CN109608143A - A kind of quick-setting early strength cement-silicate double solution grouting material and its application method - Google Patents

A kind of quick-setting early strength cement-silicate double solution grouting material and its application method Download PDF

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Publication number
CN109608143A
CN109608143A CN201910136707.8A CN201910136707A CN109608143A CN 109608143 A CN109608143 A CN 109608143A CN 201910136707 A CN201910136707 A CN 201910136707A CN 109608143 A CN109608143 A CN 109608143A
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CN
China
Prior art keywords
water
reducing agent
cementitious material
early strength
grouting
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Pending
Application number
CN201910136707.8A
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Chinese (zh)
Inventor
韩立军
孟庆彬
刘俊
龙周彪
宗义江
金煜皓
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China University of Mining and Technology CUMT
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China University of Mining and Technology CUMT
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Priority to CN201910136707.8A priority Critical patent/CN109608143A/en
Publication of CN109608143A publication Critical patent/CN109608143A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B28/00Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
    • C04B28/02Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing hydraulic cements other than calcium sulfates
    • C04B28/04Portland cements
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/00474Uses not provided for elsewhere in C04B2111/00
    • C04B2111/00724Uses not provided for elsewhere in C04B2111/00 in mining operations, e.g. for backfilling; in making tunnels or galleries
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2111/00Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
    • C04B2111/70Grouts, e.g. injection mixtures for cables for prestressed concrete

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Inorganic Chemistry (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Curing Cements, Concrete, And Artificial Stone (AREA)
  • Lining And Supports For Tunnels (AREA)

Abstract

The invention discloses a kind of quick-setting early strength cement-silicate double solution grouting material and its application method, the injecting paste material is to mix component by matrix component and outside and be formulated, and matrix component includes cementitious material, water, and mixing component outside includes accelerator, water-reducing agent;The cementitious material ratio of mud is 0.3~0.5, and accelerator and the cementitious material slurry volume ratio for preparing completion are 1:1, and water-reducing agent addition content is the 1.0~3.0% of cementitious material.Injecting paste material of the invention has the feature that setting time is short, early strength is high, calculus rate is high, pumpability is good, stability is good, and the pre-grouting that can be applied to breaking roof country rock is reinforced, and tunnelling efficiency can be improved in roof fall when preventing tunnelling.

