CN109586329A - Mixed energy storage system, configuration method and the operation method of off-network solar power system - Google Patents

Mixed energy storage system, configuration method and the operation method of off-network solar power system Download PDF

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Publication number
CN109586329A
CN109586329A CN201710894043.2A CN201710894043A CN109586329A CN 109586329 A CN109586329 A CN 109586329A CN 201710894043 A CN201710894043 A CN 201710894043A CN 109586329 A CN109586329 A CN 109586329A
Authority
CN
China
Prior art keywords
power
load
flow battery
vanadium flow
mould group
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201710894043.2A
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Chinese (zh)
Inventor
张宇
张华民
赵洪贵
王晓丽
李春来
郭树峰
李正曦
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dalian Rongke Power Co Ltd
State Grid Qinghai Electric Power Co Ltd
Electric Power Research Institute of State Grid Qinghai Electric Power Co Ltd
Original Assignee
Dalian Rongke Power Co Ltd
State Grid Qinghai Electric Power Co Ltd
Electric Power Research Institute of State Grid Qinghai Electric Power Co Ltd
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Filing date
Publication date
Application filed by Dalian Rongke Power Co Ltd, State Grid Qinghai Electric Power Co Ltd, Electric Power Research Institute of State Grid Qinghai Electric Power Co Ltd filed Critical Dalian Rongke Power Co Ltd
Priority to CN201710894043.2A priority Critical patent/CN109586329A/en
Publication of CN109586329A publication Critical patent/CN109586329A/en
Pending legal-status Critical Current

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Classifications

    • H02J3/383
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M10/00Secondary cells; Manufacture thereof
    • H01M10/42Methods or arrangements for servicing or maintenance of secondary cells or secondary half-cells
    • H01M10/425Structural combination with electronic components, e.g. electronic circuits integrated to the outside of the casing
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04223Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells
    • H01M8/04225Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids during start-up or shut-down; Depolarisation or activation, e.g. purging; Means for short-circuiting defective fuel cells during start-up
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01MPROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
    • H01M8/00Fuel cells; Manufacture thereof
    • H01M8/04Auxiliary arrangements, e.g. for control of pressure or for circulation of fluids
    • H01M8/04298Processes for controlling fuel cells or fuel cell systems
    • H01M8/043Processes for controlling fuel cells or fuel cell systems applied during specific periods
    • H01M8/04302Processes for controlling fuel cells or fuel cell systems applied during specific periods applied during start-up
    • HELECTRICITY
    • H02GENERATION; CONVERSION OR DISTRIBUTION OF ELECTRIC POWER
    • H02JCIRCUIT ARRANGEMENTS OR SYSTEMS FOR SUPPLYING OR DISTRIBUTING ELECTRIC POWER; SYSTEMS FOR STORING ELECTRIC ENERGY
    • H02J7/00Circuit arrangements for charging or depolarising batteries or for supplying loads from batteries
    • H02J7/0068Battery or charger load switching, e.g. concurrent charging and load supply
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/56Power conversion systems, e.g. maximum power point trackers
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/10Energy storage using batteries
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E60/00Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
    • Y02E60/30Hydrogen technology
    • Y02E60/50Fuel cells

Abstract

The mixed energy storage system of off-network solar power system, configuration method and operation method, belong to field of batteries, solve the problems, such as be: existing off-network solar power system charging when fluctuation it is larger, system stability is not high, main points are: including: lithium battery, several all-vanadium flow battery mould groups and control system, the public capacity cell of several all-vanadium flow battery mould groups, the control system controls the starting opportunity of each all-vanadium flow battery mould group according to load power, quantity and charging and discharging state, and the corresponding lithium battery of starting is controlled in corresponding opportunity and is filled, electric discharge, with the method for operation control to off-network solar power system.

