CN109594334A - A kind of fabric printing finishing agent and preparation method thereof - Google Patents
A kind of fabric printing finishing agent and preparation method thereof Download PDFInfo
- Publication number
- CN109594334A CN109594334A CN201811209250.0A CN201811209250A CN109594334A CN 109594334 A CN109594334 A CN 109594334A CN 201811209250 A CN201811209250 A CN 201811209250A CN 109594334 A CN109594334 A CN 109594334A
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- Prior art keywords
- parts
- fabric
- finishing agent
- agent
- fabric printing
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- 239000004744 fabric Substances 0.000 title claims abstract description 47
- 238000002360 preparation method Methods 0.000 title claims abstract description 8
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 42
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 32
- PMZURENOXWZQFD-UHFFFAOYSA-L Sodium Sulfate Chemical compound [Na+].[Na+].[O-]S([O-])(=O)=O PMZURENOXWZQFD-UHFFFAOYSA-L 0.000 claims abstract description 26
- 235000011187 glycerol Nutrition 0.000 claims abstract description 15
- 239000003755 preservative agent Substances 0.000 claims abstract description 14
- 230000002335 preservative effect Effects 0.000 claims abstract description 14
- 239000002216 antistatic agent Substances 0.000 claims abstract description 13
- IPCSVZSSVZVIGE-UHFFFAOYSA-N hexadecanoic acid Chemical compound CCCCCCCCCCCCCCCC(O)=O IPCSVZSSVZVIGE-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229910052938 sodium sulfate Inorganic materials 0.000 claims abstract description 13
- 235000011152 sodium sulphate Nutrition 0.000 claims abstract description 13
- 102000006602 glyceraldehyde-3-phosphate dehydrogenase Human genes 0.000 claims abstract description 11
- 108020004445 glyceraldehyde-3-phosphate dehydrogenase Proteins 0.000 claims abstract description 11
- 239000000203 mixture Substances 0.000 claims abstract description 11
- 239000004640 Melamine resin Substances 0.000 claims abstract description 10
- 229920000877 Melamine resin Polymers 0.000 claims abstract description 10
- VXSIXFKKSNGRRO-MXOVTSAMSA-N [(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-2,2-dimethyl-3-(2-methylprop-1-enyl)cyclopropane-1-carboxylate;[(1s)-2-methyl-4-oxo-3-[(2z)-penta-2,4-dienyl]cyclopent-2-en-1-yl] (1r,3r)-3-[(e)-3-methoxy-2-methyl-3-oxoprop-1-enyl Chemical class CC1(C)[C@H](C=C(C)C)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1.CC1(C)[C@H](/C=C(\C)C(=O)OC)[C@H]1C(=O)O[C@@H]1C(C)=C(C\C=C/C=C)C(=O)C1 VXSIXFKKSNGRRO-MXOVTSAMSA-N 0.000 claims abstract description 10
- YGCOKJWKWLYHTG-UHFFFAOYSA-N [[4,6-bis[bis(hydroxymethyl)amino]-1,3,5-triazin-2-yl]-(hydroxymethyl)amino]methanol Chemical compound OCN(CO)C1=NC(N(CO)CO)=NC(N(CO)CO)=N1 YGCOKJWKWLYHTG-UHFFFAOYSA-N 0.000 claims abstract description 10
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 10
- 150000002148 esters Chemical class 0.000 claims abstract description 10
- HYJYGLGUBUDSLJ-UHFFFAOYSA-N pyrethrin Natural products CCC(=O)OC1CC(=C)C2CC3OC3(C)C2C2OC(=O)C(=C)C12 HYJYGLGUBUDSLJ-UHFFFAOYSA-N 0.000 claims abstract description 10
- 229940070846 pyrethrins Drugs 0.000 claims abstract description 10
- 239000002728 pyrethroid Substances 0.000 claims abstract description 10
- -1 sorbitan ester Chemical class 0.000 claims abstract description 10
- HGWAKQDTQVDVRP-OKULMJQMSA-N butyl (z,12r)-12-hydroxyoctadec-9-enoate Chemical compound CCCCCC[C@@H](O)C\C=C/CCCCCCCC(=O)OCCCC HGWAKQDTQVDVRP-OKULMJQMSA-N 0.000 claims abstract description 9
- 239000000839 emulsion Substances 0.000 claims abstract description 8
- 238000000034 method Methods 0.000 claims abstract description 8
- 239000004814 polyurethane Substances 0.000 claims abstract description 8
- 229920002635 polyurethane Polymers 0.000 claims abstract description 8
- VBICKXHEKHSIBG-UHFFFAOYSA-N 1-monostearoylglycerol Chemical compound CCCCCCCCCCCCCCCCCC(=O)OCC(O)CO VBICKXHEKHSIBG-UHFFFAOYSA-N 0.000 claims abstract description 7
- DNIAPMSPPWPWGF-UHFFFAOYSA-N Propylene glycol Chemical compound CC(O)CO DNIAPMSPPWPWGF-UHFFFAOYSA-N 0.000 claims description 9
