CN109608170A - A kind of high-strength ceramic brick and preparation method thereof - Google Patents
A kind of high-strength ceramic brick and preparation method thereof Download PDFInfo
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- CN109608170A CN109608170A CN201811587190.6A CN201811587190A CN109608170A CN 109608170 A CN109608170 A CN 109608170A CN 201811587190 A CN201811587190 A CN 201811587190A CN 109608170 A CN109608170 A CN 109608170A
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- waste residue
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- 239000000919 ceramic Substances 0.000 title claims abstract description 48
- 239000011449 brick Substances 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims description 10
- 239000002994 raw material Substances 0.000 claims abstract description 35
- 239000002699 waste material Substances 0.000 claims abstract description 27
- GFNGCDBZVSLSFT-UHFFFAOYSA-N titanium vanadium Chemical compound [Ti].[V] GFNGCDBZVSLSFT-UHFFFAOYSA-N 0.000 claims abstract description 26
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 19
- 239000004927 clay Substances 0.000 claims abstract description 19
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 15
- 235000017166 Bambusa arundinacea Nutrition 0.000 claims abstract description 15
- 235000017491 Bambusa tulda Nutrition 0.000 claims abstract description 15
- 241001330002 Bambuseae Species 0.000 claims abstract description 15
- 235000015334 Phyllostachys viridis Nutrition 0.000 claims abstract description 15
- 239000006004 Quartz sand Substances 0.000 claims abstract description 15
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 15
- 239000011425 bamboo Substances 0.000 claims abstract description 15
- 239000000440 bentonite Substances 0.000 claims abstract description 15
- 229910000278 bentonite Inorganic materials 0.000 claims abstract description 15
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000003610 charcoal Substances 0.000 claims abstract description 15
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 15
- 239000002270 dispersing agent Substances 0.000 claims abstract description 7
- 239000012744 reinforcing agent Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 5
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 14
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical group [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 14
- 229920000881 Modified starch Polymers 0.000 claims description 13
- 239000004368 Modified starch Substances 0.000 claims description 13
- 235000019426 modified starch Nutrition 0.000 claims description 13
- 239000002253 acid Substances 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 7
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims description 7
- 150000003839 salts Chemical class 0.000 claims description 7
- 239000002002 slurry Substances 0.000 claims description 7
- NIXOWILDQLNWCW-UHFFFAOYSA-N acrylic acid group Chemical group C(C=C)(=O)O NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 6
- 235000019832 sodium triphosphate Nutrition 0.000 claims description 6
- 238000001354 calcination Methods 0.000 claims description 5
- 238000000498 ball milling Methods 0.000 claims description 4
- 238000001816 cooling Methods 0.000 claims description 3
- 238000000465 moulding Methods 0.000 claims description 3
- 238000005498 polishing Methods 0.000 claims description 3
- 235000019353 potassium silicate Nutrition 0.000 claims description 3
- 238000007873 sieving Methods 0.000 claims description 3
- NTHWMYGWWRZVTN-UHFFFAOYSA-N sodium silicate Chemical compound [Na+].[Na+].[O-][Si]([O-])=O NTHWMYGWWRZVTN-UHFFFAOYSA-N 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- 229910000147 aluminium phosphate Inorganic materials 0.000 claims description 2
- 238000001035 drying Methods 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N phosphoric acid Substances OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 claims description 2
- 229920000058 polyacrylate Polymers 0.000 claims description 2
- 238000002791 soaking Methods 0.000 claims description 2
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims description 2
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 claims description 2
- 239000004615 ingredient Substances 0.000 claims 2