Description

Mixed energy storage system, configuration method and the operation method of off-network solar power system
Technical field
The invention belongs to field of batteries, are related to a kind of mixed energy storage system of off-network solar power system.
Background technique
Off-network solar energy system includes that solar panel, photovoltaic controller, energy-storage battery and off-network inverter etc. are several Main component.All-vanadium flow battery due to it with the long-life, safety is good, overcharge, over-discharge ability is good, advantages of environment protection It is one of the ideal chose of off-network solar energy system.
The operational mode of off-network solar energy system is the direct powering load of solar power generation on daytime, and extra electricity is to electricity Then pond charging is used in the electricity supply load of remaining Time Dependent storage in the battery.For load 24 in off-grid system Hour continuous operation, the design of off-network solar energy system are usually that the nominal power of solar panel is greater than the power of load, Generally 6~10 times, it just can guarantee be rapidly filled with battery in the good finite time of daylight in this way.In this case, electric The charge power of cell system will generally be matched with solar power, and discharge power is basic consistent with bearing power, therefore for It is in high-power charging, the operational mode of small-power electric discharge for battery.
In the case, for all-vanadium flow battery, to meet system charge power, system power is normally close to too The rated power of positive energy, all auxiliary devices, including circulating pump, pipeline, electrical sensor, temperature control system are all according to charging function The size of rate configures.But efficiency for charge-discharge is low under this configuration, and overall operation is ineffective, specially under discharge mode, by In load very little, all-vanadium redox flow battery system is in low-power (10%~20% rated power) operation, and internal power consumption is very big, effect Rate is very low.Under charge mode, solar charging electrical power is also variation, and battery charge power is from 100%~20% rated power Operation, span is very big, and stable operation efficiency of the flow battery near rated power is highest, therefore in a charging situation Efficiency is also undesirable.In addition, solar energy can encounter the case where instantaneous power fluctuates, it is desirable that battery when black clouds is sailed There is cracking power response rate request.Lithium battery feature is that multiplying power property is good, and full power range is high-efficient, standby high-efficient, All-vanadium flow battery can be avoided to overload very well, the shortcomings that low-power, standby aspect.
It is the first to file again of applicant such as the Chinese invention patent that Authorization Notice No. is CN 103825042B, it discloses A kind of flow battery system for off-network type solar power system, specially a set of capacity cell, two sets of power cells, In it is a set of be charged as high powe design, another set of is discharge cell, and small-power designs (load power), charge power module: puts Electrical power module=5:9.However since its charging module is one, but solar recharging is fluctuation, makes the mould that individually charges The power interval span of block is big, low efficiency.
Summary of the invention
The problem to be solved in the present invention is: fluctuation of the existing off-network solar power system in charging is larger, system Stability is not high.Technical solution provided by the invention:
A kind of mixed energy storage system of off-network solar power system, comprising: lithium battery, several all-vanadium flow battery moulds Group and control system, the public capacity cell of several all-vanadium flow battery mould groups, the control system is according to load power Starting opportunity, quantity and the charging and discharging state of each all-vanadium flow battery mould group are controlled, and is controlled in corresponding opportunity and starts corresponding lithium Battery carries out charge and discharge, with the method for operation control to off-network solar power system.
Further, the power of the solar power system is configured as:
PSolar energy=24*K2*PLoad is average/K1
The power of each all-vanadium flow battery mould group is configured as:
PLiquid=K2*PLoad is average
The capacity of several common capacity cells of all-vanadium flow battery mould group is configured as:
CLiquid=K3*PLiquid
The power of the lithium battery is configured as:
PLithium=K4*K2*PLoad is average
The capacity of the lithium battery is configured as
CLithium=K5*K4*K2*PLoad is average
Wherein:
K1For solar energy daily averagely generate electricity hourage;
K2=1~1.3;
K3=6~20;
PLoad is averageFor the power of off-network load;
K4=0.2~1;
K5=0.2~1.
Further, the control system is based on such as under type Controlling operation method: if the power of solar power system Greater than load power, mixed energy storage system is in charged state, calculates P/PLiquid, result includes integer part and fractional part, P For the charge power of energy storage, PLiquidFor the power of all-vanadium flow battery mould group, P=PSolar energy is real-time-PLoad is real-time
If judgement are as follows: fractional part > 0.7 starts all-vanadium flow battery mould group, and the quantity of starting is integer part+1;
If judgement are as follows: fractional part < 0.7 starts all-vanadium flow battery mould group, and starting quantity is integer part, remaining Power section is charged by lithium battery and is compensated.
Further, the control system is based on such as under type Controlling operation method:
If the power of solar power system is less than load power;
Work as judgement are as follows:
PLoad is real-time/PLiquid<0.7
PLoad is real-timeFor load realtime power;
Then lithium battery discharges, after lithium battery discharges into blanking voltage, starting one all-vanadium flow battery mould group electric discharge;
Work as judgement are as follows:
PLoad is real-time/PLiquid>0.7
Then start all-vanadium flow battery mould group electric discharge.
Further, the SOC range of all-vanadium flow battery mould group is 0~100%, and lithium battery SOC range is 30~70%.
The invention further relates to a kind of mixed energy storage system configuration method of off-network solar power system, the energy-storage systems It include: lithium battery, several all-vanadium flow battery mould groups and control system, the public appearance of several all-vanadium flow battery mould groups Measure unit;
The power of the solar power system is configured as:
PSolar energy=24*K2*PLoad is average/K1
The power of each all-vanadium flow battery mould group is configured as:
PLiquid=K2*PLoad is average
The capacity of several common capacity cells of all-vanadium flow battery mould group is configured as:
CLiquid=K3*PLiquid
The power of the lithium battery is configured as:
PLithium=K4*K2*PLoad is average
The capacity of the lithium battery is configured as
CLithium=K5*K4*K2*PLoad is average
Wherein:
K1For solar energy daily averagely generate electricity hourage;
K2=1~1.3;
K3=6~20;
PLoad is averageFor the power of off-network load;
K4=0.2~1;
K5=0.2~1.
The invention further relates to a kind of progress control method of the mixed energy storage system of off-network solar power system, the storages Energy system includes: lithium battery, several all-vanadium flow battery mould groups and control system, several all-vanadium flow battery mould groups are public One capacity cell;
If the power of solar power system is greater than load power, mixed energy storage system is in charged state, calculates P/PLiquid, Its result includes integer part and fractional part, P=PSolar energy is real-time-PLoad is real-time, it is the charge power of energy-storage system, PLiquidFor full vanadium liquid The power of galvanic battery mould group;If judgement are as follows: fractional part > 0.7 starts all-vanadium flow battery mould group, and the quantity of starting is whole Number part+1;
If judgement are as follows: fractional part < 0.7 starts all-vanadium flow battery mould group, and starting quantity is integer part, remaining Power section is charged by lithium battery and is compensated.
Further, if the power of solar power system is less than load power;
Work as judgement are as follows:
PLoad is real-time/PLiquid<0.7
PLoad is real-timeFor load realtime power;
Then lithium battery discharges, after lithium battery discharges into blanking voltage, starting one all-vanadium flow battery mould group electric discharge;
Work as judgement are as follows:
PLoad is real-time/PLiquid>0.7
Then start all-vanadium flow battery mould group electric discharge.
The utility model has the advantages that lithium battery and several all-vanadium flow battery mould groups are formed mixed energy storage system by the present invention, according to Load controls the use of different batteries according to load power, and also can be improved off-network solar energy hair to power, capacity configuration Stability and system effectiveness of the electric system in charging.