- LRBQNJMCXXYXIU-PPKXGCFTSA-N Chinese gallotannin Chemical compound OC1=C(O)C(O)=CC(C(=O)OC=2C(=C(O)C=C(C=2)C(=O)OC[C@@H]2[C@H]([C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)[C@H](OC(=O)C=3C=C(OC(=O)C=4C=C(O)C(O)=C(O)C=4)C(O)=C(O)C=3)O2)OC(=O)C=2C=C(OC(=O)C=3C=C(O)C(O)=C(O)C=3)C(O)=C(O)C=2)O)=C1 LRBQNJMCXXYXIU-PPKXGCFTSA-N 0.000 claims description 6
- 102000016943 Muramidase Human genes 0.000 claims description 6
- 108010014251 Muramidase Proteins 0.000 claims description 6
- 108010062010 N-Acetylmuramoyl-L-alanine Amidase Proteins 0.000 claims description 6
- 239000007864 aqueous solution Substances 0.000 claims description 6
- 150000005686 dimethyl carbonates Chemical class 0.000 claims description 6
- 239000004325 lysozyme Substances 0.000 claims description 6
- 229960000274 lysozyme Drugs 0.000 claims description 6
- 235000010335 lysozyme Nutrition 0.000 claims description 6
- 239000003921 oil Substances 0.000 claims description 6
- 239000001397 quillaja saponaria molina bark Substances 0.000 claims description 6
- 229930182490 saponin Natural products 0.000 claims description 6
- 150000007949 saponins Chemical class 0.000 claims description 6
- 239000000243 solution Substances 0.000 claims description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- QGZKDVFQNNGYKY-UHFFFAOYSA-O Ammonium Chemical compound [NH4+] QGZKDVFQNNGYKY-UHFFFAOYSA-O 0.000 claims description 4
- 230000031709 bromination Effects 0.000 claims description 4
- 238000005893 bromination reaction Methods 0.000 claims description 4
- 229910019142 PO4 Inorganic materials 0.000 claims description 3
- 150000001408 amides Chemical class 0.000 claims description 3
- 125000002091 cationic group Chemical group 0.000 claims description 3
- 235000009508 confectionery Nutrition 0.000 claims description 3
- 150000002191 fatty alcohols Chemical class 0.000 claims description 3
- 239000004519 grease Substances 0.000 claims description 3
- NBIIXXVUZAFLBC-UHFFFAOYSA-K phosphate Chemical compound [O-]P([O-])([O-])=O NBIIXXVUZAFLBC-UHFFFAOYSA-K 0.000 claims description 3
- 239000010452 phosphate Substances 0.000 claims description 3
- 229940051841 polyoxyethylene ether Drugs 0.000 claims description 3
- 229920000056 polyoxyethylene ether Polymers 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 235000004443 Ricinus communis Nutrition 0.000 claims 1
- 240000000528 Ricinus communis Species 0.000 claims 1
- WIBFFTLQMKKBLZ-SEYXRHQNSA-N n-butyl oleate Chemical compound CCCCCCCC\C=C/CCCCCCCC(=O)OCCCC WIBFFTLQMKKBLZ-SEYXRHQNSA-N 0.000 claims 1
- 238000004043 dyeing Methods 0.000 abstract description 7
- 239000000675 fabric finishing Substances 0.000 abstract description 3
- 238000009962 finishing (textile) Methods 0.000 abstract description 3
- 239000004753 textile Substances 0.000 abstract description 3
- 239000000463 material Substances 0.000 abstract description 2
- 239000007788 liquid Substances 0.000 description 4
- JNYAEWCLZODPBN-JGWLITMVSA-N (2r,3r,4s)-2-[(1r)-1,2-dihydroxyethyl]oxolane-3,4-diol Chemical compound OC[C@@H](O)[C@H]1OC[C@H](O)[C@H]1O JNYAEWCLZODPBN-JGWLITMVSA-N 0.000 description 2
- 102000005369 Aldehyde Dehydrogenase Human genes 0.000 description 2
- 108020002663 Aldehyde Dehydrogenase Proteins 0.000 description 2
- JOYRKODLDBILNP-UHFFFAOYSA-N Ethyl urethane Chemical compound CCOC(N)=O JOYRKODLDBILNP-UHFFFAOYSA-N 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 239000003093 cationic surfactant Substances 0.000 description 2
- 238000005260 corrosion Methods 0.000 description 2
- ORCZURMCIBKBLX-UHFFFAOYSA-M diethyl-methyl-tetradecoxyazanium bromide Chemical compound [Br-].C(CCCCCCCCCCCCC)O[N+](CC)(CC)C ORCZURMCIBKBLX-UHFFFAOYSA-M 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000000835 fiber Substances 0.000 description 2
- 230000002209 hydrophobic effect Effects 0.000 description 2
- 239000006210 lotion Substances 0.000 description 2
- 239000011574 phosphorus Substances 0.000 description 2
- 229910052698 phosphorus Inorganic materials 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 125000001453 quaternary ammonium group Chemical group 0.000 description 2
- 230000002940 repellent Effects 0.000 description 2
- 239000005871 repellent Substances 0.000 description 2
