CN109589441A

CN109589441A - For using the equipment, system and method for the advanced oxidation processes of optical hydrogen ion

Info

Publication number: CN109589441A
Application number: CN201910048034.0A
Authority: CN
Inventors: R·G·芬克; W·B·埃利斯
Original assignee: Agefer Environment Group Co
Current assignee: Agefer Environment Group Co; RGF Environmental Group Inc
Priority date: 2019-01-18
Filing date: 2019-01-18
Publication date: 2019-04-09
Anticipated expiration: 2039-01-18
Also published as: CN113599562A; CN109589441B; CN113599562B

Abstract

For forming the equipment, system and method for advanced oxidation product by making the hydration catalytic surface for being catalyzed object construction and the wide range ultraviolet light exposure for (preferably including 185nm and 254nm wavelength) in 100nm to 300nm wave-length coverage.Catalytic surface and UV energy and the hydrate at catalytic surface react to form advanced oxidation product.In one embodiment, catalytic surface includes hydrophilic agent, titanium dioxide, silver, copper and rhodium.Preferably, catalytic surface is coated with the coating including hydrophilic agent, titanium dioxide, silver, copper and rhodium.Additionally provide optical hydrogen ion unit (100) comprising the ultraviolet source (204) and catalysis object construction (110) in air environment are to form advanced oxidation product.It additionally provides for the ultraviolet optical indicator of optical hydrogen ion unit (100) and monitoring and/or control system.

Description

For using the equipment, system and method for the advanced oxidation processes of optical hydrogen ion

Technical field

Present invention relates generally to ultraviolet light is applied to environment with generate be used to kill microorganism (such as bacterium, mould and Virus) and drive away smell oxidant field, relate more particularly to using ultraviolet light come to environment offer advanced oxidation product Advanced oxidation processes.

Background technique

Oxidation is a kind of chemical reaction, wherein the nominal price of element or ion increases, and loses electronics and is supplied to oxidant.Oxygen Change is to change substance by the way that substance occurs to chemically react (such as by firing or corroding) in conjunction with oxygen.Oxidation process is available In killing bacterium, mould and virus.They also routinely for chemicals (such as the volatile organic compound that generates smell Object and other inorganic and organic chemicals) it reacts.

Germicidal ultraviolet light line (254nm) is for inactivating microorganism (such as germ, virus and bacterium).Ultraviolet light is reliable , and be easy to be mounted.However, germicidal ultraviolet light can only efficiently reduce the airborne micro- life for directly passing through light Object.Unfortunately, germicidal ultraviolet light is on gas, steam or the very little or none influence of odor impact.

Although UV energy (185nm) is in the air being applied in environment there may be ozone gas and ozone is Strong oxidizer, but the ozone of raised quantity may be toxic to human and animal, and may occur not wish with environment Hope the reaction having.

Therefore, it is necessary to overcome issue discussed above, it is to provide the oxidation process for significantly improving especially to reduce The equipment, system and method for microorganism and smell in environment.

Summary of the invention

Alternative preferred embodiment according to the present invention, advanced oxidation product (such as hydroxyl, ozone, hydrogen peroxide-based, Ozonide ion, hydroxide and superoxide ion, hydrogen peroxide) it can be by new-type and novel equipment, system and method It is formed.These advanced oxidation products include in environment undesirable compound (such as microorganism, generate smell chemistry Product and other inorganic and organic chemicals) it reacts to eliminate and/or inactivate the strong effective oxidant of such compound.

According to the preferred embodiment of the present invention, equipment includes: the ultraviolet source for emitting ultraviolet light, from ultraviolet source The ultraviolet light of transmitting includes the UV energy at about 100nm and at about 300nm；And it is mechanically coupled to ultraviolet Light source and catalysis object construction including surface, the surface for being catalyzed object construction includes in titanium dioxide and following metallic compound At least one: silver, copper and rhodium, and wherein are catalyzed the surface of object construction after with ultraviolet light exposure and at surface Hydrate react to form advanced oxidation product.

The catalytic surface of catalysis object construction preferably includes titanium dioxide, silver, copper and rhodium.In addition, according to alternative excellent Embodiment is selected, catalytic surface includes hydrating agents (hydrophilic compounds) and titanium dioxide, silver, copper and rhodium.Hydrating agents may include Water, moisture and/or moisture at catalytic surface, and hydrophilic agent may include silica gel, calcium chloride, sodium chloride or other known tool There is the reagent of hydration properties.

According to alternative preferred embodiment, catalytic surface is designed to the maximized surface contact with ultraviolet light.It is preferred that Ground, surface include carinate or crimp design.

According to preferred embodiment, optical hydrogen ion unit includes the catalysis object construction generally about ultraviolet source.Newly Formula and novel optical hydrogen ion unit can be effectively formed the advanced oxidation product for advanced oxidation processes.

Alternative preferred embodiment according to the present invention, the system for being used to form advanced oxidation product include: for sending out At least one ultraviolet source for penetrating ultraviolet light, from least one ultraviolet source emit ultraviolet light be included in from about 100nm with UV energy at about 300nm；And include and the surface of the ultraviolet light exposure from least one ultraviolet source At least one catalysis object construction, the surface of at least one catalysis object construction includes in titanium dioxide and following metallic compound At least one (preferably three): silver, copper and rhodium, and wherein, the surface of at least one catalysis object construction with it is ultraviolet It is reacted with the hydrate at surface after light contact to form advanced oxidation product.In an alternate embodiment, it is System includes multiple ultraviolet sources and multiple catalysis object constructions.

The new-type and novel coating for being catalyzed the surface of object construction preferably includes the various combinations of lower list: hydrophilic Agent, titanium dioxide, silver, copper and rhodium, so that having cated catalysis target surface at surface for being formed according to the present invention The advanced oxidation product of alternative preferred embodiment will be useful.

Alternative embodiments according to the present invention additionally provide and are used to form the new-type and novel of advanced oxidation product Method.This method preferably includes: it is hydrated catalytic surface, catalytic surface includes titanium dioxide and following metallic compound: silver, Copper and rhodium；Make catalytic surface and ultraviolet light exposure；And advanced oxidation product is formed at catalytic surface.This method can be optional Ground includes absorbing the hydrate from the atmosphere around catalytic surface hydrophilicly.

Detailed description of the invention

In conjunction with the accompanying drawings to the detailed further below of embodiment, the features and advantages of the present invention be will be apparent, real Mode is applied only to be provided as non-limitative example, in which:

Fig. 1 is the perspective view of PHI unit according to the preferred embodiment of the present invention.

Fig. 2 is the perspective view of the PHI unit of Fig. 1 according to the preferred embodiment of the present invention, the side quilt of the PHI unit Partly cut away a part to show internal UV light source.

Fig. 3 is the cross-sectional side view of the PHI unit of Fig. 1 according to the preferred embodiment of the present invention, shows inside The catalysis object construction of UV light source and surrounding.

Fig. 4 is the cross-sectional side view of the alternative PHI unit of alternative preferred embodiment according to the present invention, is shown The catalysis object construction of internal UV light source and surrounding out.

Fig. 5 to 8 is the cross section side view of a part of exemplary PHI unit according to embodiment of the present invention Figure shows the advanced oxidation processes that advanced oxidation product is generated on the surface of catalysis object construction and in ambient enviroment.

Fig. 9 is the saturating of the exemplary application of the PHI unit of a preferred embodiment according to the present invention on a mounting board View.

Figure 10 is the cross-sectional side view of exemplary air-conditioning (AC) pipe-line system according to the preferred embodiment of the present invention, The AC pipe-line system includes the PHI unit being mounted in AC pipe-line system.

Figure 11 is that a preferred embodiment according to the present invention shows the PHI unit being mounted in AC pipe-line system The bottom view of AC return air duct.It includes other embodiment that we, which need, only with inner air shifter (fan) Vertical unit, the separate unit using convection current.

Figure 12 is the illustrative principles frame of the system using new-type and novel PHI unit of embodiment according to the present invention Figure.

Figure 13 shows the part-structure signal of according to an embodiment of the invention new-type and novel PHI unit Figure.

