CN109589294A - A method of with rice milk and rice wine production shampoo - Google Patents
A method of with rice milk and rice wine production shampoo Download PDFInfo
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- CN109589294A CN109589294A CN201910095764.6A CN201910095764A CN109589294A CN 109589294 A CN109589294 A CN 109589294A CN 201910095764 A CN201910095764 A CN 201910095764A CN 109589294 A CN109589294 A CN 109589294A
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- milk
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/96—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution
- A61K8/97—Cosmetics or similar toiletry preparations characterised by the composition containing materials, or derivatives thereof of undetermined constitution from algae, fungi, lichens or plants; from derivatives thereof
- A61K8/9783—Angiosperms [Magnoliophyta]
- A61K8/9794—Liliopsida [monocotyledons]
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K8/00—Cosmetics or similar toiletry preparations
- A61K8/18—Cosmetics or similar toiletry preparations characterised by the composition
- A61K8/30—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds
- A61K8/33—Cosmetics or similar toiletry preparations characterised by the composition containing organic compounds containing oxygen
- A61K8/34—Alcohols
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- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/006—Antidandruff preparations
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q5/00—Preparations for care of the hair
- A61Q5/02—Preparations for cleaning the hair
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61Q—SPECIFIC USE OF COSMETICS OR SIMILAR TOILETRY PREPARATIONS
- A61Q7/00—Preparations for affecting hair growth
-
- A—HUMAN NECESSITIES
- A61—MEDICAL OR VETERINARY SCIENCE; HYGIENE
- A61K—PREPARATIONS FOR MEDICAL, DENTAL OR TOILETRY PURPOSES
- A61K2800/00—Properties of cosmetic compositions or active ingredients thereof or formulation aids used therein and process related aspects
- A61K2800/80—Process related aspects concerning the preparation of the cosmetic composition or the storage or application thereof
- A61K2800/85—Products or compounds obtained by fermentation, e.g. yoghurt, beer, wine
Abstract
The invention discloses a kind of method with rice milk and rice wine production shampoo, especially a kind of method with rice milk and rice wine production Anti-hair loss dandruff control shampoo containing belongs to brewing technical field.Inoculating lactic acid bacterium rice steeping of the present invention is to inhibit harmful microorganism to grow, eliminate the different odor of rice milk and surface " white flower ", keep rice milk smell pleasant, containing B family vitamin is enriched in rice milk, contain the nutrient substances such as abundant protein, amino acid, vitamin, organic acid, bacteriocin, polyphenol and polysaccharide in yellow rice wine.The shampoo prepared using rice milk and yellow rice wine, can improve alopecia seborrheica, aminoacid ingredient can repair hair scale piece, while carrying out moisturizing to hair carry, moreover it is possible to which alopecia problem caused by improving because of hair follicle trophism missing, strong root of hair makes hair more tough, not short-tempered.Natural organic acids, which removes, effectively to assist decontamination anti-dandruff, moreover it is possible to which antibacterial and sterilization, the natural weakly acidic condition of balance scalp further maintain the ecological balance of scalp flora.
Description
Technical field
The present invention relates to a kind of methods with rice milk and rice wine production shampoo, and especially one kind is with rice milk and yellow rice wine
The method for producing Anti-hair loss dandruff control shampoo containing, belongs to brewing technical field.
Background technique
Unique production technology of shao-hsing rice wine first is that the rice steeping period is long, need rice steeping under the conditions of traditional handicraft natural temperature
15 days or more, rice steeping is needed 4~5 days under 20~25 DEG C of heat-retaining conditions of modern mechanical metaplasia production. art, is about produced after rice dipping per ton
Raw 0.8 ton of rice milk.Traditionally after " Winter Solstice " season due to more than lactic acid bacteria in rice milk and harmful microorganism is reduced, make rice milk
In pleasant acid gas, can be used for the water use that feeds intake instead of part after clarified processing and appropriate dilution, ratio is " three four water of slurry ",
Not only it can guarantee normal fermentation but also be conducive to the fragrance and mouthfeel of product, but be only limitted to " Winter Solstice " afterwards in temperature lower a period of time
Rice milk could be used to feed intake.When temperature is higher, due to living contaminants, the rice milk obtained after through a long time rice steeping is often
" white flower " and different odor can be generated, and miscellaneous bacteria content is more in rice milk easily causes karusen rancid.Therefore, the eighties in last century
Rice milk has almost been deactivated to feed intake, and a large amount of rice milks is made to become waste water.Recently, environmental protection is increasingly paid attention to due to people,
Sewage drainage standard is more stringent, and the COD of rice milk is up to 30000mg/L, and not only processing cost is high, and ammonia often occurs
Nitrogen is unable to reach the problem of discharge standard.The reuse of rice milk becomes urgent problem to be solved once again.
