CN109593397A - It is a kind of suitable for intaglio printing and with special artistic effect aqueous UV ink - Google Patents
It is a kind of suitable for intaglio printing and with special artistic effect aqueous UV ink Download PDFInfo
- Publication number
- CN109593397A CN109593397A CN201811391991.5A CN201811391991A CN109593397A CN 109593397 A CN109593397 A CN 109593397A CN 201811391991 A CN201811391991 A CN 201811391991A CN 109593397 A CN109593397 A CN 109593397A
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- Prior art keywords
- aqueous
- ink
- powder
- printing
- water
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/102—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions other than those only involving unsaturated carbon-to-carbon bonds
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention provides it is a kind of suitable for intaglio printing and with special artistic effect aqueous UV ink, the aqueous UV ink include weight percent be 50-70% aqueous UV resin emulsion, the water-soluble photoinitiator of 2-5%, the organic resin powder that 15-30% partial size is 15~45um, the defoaming agent of 0.1-0.3% and 4-6% water；Wherein aqueous UV resin emulsion is emulsion acrylic resin or ester-polyurethane resin emulsion；Organic resin powder be one of amino resins powder, methyl methacrylate powder, Polyurethane resin powder or polypropylene powder resin or more than one；Water-soluble photoinitiator is 4 dihydroxy benaophenonels or bis- (2,4,6- trimethylbenzoyl) phosphine oxides of phenyl；After above-mentioned aqueous UV ink printing, first through heated-air drying, then solidify through UV.Aqueous UV ink of the invention, not only concave-convex effect is obvious, but also wearability, attachment fastness and flexibility are excellent in, and good drying property, also makes it suitable for gravure printing technique.
Description
Technical field
The invention belongs to print ink area, more particularly to one kind has special art effect with dumb light, frosted, wrinkle etc.
The ink of fruit specifically relates to a kind of suitable for intaglio printing and with the aqueous UV ink of special artistic effect.
Background technique
Ink with special artistic effect refer to the UV curing system generallyd use in industry, with silk screen printing process printing,
Ink with special visual impact.The ink of the special artistic effect of UV curing system is usually single by prepolymer, activity
The composition such as body, filler, photoinitiator utilizes this due to that ink can be caused to shrink because monomer crosslinks when the solidification of UV system
Principle can obtain the apparent of different contraction lines by the collocation of component, the selection of filler, the curing process for controlling UV lamp
Visual effect, is had using the product that such ink prints or sense of touch is fine and smooth or dumb light is thick and heavy or has metal sense frosted
Effect is particularly suitable for the class for being used to promote package.But there are costs for the UV curing system ink due to being commonly used
It is high, smell is big and operating environment is difficult to the shortcomings that controlling, and uses silk-screen printing, that there are print speed printing speeds is slow, production efficiency is low
The problem of, and the ink of the UV curing system is used for gravure printing technique, not only concave-convex effect does not have silk screen printing process effect strong,
And scraper cannot scrape ink completely, the defects of being also easy to produce bracing wire, at dirty, it is difficult to on line gravure.
Water-based printing ink is a kind of environment-friendlyink ink using water as solvent, due to not containing volatile organic solvent,
The discharge of organic volatile (VOC) can be greatly reduced, to alleviate atmosphere pollution, printing operation environment is improved, be conducive to
The health of worker, and facilitate the cleaning of printing equipment, and reduce the fire hazard due to caused by electrostatic and flammable solvent
And hidden danger, the dirt for printing harmful substance remained on surface to the harm of human body and to packaged commodity can also be reduced or eliminated
Therefore dye increasingly becomes extensive in the application of the packages printings industries such as food packaging, medical packaging and toy for children packaging.
In view of this, in recent years for the research and development of aqueous special artistic effect ink when have been reported that also there is water breakthrough frosted ink to exist
It is used on a small amount of printing product, but since there are probelem in two aspects: first is that service performance (such as erasibility, attached of water-based ink
Put forth effort) still there is a certain distance compared with UV ink；Second is that also variant compared with UV ink in appearance；Institute
To have no the large-scale popularization of aqueous special artistic effect ink.
In addition, be the auxiliary agent for making paint film that there is special concave-convex effect with the filler in special artistic effect ink formulations,
The special artistic effect ink of existing either UV curing system or heat cured water system, formula in filler all adopt
With inorganic powder or wax powder, these powder hardness are inadequate, and the Wear Resistance obtained after printing is poor, easily occur wiping the phenomenon of flower.
Summary of the invention
To solve the problems, such as present on, it is suitable for intaglio printing the object of the present invention is to provide one kind and there is special skill
The aqueous UV ink of art effect, the product printed using the ink, not only concave-convex effect is obvious, but also wearability and softness
Property is good.