Specific embodiment
The present invention provides a kind of mixed energy storage system of off-network solar power system, have multiple groups all-vanadium flow mould group and Lithium battery, solar power system, all-vanadium flow mould group, the power of lithium battery, the configuration method of capacity are as follows:
Variable declaration: off-network load power is PLoad is average, daily electricity consumption is CLoad, solar power PSolar energy, full vanadium liquid Galvanic battery mould group power is PLiquid, lithium battery power is PLithium, lithium battery capacity CLithium, solar energy realtime power is PSolar energy is real-time, load Realtime power is PLoad is real-time
According to the design principle of off-network solar power system, 24 hours electric quantity consumptions are loaded daily and both are from solar energy Power generation, and solar power system, according to the difference of region, averagely generate electricity hourage K daily1Generally on 3~6 hours left sides The right side considers certain redundancy of system, de-redundancy COEFFICIENT K2=1~1.3, then PSolar energy=24*K2*PLoad is average/K1, i.e. 3~10 times of PIt is negative Lotus is average.
Designing N number of power according to off-network solar power system feature is respectively PLiquidAll-vanadium flow mould group and 1 power For PLithiumLithium battery system, the value range of N: 3~6.
The power P of each all-vanadium flow battery mould groupLiquid=K2*PLoad is average
N number of public capacity cell of all-vanadium flow battery mould group, the capacity C of the capacity cellLiquid=K3*PLiquid, wherein K3= 6~20;
The power configuration of lithium battery is PLithium=K4*K2*PLoad is average, in which: K4=0.2~1, lithium battery capacity CLithium=K5*K4* K2*PLoad is average, in which: K5=0.2~1.
Off-network solar power system run when, any one all-vanadium flow battery mould group all can serve as charging module or Person's discharge module, control system according to power generation and the case where load the charge and discharge of decision battery and with the cooperation of lithium battery:
The method of operation is as follows: when solar power is greater than load power, mixed energy storage system is in charged state, P= PSolar energy is real-time-PLoad is real-time, it is the charge power of energy-storage system, works as P/PLiquid=integer+decimal, when decimal > 0.7, the full vanadium liquid of starting Galvanic battery mould group number is integer+1, and when decimal < 0.7, the full vanadium cell of starting integer, remaining power section is filled by lithium battery Electricity.
When solar power is less than load power, load realtime power PLoad is real-time/PLiquidWhen < 0.7, lithium battery electric discharge, lithium electricity After tank discharge to blanking voltage, starts a set of vanadium cell mould group electric discharge, work as PLoad is real-time/PLiquidWhen > 0.7, start a set of vanadium cell mould group Electric discharge.
In the above scheme, the SOC range of all-vanadium flow battery mould group be 0~100%, lithium battery SOC range be 30~ 70%.
The solution of the present invention has the effect that
1. this programme hybrid energy-storing whole efficiency is high
2. hybrid energy-storing scheme and the method for operation make the efficiency of solar energy utilization high indirectly, configuration power is small under similarity condition
3. two kinds of energy-storage systems have complementary advantages, the service life is long
4. system redundancy is good, mutual backup
The present invention uses multiple groups all-vanadium flow mould group as a result, and combines the characteristic of lithium battery and vanadium cell, is based on multimode The flow battery of block cooperates a certain proportion of lithium battery, makes under off-grid operation mode, system effectiveness highest, longest-lived is superfluous Remaining property is good.
Following table is different configuration method Solar energy design power and operating condition (load average power under same workload demand For 100KW, local solar power generation hourage 6 daily)
The preferable specific embodiment of the above, only the invention, but the protection scope of the invention is not It is confined to this, anyone skilled in the art is in the technical scope that the invention discloses, according to the present invention The technical solution of creation and its inventive concept are subject to equivalent substitution or change, should all cover the invention protection scope it It is interior.