- OQUFOZNPBIIJTN-UHFFFAOYSA-N 2-hydroxypropane-1,2,3-tricarboxylic acid;sodium Chemical compound [Na].OC(=O)CC(O)(C(O)=O)CC(O)=O OQUFOZNPBIIJTN-UHFFFAOYSA-N 0.000 claims 1
- 239000000843 powder Substances 0.000 claims 1
- 238000004519 manufacturing process Methods 0.000 abstract description 6
- 230000008021 deposition Effects 0.000 abstract description 2
- 230000007613 environmental effect Effects 0.000 abstract description 2
- UQSXHKLRYXJYBZ-UHFFFAOYSA-N Iron oxide Chemical compound [Fe]=O UQSXHKLRYXJYBZ-UHFFFAOYSA-N 0.000 description 4
- 239000000463 material Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 239000000047 product Substances 0.000 description 3
- 238000005245 sintering Methods 0.000 description 3
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 2
- 239000000292 calcium oxide Substances 0.000 description 2
- ODINCKMPIJJUCX-UHFFFAOYSA-N calcium oxide Inorganic materials [Ca]=O ODINCKMPIJJUCX-UHFFFAOYSA-N 0.000 description 2
- 239000002241 glass-ceramic Substances 0.000 description 2
- XEEYBQQBJWHFJM-UHFFFAOYSA-N iron Substances [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- 238000005360 mashing Methods 0.000 description 2
- 229920000642 polymer Polymers 0.000 description 2
- 239000000377 silicon dioxide Substances 0.000 description 2
- KKCBUQHMOMHUOY-UHFFFAOYSA-N Na2O Inorganic materials [O-2].[Na+].[Na+] KKCBUQHMOMHUOY-UHFFFAOYSA-N 0.000 description 1
- 230000006978 adaptation Effects 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 229910052661 anorthite Inorganic materials 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- BRPQOXSCLDDYGP-UHFFFAOYSA-N calcium oxide Chemical compound [O-2].[Ca+2] BRPQOXSCLDDYGP-UHFFFAOYSA-N 0.000 description 1
- 229910052681 coesite Inorganic materials 0.000 description 1
- 229910000960 colored gold Inorganic materials 0.000 description 1
- 239000012141 concentrate Substances 0.000 description 1
- 230000008602 contraction Effects 0.000 description 1
- 229910052593 corundum Inorganic materials 0.000 description 1
- 229910052906 cristobalite Inorganic materials 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000000280 densification Methods 0.000 description 1
- GWWPLLOVYSCJIO-UHFFFAOYSA-N dialuminum;calcium;disilicate Chemical compound [Al+3].[Al+3].[Ca+2].[O-][Si]([O-])([O-])[O-].[O-][Si]([O-])([O-])[O-] GWWPLLOVYSCJIO-UHFFFAOYSA-N 0.000 description 1
- 238000009792 diffusion process Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005496 eutectics Effects 0.000 description 1
- 239000012467 final product Substances 0.000 description 1
- 238000007654 immersion Methods 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 1
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 description 1
- 238000010907 mechanical stirring Methods 0.000 description 1
- 239000007769 metal material Substances 0.000 description 1
- 238000005272 metallurgy Methods 0.000 description 1
- 238000005065 mining Methods 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 238000007670 refining Methods 0.000 description 1
- 239000001509 sodium citrate Substances 0.000 description 1
- NLJMYIDDQXHKNR-UHFFFAOYSA-K sodium citrate Chemical compound O.O.[Na+].[Na+].[Na+].[O-]C(=O)CC(O)(CC([O-])=O)C([O-])=O NLJMYIDDQXHKNR-UHFFFAOYSA-K 0.000 description 1
- 229910052682 stishovite Inorganic materials 0.000 description 1
- 229910052905 tridymite Inorganic materials 0.000 description 1
- 229910001845 yogo sapphire Inorganic materials 0.000 description 1
Classifications
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/138—Waste materials; Refuse; Residues from metallurgical processes, e.g. slag, furnace dust, galvanic waste
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/34—Non-metal oxides, non-metal mixed oxides, or salts thereof that form the non-metal oxides upon heating, e.g. carbonates, nitrates, (oxy)hydroxides, chlorides
- C04B2235/3418—Silicon oxide, silicic acids, or oxide forming salts thereof, e.g. silica sol, fused silica, silica fume, cristobalite, quartz or flint
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/02—Composition of constituents of the starting material or of secondary phases of the final product
- C04B2235/30—Constituents and secondary phases not being of a fibrous nature
- C04B2235/42—Non metallic elements added as constituents or additives, e.g. sulfur, phosphor, selenium or tellurium
- C04B2235/422—Carbon