- 239000002689 soil Substances 0.000 description 2
- 229920000742 Cotton Polymers 0.000 description 1
- 229920004934 Dacron® Polymers 0.000 description 1
- 208000027418 Wounds and injury Diseases 0.000 description 1
- 238000005299 abrasion Methods 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000013043 chemical agent Substances 0.000 description 1
- 230000006378 damage Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 208000014674 injury Diseases 0.000 description 1
- 238000004519 manufacturing process Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000001151 other effect Effects 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 239000005020 polyethylene terephthalate Substances 0.000 description 1
- 238000009988 textile finishing Methods 0.000 description 1
Classifications
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/244—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus
- D06M13/248—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing sulfur or phosphorus with compounds containing sulfur
- D06M13/262—Sulfated compounds thiosulfates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/51—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof
- D06M11/55—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with sulfur, selenium, tellurium, polonium or compounds thereof with sulfur trioxide; with sulfuric acid or thiosulfuric acid or their salts
- D06M11/56—Sulfates or thiosulfates other than of elements of Groups 3 or 13 of the Periodic Table
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/144—Alcohols; Metal alcoholates
- D06M13/148—Polyalcohols, e.g. glycerol or glucose
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/184—Carboxylic acids; Anhydrides, halides or salts thereof
- D06M13/188—Monocarboxylic acids; Anhydrides, halides or salts thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2243—Mono-, di-, or triglycerides
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/2246—Esters of unsaturated carboxylic acids
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/10—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing oxygen
- D06M13/224—Esters of carboxylic acids; Esters of carbonic acid
- D06M13/232—Organic carbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/01—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with natural macromolecular compounds or derivatives thereof
- D06M15/15—Proteins or derivatives thereof
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/39—Aldehyde resins; Ketone resins; Polyacetals
- D06M15/423—Amino-aldehyde resins
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/02—Natural fibres, other than mineral fibres
- D06M2101/04—Vegetal fibres
- D06M2101/06—Vegetal fibres cellulosic
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2200/00—Functionality of the treatment composition and/or properties imparted to the textile material
- D06M2200/35—Abrasion, pilling or fibrillation resistance
Landscapes
- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
Abstract
The present invention relates to textile material technical field, especially a kind of fabric printing finishing agent and preparation method thereof；Its mass parts composition is as follows: 2-8 parts of 15-18 parts of 40-50 parts of sulfuric ester, sorbitan ester, sodium sulphate, 2.5-5 parts of methyl-etherified hexamethylol melamine resin initial reduced body crosslinking agent, 2-4.8 parts of aqueous polyurethane emulsion, 6-12 parts of glyceraldehyde 3-phosphate dehydro-genase, 1-7 parts of palmitinic acid, 0.02-0.15 parts of antistatic agent, 0.01-0.02 parts of preservative, 0.2-0.5 parts of glycerin monostearate, 0.1-0.24 parts of the pyrethrins, 50-80 parts of glycerol of ricinoleic acid butyl ester；Gained fabric of the invention printing and dyeing finishing agent, simple process, it is at low cost, using fabric finishing agent of the invention, the stretch resistance energy and wear-resisting property of fabric can not only be significantly improved, but also can be suitably used for different types of fabric, keeps the original wearability of fabric and feel, have a wide range of application, has excellent performance.