Description

A kind of quick-setting early strength cement-silicate double solution grouting material and its application method
Technical field
The present invention relates to a kind of quick-setting early strength cement-silicate double solution grouting material and its application methods, are suitable for mine The pre-grouting of tunnel broken top plate is reinforced, and mine and underground engineering security technology area are belonged to.
Background technique
The exploitation of mineral resources is that human society advances and a developing important component, it is to human society Development and the progress of civilization have important impetus.The state of country rock is stability of the roadway after the property and tunnel initating of country rock An important factor for.Quite a few in country rock high stress is caused by excavation, can be undertaken by country rock itself.Once rock mass is destroyed And intensity is lost, it not only can't be the ballast in tunnel, can become the load of supporting instead.In many mining area coals in China Mine can encounter that lumpiness is smaller, roadway surrounding rock in loose crushing shape during exploiting, in the coal seam acted on by mining induced stress Or digging laneway in breaking surrounding rock, discrete coal seam or rock mass equilibrium state in original equilibrium state are destroyed, lane Road country rock causes plane of weakness to further expand, new crack generation because deformation discharges big energy, broken so as to cause wall rock loosening It is broken.According to unsuitable maintenance measure, it will cause roadway surrounding rock crack and more develop, supporting difficulty increases, and eventually leads to lane Road destroys;Roadway surrounding rock after destruction is more broken, and regeneration crack is more developed, and brings bigger difficulty to roadway maintenance.
In China, there are small kiln destruction areas for many coal mines, and when exploiting to lower leaf, most of coal seam is broken by small kiln Bad, roof is broken after coal seam higher slice is destroyed by small kiln is caving, and partial region be located at old coal pit goaf stay set it is narrow Under coal column, so that roof rock is caving significantly affecting for the stress concentration region to be formed by goaf around, exploitation difficulty is caused Increase.Breaking surrounding rock grouting and reinforcing, be the various planes of weakness of country rock are enriched using slurries, re-start it is cementing, to mention High country rock overall stability and mechanical property, enhance the self-bearing ability of country rock, participate in the further equilibrium process in tunnel.Country rock note Slurry, which is reinforced, often to be combined with other roadway support forms, it not only improves rock property lithology and stress distribution, but also Deformation of the surrounding rock in tunnel is greatly reduced, to substantially improve the force-bearing situation of other support forms.But cement base is mostly used at present Class injecting paste material, such injecting paste material setting time is long, intensity is increased slow, and tunnel is in a short time after being unfavorable for grouting and reinforcing Driving, causes coal mine excavation engineering to take over anxiety.
In conclusion need to research and develop a kind of quick-setting early strength cement-silicate double solution grouting material, it can be in the short time after slip casting The interior Seed harvest for forming high intensity prevents the generation of tunnelling roof fall accident to guarantee the stability of roof cracking country rock, can Guarantee the safety of tunnelling and working face equipment installation, the safety and high efficiency for modern mine provides safeguard.
Summary of the invention
Goal of the invention: in order to overcome the deficiencies in the prior art, the present invention provides a kind of quick-setting early strength cement-water glass Glass dual-liquid slip-casting material and its application method, the injecting paste material is with setting time is short, early strength is high, calculus rate is high, pumpable The feature that property is good, stability is good.
Technical solution: to achieve the above object, the technical solution adopted by the present invention are as follows:
A kind of quick-setting early strength cement-silicate double solution grouting material, including matrix component mix component, matrix component packet with outer Cementitious material is included, mixing component outside includes accelerator and water-reducing agent;The cementitious material is used for cementing breaking surrounding rock, and accelerator is used for Accelerate the rate of set of cementitious material hydration reaction, water-reducing agent is used to reduce unit consumption of water and improves the workability of slurry.
Preferably, the cementitious material in the injecting paste material and mix outside accelerator in component proportion it is as follows: mix according to the ratio It closes cementitious material and water and carries out mechanical stirring formation mixed slurry, the volume ratio of mixed slurry and accelerator is 0.9~1.1: 1;
Cementitious material in the injecting paste material and the proportion for mixing water-reducing agent in component outside are as follows: the quality of water-reducing agent is glue The 1.0~3.0% of gel material.
Preferably, the cementitious material is ordinary portland cement (marked as PO 32.5~42.5), accelerator 10 (accelerator can accelerate the hydration reaction of cementitious material to the water glass solution of~17 ° of Be', be rapidly achieved initial setting strength, improve lane Strength and stability after road breaking roof is cementing, the generation of roof fall accident when preventing tunnelling guarantee tunnelling peace Entirely), water-reducing agent is naphthalene series high-efficiency water-reducing agent.
A kind of above-mentioned quick-setting early strength cement-silicate double solution grouting materials'use method, includes following steps:
Step 1: pouring into cementitious material, water and water-reducing agent in blender be uniformly mixed according to the ratio, forms matrix mixing Body;
Step 2: configuring water glass solution according to the ratio, then stirs evenly water glass solution with matrix mixture to be formed Cement-water glass double grouting material;
Step 3: cement-water glass double grouting transport of materials is carried out into tunnel by grouting pump and high-pressure hose Filling;
Specifically, the mass ratio of water and cementitious material is 0.3~0.5:1 in the step 1.
The utility model has the advantages that quick-setting early strength cement provided by the invention-silicate double solution grouting material, using matrix component (glue Gel material, water) and it mixes component (accelerator, water-reducing agent) outside and is formulated, which has that setting time is short, early strength Feature high, calculus rate is high, pumpability is good, stability is good;It, can be in the short time after slip casting using application method provided by the invention It is mined out can preferably to solve the old kiln in second mining tunnel to guarantee the stabilization of roof cracking country rock for the interior Seed harvest for forming high intensity Area and little Lao Yao coal column area roof cracking problem, are conducive to roadway surrounding rock stability contorting.
Specific embodiment
Below with reference to embodiment, the present invention will be further explained.
A kind of quick-setting early strength cement-silicate double solution grouting material, including matrix component and mix group outside and be divided into two parts, wherein Matrix component be include cementitious material and water, mix group outside and be divided into including accelerator and water-reducing agent.
The cementitious material is common P.0 32.5~42.5R portland cement;The water-reducing agent subtracts for naphthalene series high-efficiency Aqua, quality are the 1.0~3.0% of cementitious material;The accelerator is the water glass solution of 10~17 ° of Be', accelerator It is 1:1 with the cementitious material slurry volume ratio completed is prepared.
A kind of application method of quick-setting early strength cement-silicate double solution grouting material, includes the following steps:
Step 1: pouring into cementitious material, water and water-reducing agent in blender be uniformly mixed according to the ratio, forms matrix mixing Body.
Step 2: preparing the water glass solution of required Baume degrees complete according to the ratio, and formation is outer to mix rapid hardening solution, then will Rapid hardening solution is mixed outside and matrix mixture stirs evenly to form cement-water glass double grouting material.
Step 3: by grouting pump and high-pressure hose by cement-water glass double grouting transport of materials into tunnel.
In conclusion this case injecting paste material mixes component (accelerator, diminishing using matrix component (cementitious material, water) and outside Agent) it is formulated.The injecting paste material is with setting time is short, early strength is high, calculus rate is high, pumpability is good, stability is good Feature;Injecting paste material mix proportion scheme provided by the invention can form high-intensitive Seed harvest in a short time after slip casting, to guarantee The stabilization of roof cracking country rock, can preferably solve the second mining tunnel goaf Lao Yao and little Lao Yao coal column area roof cracking is difficult Topic, is conducive to roadway surrounding rock stability contorting.
The above is only a preferred embodiment of the present invention, it should be pointed out that: for the ordinary skill people of the art For member, various improvements and modifications may be made without departing from the principle of the present invention, these improvements and modifications are also answered It is considered as protection scope of the present invention.