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/65—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes
- C04B2235/656—Aspects relating to heat treatments of ceramic bodies such as green ceramics or pre-sintered ceramics, e.g. burning, sintering or melting processes characterised by specific heating conditions during heat treatment
- C04B2235/6567—Treatment time
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/74—Physical characteristics
- C04B2235/77—Density
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- C04B2235/00—Aspects relating to ceramic starting mixtures or sintered ceramic products
- C04B2235/70—Aspects relating to sintered or melt-casted ceramic products
- C04B2235/96—Properties of ceramic products, e.g. mechanical properties such as strength, toughness, wear resistance
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- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Environmental & Geological Engineering (AREA)
- Dispersion Chemistry (AREA)
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- Compositions Of Oxide Ceramics (AREA)
- Preparation Of Clay, And Manufacture Of Mixtures Containing Clay Or Cement (AREA)
Abstract
The invention discloses a kind of high-strength ceramic bricks, it is characterised in that: prepares and contains following component in raw material: clay, quartz sand, kaolin, vanadium titanium waste residue, bamboo charcoal, bentonite, dispersing agent, reinforcing agent.It uses vanadium titanium waste residue to manufacture Ceramic Tiles as raw material in the present invention, solves vanadium titanium waste residue bulk deposition bring environmental problem, alleviate the problem increasingly in short supply of the high-quality ceramic raw material of the tradition such as clay, reduce Ceramic Tiles manufacturing cost.The various composition collocation of high-strength ceramic brick in the present invention prepared in raw material rationally, is substantially improved the performance of Ceramic Tiles.
Description
Technical field
The present invention relates to a kind of high-strength ceramic bricks and preparation method thereof.
Background technique
The stacking of industrial residue has become a serious society and environmental problem, vanadium titanium waste residue are v-ti magnetite mining and metallurgys
Waste after refining concentrates on the southwest in China, and heap high-volume gradually increases, and how to efficiently use vanadium titanium waste residue, saves
Resource is of great significance.
Ceramic Tiles are mainly raw material by clay and other inorganic non-metallic materials, the plate of techniques production such as are formed, are sintered
Shape or Bulk ceramic product.Ceramic Tiles are high with its consistency, contraction distortion is small, wearability is good, have preferable decorative effect,
As a kind of relatively common building decoration materials.The preparation of traditional ceramics brick needs to consume a large amount of natural resources, excessively
Consumption will cause the shortage problem of natural resources.And contain Fe in vanadium titanium waste residue2O3、TiO2、CaO、SiO2And a small amount of
Al2O3、K2O、Na2O etc., these are the necessary compositions for preparing Ceramic Tiles.It therefore, can be using vanadium titanium waste residue as production Ceramic Tiles
Raw material.
Zhouyang, Zhang Ping, Yang Weizhong, Fe in et al. vanadium titanium waste residue2O3Influencing the Sichuan [J] to Ceramic Tiles performance has coloured gold
Belong to, 2017 (2): replacing 15% clay with vanadium titanium waste residue in 47-50., prepares Ceramic Tiles.Result of study shows: addition difference contains
Measure Fe2O3The principal crystalline phase of Ceramic Tiles is quartz, anorthite and iron oxide；Iron oxide and calcium oxide, silica in vanadium titanium waste residue
Etc. forming eutectic, sintering temperature is reduced, blank Densification degree is increased.In sample, Fe3+Exist with octahedral coordination, breaks
Bad glass-ceramic phase network structure reduces the viscosity of glass-ceramic phase, is conducive to atom in sintering, ion diffusion, improves ceramics
Brick comprehensive performance.But the specific formula of Ceramic Tiles is not provided in the paper, also, the data according to disclosed in the paper,
The flexural strength of Ceramic Tiles is more general.