Description
Technical field
The present invention relates to textile material technical field, especially a kind of fabric printing finishing agent and preparation method thereof.
Background technique
Arrangement is to improve the appearances such as gloss, the form of fabric by physical action or using chemical agent；Improve fabric
Wearability makes fabric have water repellent, refuse the characteristics such as oil.Textile finishing is to apply a kind of finishing agent on the fabric, it can change
The surface property of fabric, to assign fabric special function.Such as hydrophobic and oil repellent arrangement is with the whole of low surface tension
It manages agent and handles fabric, change the surface characteristic of fiber, be not easy fabric surface by water or glossy wet and sprawl, to reach hydrophobic
Hate the purpose of oil.Soil resistant finish and soil-releasing finiss are the surface property or surface state by changing fiber, are wearing fabric
, be not easy under use condition to attach dirt, or the dirt attached is easy to wash the processing technology of not recontamination.It printed and dyed
Cheng Zhong is mostly used various printing and dyeing agent, but the multipair fabric injury of existing finishing agent is larger, and treated, and fabric is unable to meet production
It needs.
Currently, have a large amount of printing and dyeing finishing agents in the prior art, although can all enhance to a certain extent fabric abrasion resistance,
Stretch resistance, washability etc., but there is also some defects to be only applicable in certain fabric if application range is small；Wearability, resistance to drawing
Stretching property and other effects is not satisfactory etc..
Summary of the invention
The object of the present invention is to provide a kind of fabric printing finishing agent, which can not only significantly be mentioned
The stretch resistance energy and wear-resisting property of high fabric, but also can be suitably used for different types of fabric, have a wide range of application, it is of the invention
Another purpose is: providing a kind of preparation method of fabric printing finishing agent.
In order to solve the above technical problems, The technical solution adopted by the invention is as follows:
A kind of fabric printing finishing agent, mass parts composition are as follows: 40-50 parts of sulfuric ester, the Sorbitan of ricinoleic acid butyl ester
It is 15-18 parts of alcohol ester, 2-8 parts of sodium sulphate, 2.5-5 parts of methyl-etherified hexamethylol melamine resin initial reduced body crosslinking agent, aqueous poly-
2-4.8 parts of urethane lotion, 6-12 parts of glyceraldehyde 3-phosphate dehydro-genase, 1-7 parts of palmitinic acid, 0.02-0.15 parts of antistatic agent, anti-corrosion
0.01-0.02 parts of agent, 0.2-0.5 parts of glycerin monostearate, 0.1-0.24 parts of pyrethrins, 50-80 parts of glycerol.
Further, the antistatic agent selects PMS, short chain fatty alcohol glycerin polyoxyethylene ether monoalkyl phosphate, quaternary ammonium
One of cationic surfactants.
Further, the quaternary cationics are that myristyl monomethyl diethyl hydroxyl ammonium bromide is water-soluble
Liquid or cetyl monomethyl diethyl hydroxyl bromination aqueous ammonium.
Further, the mass parts composition of the preservative is as follows: two 1-3 parts of dimethyl carbonates, lysozyme 0.8-1.2
Part, 1.2-2.4 parts of saponin extract solution.
Further, the mass parts composition of the preservative is as follows: two 2 parts of dimethyl carbonates, 1 part of lysozyme, saponin(e mention
Take 1.8 parts of liquid.
Further, mass parts composition is as follows: 16 parts of 45 parts of sulfuric ester, the sorbitan ester of ricinoleic acid butyl ester,
5 parts of sodium sulphate, 4 parts of methyl-etherified hexamethylol melamine resin initial reduced body crosslinking agent, 3.2 parts of aqueous polyurethane emulsion, 3- phosphorus
9 parts of acid glycerol aldehyde dehydrogenase, 4 parts of palmitinic acid, 0.08 part of antistatic agent, 0.015 part of preservative, 0.3 part of glycerin monostearate,
0.18 part of pyrethrins, 65 parts of glycerol.