Specific embodiment

As required, disclosed herein is detailed embodiments of the invention；It should be understood, however, that disclosed embodiment is only It is only example of the invention, can presents in a variety of manners.Therefore, specific structure and function details disclosed herein is not answered Be interpreted it is restrictive, but as just the basis of claim and as instructing those skilled in the art with essence Upper any detailed construction appropriate uses representative basis of the invention in many aspects.In addition, terms used herein and phrase It is not intended to limit；But more precisely provide intelligible description of the invention.

Term " one " as used herein is defined as one or more than one.Term " multiple " as used herein is determined Justice is two or more.Term " another " as used herein is defined as more than at least second or the.As herein The term " comprising (including) and/or having " used is defined to include (comprising) (that is, open language).

Alternative preferred embodiment according to the present invention, equipment, system and method using advanced oxidation processes come with The chemicals and other inorganic and organic chemicals compounds of such as microorganism, generation smell in environment react.? The oxidant generated during advanced oxidation processes with such as microorganism, generate the chemicals of smell and other inorganic and organise The compound of product is more much effective than conventional oxidation agent when reacting.The oxidant that can be generated in advanced oxidation processes is obvious It is better than the typical decontamination agent of such as chlorine.These oxidants of commonly known as advanced oxidation product or AOP include ozone, hydroxyl, Hydrogen peroxide, ozonide ion, hydroxide and superoxide ion.All these compounds are during advanced oxidation processes Used or as advanced oxidation processes result and generate.In general, advanced oxidation product will with generally not with it is other common The compound that reacts of oxidant react.

The example of one of the strong oxidizer generated by advanced oxidation processes is hydroxyl.Hydroxyl (OH-) be it is highly unstable, To make it become have very much aggressivity to free radical.Generate hydroxyl or free radical a kind of method be when ozone and water with it is ultraviolet When light energy reacts and proton transfer occurs.Although the service life of hydroxyl is shorter, they have than ozone, chlorine or hydrogen peroxide Higher oxidation potential, and their instability quality improves their reaction speed.The powerful benefit of advanced oxidation is two Carbonoxide and water final product.

According to the preferred embodiment of the present invention, by utilizing the speed and efficiency of redundancy oxidant, oxidation process can pole The earth increases, in some cases more than 40 times.The combination during as will be discussed below using oxidant can be passed through The clearly more powerful oxidant of the conventional purge chemicals of ratio such as chlorine is generated in large quantities.Such as hydroxyl, ozone, hydrogen peroxide and super The oxidant of oxide ion can be used during advanced oxidation processes or as advanced oxidation processes result and generate. By in the process utilize advanced oxidation, it generates in the environment offer such as hydrogen peroxide and superoxide ion purification from The reaction of son, compound of the purification ion in the environment with ambient atmosphere and such as chemicals of microorganism or generation smell occur Reaction.Preferred ambient according to the present invention, when from ultraviolet source light energy and oxygen, ozone, a small amount of moisture in air and There is advanced oxidation reaction process when reacting in the hydration of object construction more metal catalytic surfaces, and will such as beg in further detail below Opinion.

According to the preferred embodiment of the present invention, advanced oxidation processes utilize wide range ultraviolet source comprising with target knot More metal catalytic surfaces of structure are the ultraviolet optical element of target.The surface preferably includes more metal catalytics and water wetted material, It can be presented with a lot of different ways, as discussed in more detail below.Water-wetted surface attracts from surrounding air and absorbs moisture. Preferably, wide range ultraviolet source is used to irradiate the surface of object construction and provides energy to the ambient atmosphere of environment.Wide range is purple Outer light source includes two ultraviolet light bands at about 254nm wavelength and at about 185nm wavelength.In the ultraviolet of 254nm Generation of the energy exposure to target surface and the hydroxyl, superoxide ion and hydrogen peroxide of activation on a surface.The surface It is also preferably hydrophilic, to absorb moisture from the surrounding air in environment.UV energy at 254nm frequency is urged Change surface and energy is provided, makes the surface and in surrounding air and mainly hydrone on hydrophilic surfaces reacts, make They split into hydroxyl in advanced oxidation processes, as will be discussed in more detail below.

Wide range ultraviolet source also generates the UV energy emitted at 185nm.In the photon energy of this emitted at wavelengths Amount is enough to make oxygen quantum splitting to form ozone gas.Then ultraviolet via the 254nm also emitted from wide range UV energy source Light energy (another type of advanced oxidation reaction is provided) initiate decomposable process by these aerial ozone molecules also Original is at oxygen.Result from this reaction process also generates hydroxyl, superoxide ion and hydrogen peroxide, discusses before being similar to Surface reaction.Using optical hydrogen ion process, not only target surface is active, but also in target surface and UV energy Air space between source is also active.

Advantageously, the air that germicidal ultraviolet light energy comes in processing environment is not used only for this process, and there are also additional effects for it Fruit, it may be assumed that continue after the peripheral region that air leaves target surface processed.This process is in reducing environment It is very effective in terms of microorganism, smell and other chemicals.This is compared to microorganism and the change only reduced at process points Close the Conventional UV light of object and the clear superiority of advanced oxidation system.According to the preferred embodiment of the present invention, by light hydrogen from The advanced oxidation gas that sub-ization process generates includes safe and environmental-friendly oxidant, is returned when reacting with pollutant To oxygen and hydrogen.The residue ozone for decomposing the by-product of (advanced oxidation reaction) as ozone and generating is safe low concentration.Root According to the preferred embodiment of the present invention, this advantageous optical hydrogen ion (PHI) process generates ozone and ozone is reduced to peace Full low-level.This process does not need maintenance or technology intervention yet.The process is the passively and table of target in operation Face serves as catalyst to generate advanced oxidation reaction and have virtually no impact on object construction itself.This advanced oxidation system and mistake Journey is more effective than conventional sterilization ultraviolet system more than traditions of the past ozone generators safety, and in terms of the elimination of micro-organisms It is more.In addition, new-type and novel advanced oxidation system and process reduce the smell in environment, this is that germicidal ultraviolet light system fails It completes.Advanced oxidation product is generated together with surrounding air by the surface of the target of ultraviolet light supply energy, without generating Nitrogen oxide gas or nitric acid, nitrogen oxide gas or nitric acid are generally acknowledged to the harmful stimulant of human and animal and pollutant (this It is usually generated a bit by other means of ozone generation).According to the preferred embodiment of the present invention, new-type and novel advanced Oxidation process generates the combination of the strong oxidant of such as hydrogen peroxide, oxide ion, hydroxyl and superoxide ion, Also generate the redundancy oxidizing gas that can be used for various useful applications.

We need to refer to the insulation and anti-leak characteristic of PPC benefit, UV lamp and mercury.We should also include by using The voltage of the variation at lamp both ends and frequency come change UV external spectrum by by it be tuned in a manner of our desired output.

Fig. 1 and 2 shows optical hydrogen ion (PHI) unit 100 according to the preferred embodiment of the present invention.PHI unit 100 It is the exemplary high-level oxidation reaction unit that can be used for many different applications, as will be discussed below.PHI unit 100 includes Generally about the catalysis object construction 110 of UV energy source (not shown in FIG. 1).Preferably, it is catalyzed object construction 110 It is the hydrophilic-structure for absorbing the hydrone at the surface of object construction, as being already discussed above.

PHI unit 100 includes bottom cover 102 and top cover 104, and unit is in combination in structural support ultraviolet light as a whole The catalysis object construction 110 of energy source and surrounding.Although not as shown in figs. 1 and 2, according to an illustrative embodiments, Silicon retaining ring (or washer) and metal collar inside bottom cover 102 are operated in combination by an end of ultraviolet light (U.V.) lamp 204 Bottom cover 102 is fixed and is sealed in portion, and the other end of U.V. lamp 204 is fixed to by the fixing inside top cover 104 Top cover 104.Bottom cover 102 and top cover 104 may also comprise for engaging and further supporting PHI unit 100 together with other structures Feature or additional structural detail, such as lug 106,108, such as cope with ordinary skill people in view of current discussion Member becomes apparent.