Summary of the invention
The purpose of the present invention is to provide a kind of high-strength ceramic bricks and preparation method thereof.
The technical solution used in the present invention is:
A kind of high-strength ceramic brick, prepares and contains following component in raw material: clay, quartz sand, kaolin, vanadium titanium waste residue,
Bamboo charcoal, bentonite, dispersing agent, reinforcing agent.
Further, it in terms of mass fraction, prepares and contains following component in raw material: 10~20 parts of clay, quartz sand 10~
20 parts, 10~15 parts of kaolin, 30~45 parts of vanadium titanium waste residue, 3~5 parts of bamboo charcoal, 2~5 parts of bentonite, dispersing agent 0.01~0.5
Part, 0.6~0.8 part of reinforcing agent.
Further, dispersing agent is selected from sodium tripolyphosphate, sodium citrate, calgon, waterglass, polyacrylate
At least one of ester, polymethyl-benzene olefin(e) acid salt, acrylic acid-acrylic ester-phosphoric acid-sulfonate quadripolymer.
Further, reinforcing agent is selected from least one of Sodium Polyacrylate, modified starch.
Further, the mass ratio of Sodium Polyacrylate and modified starch is (1:2)~(1:4).
Further, it in terms of mass fraction, prepares and contains following component in raw material: 10~20 parts of clay, quartz sand 10~
20 parts, 10~15 parts of kaolin, 30~45 parts of vanadium titanium waste residue, 3~5 parts of bamboo charcoal, 2~5 parts of bentonite, sodium tripolyphosphate 0.2~
0.3 part, 0.1~0.2 part of polymethyl-benzene olefin(e) acid salt, 0.15~0.2 part of Sodium Polyacrylate, 0.45~0.6 part of modified starch.
Further, it in terms of mass fraction, prepares and contains following component in raw material: 10~20 parts of clay, quartz sand 10~
20 parts, 10~15 parts of kaolin, 30~45 parts of vanadium titanium waste residue, 3~5 parts of bamboo charcoal, 2~5 parts of bentonite, acrylic acid-acrylic ester-
Phosphoric acid -0.01~0.3 part of sulfonate quadripolymer, 0.15~0.2 part of Sodium Polyacrylate, 0.45~0.6 part of modified starch.
The preparation method of above-mentioned high-strength ceramic tile, comprising the following steps:
1) each raw material will be mixed by composition of raw materials, and will enter ball mill ball milling after soaking in water, to slurry after ball milling
Material carries out sieving；
2) de-watering of slurries obtained in step 1, twirl are rubbed into obtain raw material, by raw material using the side of single side pressurization in tablet press machine
Formula is pressed into blanket；
3) it will calcine, cool down through natural cooling, and finished product ceramic wafer is carried out at polishing after the drying of molding blanket
It manages to obtain the final product.
Further, aperture of filter screen employed in step 1) is 200~300 mesh.
Further, calcination temperature is at 900 DEG C~1100 DEG C, and calcination time is in 100~200min.
The beneficial effects of the present invention are:
It uses vanadium titanium waste residue to manufacture Ceramic Tiles as raw material in the present invention, solves vanadium titanium waste residue bulk deposition bring ring
Border problem alleviates the problem increasingly in short supply of the high-quality ceramic raw material of the tradition such as clay, reduces Ceramic Tiles manufacturing cost.
The performance of Ceramic Tiles is substantially improved in various composition in the present invention in reasonably combined raw material.