A kind of hair washing being prepared using rice washing water is disclosed in the patent application of 106667861 A of Publication No. CN
Water is mainly used for enhancing toughness, the pitch black degree of hair, cannot anti-dandruff, Anti-hair loss.And other existing Hair-loss-preventingshampoo shampoos are main
For alopecia seborrheica, alopecia problem caused by the reasons such as hair follicle malnutrition not can solve;Meanwhile existing shampoo effect
Single effect, without anti-dandruff Anti-hair loss double effects.
Summary of the invention
[technical problem]
The technical problem to be solved in the present invention is to provide the Anti-hair loss anti-dandruff shampoos that a kind of raw material includes rice milk and yellow rice wine
Water, the rice steeping water that can be generated in reuse production process of yellow rice wine and the hair washing for obtaining having both the significant anti-dandruff function of Anti-hair loss
Water.
[technical solution]
The present invention provides a kind of methods with rice milk and rice wine production shampoo, comprising the following steps:
Step (1) lactobacillus inoculum rice steeping: glutinous rice and water are mixed in proportion and are accessed lactic acid bacteria culture solution, in room temperature 24
It is impregnated under~25 DEG C of heat-retaining conditions, so that rice milk total acid is reached 7~8g/L, drain, it is stand-by to collect whole rice milks;
Step (2) Rice & peanut milk clarification of water, filtering: the rice milk collected in clarification steps (1), after removal tank bottom precipitates, filtering,
For producing shampoo;
Step (3) takes the rice milk in (2), with Shaoxing unit's red wine and other prepare raw material necessary to shampoo and mix,
Shampoo is prepared.
In one embodiment of the invention, step (1) lactobacillus inoculum rice steeping: rice steeping step specifically: glutinous rice and
Water quality ratio is 1:1.2, accesses lactic acid bacteria culture solution with 0.5% inoculum concentration of glutinous rice quality, keeps the temperature at 24~25 DEG C of room temperature
Under the conditions of impregnate 3 days, so that rice milk total acid is reached 7~8g/L, drain, it is stand-by to collect whole rice milks.Further, the cream
The cultural method of sour bacteria culture fluid: big by three by solid slope test tube, liquid triangular flask, liquid using CGMCC No.7184 as strain
Angle bottle and the order of culture tank expand step by step to be cultivated.Further, the solid slope test tube strains cultural method are as follows: adopt
With MRS agar medium, 4~5 days under 30 DEG C of cultures.Further, the liquid triangular flask and the big triangular flask kind of liquid
The preparation method comprises the following steps: glutinous rice impregnates 36~48 hours, steamed rice is added 3.5 times of water by glutinous rice quality, cools the temperature to 60 sub- culture medium
DEG C, the carbohydrase of 3% ripe wheat koji and 2 ‰ 100,000 units is added by glutinous rice quality, stirs evenly, is kept the temperature at 58~60 DEG C
Saccharification 4~5 hours, stirring is primary per hour therebetween, filtering, and sugar addition is 6~7 ° of Bx, be packed into 500 milliliter triangular flasks and
In the big triangular flask of 3000 milliliters, loading amount is respectively 200 milliliters and 2000 milliliters, sterilizes 30 minutes, is cooled in 115 DEG C after packet support
Room temperature is spare.Further, the liquid triangular flask and the big triangular flask seed method of making of liquid are as follows: in aforesaid liquid triangle
It is inoculated with strain 1~2 ring in test tube slant in bottle, is cultivated at 30 DEG C 22~24 hours, it is then above-mentioned by 10% inoculum concentration access
In the big triangular flask of liquid, cultivated 22~24 hours at 30 DEG C.Further, lactic acid bacteria culture solution in the culture tank
Culture medium the preparation method comprises the following steps: glutinous rice impregnate 36~48 hours, steamed rice, by glutinous rice quality addition 3.5 times of water, cool the temperature to 60
DEG C, the carbohydrase of 3% ripe wheat koji and 2 ‰ 100,000 units is added by glutinous rice quality, stirs evenly, is kept the temperature at 58~60 DEG C
Saccharification 4 hours, stirring is primary per hour therebetween, filtering, and sugar addition is 6~7 ° of Bx, and 70 DEG C sterilize 30 minutes, is cooled to room temperature
It is spare.Further, in the culture tank lactic acid bacteria culture solution the preparation method comprises the following steps: the inoculum concentration by 10% accesses above-mentioned liquid
The big triangular flask seed of body, cultivated 18~22 hours at 30~32 DEG C.