In order to achieve the above object, of the invention is suitable for intaglio printing and the aqueous UV ink with special artistic effect,
Including weight percent be 50-70% aqueous UV resin emulsion, the water-soluble photoinitiator of 2-5%, 15-30% partial size be 15~
Organic resin powder, the defoaming agent of 0.1-0.3% and the water of 4-6% of 45um；Wherein aqueous UV resin emulsion is acrylic resin
Lotion or ester-polyurethane resin emulsion；Organic resin powder is amino resins powder, methyl methacrylate powder, polyurethane resin
One of powder or polypropylene powder resin or more than one；Water-soluble photoinitiator be 4 dihydroxy benaophenonels or phenyl it is bis- (2,
4,6- trimethylbenzoyl) phosphine oxide；After above-mentioned aqueous UV ink printing, first through heated-air drying, then solidify through UV.
Preferably, above-mentioned aqueous UV ink further includes the ethyl alcohol of 5-15%.
Preferably, model lrgacure127, lrgacure2100 that the preferred BASF of above-mentioned water-soluble photoinitiator is produced
Or the photoinitiator of lrgacure819DW.
In order to obtain the printed matter with dumb light visual effect, it is preferred that the partial size of above-mentioned organic resin powder is preferred
15um-20um。
In order to obtain the printed matter with frosted visual effect, it is preferred that the preferred 20- of partial size of above-mentioned organic resin powder
45um。
Preferably, above-mentioned aqueous UV ink is suitable for the printing of paper.
Of the invention is suitable for intaglio printing and the aqueous UV ink with special artistic effect, with existing with special
The ink of artistic effect is compared, and is had the advantage that
(1), using the characteristic of organic resin powder hardness height and good sphericity, make to print as filler using organic resin powder
Not only wearability is good for the product obtained afterwards, but also the concave-convex obvious, artistic effect of appearance is more prominent；In addition, due to organic resin
Powder has elasticity well, and powder can be restored quickly after deforming under external force, therefore, when printed matter surface is because rubbing
When clashing existing scratch, has the function of selfreparing.
(2) it using the formula for only having the aqueous UV lotion of macromolecular to be crosslinked, avoids participating in due to small molecule monomer anti-
The big problem of seasonable cure shrinkage occurs, make paint film tell fastness and folding resistance (flexibility) is greatly improved.
(3) using that can dissolve very well in water and the photoinitiator good with aqueous UV resin emulsion intermiscibility, make macromolecular
Aqueous UV lotion can UV light source irradiation under can carry out crosslinking curing quickly, better conform to intaglio printing technique requirement.
(4) after aqueous UV ink printing, using first through heated-air drying, again through the cured technique of UV, it is ensured that scraper energy handle
Ink is scraped completely, and the defects of generating bracing wire, at dirty is avoided, and is suitble to line gravure.
Specific embodiment
Here is several specific realities that the present invention is suitable for intaglio printing and the aqueous UV ink with special artistic effect
Example is applied, these embodiments only illustrate the aqueous UV ink formulations of the present invention and preparation, are not intended to limit the invention
Protection scope.
One, product embodiments
Embodiment 1
1, it is formulated
2, it prepares
By above-mentioned formula, photoinitiator is first dissolved in the in the mixed solvent of water and ethanol composition, add emulsion acrylic resin,
Methyl methacrylate powder and defoaming agent, stir evenly, and stand to stable system, obtain the water with dumb light view effect
Property UV ink 1.
Embodiment 2
1, it is formulated
2, it prepares
Preparation method is same as Example 1, the aqueous UV ink 2 with dumb light view effect.
Embodiment 3
1, it is formulated
2, it prepares
Preparation method is identical as embodiment, the aqueous UV ink 1 with frosted view effect.
Embodiment 4
1, it is formulated
2, it prepares
Preparation method is same as Example 1, obtains the aqueous UV ink 2 with frosted view effect.
Two, properties of product are tested
1, using following process conditions in printed on paper, what is obtained has the product that embodiment 1 and embodiment 2 are prepared
The printing 1,2 of dumb light view effect.
Printing equipment: BOBST high-speed press
Plate: 50UM electronic engraving version
Upper machine viscosity: 20 seconds (2# looks into grace cup, with ethyl alcohol: water=2:1 dilution)
Oven temperature: 80 °C
Print speed printing speed: 180 ms/min
Drying mode: the heated-air drying of baking oven is first passed through, is solidified using ultraviolet light.High-pressure sodium lamp, halogen can be used in curing light source
Plain lamp or LED UV lamp.Light source is divided to two groups, every group of two lamps, the power 15KW of every lamp.
2, the product that embodiment 2 and embodiment 3 are prepared is obtained using following process conditions in printed on paper
Printing 3,4 with frosted view effect.
Printing equipment: BOBST high-speed press
Plate: 650UM electronic engraving version
Upper machine viscosity: 25 seconds (2# looks into grace cup, with ethyl alcohol: water=2:1 dilution)
Oven temperature: 80 °C
Print speed printing speed: 180 ms/min
Drying mode: the heated-air drying of baking oven is first passed through, is solidified using ultraviolet light.