At 102 end of bottom cover of PHI unit 100, the matching connector in the UV energy source 204 for such as UV lamp 204 End 120 is shown with for providing the matching connector 122 of electrical contact, and electrical contact is used for 204 thermocouple of UV energy source Close external power source (not shown).In this example, at bottom cover 102, have and be mechanically coupled to PHI unit 100 separately The mechanical matching structure 130,132 of one structure (not shown).For example, mechanical matching structure 130,132 can be by making screw bolt PHI unit 100 support construction is connected to across the corresponding opening in mechanical couplings structure 130,132 (such as to install Plate), PHI unit 100 is fixed to another structure with the lock nut (not shown) being screwed on screw bolt, such as will PHI unit 100 is fixed to mounting plate.

Catalysis object construction 110 preferably only includes the partially enclosed structure with such as open area in hole 112,114, Open area allows the ambient gas near catalysis target surface to pass through, and also a part of UV energy is allowed to pass through.? In one illustrative embodiments, machinery catalysis object construction 110 has about 50% active catalytic surface, and remaining area is Such as the open area in hole 112,114, to allow UV photon energy to pass through from object construction 110, thus promote in PHI unit Additional reaction outside 100.According to the needs to different application, object construction 110 can be opened in 0% (flow-through cell) and 95% It puts and changes between region, preferred open area percentage is between 40% and 60% open area.

Catalysis object construction 110 is preferably shaped to allow substantially maximum surface region, while limiting direction target The incidence angle of the UV photon energy of structure 110.For example, the duplicate V-arrangement geometry in carinate or crimp design allows The proper proportion of open area and closed area and maximizing will be exposed to occur with UV energy and ambient enviroment anti- The surface region for the catalysis target 110 answered.Duplicate v-shaped structure can be altered or modified certainly as other geometries to adapt to Optional manufacture demand, new available manufacturing technology, the surface impacts, circle or the wavy object construction that texture or have facet, Air or fibrous material or usually increase can for make that hydrophilic catalysis material and UV energy and ambient gas react With any structure appropriate of surface region.Due to specifically applying, the structure of PHI unit 100 can also be from preferred embodiment Change to meet specific topology requirement, it is apparent such as to cope with those of ordinary skill in the art in view of current discussion.For example, In specific applications, big or customization PHI unit may have different topology requirements.

Fig. 2 is referred in the case where continuing to refer to figure 1, in a part and top cover 104 for removing catalysis object construction 110 Fig. 2 cross-sectional view in expose internal UV energy source 204.(the ultraviolet light in this example of UV energy source 204 Lamp) it include sealing cover 206 in the top end of lamp 204.UV lamp 204 is illustrated as at cut ends 202 from catalysis object construction 110 Extend outwardly.However, UV light source 204 is substantially surrounded by catalysis object construction 110 substantially to maximize exposure in preferred arrangement In the surface region of the catalysis object construction 110 of the UV energy from U.V. lamp 204.In this example, it is catalyzed target Structure 10 is along the central axis of UV lamp 204 radially generally about UV energy source 204.This is preferably provided to available U.V. The maximum catalytic surface of light photon energy contacts.Wide range UV light source 204 is preferably designed so that substantially 100 to (total between 300nm The frequency band for including about wavelength 185nm and 254nm) wave-length coverage in operation.UV light source 204 can be low-pressure mercury vapor lamps (typical standard HO or VHO output), middle pressure mercury vapor light or LED based technology (or these any combination).

Although catalysis object construction 110 works as radially around UV lamp 204 and uses LED based in this example When technology, LED array can arrange radially or in plane axis relative to catalysis object construction, it is intended that catalysis object construction symbol The overall shape of LED array is closed to allow the maximum catalytic surface exposure to UV light source.According to the design alternative of optional application, base In current discussion come other arrangements between the surface imagining at least one U.V. light source and be catalyzed object construction, such as in view of Current discussion and to cope with those of ordinary skill in the art apparent.For example, at least one U.V. light source and preferably multiple U.V. light source may be positioned to relatively very close at least one of environment specific at least the one of the catalysis object construction of application A surface, wherein can each be specially shaped and be suitable for specific specific to the surface of the catalysis object construction of application Expected utility is provided in, while also being provided for enhancing in such being catalyzed at the surface of object construction specific to application Advanced oxidation product formation catalysis target surface.

As more detailed non-limitative example, multiple wide range U.V. lamps can be located in air conditioning duct system, wherein Inner surface generally about the pipeline (or multiple pipelines) of multiple wide range U.V. lamps includes catalysis object construction material, and is come from U.V. the formation that the U.V. light photon energy of lamp is substantially contacted to promote the advanced oxidation product at such surface to react.When So, each such U.V. lamp can be extraly by catalysis object construction 110 radially around as having already discussed above, with volume Other places promotes the formation of the advanced oxidation product reaction at the surface of catalysis object construction 110.As the multiple U.V. light of utilization Another optional example in source --- wherein at least one U.V. light source is substantially surrounded by catalysis object construction 110, each in this way The outer surface of catalysis object construction 110 can be exposed in the specifically outside of catalysis object construction 110 and close to specific It is catalyzed the U.V. light of the U.V. lamp of object construction 110, to additionally facilitate in the outer surface of specifically catalysis object construction 110 The formation of the advanced oxidation product reaction at place.In general, by least one catalysis object construction and according to the multiple of specific application A large amount of available surface regions that are exposed of catalysis object construction are contacted with U.V. light photon energy, it will correspondingly enhance advanced oxygen Change product forming process.

Catalysis object construction material includes the multiple compounds especially at the surface of catalysis object construction 110.Preferably, Being catalyzed targeted surface material includes five kinds of compounds, that is, four kinds of metallic compounds and hydrating agents.These compounds preferably include Titanium dioxide (TiO₂), copper metal (Cu), silver metal (Ag), rhodium (Rh) and hydrating agents (such as silica gel (tetraalkoxysilane TMOS, tetramethoxy-silicane, tetraethoxysilane TEOS)).Hydrating agents also may include with affinity to attract or absorb surrounding The combination (that is, hydrophilic and hydrating agents) of any compound appropriate or compound of water.At the surface of catalysis object construction 110 The upper surface of determine various metals compound combination and preferably four kinds metallic compounds combination include be used for advanced oxygen Change process generates the new-type and novel structure of advanced oxidation product reaction, as discussed in more detail below.

Silver has antimicrobial property.For example, it will if air bumps against the silver at the surface in catalysis target 110 Kill the microorganism in air.It has been found that combined at the surface of catalysis target 110 with silver titanium dioxide (with using only two Titanium oxide is compared without silver) formation (such as hydroxyl, superoxide ion and peroxidating that advanced oxidation product can be made to react The formation of hydrogen) it is about 3 times fast.Copper has antimicrobial property, also helps speed up anti-at the surface of catalysis object construction 110 It should be to generate advanced oxidation product.Rhodium has antimicrobial property, or destroys nitrogen compound and enhance advanced oxidation product The catalyst of formation.

Hydration immunomodulator compounds obviously increase the reaction of advanced oxidation product (mainly on the surface of catalysis object construction 110 With around catalysis target 110 environment in hydroxylated product) formation.Environmental wet in the environment around catalysis target 110 Degree and (via forced evaporation, ultrasonic atomizatio or other means appropriate) induction humidity are usually in the table of catalysis target 110 Humidity is provided at face, to provide the hydrating agents (that is, water) at the surface of catalysis target 110 to promote advanced oxidation product anti- The formation answered.In addition, ambient humidity and induce humidity can by the surface of catalysis target 110 such as silica gel hydrophilic and Hydration immunomodulator compounds are attracted to catalysis target surface, the advanced oxidation product at the surface of catalysis target 110 is remarkably reinforced The formation of reaction.This is particularly apparent advantage of the invention.

The combination of five kinds of compounds discussed above, which can be arrived in any one of this five kinds of compounds less than 1%, is more than 90% Between change, as alternative embodiments according to the present invention different application may expect.Different manufacturing technologies It can be used for providing the combination with desired compound discussed above to the surface of catalysis object construction 110 with method.For example, packet The coating for including desired compound can be provided that the surface of catalysis object construction 110.These different manufacturing technologies and method can Including but not limited to adhesive, polymer, baking (low-heat and high fever application), charging and pigment carrier technology.In addition, other non- Specific compound can be added to the combination of five kinds of compounds, to help to adhere to and/or be adhered to appointing for catalysis object construction 110 What particular surface, such as in view of current discussion and coping with those of ordinary skill in the art becomes apparent.