Specific embodiment
Enumerate embodiment further below with the present invention will be described in detail.It will similarly be understood that following embodiment is served only for this
Invention is further described, and should not be understood as limiting the scope of the invention, those skilled in the art are according to the present invention
Some nonessential modifications and adaptations that the principle of elaboration is made all belong to the scope of protection of the present invention.Following specific works of example
Skill parameter etc. is also only an example in OK range, i.e. those skilled in the art can do suitable model by the explanation of this paper
Interior selection is enclosed, and does not really want to be defined in hereafter exemplary specific data.
Embodiment 1
A kind of high-strength ceramic brick is prepared in terms of mass fraction and is contained following component in raw material: 10 parts of clay, quartz sand
10 parts, 10 parts of kaolin, 30 parts of vanadium titanium waste residue, 3 parts of bamboo charcoal, 2 parts of bentonite, 0.2 part of sodium tripolyphosphate, polymethyl-benzene olefin(e) acid salt
0.1 part, 0.15 part of Sodium Polyacrylate, 0.45 part of modified starch.
Embodiment 2
A kind of high-strength ceramic brick is prepared in terms of mass fraction and is contained following component in raw material: 20 parts of clay, quartz sand
20 parts, 15 parts of kaolin, 45 parts of vanadium titanium waste residue, 5 parts of bamboo charcoal, 5 parts of bentonite, 0.3 part of sodium tripolyphosphate, polymethyl-benzene olefin(e) acid salt
0.2 part, 0.2 part of Sodium Polyacrylate, 0.6 part of modified starch.
Embodiment 3
A kind of high-strength ceramic brick is prepared in terms of mass fraction and is contained following component in raw material: 10 parts of clay, quartz sand
10 parts, 10 parts of kaolin, 30 parts of vanadium titanium waste residue, 3 parts of bamboo charcoal, 2 parts of bentonite, acrylic acid-acrylic ester-phosphoric acid-sulfonate four
0.01 part of first polymer, 0.15 part of Sodium Polyacrylate, 0.45 part of modified starch.
Embodiment 4
A kind of high-strength ceramic brick is prepared in terms of mass fraction and is contained following component in raw material: 20 parts of clay, quartz sand
20 parts, 15 parts of kaolin, 45 parts of vanadium titanium waste residue, 5 parts of bamboo charcoal, 5 parts of bentonite, acrylic acid-acrylic ester-phosphoric acid-sulfonate four
0.3 part of first polymer, 0.2 part of Sodium Polyacrylate, 0.6 part of modified starch.
Embodiment 5
A kind of high-strength ceramic brick is prepared in terms of mass fraction and is contained following component in raw material: 20 parts of clay, quartz sand
20 parts, 15 parts of kaolin, 45 parts of vanadium titanium waste residue, 3 parts of bamboo charcoal, 2 parts of bentonite, 0.2 part of waterglass, 0.15 part of Sodium Polyacrylate,
0.45 part of modified starch.
Embodiment 6
A kind of high-strength ceramic brick is prepared in terms of mass fraction and is contained following component in raw material: 10 parts of clay, quartz sand
10 parts, 10 parts of kaolin, 30 parts of vanadium titanium waste residue, 5 parts of bamboo charcoal, 5 parts of bentonite, 0.3 part of polymethyl-benzene olefin(e) acid salt, Sodium Polyacrylate
0.2 part, 0.6 part of modified starch.
In Examples 1 to 6 high-strength ceramic tile the preparation method is as follows:
(1) above-mentioned raw materials are mixed by ratio of weight and the number of copies, the water that total weight 50% is added carries out immersion 4h, will be above-mentioned
Progress mechanical stirring mashing in stock tank is smash in raw material addition；It is miscellaneous that the bulky grain that sieving removes in slurry is carried out to slurry after mashing
Matter, used aperture of filter screen are 200~300 mesh；
(2) by de-watering of slurries that step (1) obtains, twist and rub to obtain raw material, by raw material using single side pressurization in tablet press machine
Mode is pressed into blanket, and used pressure size is 6MPa；
(3) blanket after molding is placed in air dry oven dry, is then calcined in sintering furnace to blanket, is calcined
At 1100 DEG C, calcination time most cools down through natural cooling process temperature afterwards in 150min, and finished product material carries out polishing processing.
