parts of solvent.
Wherein, the triggering agent is the mixed acid that carbonic acid and phosphoric acid are added by the mass ratio of 2:3;The protective glue is bright
Glue.
Embodiment 4
In the embodiment of the present invention, a kind of environmental protection coating material of green building wall, including following raw material by weight: base
120 parts of material, 57 parts of pigment, 45 parts of sodium carbonate, triggering 80 parts of agent, 30 parts of protective glue, 62 parts of solvent.
Wherein, the triggering agent is the mixed acid that carbonic acid and phosphoric acid are added by the mass ratio of 2:3;The protective glue is bright
Glue.
Embodiment 5
In the embodiment of the present invention, a kind of environmental protection coating material of green building wall, including following raw material by weight: base
100 parts of material, 50 parts of pigment, 40 parts of sodium carbonate, triggering 76 parts of agent, 28 parts of protective glue, 58 parts of solvent.
Wherein, the triggering agent is the mixed acid that carbonic acid and phosphoric acid are added by the mass ratio of 2:3;The protective glue is bright
Glue.
Recipe ingredient such as the following table 1 of the environmental protection coating material of above-described embodiment 1-5 Green construction wall:
Table 1
Comparative example 1
The difference of this comparative example and embodiment 5 is only that, does not add sodium carbonate.
A kind of environmental protection coating material of green building wall, including following raw material by weight: 100 parts of base-material, pigment 50
Part, triggering 76 parts of agent, 28 parts of protective glue, 58 parts of solvent.
Comparative example 2
The difference of this comparative example and embodiment 5 is only that, does not add triggering agent.
A kind of environmental protection coating material of green building wall, including following raw material by weight: 100 parts of base-material, pigment 50
Part, 40 parts of sodium carbonate, 28 parts of protective glue, 58 parts of solvent.
Comparative example 3
The difference of this comparative example and embodiment 5 is only that, does not add triggering agent and sodium carbonate.
A kind of environmental protection coating material of green building wall, including following raw material by weight: 100 parts of base-material, pigment 50
Part, 28 parts of protective glue, 58 parts of solvent.
Comparative example 4
The difference of this comparative example and embodiment 5 is only that, does not add protective glue.
A kind of environmental protection coating material of green building wall, including following raw material by weight: 100 parts of base-material, pigment 50
Part, 40 parts of sodium carbonate, triggering 76 parts of agent, 58 parts of solvent.
Recipe ingredient such as the following table 2 of the environmental protection coating material of above-mentioned comparative example 1-4 Green construction wall:
Table 2
The material that embodiment 1-5 and comparative example 1-4 are prepared is according to national standard QB-T2761-2006 " indoor air purification
Product clean-up effect measuring method " experimental provision is built, carry out experiment test.After 24 hours, measure in each sample cabin respectively
Concentration of formaldehyde (milligram/cubic meter) calculates clearance rate.The initial concentration of formaldehyde and benzene is all 0.900mg/m in each sample cabin3,
It is 110 μ g/m for PM2.5 value3.As a result 3 be see the table below.
Table 3
Concentration of formaldehyde after for 24 hours | Benzene concentration after for 24 hours | PM2.5 after for 24 hours | |
Embodiment 1 | 0.012mg/m3 | 0.022mg/m3 | 25μg/m3 |
Embodiment 2 | 0.011mg/m3 | 0.021mg/m3 | 28μg/m3 |
Embodiment 3 | 0.010mg/m3 | 0.020mg/m3 | 30μg/m3 |
Embodiment 4 | 0.010mg/m3 | 0.020mg/m3 | 20μg/m3 |
Embodiment 5 | 0.010mg/m3 | 0.020mg/m3 | 20μg/m3 |
Comparative example 1 | 0.850mg/m3 | 0.800mg/m3 | 100μg/m3 |
Comparative example 2 | 0.880mg/m3 | 0.820mg/m3 | 105μg/m3 |
Comparative example 3 | 0.890mg/m3 | 0.880mg/m3 | 108μg/m3 |
Comparative example 4 | 0.300mg/m3 | 0.400mg/m3 | 50μg/m3 |
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (9)
1. a kind of environmental protection coating material of green building wall, which is characterized in that including following raw material by weight: base-material 80-
130 parts, 40-60 parts of pigment, 30-50 parts of sodium carbonate, triggering agent 60-85 parts, 20-35 parts of protective glue, 50-65 parts of solvent.
2. a kind of environmental protection coating material of green building wall according to claim 1, which is characterized in that the green building
The environmental protection coating material of wall, including following raw material by weight: 95-120 parts of base-material, 45-57 parts of pigment, sodium carbonate 37-45
Part, triggering agent 70-80 parts, 25-30 parts of protective glue, 55-62 parts of solvent.
3. a kind of environmental protection coating material of green building wall according to claim 1, which is characterized in that the green building
The environmental protection coating material of wall, including following raw material by weight: 100 parts of base-material, 50 parts of pigment, 40 parts of sodium carbonate, triggering agent
76 parts, 28 parts of protective glue, 58 parts of solvent.
4. a kind of environmental protection coating material of green building wall according to claim 1 to 3, which is characterized in that the touching
Sending out agent is the mixed acid that carbonic acid and phosphoric acid are added by the mass ratio of 1-3:2-5.
5. a kind of environmental protection coating material of green building wall according to claim 4, which is characterized in that the triggering agent is
The mixed acid that carbonic acid and phosphoric acid are added by the mass ratio of 2:3.
6. a kind of environmental protection coating material of green building wall according to claim 1 to 3, which is characterized in that the guarantor
Shield glue is gelatin.
7. a kind of preparation method of the environmental protection coating material of -6 any green building walls according to claim 1, feature
It is, comprising the following steps:
1), base-material and pigment are poured into and stirred together with the revolving speed of 50-60r/min, solvent is at the uniform velocity added in whipping process again, to
Solvent continues to stir 30-40min after being added completely into, and obtains initial material;
2) after initial material, is carried out first time ultrasonic vibration, sodium carbonate and protective glue are added into initial material, continues to stir 30min, then
2.8h is stood after carrying out second of ultrasonic vibration, obtains quasi- coating;
3), into quasi- coating, stirring stands 1.2h after triggering agent is added, and the environmental protection coating material of green building wall is made.
8. a kind of preparation method of the environmental protection coating material of green building wall according to claim 7, which is characterized in that institute
Stating the first time mixing speed in step 1) is 58r/min.
9. a kind of preparation method of the environmental protection coating material of green building wall according to claim 7, which is characterized in that institute
Stating second of mixing time in step 1) is 25min.
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