In one embodiment of the invention, the lactic acid bacteria is the plant screened from shao-hsing rice wine rice steeping water
Lactobacillus (Lactobacillus plantarum) CGMCC NO.7184 is preserved in China Microbiological on January 12nd, 2013
Culture presevation administration committee common micro-organisms center, is documented in the patent application document of publication number CN103255092A, should
Bacterium is generation amine negative bacterium, is suitble to that acid is grown and produced in rice milk, increases the acidity of rice milk comparatively fast.
In one embodiment of the invention, step (2) Rice & peanut milk clarification of water, filtering: the rice milk that will be collected in step 1
Clarification overnight, after removal tank bottom precipitating, is filtered, for producing shampoo.
In one embodiment of the invention, in step (3), formula and production method used in shampoo are prepared such as
Under:
Table 1
(1) A is uniformly mixed, B phase is added, is heated to 80 DEG C, stirring is to being completely dissolved.
(2) C phase is added, is kept for 80 DEG C of temperature, insulated and stirred 20 minutes, D phase, 40 DEG C of cooling or less is added.
(3) it is added and is sterilized through 80 DEG C, 15~20 minutes and be cooled to 40 DEG C of E phases below
(3) F phase is added, after twenty minutes, G phase is added in stirring, after stirring 15 minutes, discharging.
[beneficial effect]
1, inoculating lactic acid bacterium rice steeping of the present invention eliminates the different odor of rice milk and surface is " white to inhibit harmful microorganism to grow
Flower ", keeps rice milk smell pleasant, and B family vitamin abundant is contained in rice milk, while lactobacillus-fermented generates ammonia during rice steeping
Base acid, organic acid, bacteriocin and polysaccharide etc., in yellow rice wine containing protein abundant, amino acid, vitamin, organic acid, bacteriocin,
The nutrient substances such as polyphenol and polysaccharide.Shampoo 2720mg/L containing free amino acid or more of the present invention, 5 kinds of B family vitamins (dimensions
Raw element PP+ vitamin B1+ vitamin B2+ vitamin B6) total amount 11mg/L or more, B family vitamin can be effectively controlled the grease of scalp
Secretion improves alopecia seborrheica, and aminoacid ingredient can repair hair scale piece, while carrying out moisturizing to hair carry, moreover it is possible to improve because of hair
Alopecia problem caused by capsule trophism lacks, strong root of hair makes hair more tough, not short-tempered.Rice milk is during the fermentation
The natural organic acids of generation, which removes, effectively to assist decontamination anti-dandruff, moreover it is possible to antibacterial and sterilization, the natural weakly acidic condition of balance scalp, into
The ecological balance of one step maintenance scalp flora.
2, the alcoholic strength of yellow rice wine is 16%vol or so, contains albumen abundant and polyphenol substance, alcohol can assist decontamination, more
The effect of phenol has antibacterial and prevents hair loss, protein can enhance foam and play moisture-keeping function.