The performance parameter index of Ceramic Tiles is as shown in the table in Examples 1 to 6:
Claims (10)
1. a kind of high-strength ceramic brick, it is characterised in that: prepare and contain following component in raw material: clay, quartz sand, kaolin,
Vanadium titanium waste residue, bamboo charcoal, bentonite, dispersing agent, reinforcing agent.
2. high-strength ceramic brick according to claim 1, it is characterised in that: in terms of mass fraction, prepare in raw material and contain
Following component: 10~20 parts of clay, 10~20 parts of quartz sand, 10~15 parts of kaolin, 30~45 parts of vanadium titanium waste residue, bamboo charcoal 3~5
Part, 2~5 parts of bentonite, 0.01~0.5 part of dispersing agent, 0.6~0.8 part of reinforcing agent.
3. high-strength ceramic brick according to claim 1, it is characterised in that: dispersing agent is selected from sodium tripolyphosphate, citric acid
Sodium, calgon, waterglass, polyacrylate ester, polymethyl-benzene olefin(e) acid salt, acrylic acid-acrylic ester-phosphoric acid-sulfonate
At least one of quadripolymer.
4. high-strength ceramic brick according to claim 1, it is characterised in that: reinforcing agent is selected from Sodium Polyacrylate, modified shallow lake
At least one of powder.
5. high-strength ceramic tile according to claim 4, it is characterised in that: the mass ratio of Sodium Polyacrylate and modified starch is
(1:2)~(1:4).
6. high-strength ceramic tile according to claim 1, it is characterised in that: in terms of mass fraction, prepare in raw material containing with
Lower ingredient: 10~20 parts of clay, 10~20 parts of quartz sand, 10~15 parts of kaolin, 30~45 parts of vanadium titanium waste residue, bamboo charcoal 3~5
Part, 2~5 parts of bentonite, 0.2~0.3 part of sodium tripolyphosphate, 0.1~0.2 part of polymethyl-benzene olefin(e) acid salt, Sodium Polyacrylate 0.15
~0.2 part, 0.45~0.6 part of modified starch.
7. high-strength ceramic tile according to claim 1, it is characterised in that: in terms of mass fraction, prepare in raw material containing with
Lower ingredient: 10~20 parts of clay, 10~20 parts of quartz sand, 10~15 parts of kaolin, 30~45 parts of vanadium titanium waste residue, bamboo charcoal 3~5
Part, 2~5 parts of bentonite, acrylic acid-acrylic ester-phosphoric acid -0.01~0.3 part of sulfonate quadripolymer, Sodium Polyacrylate
0.15~0.2 part, 0.45~0.6 part of modified starch.
8. the preparation method of the described in any item high-strength ceramic tiles of claim 1~7, it is characterised in that: the following steps are included:
1) each raw material will be mixed by composition of raw materials, and enter ball mill ball milling after soaking in water, after ball milling to slurry into
Row sieving；
2) by de-watering of slurries obtained in step 1, twist rub to obtain raw material, by raw material in tablet press machine using single side pressurize by the way of pressure
Blanket is made；
3) it will calcine, cool down through natural cooling, and polishing processing is carried out i.e. to finished product ceramic wafer after the drying of molding blanket
?.
9. the preparation method of high-strength ceramic tile according to claim 8, it is characterised in that: strainer employed in step 1)
Aperture is 200~300 mesh.
10. the preparation method of high-strength ceramic tile according to claim 8 or claim 9, it is characterised in that: calcination temperature is at 900 DEG C
~1100 DEG C, calcination time is in 100~200min.
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| CN113754451A (en) * | 2021-10-22 | 2021-12-07 | 辽宁工业大学 | Refractory brick prepared from industrial solid waste and preparation method thereof |
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Application publication date: 20190412 |