According to a non-limitative example, preferred five kinds of compounds can be provided in the mixture for also including base solvent Be combined to provide mixed solution.It then can be for example by sprinkling or by other known deposition method by mixed solution It deposits on the surface of catalysis object construction 110.Then base solvent will evaporate, stay at the surface of catalysis object construction 110 The expectation of lower compound is combined.Method for the combination of desired compound to be provided to the surface of catalysis object construction 110 will Depend entirely on the design alternative to the available techniques for using specific object construction in the application.

With reference to Fig. 3, the cross section side view of exemplary PHI unit 100 according to the preferred embodiment of the present invention is shown Figure.Internal UV lamp 204 is substantially surrounded by external catalyst object construction 110.In this example, UV lamp 204 includes mercuryvapour gas Body 302, when it is energized under frequency appropriate (such as the electricity by the electrical contact offer via matching connector 122 Can) when will generate the wide range UV energy that radiates from UV lamp 204.UV lamp 204, which has, is preferably substantially coated with protective barrier The outer surface of coating, is coated with fluorocarbon protective coating or film 208 in this example, and protective barrier coating substantially wraps Firmly UV light source 204 and by allowing UV light to be made approximately through the material of protective barrier coating, for example, preferred fluorocarbon or Other protection plastic coatings or barrier material.The main purpose of this outer protection barrier coatings or membrane structure 208 is to provide To the insulation barrier of UV light source, to prevent the heat loss in cold operating environment, reduce temperature shock, and thus optimize UV light Source efficiency.This outer protection coating structure 208 also functions as physical barriers (leakage barriers), prevents in UV light source 204 Quartz, glass used in construction, mercury or other materials leave fluorocarbon protective barrier coating 208, that is, to PHI unit The case where 100 accidental destruction or damage.Another apparent benefit of this fluorocarbon coating or membrane structure 208 is it Prevent fragment and other pollutants from contacting and being possibly adhered to UV light source 204 and possibly reduce its working efficiency or heavier Strategic point is to its physical damage.Preferably, protective barrier coating 208 is made of the fluorocarbon for providing external apolar surfaces, It does not attract external contaminants or fouling products, therefore provides soiling protective barrier surface for UV light source 204.It is this new-type and novel Construction and arrangement allow all U.V. light energies from UV light source 204 all to launch from protective barrier coating 208.At this In a example, protective coating structure 208 can be the contracting tubular-film or coating structure in the outer surface of UV lamp 204.However, At the inner surface of U.V. lamp 204 and/or other protections and/or coating structure can be used in outer surface, such as begs in view of current By and coping with those of ordinary skill in the art becomes apparent.In addition, the material and shape and texture of coating structure can be from working as precedent The fluorocarbon draw of son changes to alternative material and shape and texture, as long as alternative coating material, shape and texture Allow U.V. light to pass through optional coating structure so that the surface of the accessible catalysis object construction 110 of U.V. light photon energy with The advanced oxidation product at the surface of catalysis object construction 110 is promoted to form reaction.

Being catalyzed object construction 110 includes inner surface 304 and outer surface 306.Inner surface 304 is directly exposed to internal UV lamp 204.Inner surface 304 directly receives UV energy from UV lamp 204.Outer surface 306 is preferably also coated with catalysis material, so that It can be exposed to the UV energy from external ultraviolet source or may be from the reflection ultraviolet light of internal UV lamp 204, i.e., from The U.V. light of external reflective surface (not shown) reflection.Particularly, the UV light of this reflection may originate from UV lamp 204, then pass through It is catalyzed the opening 112,114 (see Fig. 1) of object construction 110, then reflects back into outer surface 306 from external structure.With this side Formula, catalysis object construction 110 maximize exposed surface region substantially substantially to maximize at surface 304,206 and in week The advanced oxidation product enclosed in gaseous environment forms reaction.

With reference to Fig. 4, the alternative arrangement 400 of PHI unit according to the preferred embodiment of the present invention is shown.This can The variation that PHI unit 400 includes internal UV light source is substituted, so that UV lamp 204 is surrounded by barrier structure 402, barrier structure 402 is right The U.V. light emitted from U.V. lamp 204 be it is sufficiently transparent, to allow U.V. light to pass through barrier structure 402 and contact surface 304 To promote the formation of the advanced oxidation product reaction at surface 304.Preferably, barrier structure 402 is located at the appearance of UV lamp 204 Face very close in region 404.In this alternative embodiment, the barrier structure 402 of surrounding includes by emerging in sense Near interesting frequency made of the sufficiently transparent material (such as quartz) of the UV energy of (i.e. about 100 arrive 300nm wavelength) thoroughly Bright pipe.This external barrier structure 402 in the whole length of UV lamp 204 generally about and encase internal UV lamp 204.At this In example, the surface of external barrier pipe 402 and internal UV lamp 204 in very close to region 404 (at nominal range), and it is excellent It is close that selection of land, silicon or teflon seal object generate the bonding between the end of barrier tube 402 and the end of internal UV lamp 204 Envelope.This exterior tube 402 provides in the case where internal UV lamp 204 breaks down leakage barriers (such as to accommodate due to breaking down U.V. lamp 204 and generate mercuryvapour 302 and any rupture glass and fragment), also offer UV lamp 204 Thermal protection benefit Place, to be obviously prolonged the probable life in UV energy source 204 and maximize output by making 204 thermostabilization of light energy source Efficiency, and light energy source 204 is protected to influence from wet environment (condensation etc. in cold environment).

Generally, it is catalyzed being designed and arranged for target and preferably considers 1) at a distance from UV light source and 2) how to maximize and urge Change the surface region that is exposed of target, to enhance the formation of advanced oxidation product.It is closer from UV light source to be catalyzed target, is provided to The UV light photon energy for being catalyzed the surface region of target is higher.In addition, the surface region that is exposed of target should be maximized To allow the maximum surface region contacted with U.V. light photon energy and ambient enviroment, for maximizing formation and activating advanced oxygen Change the reaction of product.Preferably, catalysis target includes carinate or crimp design to maximize is exposed to UV light photon energy and week The surface region in collarette border.

With reference to Fig. 5,6,7 and 8, the formation of advanced oxidation product process is more thoroughly discussed below.It is according to the present invention to show Example property embodiment, the UV energy from U.V. light source 204 are launched and are directed to the surface district of catalysis object construction 110 Domain is such as having also been discussed above and as shown in FIG. 5.UV energy includes the frequency at about 185nm wavelength 502 Rate interacts to generate ozone 602, as shown in Figure 6 with oxygen 504 in the environment.Ozone is can to kill microorganism (example Such as bacterium, mould, virus) and can also react with the chemicals in environment to reduce the strong oxidizer of smell.Emit simultaneously The UV light source 204 of 185nm UV light energy also emits the UV light energy at about 254nm wavelength 702, as shown in Figure 7.? Ozone is decomposed back to oxygen (704) by this UV light energy at 254nm, to also advantageously discharge hydroxyl and other advanced oxidations Product.In addition, the surface of the U.V. light energy contact catalysis object construction 110 at 254nm 702.It is catalyzed object construction 110 Preferably also include hydrophilic agent including hydrating agents, moisture is attracted to catalysis object construction 110 from the air in ambient enviroment Surface.The U.V. light energy at 254nm 702 contacted with the surface of catalysis object construction 110 and the moisture at surface The set of son and metal reacts to generate advanced oxidation product, such as hydroxyl, hydrogen peroxide, superoxide ion, these Advanced oxidation product is highly reactive and will react with ambient enviroment to kill microorganism, reduce smell, and will be with The other undesirable organic and inorganic chemicals found in the environment react and eliminate these organic and inorganic chemistry Product.This leads to the purification and purification process of the surrounding air of environment.These advanced oxidation products are very short-life and height It is reactive, so that advanced oxidation product will be restored to (in a short time) after reacting with the compound in environment Safe and harmless oxygen and hydrone.In addition, the ozone generated in this process is by fast decoupled and reverts to oxygen (704), with So that after the environment that advanced oxidation processes have purified microorganism, smell and other undesirable compounds and impurity, Level of ozone in environment is usually maintained at safe low-level immediately.In addition, the U.V. light energy at 254nm wavelength shows Sterilization idiocratic out, and valuably kill the bacterium and microorganism directly contacted with UV light energy.This also helps to kill empty around Gas neutralizes microorganism in the environment.Also the additional wavelength from 100 to 300nm is utilized to use and correspond to UV light source 204 not The activation energy of co-wavelength reacts with compound.