3, the present invention foreshortens to rice dipping time 4~5 days 3 days by original, reduces heat preservation energy consumption, and starch loses than former rice steeping
Method decline 20%, and effectively eliminate steamed rice caking phenomenon.
4, so that rice wine production rice milk is turned waste into wealth, save processing cost.
Specific embodiment
Laureth sodium sulfovinate (content 70%) used in following embodiments is purchased from BASF (Basf);Cocounut oil
Amido propyl betaine (content 30%) is bought from Clariant;Kathon CG (methylchloroisothiazandnone: methylisothiazolinone=
1:3, content 0.15%), it buys from Germany Shu Mei.
Embodiment 1
1, lactobacillus inoculum rice steeping: rice steeping step specifically: glutinous rice and water quality ratio are 1:1.2, with glutinous rice quality
0.5% inoculum concentration accesses lactic acid bacteria culture solution, impregnates 3 days under 24~25 DEG C of heat-retaining conditions of room temperature, reaches rice milk total acid
It to 7~8g/L, drains, it is stand-by to collect whole rice milks;
The cultural method of the lactic acid bacteria culture solution: using CGMCC No.7184 as strain, by solid slope test tube, liquid
The big triangular flask of triangular flask, liquid and the order of culture tank expand step by step to be cultivated.
The solid slope test tube strains cultural method are as follows: MRS agar medium is used, 4~5 days under 30 DEG C of cultures.
The liquid triangular flask and the big triangular flask seed culture medium of liquid are the preparation method comprises the following steps: glutinous rice immersion 36~48 is small
When, steamed rice is added 3.5 times of water by glutinous rice quality, cools the temperature to 60 DEG C, and 3% ripe wheat koji and 2 ‰ is added by glutinous rice quality
The carbohydrase of 100000 units, stirs evenly, and heat preservation saccharification 4~5 hours at 58~60 DEG C, stirring is primary per hour therebetween, mistake
Filter, sugar addition are 6~7 ° of Bx, are fitted into 500 milliliter triangular flasks and the big triangular flask of 3000 milliliters, loading amount is respectively 200 milliliters
With 2000 milliliters, packet support after in 115 DEG C sterilize 30 minutes, be cooled to room temperature spare.
The liquid triangular flask and the big triangular flask seed method of making of liquid are as follows: examination is inoculated in aforesaid liquid triangular flask
1~2 ring of pipe slant strains is cultivated 22~24 hours at 30 DEG C, then accesses the big triangle of aforesaid liquid by 10% inoculum concentration
In bottle, cultivated 22~24 hours at 30 DEG C.
In the culture tank lactic acid bacteria culture solution culture medium the preparation method comprises the following steps: glutinous rice impregnate 36~48 hours, steamed rice,
3.5 times of water are added by glutinous rice quality, cool the temperature to 60 DEG C, 3% ripe wheat koji and 2 ‰ 100,000 units is added by glutinous rice quality
Carbohydrase, stir evenly, heat preservation saccharification 4 hours at 58~60 DEG C, stirring is primary per hour therebetween, filtering, sugar addition
For 6~7 ° of Bx, 70 DEG C sterilize 30 minutes, are cooled to room temperature spare.
In the culture tank lactic acid bacteria culture solution the preparation method comprises the following steps: by 10% inoculum concentration access aforesaid liquid it is big by three
Angle bottle seed, cultivated 18~22 hours at 30~32 DEG C.
The CGMCC NO.7184 strain is the lactobacillus plantarum screened from shao-hsing rice wine rice steeping water
(Lactobacillus plantarum) it is general to be preserved in China Committee for Culture Collection of Microorganisms on January 12nd, 2013
Logical microorganism center, is documented in the patent application document of publication number CN103255092A, which is generation amine negative bacterium, fits
It closes and acid is grown and produced in rice milk, increase the acidity of rice milk comparatively fast.
2, Rice & peanut milk clarification of water, filtering: the rice milk collected in step 1 is clarified overnight, after removal tank bottom precipitating, filtering,
For producing shampoo.