A kind of preparation method of fabric printing finishing agent, the described method comprises the following steps:
(1) sulfuric ester of ricinoleic acid butyl ester, sodium sulphate, aqueous polyurethane emulsion, glyceraldehyde 3-phosphate dehydro-genase, palmitinic acid,
Antistatic agent, pyrethrins take sodium sulphate, palmitinic acid and enuatrol, are added in pure water, and aqueous solution is made；
(2) sorbitan ester, methyl-etherified hexamethylol melamine resin initial reduced body crosslinking agent, preservative, monostearate are sweet
Grease, glyceraldehyde 3-phosphate dehydro-genase, cocounut oil diglycollic amide, are added in glycerol, and 40-60 DEG C is made glycerite；
(3) above-mentioned aqueous solution and glycerite are mixed, and propylene glycol are added, stirring to get.
It is using the beneficial effect of technical solution of the present invention:
Gained fabric of the invention printing and dyeing finishing agent, simple process and low cost can not only using fabric finishing agent of the invention
The stretch resistance energy and wear-resisting property of fabric are enough significantly improved, but also can be suitably used for different types of fabric, keeps fabric former
Some wearability and feel, have a wide range of application, and have excellent performance.
Specific embodiment
The following examples can make those skilled in the art that the present invention be more fully understood, but these embodiments are not
Limiting the scope of the invention." one embodiment " or " embodiment " referred to herein, which refers to, may be included in the present invention at least
Special characteristic in one implementation, structure or characteristic.In the present specification different places occur " in one embodiment
In " the same embodiment not is referred both to, nor the individual or selective embodiment mutually exclusive with other embodiments.
Embodiment 1
A kind of fabric printing finishing agent, mass parts composition are as follows: 40-50 parts of sulfuric ester, the Sorbitan of ricinoleic acid butyl ester
It is 15-18 parts of alcohol ester, 2-8 parts of sodium sulphate, 2.5-5 parts of methyl-etherified hexamethylol melamine resin initial reduced body crosslinking agent, aqueous poly-
2-4.8 parts of urethane lotion, 6-12 parts of glyceraldehyde 3-phosphate dehydro-genase, 1-7 parts of palmitinic acid, 0.02-0.15 parts of antistatic agent, anti-corrosion
0.01-0.02 parts of agent, 0.2-0.5 parts of glycerin monostearate, 0.1-0.24 parts of pyrethrins, 50-80 parts of glycerol.
Further, the antistatic agent selects PMS, short chain fatty alcohol glycerin polyoxyethylene ether monoalkyl phosphate, quaternary ammonium
One of cationic surfactants.
Further, the quaternary cationics are that myristyl monomethyl diethyl hydroxyl ammonium bromide is water-soluble
Liquid or cetyl monomethyl diethyl hydroxyl bromination aqueous ammonium.
Further, the mass parts composition of the preservative is as follows: two 1-3 parts of dimethyl carbonates, lysozyme 0.8-1.2
Part, 1.2-2.4 parts of saponin extract solution.
Further, the mass parts composition of the preservative is as follows: two 2 parts of dimethyl carbonates, 1 part of lysozyme, saponin(e mention
Take 1.8 parts of liquid.
Further, mass parts composition is as follows: 16 parts of 45 parts of sulfuric ester, the sorbitan ester of ricinoleic acid butyl ester,
5 parts of sodium sulphate, 4 parts of methyl-etherified hexamethylol melamine resin initial reduced body crosslinking agent, 3.2 parts of aqueous polyurethane emulsion, 3- phosphorus
9 parts of acid glycerol aldehyde dehydrogenase, 4 parts of palmitinic acid, 0.08 part of antistatic agent, 0.015 part of preservative, 0.3 part of glycerin monostearate,
0.18 part of pyrethrins, 65 parts of glycerol.
A kind of preparation method of fabric printing finishing agent, the described method comprises the following steps:
(1) sulfuric ester of ricinoleic acid butyl ester, sodium sulphate, aqueous polyurethane emulsion, glyceraldehyde 3-phosphate dehydro-genase, palmitinic acid,
Antistatic agent, pyrethrins take sodium sulphate, palmitinic acid and enuatrol, are added in pure water, and aqueous solution is made；
(2) sorbitan ester, methyl-etherified hexamethylol melamine resin initial reduced body crosslinking agent, preservative, monostearate are sweet
Grease, glyceraldehyde 3-phosphate dehydro-genase, cocounut oil diglycollic amide, are added in glycerol, and 40-60 DEG C is made glycerite；
(3) above-mentioned aqueous solution and glycerite are mixed, and propylene glycol are added, stirring to get.
Using the performance such as following table for the fabric that printing and dyeing finishing agent of the invention arranges.