Claims (5)

1. a kind of quick-setting early strength cement-silicate double solution grouting material, it is characterised in that: including matrix component and outside component is mixed, Matrix component includes cementitious material, and mixing component outside includes accelerator and water-reducing agent;The cementitious material is used for cementing breaking surrounding rock, Accelerator is used to accelerate the rate of set of cementitious material hydration reaction, and water-reducing agent is for reducing unit consumption of water and improving slurry Workability.
2. quick-setting early strength cement according to claim 1-silicate double solution grouting material, it is characterised in that: the slip casting material Cementitious material in material and the proportion for mixing accelerator in component outside are as follows: mixing cementitious material and water according to the ratio and carry out machinery It stirs and forms mixed slurry, the volume ratio of mixed slurry and accelerator is 0.9~1.1:1;
Cementitious material in the injecting paste material and the proportion for mixing water-reducing agent in component outside are as follows: the quality of water-reducing agent is gelling material The 1.0~3.0% of material.
3. quick-setting early strength cement according to claim 1-silicate double solution grouting material, it is characterised in that: the gelling Material is ordinary portland cement, and accelerator is the water glass solution of 10~17 ° of Be', and water-reducing agent is naphthalene series high-efficiency water-reducing agent.
4. a kind of quick-setting early strength cement described in claims 1 to 3-silicate double solution grouting materials'use method, feature exist In: include the following steps:
Step 1: pouring into cementitious material, water and water-reducing agent in blender be uniformly mixed according to the ratio, forms matrix mixture;
Step 2: configuring water glass solution according to the ratio, then stirs evenly water glass solution and matrix mixture to form cement- Silicate double solution grouting material;
Step 3: cement-water glass double grouting transport of materials is filled into tunnel by grouting pump and high-pressure hose.
5. application method according to claim 4, it is characterised in that: in the step 1, the quality of water and cementitious material Than for 0.3~0.5:1.
CN201910136707.8A 2019-02-25 2019-02-25 A kind of quick-setting early strength cement-silicate double solution grouting material and its application method Pending CN109608143A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113185256A (en) * 2021-03-30 2021-07-30 中国十七冶集团有限公司 Performance-controllable cement composite slurry and preparation method thereof

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1149549A (en) * 1997-07-31 1999-02-23 Mitsubishi Materials Corp Cementitious non-shrinkable high strength grout material
CN103265237A (en) * 2013-05-15 2013-08-28 北京市政建设集团有限责任公司 Dual-fluid grouting material for sand and gravel stratum and application method thereof
CN103306684A (en) * 2012-03-08 2013-09-18 中铁隧道集团有限公司 Process for grouting on back of shield segment
CN108358586A (en) * 2018-04-04 2018-08-03 北京市市政工程研究院 Add the dual-liquid slip-casting material and preparation method thereof of waste and old textile fabric
CN108439934A (en) * 2018-04-26 2018-08-24 石家庄铁道大学 A kind of rich water tunnel grouting serous fluid and grouting process
CN108840655A (en) * 2018-09-17 2018-11-20 合诚工程咨询集团股份有限公司 A kind of modified dual-liquid slip-casting material

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH1149549A (en) * 1997-07-31 1999-02-23 Mitsubishi Materials Corp Cementitious non-shrinkable high strength grout material
CN103306684A (en) * 2012-03-08 2013-09-18 中铁隧道集团有限公司 Process for grouting on back of shield segment
CN103265237A (en) * 2013-05-15 2013-08-28 北京市政建设集团有限责任公司 Dual-fluid grouting material for sand and gravel stratum and application method thereof
CN108358586A (en) * 2018-04-04 2018-08-03 北京市市政工程研究院 Add the dual-liquid slip-casting material and preparation method thereof of waste and old textile fabric
CN108439934A (en) * 2018-04-26 2018-08-24 石家庄铁道大学 A kind of rich water tunnel grouting serous fluid and grouting process
CN108840655A (en) * 2018-09-17 2018-11-20 合诚工程咨询集团股份有限公司 A kind of modified dual-liquid slip-casting material

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113185256A (en) * 2021-03-30 2021-07-30 中国十七冶集团有限公司 Performance-controllable cement composite slurry and preparation method thereof

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Application publication date: 20190412