3, filtered rice milk is taken, for producing shampoo, formula and production method are as follows:
Table 2
(1) A is uniformly mixed, B phase is added, is heated to 80 DEG C, stirring is to being completely dissolved.
(2) C phase is added, is kept for 80 DEG C of temperature, insulated and stirred 20 minutes, D phase, 40 DEG C of cooling or less is added.
(3) it is added and is sterilized through 80 DEG C, 15~20 minutes and be cooled to 40 DEG C of E phases below
(3) F phase is added, after twenty minutes, G phase is added in stirring, after stirring 15 minutes, discharging.
Comparative example 1
Using common rice steeping method, without inoculating lactic acid bacterium.Shampoo formula is the same as embodiment 1.
1, rice steeping: rice steeping step specifically: glutinous rice and water quality ratio are 1:1.2, under 24~25 DEG C of heat-retaining conditions of room temperature
It impregnates 4~5 days, drains, it is stand-by to collect whole rice milks;
2, rice milk is taken, by the formula of embodiment 1 and method shampoo.
Comparative example 2
It is 100 parts except Shaoxing unit's red wine and rice milk number are not added in shampoo formula, remaining is the same as embodiment 1.
The anti-dandruff effect assessment of shampoo:
Selection dandruff is more from the student of school big one to big three 4 groups of student volunteer, every group of 15 people make respectively
With embodiment 1 and comparative example 1,2 and reputable brand dandruff control shampoo containing 1 month commercially available, it is believed that dandruff adds severe one score 0 to divide, without changing
Kind person's score 1 is divided, and moderate improver score 2 is divided, and complete improver's score 3 is divided.Embodiment 1 and comparison 1,2 and internationally famous product
The anti-dandruff effect of board dandruff control shampoo containing is shown in Table 3.
3 embodiment 1 of table and comparison 1,2 and the internationally famous anti-dandruff effect of brand dandruff control shampoo containing
As can be seen from Table 3, the anti-dandruff effect Yu comparative example 2 of 1 shampoo of the embodiment of the present invention are suitable, but are substantially better than comparison
Example 1 and commercially available dandruff control shampoo containing, and using the embodiment of the present invention 1 shampoo without dandruff aggravate phenomenon, may with used rice
Pulp-water and yellow rice wine have protective effect related scalp.
Shampoo Anti-hair loss effect assessment
45 40~50 one full year of life health volunteers are bisected into 3 groups, every group of age bracket is roughly the same, every group of volunteer
Embodiment 1, comparative example 1, comparative example 2 and certain commercially available Hair-loss-preventingshampoo shampoo product are used respectively, and every other day using once, volunteer exists
Before product use the 20th day after (0 day) and use, combing hair is distinguished in the morning, afternoon and evening within 40 days, 60 days, collect the hair to fall off simultaneously
Record count finds out round numbers after average value, calculates rate of descent, the results are shown in Table 4.Rate of descent=(the 0th day hair number-to fall off
The 60th day hair number to fall off)/the 0th day hair number to fall off.
4 present invention of table and comparison 1,2 and commercially available brand Hair-loss-preventingshampoo shampoo effect
As can be seen from Table 4, using the subject of shampoo of the present invention and use comparative example 1,2 and commercially available Hair-loss-preventingshampoo shampoo
It compares, average alopecia number substantially reduces.
Although the present invention has been described by way of example and in terms of the preferred embodiments, it is not intended to limit the invention, any to be familiar with this skill
The people of art can do various change and modification, therefore protection model of the invention without departing from the spirit and scope of the present invention
Enclosing subject to the definition of the claims.
Claims (5)
1. a kind of method with rice milk and rice wine production shampoo, which comprises the following steps:
Step (1) lactobacillus inoculum rice steeping: glutinous rice and water are mixed in proportion and are accessed lactic acid bacteria culture solution, in room temperature 24~25
It is impregnated under the conditions of DEG C, so that rice milk total acid is reached 7~8g/L, drain, it is stand-by to collect whole rice milks;
Step (2) Rice & peanut milk clarification of water, filtering: the rice milk collected in clarification steps (1), after removal tank bottom precipitates, filtering is used for
Produce shampoo;
Step (3) takes the rice milk in (2), with Shaoxing unit's red wine and other prepare raw material necessary to shampoo and mix, prepare
Obtain shampoo.