Fig. 8 shows total exemplary high-level oxidation product forming process according to the preferred embodiment of the present invention.It comes from U.V. the wide range U.V. light energy 802 of light source 204 interacts with ambient enviroment and contacts the surface of catalysis object construction 110. In this example, the 185nm wavelength from wide range U.V. light source 204 substantially generates ozone, and substantially simultaneously in 254nm wavelength Place destroys ozone and is converted into oxygen.The group that ozone in the atmosphere of environment around U.V. light source 204 is generated and destroyed It closes and reacts generation sterilization U.V. light, hydroxyl, superoxide ion, mistake at the surface of hydration catalysis object construction 110 Multiple benefits of hydrogen oxide, oxide ion and peroxide and other such advanced oxidation products.Advanced oxidation product Surface combination with sterilization U.V. light provide simultaneously the reduction of apparent microorganism, the smell of reduction and in the environment it is certain not The benefits such as the removal of desirable chemicals.For example, advanced oxidation processes elimination is as follows: paint, pet odors, sewer gas Taste, volatile organic compounds, chemical foul smell, decontamination chemicals smell, culinary art smell, rotten organic substance, virus, fire and Cigarette, waste odours, hydrocarbon, mould and mould and other microorganisms.

With reference to Fig. 9,10 and 11, new-type and novel advanced oxygen one of according to the preferred embodiment of the present invention is shown The exemplary application of change process.System for purifying and purifying air conditioning and/or heat (AC) pipe-line system, benefit are shown With new-type and novel advanced oxidation processes for example, by reducing smell, air pollutants, chemical odor, cigarette, mould, bacterium Sick buildings object risk of Syndrome is eliminated with virus.As shown in figure 9, PHI unit 100 is installed at its bottom cover 102 In loading board 803, mounting plate 803 provides the structural support to PHI unit 100 when being located in AC pipeline 904 (see Figure 10).Pacifying Shell 804 comprising the circuit for PHI unit 100 to be powered and controlled to PHI unit 100 is shown on the opposite side of loading board 803. Shell 804 is for example including the power supply and ballast circuit for energizing to PHI unit 100.In addition, according to the present invention alternative Embodiment, fiber optic cable 806 extend through mounting plate 803 and shell 804 from PHI unit 100 to provide and indicate that PHI is mono- The optical indicator when member 100 comes into operation.This optical fiber optical indicator 806 can be detected failure feelings by monitoring system use When condition, such as PHI unit 100 improperly run and may need replacing U.V. lamp 204.In addition, optical fiber optical indicator 806 may be provided in the means that the operation of PHI unit 100 is monitored and controlled under various applications.One end of fiber optic cable 806 is excellent Selection of land is substantially contacted with the wide range ultraviolet light emitted from the U.V. light source 204 of PHI unit 100, and fiber optic cable 806 is another One end preferably emits visible light as the manipulable instruction of U.V. light source 204 in PHI unit 100.Fiber optic cable Material can provide filtering effect for the U.V. light transmitted by fiber optic cable, so that from fiber optic cable indicator 806 transmittings that come out are wide mostly in visible-range and by most equipment and using being safe.Optionally, it filters Wave device (not shown) can be inserted into appointing between the output of U.V. light and fiber optic cable indicator 806 from PHI unit 100 What at point, so that filter will substantially remove unwanted U.V. light energy (such as at unwanted frequency), allow simultaneously Light in visible-range emits from fiber optic cable indicator 806.In short, fiber optic cable 806 is (any appropriate Type can be used) means for remotely monitoring the state of PHI unit 100 are provided.As security feature, using cable itself or Second filter absorbs 100 and arrives 300nm wavelength, while allowing visible light part (typically within the scope of 500nm) from optical fiber light Cable transmission is learned to go out to be used at the long-range display point that can directly indicate the state of PHI unit 100.Alternatively, optical fiber Monitoring can also be realized by UV light (100-300nm) is transmitted to photoelectric detector (not shown) and optionally controls U.V. lamp Any material appropriate of the real-time method of 204 outputs is made.In addition, can be coupled to can for this photoelectric detector and sensor Frequency, variable voltage power supply (not shown) with to U.V. lamp 204 energize so that it can be then used to adjust and change U.V. the overall output power (photon energy) of lamp and in one or more ranges of U.V. modulation frequency specific to frequency Export energy.This is the valuable feature of the preferred embodiment of the present invention.

For example, with reference to Figure 12, the exemplary of the system 1200 for utilizing new-type and novel PHI unit 100 is discussed below Functional block diagram.System 1200 includes at least one PHI unit 1202 comprising corresponding in its output end transmission such as instruction The fiber optic cable 1204 of the optical signal of the U.V. lamp mode of operation of PHI unit 1202.

Preferred embodiment in accordance with the present invention, the visible light emitted from fiber optic cable 1204 will serve as at least one The direct pop-up indicator of 1202 mode of operation of PHI unit.It is directly coupled to the source UV 204 in PHI unit 100 (referring to Fig. 1) Fiber optic components will be preferably equipped with UV filtering characteristic, or alternatively add individual UV filter and (do not show Out), can be used to be transferred to remotely from the visible light (usually within the scope of 400 to 500nm) that PHI unit 1202 emits Position or unit panel are to monitor PHI location mode.The example of both Setup Types may is that the display surface in an equipment Plate or Remote Installation (such as needed in the installation of certain HVAC systems) indicator far from PHI unit.Along fiber optic cable The light of 1204 transmission is terminated at lens (not shown), which will illuminate and serve as visual displays (not shown) for operation Person's monitoring or other equipment monitoring.

For example, being coupled to the photoelectric detector of computer system 1208 or photometer (not shown) can be used for monitoring automatically extremely The ON/OFF state of a few PHI unit 1202.Computer system 1208, when detecting fault condition, such as when at least one A PHI unit 1202 should be ON but detect that it is OFF (for example, without UV light quilt at photoelectric detector or photometer Detect or UV light be not detected higher than predetermined power level) when, then it can be to user and/or operator and/or skill Art personnel (it is alternatively referred to as user/operator/technical staff herein) send alarm signal.Alarm signal may include sound Sound signal (such as passing through audio alarm sound), visual signal (such as by lamp on console display or pass through user/operation The light source at position that member/technical staff is readily seen that, it might even be possible to the data including being sent to remote computer (not shown) Signal (such as email message), so it is sent to the wireless transmission signal of the portable unit (not shown) of people, such as bee Cellular telephone or paging equipment, then, even if user/operator/technical staff is far from least one PHI unit 1202 at facility Specific installation, monitored fault condition can also be alerted to user/operator/technical staff.It is alternative in view of this discussion Monitoring system configuration and operation should be obvious to those skilled in the art.

With continued reference to Figure 12, another preferred embodiment according to the present invention, system 1200 can be in optical fiber optics electricity The reality for using UV transparent optical fibers optical material (such as quartz) to be generated as transmission by UV lamp 204 (referring to Fig. 1) in cable 1204 The device of UV light wave.Therefore preferably straight equipped with the fiber optic cable 1204 of UV transparent optical fibers optical material (such as quartz) Meet the UV for being mechanical coupling to UV lamp 204 (without air space) to collect the entire 100-300nm range emitted by the source UV 204 Then light is directed to so that UV light (by optical coupled) is transferred to UV photodetector 1206 from least one PHI unit 1202 Each of at least one PHI unit 1202, the UV spectrum that UV photodetector 1206 emits analysis from UV lamp 204.According to this Alternative embodiments, UV photoelectric detector 1206 include photometer or other spectral analysis apparatus, pass through user interface (example Such as via display (not shown)) to user/operator/technical staff provide output.This will make user/operator/technology people Member can direct monitoring and quantify at least one PHI unit 1202 practical UV wavelength and energy output.This can be at least one The local of the installation of a PHI unit 1202 is completed, or be can be and be done remotely, such as will by fiber optic cable 1204 UV optical signal is transmitted to the UV photoelectric detector 1206 of long range positioning.