Control group 1 is commercially available conventional polyester fabric printing and dyeing finishing agent, is used to finishing of cotton textiles；
Control group 2 is commercially available conventional polyester fabric printing and dyeing finishing agent, for arranging dacron.
In conclusion those skilled in the art it should be understood that the purpose of the present invention is:
Gained fabric of the invention printing and dyeing finishing agent, simple process and low cost can not only using fabric finishing agent of the invention
The stretch resistance energy and wear-resisting property of fabric are enough significantly improved, but also can be suitably used for different types of fabric, keeps fabric former
Some wearability and feel, have a wide range of application, and have excellent performance.
Taking the above-mentioned ideal embodiment according to the present invention as inspiration, through the above description, relevant staff is complete
Various changes and amendments can be carried out without departing from the scope of the technological thought of the present invention' entirely.It is all in essence of the invention
Within mind and principle, any modification made, equivalent replacement, improve etc., it should all be included in the protection scope of the present invention.This
The technical scope of item invention is not limited to the contents of the specification, it is necessary to its technology is determined according to scope of the claims
Property range.
Claims (7)
1. a kind of fabric printing finishing agent, it is characterised in that: its mass parts composition is as follows: the sulfuric ester 40- of ricinoleic acid butyl ester
50 parts, 15-18 parts of sorbitan ester, 2-8 parts of sodium sulphate, methyl-etherified hexamethylol melamine resin initial reduced body crosslinking agent
2.5-5 parts, 2-4.8 parts of aqueous polyurethane emulsion, 6-12 parts of glyceraldehyde 3-phosphate dehydro-genase, 1-7 parts of palmitinic acid, antistatic agent
0.02-0.15 parts, 0.01-0.02 parts of preservative, 0.2-0.5 parts of glycerin monostearate, 0.1-0.24 parts of pyrethrins, glycerol
50-80 parts.
2. a kind of fabric printing finishing agent according to claim 1, it is characterised in that: the antistatic agent selects PMS, short
One of chain fatty alcohol glycerin polyoxyethylene ether monoalkyl phosphate, quaternary cationics.
3. a kind of fabric printing finishing agent according to claim 2, it is characterised in that: the quaternary ammonium salt cationic surface is living
Property agent be myristyl monomethyl diethyl hydroxyl bromination aqueous ammonium or cetyl monomethyl diethyl hydroxyl bromination aqueous ammonium.
4. a kind of fabric printing finishing agent according to claim 1, it is characterised in that: the mass parts of the preservative form
It is as follows: two 1-3 parts of dimethyl carbonates, 0.8-1.2 parts of lysozyme, 1.2-2.4 parts of saponin extract solution.
5. a kind of fabric printing finishing agent according to claim 4, it is characterised in that: the mass parts of the preservative form
It is as follows: two 2 parts of dimethyl carbonates, 1 part of lysozyme, 1.8 parts of saponin extract solution.
6. a kind of fabric printing finishing agent according to claim 1, it is characterised in that: its mass parts composition is as follows: castor-oil plant
At the beginning of 5 parts of 16 parts of 45 parts of sulfuric ester, sorbitan ester, the sodium sulphate of butyl oleate, methyl-etherified hexamethylol melamine resin
4 parts of contracting body crosslinking agent, 3.2 parts of aqueous polyurethane emulsion, 9 parts of glyceraldehyde 3-phosphate dehydro-genase, 4 parts of palmitinic acid, antistatic agent
0.08 part, 0.015 part of preservative, 0.3 part of glycerin monostearate, 0.18 part of pyrethrins, 65 parts of glycerol.
7. preparation such as a kind of method of fabric printing finishing agent of any of claims 1-6, it is characterised in that: described
Method the following steps are included:
(1) sulfuric ester of ricinoleic acid butyl ester, sodium sulphate, aqueous polyurethane emulsion, glyceraldehyde 3-phosphate dehydro-genase, palmitinic acid,
Antistatic agent, pyrethrins take sodium sulphate, palmitinic acid and enuatrol, are added in pure water, and aqueous solution is made；
(2) sorbitan ester, methyl-etherified hexamethylol melamine resin initial reduced body crosslinking agent, preservative, monostearate are sweet
Grease, glyceraldehyde 3-phosphate dehydro-genase, cocounut oil diglycollic amide, are added in glycerol, and 40-60 DEG C is made glycerite；
(3) above-mentioned aqueous solution and glycerite are mixed, and propylene glycol are added, stirring to get.
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