2. a kind of method with rice milk and rice wine production shampoo according to claim 1, which is characterized in that step
(1) lactobacillus inoculum rice steeping: rice steeping step specifically: glutinous rice and water quality ratio be 1:1.2, is connect with the 0.5% of glutinous rice quality
Kind amount access lactic acid bacteria culture solution, impregnates 3 days under 24~25 DEG C of heat-retaining conditions of room temperature, rice milk total acid is made to reach 7~8g/L,
It drains, it is stand-by to collect whole rice milks.
3. a kind of method with rice milk and rice wine production shampoo according to claim 1 or 2, which is characterized in that institute
The deposit number for stating lactic acid bacteria is CGMCC No.7184, by solid slope test tube, liquid triangular flask and culture tank order step by step
Expand culture and obtains seed liquor.
4. a kind of method with rice milk and rice wine production shampoo according to claim 1 or 2, which is characterized in that step
Suddenly it in (3), prepares ingredient used in shampoo and proportion is as follows:
A phase:
B phase:
Laureth sodium sulfovinate, 21 parts;
Sodium citrate, 0.1 part;
C phase:
D phase:
Sodium chloride, 1.0 parts;
E phase:
Shaoxing unit's red wine, 10~20 parts;
F phase:
Aqueous emulsion of dimethyl polysiloxane fluid, 2.0 parts;
Ammonia-terminated polydimethylsiloxane lotion, 1.0 parts;
Lauryldimonium Hydroxypropyl base hydrolyzed wheat protein, 0.2 part;
G phase:
Kathon CG, 0.08 part;
Daily essence, 0.7 part.
5. a kind of method with rice milk and rice wine production shampoo according to claim 4, which is characterized in that each phase
A: being 1. uniformly mixed by mixing step, and B phase is added, is heated to 80 DEG C, and stirring is to being completely dissolved;2. C phase is added, temperature 80 is kept
DEG C, insulated and stirred 20 minutes, D phase, 40 DEG C of cooling or less is added;It is sterilized through 80 DEG C, 15~20 minutes 3. being added and is cooled to 40
DEG C E phase below;4. F phase is added, after twenty minutes, G phase is added in stirring, after stirring 15 minutes, discharging.
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
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CN102614096A (en) * | 2012-03-05 | 2012-08-01 | 珀莱雅(湖州)化妆品有限公司 | Conditioner shampoo composite |
CN103211749A (en) * | 2013-05-07 | 2013-07-24 | 薛晨 | Shampoo and preparation method thereof |
CN103255092A (en) * | 2013-05-09 | 2013-08-21 | 江南大学 | Lactobacillus suitable for bio-acidification rice soaking and application for same |
CN104382809A (en) * | 2014-12-11 | 2015-03-04 | 贵州三清源生态农业科技开发有限责任公司 | Platycladus orientalis fermented shampoo and preparation method thereof |
JP2016084303A (en) * | 2014-10-24 | 2016-05-19 | 共栄化学工業株式会社 | Antioxidant, skin cosmetic, and hair cosmetic |
-
2019
- 2019-01-31 CN CN201910095764.6A patent/CN109589294B/en active Active
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN102614096A (en) * | 2012-03-05 | 2012-08-01 | 珀莱雅(湖州)化妆品有限公司 | Conditioner shampoo composite |
CN103211749A (en) * | 2013-05-07 | 2013-07-24 | 薛晨 | Shampoo and preparation method thereof |
CN103255092A (en) * | 2013-05-09 | 2013-08-21 | 江南大学 | Lactobacillus suitable for bio-acidification rice soaking and application for same |
JP2016084303A (en) * | 2014-10-24 | 2016-05-19 | 共栄化学工業株式会社 | Antioxidant, skin cosmetic, and hair cosmetic |
CN104382809A (en) * | 2014-12-11 | 2015-03-04 | 贵州三清源生态农业科技开发有限责任公司 | Platycladus orientalis fermented shampoo and preparation method thereof |
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