Claims (8)

1. a kind of mixed energy storage system of off-network solar power system characterized by comprising lithium battery, several full vanadium Flow battery mould group and control system, the public capacity cell of several all-vanadium flow battery mould groups, the control system root Starting opportunity, quantity and the charging and discharging state of each all-vanadium flow battery mould group are controlled according to load power, and are controlled in corresponding opportunity Start corresponding lithium battery and carry out charge and discharge, with the method for operation control to off-network solar power system.
2. the mixed energy storage system of off-network solar power system as described in claim 1, which is characterized in that the solar energy The power of electricity generation system is configured as:
PSolar energy=24*K2*PLoad is average/K1
The power of each all-vanadium flow battery mould group is configured as:
PLiquid=K2*PLoad is average
The capacity of several common capacity cells of all-vanadium flow battery mould group is configured as:
CLiquid=K3*PLiquid
The power of the lithium battery is configured as:
PLithium=K4*K2*PLoad is average
The capacity of the lithium battery is configured as
CLithium=K5*K4*K2*PLoad is average
Wherein:
K1For solar energy daily averagely generate electricity hourage;
K2=1~1.3;
K3=6~20;
PLoad is averageFor the power of off-network load;
K4=0.2~1;
K5=0.2~1.
3. the mixed energy storage system of off-network solar power system as claimed in claim 1 or 2, which is characterized in that the control System processed is based on such as under type Controlling operation method: if the power of solar power system is greater than load power, hybrid energy-storing system System is in charged state, calculates P/PLiquid, result includes integer part and fractional part, and P is the charge power of energy storage, PLiquidIt is complete The power of vanadium flow battery mould group, P=PSolar energy is real-time-PLoad is real-time
If judgement are as follows: fractional part > 0.7 starts all-vanadium flow battery mould group, and the quantity of starting is integer part+1;
If judgement are as follows: fractional part < 0.7 starts all-vanadium flow battery mould group, and starting quantity is integer part, remaining power It is charged and is compensated by lithium battery in part.
4. the mixed energy storage system of off-network solar power system as claimed in claim 3, which is characterized in that the control system System is based on such as under type Controlling operation method:
If the power of solar power system is less than load power;
Work as judgement are as follows:
PLoad is real-time/PLiquid<0.7
PLoad is real-timeFor load realtime power;
Then lithium battery discharges, after lithium battery discharges into blanking voltage, starting one all-vanadium flow battery mould group electric discharge;
Work as judgement are as follows:
PLoad is real-time/PLiquid>0.7
Then start all-vanadium flow battery mould group electric discharge.
5. the mixed energy storage system of the off-network solar power system as described in claims 1 or 2 or 3, it is characterised in that: Quan Fan The SOC range of flow battery mould group is 0-100%, and lithium battery SOC range is 30-70%.
6. a kind of mixed energy storage system configuration method of off-network solar power system, which is characterized in that the energy-storage system packet It includes: lithium battery, several all-vanadium flow battery mould groups and control system, the public capacity of several all-vanadium flow battery mould groups Unit;
The power of the solar power system is configured as:
PSolar energy=24*K2*PLoad is average/K1
The power of each all-vanadium flow battery mould group is configured as:
PLiquid=K2*PLoad is average
The capacity of several common capacity cells of all-vanadium flow battery mould group is configured as:
CLiquid=K3*PLiquid
The power of the lithium battery is configured as:
PLithium=K4*K2*PLoad is average
The capacity of the lithium battery is configured as
CLithium=K5*K4*K2*PLoad is average
Wherein:
K1For solar energy daily averagely generate electricity hourage;
K2=1~1.3;
K3=6~20;
PLoad is averageFor the power of off-network load;
K4=0.2~1;
K5=0.2~1.
7. a kind of progress control method of the mixed energy storage system of off-network solar power system, which is characterized in that the energy storage System includes: lithium battery, several all-vanadium flow battery mould groups and control system, several all-vanadium flow battery mould groups public one A capacity cell;
If the power of solar power system is greater than load power, mixed energy storage system is in charged state, calculates P/PLiquid, knot Fruit includes integer part and fractional part, and P is the charge power of energy storage, PLiquidFor the power of all-vanadium flow battery mould group, P= PSolar energy is real-time-PLoad is real-time
If judgement are as follows: fractional part > 0.7 starts all-vanadium flow battery mould group, and the quantity of starting is integer part+1;
If judgement are as follows: fractional part < 0.7 starts all-vanadium flow battery mould group, and starting quantity is integer part, remaining power It is charged and is compensated by lithium battery in part.
8. the progress control method of the mixed energy storage system of off-network solar power system as claimed in claim 7, feature It is, if the power of solar power system is less than load power;
Work as judgement are as follows:
PLoad is real-time/PLiquid<0.7
PLoad is real-timeFor load realtime power;
Then lithium battery discharges, after lithium battery discharges into blanking voltage, starting one all-vanadium flow battery mould group electric discharge;
Work as judgement are as follows:
PLoad is real-time/PLiquid>0.7
Then start all-vanadium flow battery mould group electric discharge.
CN201710894043.2A 2017-09-28 2017-09-28 Mixed energy storage system, configuration method and the operation method of off-network solar power system Pending CN109586329A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201710894043.2A CN109586329A (en) 2017-09-28 2017-09-28 Mixed energy storage system, configuration method and the operation method of off-network solar power system

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Application Number Priority Date Filing Date Title
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Publication Number Publication Date
CN109586329A true CN109586329A (en) 2019-04-05

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030015995A1 (en) * 2001-07-12 2003-01-23 Hiroshi Tamura Set battery charging condition detecting apparatus
CN102420455A (en) * 2011-12-12 2012-04-18 合肥聚能新能源科技有限公司 Application of battery management system to photovoltaic industry and control method
CN106961150A (en) * 2016-01-11 2017-07-18 上海电气集团股份有限公司 The control method and system of composite energy storage battery

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030015995A1 (en) * 2001-07-12 2003-01-23 Hiroshi Tamura Set battery charging condition detecting apparatus
CN102420455A (en) * 2011-12-12 2012-04-18 合肥聚能新能源科技有限公司 Application of battery management system to photovoltaic industry and control method
CN106961150A (en) * 2016-01-11 2017-07-18 上海电气集团股份有限公司 The control method and system of composite energy storage battery

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