Another alternative embodiments according to the present invention, can be used method same as described above, add and UV light The computer control system 1208 that photodetector 1206 couples.According to the alternative embodiments, UV photoelectric detector 1206 is wrapped Photometer or other spectral analysis apparatus are included, the output data for indicating the mode of operation of at least one PHI unit 1202 is provided Signal.Controller 1208 can monitor the data-signal from UV photoelectric detector 1206 to determine fault condition, such as The OFF state that any one of at least one PHI unit 1202 detects, such as it is directed at least one PHI unit Any one of 1202 exceed normal operating margin condition.It then, can from the data-signal that UV photodetector 1206 is collected To provide the adjustable source 1210 of electric power for adjusting at least one PHI unit 1202.Computer control system 1208 can To provide output signal to user interface.Right rear line/operator/technical staff provides information, user/operator/technology Then personnel can indicate how computer control system 1208 adjusts the power output of at least one PHI unit 1202.It is optional Ground, computer control system 1208 can be with the power outputs of at least one PHI unit 1202 of adjust automatically.In addition, department of computer science The case where system 1208 can monitor at least one PHI unit 1202, then can be to user and/or operator and/or technology people Member's (it is being alternatively referred to as user/operator/technical staff herein) sends information/alarm signal.Information/alarm signal may include Voice signal (such as passing through audible sound), visual signal (such as by least one lamp on display or pass through user/behaviour At least one light source at the position that author/technical staff is readily seen that), even may include being sent to remote computer (not Show) data-signal (such as email message).Information/alarm signal may include even the portable mono for being sent to people The wireless transmission signal of first (not shown), such as cellular phone or paging equipment, then, even if user/operator/technical staff Specific installation far from least one PHI unit 1202 at facility, can also notify/alert user/operator/technical staff The case where monitored.In view of this discussion, alternative monitoring system configuration and operation are to those skilled in the art It should be obvious.

Regulated power supply 1210 can be adjusted to alter the output work for being coupled to each of at least one PHI unit 1202 At least one of frequency, electric current and voltage of rate signal.By adjusting regulated power supply 1210, change electromotive power output signal, Such as its voltage level or its AC frequency, then send it at least one PHI unit 1202.This will make user/operator/ Technical staff or automatic controller 1208, or both control the operation of at least one PHI unit 1202.For example, user/operation Member/technical staff or automatic controller 1208 can according to the requirement of specific application or ensure to realize during its working life to The best output of a few PHI 1202, " dialling in " (adjusting) adjustable electrical power signal is to adjust at least one PHI unit 1202 The source U.V. output, such as gross output or for example meet specific output Energy distribution one or more frequency ranges it is defeated Power level out.

Referring again to Fig. 9,10 and 11, it illustrates the exemplary system and application of new-type and novel PHI unit 100, And it is discussed below.As shown in Figures 9 and 10, PHI unit 100 and mounting plate 803 are arranged and are installed in mounting arrangements 902 On AC pipeline 904, so that being flowed through by the air of AC pipeline 904 and contacting PHI unit 100.As shown in Figure 10, PHI Unit 100 substantially extends through the opening in one of wall of AC pipeline 904 in AC pipeline 904, and in local quilt appropriate Mounting plate 803 (being shown in FIG. 9) and include to PHI unit 100 power and control PHI unit 100 circuit outer enclosure 804 supports.Shell 804 can also be installed remotely to allow the installation in the region that cannot obtain enough spaces.

Air inlet 906 from include pollutant, smell, mould, bacterium, virus and other undesirable chemicals building Substance environment receives air.When this air passes through pipeline 904, it and PHI unit 100 and U.V. light contact and exposed to PHI Unit 100 and U.V. light, and as in early time by discussion, advanced oxidation processes will substantially purify and purified air.This A air is then driven through remaining AC pipeline 904 and in conjunction with the advanced oxidation product generated in PHI unit, wherein When the remaining advanced oxidation product generated in PHI unit is travelled downwardly along pipeline together with air, it continues to reduce Remaining pollutant.Any residue advanced oxidation product is then departed from and enters in room, they continue quickly to subtract in the room Any additional ambient contamination object encountered less.In addition, sterilization UV light helps the elimination of micro-organisms, such as pass through A.C. pipeline 904 germ, mould, virus and bacterium.In this way, the advanced oxidation processes provided in this application by PHI unit 100 To purification and purified air in conjunction with sterilization U.V. light, for building in substance environment.

Another alternative embodiments according to the present invention, PHI unit 100 is intended to serve as can be by single or multiplely (only By specifically using limitation) modular system that uses.PHI unit 100 is suitably adapted for meeting a plurality of types of installations in itself.? In one embodiment, PHI unit 100 is mounted to via attached plate convenient for the (example in many different types of installations Such as in HVAC system (such as in the AC pipe-line system being such as already discussed above)) processing.In yet another embodiment, PHI unit 100 is attached to rigid structure (having fan component sometimes) via flexible clip in order to sky in several applications Gas disposal.

In one embodiment, using new-type super hydrophilic photocatalysis coating in conjunction with active ion, optical hydrogen ion (PHI) process is the unique air and superficial treatment system for greatly reducing airborne microorganism, VOC and particle.

PHI technology is using ideally (this can be mercuryvapour technology to the wide range UV transmitter in 100-400nm spectrum LED).This UV energy is subsequently used in the unique photochemical catalyst that activation coats on the longitudinal cellular construction for folding and perforating. This energy activates photochemical catalyst then to generate advanced oxidation reaction with Inter-tier Space on the surface of PHI unit.It is unique Catalyst includes the extremely porous anhydrous magnesium carbonate substrate for being scattered with the titanium dioxide crystal (anatase structured) being formed in situ. This catalyst substrates can also include the cerium oxide with additional light reaction reinforcing agent (including silver, zinc, rhodium and copper metal) Reinforced structure.The anhydrous character of catalyst and extremely porous property generate affinity to facilitate maximum water to absorb, from And it is allowed effectively to capture water vapour from surrounding air.The titania part of matrix is continuous by multiple wavelength of UV light Ground photoactivation, the air of captured water and generation superoxide ion, hydroxyl and some ozonide ions occurs in this Advanced oxidation reaction (this reaction generates the hydrogen peroxide discharged from cellular construction).In addition, the VOC contacted with photoactivation structure It can also be by directly contacting directly reduction with this of coating with microorganism.However, the main purpose of this part of unit is The collection of water vapour and its subsequent conversion to hydroperoxides (mainly hydrogen peroxide steam), and later these Continuous release of the hydrogen peroxide to processing space.The steam (sometimes referred to as plasma) of the release is advanced and is borrowed outside unit HVAC system present in handled building as integration fan or in some cases continues.This activation air HVAC duct can be facilitated clean up when it is advanced through HVAC duct, then it is finally released to handled building or sets In the inner periphery air applied.Herein, hydrogen peroxide can all react with airborne and surface pollutant (makes it As extremely unique and effective processing system).

The part-structure of according to an embodiment of the invention new-type and novel PHI unit shown in Figure 13 shows It is intended to.Aforementioned process is further by the activation of the positive and negative ion discharged from the high-frequency bipolar ion generator 1301 of PHI unit Enhancing is generated, positive and negative ion reacts with pollutant and PHI product.Another advantage of ion enhancing is it in air Tiny charged particle (airborne particle) has building-up effect.This allows unit also to help to control and reduce PM2.5 pollution Object.By aggregation and by enhancing regular activated filtering greatly come the particle that effectively allows these very tiny from air Post separation.