2, the performance of printing 1-4 is tested, as a result as follows:
The aqueous UV ink of the invention it can be seen from above-mentioned testing result, appearance and levelability and solvent type the UV oil of printing
Ink is close, dry good, and surface smoothness US≤0.35 reaches company standard requirement, and rubs and reach 30 times without obvious scratch,
And drawing test oil layer of ink intact through 3M adhesive tape is viscous, wearability and attachment fastness are apparently higher than existing aqueous UV ink, separately
Outside, aqueous UV ink of the invention, solvent residual amount is low, on environment without influence, is suitable for producing in batches.
Claims (6)
1. it is a kind of suitable for intaglio printing and with the aqueous UV ink of special artistic effect, including weight percent is 50-70%
Aqueous UV resin emulsion, the water-soluble photoinitiator of 2-5%, 15-30% partial size be 15~45um organic resin powder, 0.1-
0.3% defoaming agent and the water of 4-6%；Wherein aqueous UV resin emulsion is emulsion acrylic resin or ester-polyurethane resin emulsion；Have
Machine toner is in amino resins powder, methyl methacrylate powder, Polyurethane resin powder or polypropylene powder resin
One or more；Water-soluble photoinitiator is 4- dihydroxy benaophenonel or bis- (2,4,6- trimethylbenzoyl) oxygen of phenyl
Change phosphine；After above-mentioned aqueous UV ink printing, first through heated-air drying, then solidify through UV.
2. according to claim 1 suitable for intaglio printing and with the aqueous UV ink of special artistic effect, feature
Be: the aqueous UV ink further includes the ethyl alcohol of 5-15%.
3. it is according to claim 1 or 2 suitable for intaglio printing and with the aqueous UV ink of special artistic effect, it is special
Sign is: model lrgacure127, lrgacure2100 that the preferred BASF of the water-soluble photoinitiator is produced or
The photoinitiator of lrgacure819DW.
4. according to claim 3 suitable for intaglio printing and with the aqueous UV ink of special artistic effect, feature
Be: the aqueous UV ink is suitable for the printing of paper.
5. according to claim 1 to 4 be suitable for intaglio printing and the aqueous UV ink with special artistic effect,
It is characterized by: the partial size of the organic resin powder is 15um-20um.
6. according to claim 1 to 4 be suitable for intaglio printing and the aqueous UV ink with special artistic effect,
It is characterized by: the partial size of the organic resin powder is 20-45um.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811391991.5A CN109593397A (en) | 2018-11-21 | 2018-11-21 | It is a kind of suitable for intaglio printing and with special artistic effect aqueous UV ink |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811391991.5A CN109593397A (en) | 2018-11-21 | 2018-11-21 | It is a kind of suitable for intaglio printing and with special artistic effect aqueous UV ink |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109593397A true CN109593397A (en) | 2019-04-09 |
Family
ID=65960227
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811391991.5A Pending CN109593397A (en) | 2018-11-21 | 2018-11-21 | It is a kind of suitable for intaglio printing and with special artistic effect aqueous UV ink |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109593397A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110525075A (en) * | 2019-09-20 | 2019-12-03 | 湖北中烟工业有限责任公司 | A kind of process of cigarette 3D raster print product |
| CN111635671A (en) * | 2020-06-09 | 2020-09-08 | 云南通印股份有限公司 | Method for repairing decolored powder falling and scratches on surface of printed matter |
| CN114605864A (en) * | 2022-04-20 | 2022-06-10 | 广东顺德洋紫薇化工有限公司 | Blue-light-proof self-repairing water-based matte ink for plastic film |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100143592A1 (en) * | 2008-12-10 | 2010-06-10 | Yoshimitsu Arai | Image forming method |
| CN104080816A (en) * | 2012-01-31 | 2014-10-01 | 日本爱克兰工业株式会社 | Composite aggregate resin particle and composition containing same particle |
| CN105238130A (en) * | 2015-11-16 | 2016-01-13 | 新东方油墨有限公司 | Water-based UV printing ink used for gravure printing and production technology thereof |
-
2018
- 2018-11-21 CN CN201811391991.5A patent/CN109593397A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20100143592A1 (en) * | 2008-12-10 | 2010-06-10 | Yoshimitsu Arai | Image forming method |
| CN104080816A (en) * | 2012-01-31 | 2014-10-01 | 日本爱克兰工业株式会社 | Composite aggregate resin particle and composition containing same particle |
| CN105238130A (en) * | 2015-11-16 | 2016-01-13 | 新东方油墨有限公司 | Water-based UV printing ink used for gravure printing and production technology thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110525075A (en) * | 2019-09-20 | 2019-12-03 | 湖北中烟工业有限责任公司 | A kind of process of cigarette 3D raster print product |
| CN111635671A (en) * | 2020-06-09 | 2020-09-08 | 云南通印股份有限公司 | Method for repairing decolored powder falling and scratches on surface of printed matter |
| CN111635671B (en) * | 2020-06-09 | 2024-02-27 | 云南通印股份有限公司 | Restoration method for decoloring, powder-removing and scratch of surface of printed matter |
| CN114605864A (en) * | 2022-04-20 | 2022-06-10 | 广东顺德洋紫薇化工有限公司 | Blue-light-proof self-repairing water-based matte ink for plastic film |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
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| RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20190409 |