Designed ionic distribution technology is further enhanced by the integrated automatic self-purification capacity of ion emitter. Due to their electrification property, with passing for time, these transmitters collect charged particle, if it is allowed to continue receipts Collection can then cause being obviously reduced to the concentration of the ion emitted.PHI unit vibrates tuning fork using auto purification is mounted directly to 1302 two carbon fiber ion emitters 1303 and 1303 ', tuning fork 1302 are direct when being activated by dither motor 1304 Cause the mechanical oscillation of carbon fiber ion emitter 1303 and 1303 ', effectively shakes them and purified with the interval of preprogramming.

Such as in view of above discussion by the advanced oxidation processes that alternative embodiments of the invention provide include with hydroxyl, Superoxide ion, hydrogen peroxide, ozonide ion and hydroxide and other such advanced oxidation products it is any Combined reaction is restored to oxygen and hydrogen after the oxidation of pollutant.In addition, in certain alternative embodiments, sterilization UV light can additionally aid in the elimination of micro-organisms, such as germ, mould, virus and bacterium.In this way, advanced oxidation processes Optionally by reducing microorganism, smell and other undesirable chemicals in the environment in conjunction with sterilization U.V. light To purify and purify environment.The advanced oxidation processes such as provided by alternative embodiments of the invention may be many different In be it is highly useful, those of ordinary skill in the art are such as coped in view of above discussion becomes apparent.

Although the content for being presently believed to be the preferred embodiment of the present invention has shown and described, this field is common The skilled person will understand that various other modifications and equivalents substitution can be made, it is without departing from true scope of the invention It can.In addition, many modifications can be made so that specific situation is suitable for the teachings of the present invention without departing from core as described herein Concept of the invention.In addition, embodiments of the present invention can not include all the above feature.Therefore, the present invention and unlimited In disclosed particular implementation, but the invention including all embodiments being within the purview of the appended claims.

Claims

1. a kind of equipment for being used to form advanced oxidation product, the equipment include:

Ultraviolet source is used to emit the ultraviolet light of the wide range with wavelength between 100nm and 300nm, from described ultraviolet It includes the UV energy at about 185nm and at about 254nm that light source, which emits the ultraviolet light,；And

Be catalyzed object construction, be mechanically coupled to the ultraviolet source and including surface, the catalysis object construction it is described Surface includes at least one of titanium dioxide and following metallic compound:

Silver；

Zinc；

Copper；And

Rhodium,

Wherein, the titanium dioxide is formed in anhydrous magnesium carbonate substrate, and at least one of described metallic compound is included in In cerium oxide reinforced structure,

And wherein, the surface of the catalysis object construction after with ultraviolet light exposure with the hydration at the surface Object reacts to form advanced oxidation product.

2. equipment as described in claim 1, wherein the surface of the catalysis object construction includes titanium dioxide and multiple Following metallic compound:

Silver；

Zinc；

Copper；And

Rhodium.

3. equipment as described in claim 1, wherein it is described catalysis object construction the surface include titanium dioxide, silver, Zinc, copper and rhodium.

4. equipment as claimed in claim 3, wherein the surface of the catalysis object construction includes hydrophilic agent.

5. equipment as claimed in claim 4, wherein the hydrophilic agent includes silica gel.

6. equipment as described in claim 1, wherein the surface of the catalysis object construction includes hydrophilic agent.

7. equipment as claimed in claim 6, wherein the hydrophilic agent includes silica gel.

8. equipment as described in claim 1, wherein the surface of the catalysis object construction is by the water on the surface Mixture hydration, and wherein, the surface is after with ultraviolet light exposure and from the hydrating agents at the surface Hydrate reacts to form advanced oxidation product.

9. equipment as claimed in claim 8, wherein the hydrating agents include at the surface of the catalysis object construction Water.

10. equipment as claimed in claim 8, wherein the hydrating agents include on the surface of the catalysis object construction At least one of the moisture and moisture at place.

11. equipment as claimed in claim 8, wherein the hydrating agents include on the surface of the catalysis object construction The hydrophilic agent at place.

12. equipment as claimed in claim 11, wherein the hydrophilic agent includes silica gel.

13. equipment as described in claim 1, wherein the surface of the catalysis object construction is coated with including dioxy Change the coating of at least one of titanium and following metallic compound:

Silver；

Zinc；

Copper；And

Rhodium,

And wherein, the surface reacts after with ultraviolet light exposure with the hydrate at the surface to form height Grade oxidation product.

14. equipment as claimed in claim 13, wherein the coating includes titanium dioxide and multiple following metallic compounds:

Silver；

Zinc；

Copper；And

Rhodium.

15. equipment as claimed in claim 13, wherein the coating includes titanium dioxide, silver, zinc, copper and rhodium.

16. equipment as claimed in claim 13, wherein the coating further includes hydrophilic agent.

17. equipment as claimed in claim 16, wherein the hydrophilic agent includes silica gel.

18. equipment as described in claim 1 further includes ion generator, for discharging cation and anion.

19. equipment as claimed in claim 18 further includes ion emitter, there is integrated self-purging ability.

20. equipment as claimed in claim 19, wherein the ion emitter is carbon fiber ion emitter.

21. a kind of optical hydrogen ion unit, comprising:

Ultraviolet source is used to provide the wide spectrum ultraviolet light with the UV light in 100nm to 300nm range, described ultraviolet Light includes the UV energy at about 185nm and at about 254nm；And

It is catalyzed object construction, is mechanically coupled to the ultraviolet source and generally about the ultraviolet source, the catalysis mesh Marking structure includes surface, and the surface is reacted with the hydrate at the surface after with ultraviolet light exposure to be formed Advanced oxidation product,

Wherein, the surface is coated with super hydrophilic photocatalysis coating.

22. optical hydrogen ion unit as claimed in claim 21, wherein it is described catalysis object construction the surface be used for The ultraviolet light exposure provided by the ultraviolet source, so that it is advanced to be formed to react with hydrate at the surface Oxidation product.

23. optical hydrogen ion unit as claimed in claim 21, wherein the surface of the catalysis object construction is designed For for being contacted with the substantially maximum catalytic surface of the ultraviolet light provided by the ultraviolet source.

24. optical hydrogen ion unit as claimed in claim 23, wherein the surface of the catalysis object construction includes ridge At least one of shape and crimp design, substantially to maximize the catalysis table with the ultraviolet light provided by the ultraviolet source Face contact.

25. optical hydrogen ion unit as claimed in claim 21, wherein the surface of the catalysis object construction is designed For with the contact of the ultraviolet light provided by the ultraviolet source, and wherein, the catalysis object construction it is such Surface include with the catalytic surface region of the ultraviolet light exposure from the ultraviolet source and allow come from the ultraviolet light The open area that the ultraviolet light in source passes through.

26. optical hydrogen ion unit as claimed in claim 25, wherein the catalysis object construction includes total surface region, The total surface region includes:

With the catalytic surface region of the ultraviolet light exposure from the ultraviolet source, and

Open area between the 0% and 95% of the total surface region.

27. optical hydrogen ion unit as claimed in claim 21, further includes:

Fiber optic cable has

It is positioned as receiving the first end of the light emitted by the ultraviolet source, and

The second end for indicating the output optical signal of mode of operation of the optical hydrogen ion unit is provided.

28. optical hydrogen ion unit as claimed in claim 27, further includes:

Ultraviolet filtering component for substantially crossing filtering ultraviolet, while making one visible visible light and passing through, the optical fiber optics electricity Cable and the ultraviolet filtering component cooperating are to provide the visible light as from described in the fiber optic cable The output optical signal of second end.

29. optical hydrogen ion unit as claimed in claim 28, wherein the ultraviolet filtering component include in following extremely It is one few:

Ultraviolet filter, and

Ultraviolet filtering material in the fiber optic cable.

30. optical hydrogen ion unit as claimed in claim 21, further includes:

Substantially encase the protective barrier of the ultraviolet source, the protective barrier for approximately through come from the ultraviolet light The ultraviolet light at least in the ultraviolet light range of 100nm to 300nm in source is substantially transparent, while the ultraviolet light that will be encased Source and external temperature completely cut off.

31. optical hydrogen ion unit as claimed in claim 30, wherein the protective barrier includes protective coating and substantially wraps State at least one of pipe of ultraviolet source in residence.

32. optical hydrogen ion unit as claimed in claim 31, wherein the protective barrier includes fluorocarbon protection screen Barrier coating.

33. optical hydrogen ion unit as claimed in claim 31, wherein the protective barrier includes quartz material.

34. optical hydrogen ion unit as claimed in claim 31, wherein the protective barrier includes antifouling outer surface, described Antifouling outer surface encases the ultraviolet source substantially to prevent clast and other pollutants contact and adhere to outer surface, described outer Surface encases the ultraviolet source, at the same make from the ultraviolet source at least in the ultraviolet light range of 100nm to 300nm Ultraviolet light approximately through.

35. optical hydrogen ion unit as claimed in claim 31, wherein the protective barrier is broken in internal ultraviolet source 204 Leakage barriers are provided in the case where splitting.

36. optical hydrogen ion unit as claimed in claim 21, further includes ion generator, for discharge cation and bear from Son.

37. optical hydrogen ion unit as claimed in claim 36, further includes ion emitter, there is integrated self-purging Ability.

38. equipment as claimed in claim 37, wherein the ion emitter is carbon fiber ion emitter.

39. a kind of for providing the mixture of the compound of the coating on the surface for being catalyzed object construction, the mixture packet Include at least one of titanium dioxide and following compounds: silver, zinc, copper and rhodium, the titanium dioxide are formed in anhydrous magnesium carbonate In substrate, at least one of described compound is included in cerium oxide reinforced structure, and wherein, in catalysis object construction The coating reaction at the surface with ultraviolet light and hydrate thereof to form advanced oxidation product.

40. a kind of for providing the mixture of the compound of the coating on the surface for being catalyzed object construction, the mixture packet Include at least one of hydrophilic agent and following compounds: titanium dioxide, silver, zinc, copper and rhodium, the titanium dioxide are formed in anhydrous In magnesium carbonate substrate, at least one of described compound is included in cerium oxide reinforced structure, and wherein, in catalysis target The coating reaction at the surface of structure with ultraviolet light and hydrate thereof to form advanced oxidation product.

41. mixture as claimed in claim 40, wherein the mixture include the hydrophilic agent and titanium dioxide, silver, Zinc, copper and rhodium.

42. a kind of system for being used to form advanced oxidation product, the system comprises:

At least one ultraviolet source is used to emit the wide range ultraviolet light in 100nm to 300nm range, from described at least one The ultraviolet light of a ultraviolet source transmitting includes the UV energy at about 185nm and at about 254nm；And

At least one catalysis object construction comprising the surface with the ultraviolet light exposure from least one ultraviolet source, The surface of at least one catalysis object construction includes at least one of titanium dioxide and following metallic compound:

Silver；

Zinc；

Copper；And

Rhodium,

And wherein, the surface of at least one catalysis object construction is after with ultraviolet light exposure and on the surface The hydrate at place reacts to form advanced oxidation product.

43. system as claimed in claim 42, wherein the surface of at least one catalysis object construction is coated with Coating including at least one of titanium dioxide and following metallic compound:

Silver；

Zinc；

Copper；And

Rhodium.

44. system as claimed in claim 42, wherein the surface of at least one catalysis object construction is coated with Coating including hydrophilic agent, titanium dioxide, silver, zinc, copper and rhodium.

45. system as claimed in claim 42, comprising:

Multiple ultraviolet sources are used to emit the wide range ultraviolet light in 100nm to 300nm range, from the multiple ultraviolet light The ultraviolet light of at least one of source transmitting includes the UV energy at about 185nm and at about 254nm；With And

At least one catalysis object construction comprising the surface with the ultraviolet light exposure from the multiple ultraviolet source, it is described The surface of at least one catalysis object construction includes at least one of titanium dioxide and following metallic compound:

Silver；

Zinc；

Copper；And

Rhodium,

46. system as claimed in claim 45, wherein the surface of at least one catalysis object construction further includes parent Aqua.

47. system as claimed in claim 42, comprising:

Multiple catalysis object constructions, each of the multiple catalysis object construction include and come from the multiple ultraviolet source At least one of ultraviolet light exposure surface, the surface includes at least one in titanium dioxide and following metallic compound It is a:

Silver；

Zinc；

Copper；And

Rhodium,

48. system as claimed in claim 47, wherein the surface further includes hydrophilic agent.

49. system as claimed in claim 42 further includes ion generator, for discharging cation and anion.

50. system as claimed in claim 49 further includes ion emitter, there is integrated self-purging ability.

51. system as claimed in claim 50, wherein the ion emitter is carbon fiber ion emitter.

52. it is a kind of at catalytic surface formed advanced oxidation product method, the catalytic surface include titanium dioxide and At least one of following metallic compound: silver, zinc, copper and rhodium, wherein the titanium dioxide is formed in anhydrous magnesium carbonate substrate In, at least one of described metallic compound is included in cerium oxide reinforced structure, which comprises

It is hydrated the catalytic surface；

Make the catalytic surface and ultraviolet light exposure；And

Advanced oxidation product is formed at the catalytic surface.

53. method as claimed in claim 52 hydrophilicly, wherein making the catalytic surface hydration includes absorbing from around institute State the hydrate of the atmosphere of catalytic surface.

54. method as claimed in claim 52, wherein the ultraviolet light is included at about 185nm and at about 254nm UV energy.

55. method as claimed in claim 52, wherein the catalytic surface includes titanium dioxide, silver, zinc, copper and rhodium.

56. method as claimed in claim 52, wherein the catalytic surface include hydrophilic agent, titanium dioxide, silver, zinc, Copper and rhodium.

57. method as claimed in claim 52 further includes enhancing to form advanced oxidation product using cation and anion Process.

58. method as claimed in claim 57 further includes self-purging.

59. a kind of system for being used to form advanced oxidation product, the system comprises:

At least one ultraviolet source is used to emit the wide range ultraviolet light in 100nm to 300nm range, from described at least one The ultraviolet light of a ultraviolet source transmitting includes the UV energy at about 185nm and at about 254nm；

Silver；

Zinc；

Copper；And

Rhodium,

And wherein, the surface of at least one catalysis object construction is after with ultraviolet light exposure and on the surface The hydrate at place reacts to form advanced oxidation product；And

Fiber optic cable, with each of at least one ultraviolet source mechanical couplings, the fiber optic cable Include:

It is positioned as receiving the first end of the light by each corresponding transmitting of the ultraviolet source, and

60. being used to form the system of advanced oxidation product as claimed in claim 59, further includes:

61. the system for being used to form advanced oxidation product as claimed in claim 59, further includes:

Regulated power supply is electrically coupled at least one ultraviolet source, for providing it adjustable electrical power signal.

62. being used to form the system of advanced oxidation product as claimed in claim 59, further includes:

Ultraviolet light photo detector, it is optical coupled with the second end of the fiber optic cable, for providing instruction at least The output signal of the mode of operation of one ultraviolet source.

63. the system for being used to form advanced oxidation product as claimed in claim 62, further includes:

Regulated power supply is electrically coupled at least one ultraviolet source, for providing it adjustable electrical power signal；With

Controller is electrically coupled with the regulated power supply and the ultraviolet light photo detector, in response to from the ultraviolet light Photodetector receives the outputting data signals of the mode of operation of instruction at least one ultraviolet source to control the adjustable electric Source, for providing adjustable electrical power signal at least one described ultraviolet source.

64. the system for being used to form advanced oxidation product as described in claim 63, further includes:

Information components are coupled with the controller, in response to from the ultraviolet light photo detector receive instruction it is described to The outputting data signals of the mode of operation of a few ultraviolet source, to user/operator/technical staff relevant to the system Send information/alarm signal.

65. the system for being used to form advanced oxidation product as claimed in claim 59, further includes ion generator, for discharging Cation and anion.

66. the system for being used to form advanced oxidation product as described in claim 65, further includes ion emitter, there is collection At self-purging ability.

67. the system for being used to form advanced oxidation product as described in claim 66, wherein the ion emitter is carbon fiber Tie up ion emitter.