CN109575727A - A kind of non-skid coating - Google Patents
A kind of non-skid coating Download PDFInfo
- Publication number
- CN109575727A CN109575727A CN201811430842.5A CN201811430842A CN109575727A CN 109575727 A CN109575727 A CN 109575727A CN 201811430842 A CN201811430842 A CN 201811430842A CN 109575727 A CN109575727 A CN 109575727A
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- Prior art keywords
- parts
- acid
- skid coating
- coating
- silicone acrylic
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Classifications
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D175/00—Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
- C09D175/04—Polyurethanes
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/65—Additives macromolecular
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/2224—Magnesium hydroxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The present invention relates to coating technologies, it is desirable to provide a kind of non-skid coating.The non-skid coating is made of the raw material components of following weight ratio: 4-6 parts of triethanolamine；10-16 parts of magnesium hydroxide；1-3 parts of bishydroxymethyl propionic acid；6-8 parts of polyglutamic acid；3-5 parts of atoleine；1-3 parts of aristolochic acid；8-10 parts of rosin acid；3-5 parts of carbon black；10-12 parts of silicone acrylic emulsion；10-12 parts of polyaminoester emulsion；20-44 parts of distilled water；The silicone acrylic emulsion solid content is 40%-60%；The polyaminoester emulsion solid content is 40%-60%.Compared with prior art, non-skid coating provided by the invention can directly be coated on ground or road surface, after room temperature curing, can reach fabulous dry state and hygrometric state antiskid effect.Compared with existing coating with the same function, paint slip-resistance of the invention improves 5 times or more.
Description
Technical field
The present invention relates to coating technologies, and in particular to a kind of non-skid coating.
Background technique
In people's daily life, anti-skidding is an important job.By carrying out anti-skidding place to travel region road surface
Reason can effectively contain the personal injury as caused by slipperiness on roads；In addition, residential area indoors, carries out indoor road surface anti-skidding
Processing helps to improve the residence comfort of people；Finally, in the elderly or the dysbasia hospital that the crowd is dense or home for destitute
Region, the anti-skidding even more most important thing in road surface and ground.
The coating on current road surface or ground, in humidity or in the state of have water, surface becomes easy skidding, meanwhile,
After causing to wear or peel off by prolonged use, antiskid effect often sharply declines.
Summary of the invention
The technical problem to be solved by the present invention is to overcome deficiency in the prior art, provide a kind of non-skid coating.
In order to solve the technical problem, solution of the invention is:
A kind of non-skid coating is provided, which is made of the raw material components of following weight ratio:
4-6 parts of triethanolamine；10-16 parts of magnesium hydroxide；1-3 parts of bishydroxymethyl propionic acid；6-8 parts of polyglutamic acid；Liquid
3-5 parts of paraffin；1-3 parts of aristolochic acid；8-10 parts of rosin acid；3-5 parts of carbon black；10-12 parts of silicone acrylic emulsion；Polyaminoester emulsion 10-
12 parts；20-44 parts of distilled water；
The silicone acrylic emulsion solid content is 40%-60%；The polyaminoester emulsion solid content is 40%-60%.
In the present invention, the magnesium hydroxide partial size is 10-30 microns.
In the present invention, the number-average molecular weight of the polyglutamic acid is 50000-150000.
In the present invention, the partial size of the carbon black is 10-50 nanometers.
Aforementioned non-skid coating can be prepared by following methods:
(1) each raw material component is taken by the weight ratio；
(2) magnesium hydroxide, carbon black are added in silicone acrylic emulsion, persistently stir 1-3 hours, obtains mixture one；
(3) rosin acid, aristolochic acid, polyglutamic acid are added in atoleine, persistently stir 1-3 hours, is mixed
Object two；
(4) triethanolamine, bishydroxymethyl propionic acid, polyaminoester emulsion are added in distilled water, are persistently stirred 1-3 hours,
Obtain mixture three；
(5) mixture two is added in mixture one, is persistently stirred 1-3 hours；It is then sonicated 10-30 minutes, obtains
Mixture four；
(6) mixture four is added in mixture three, is persistently stirred 1-3 hours；It grinds again 3-5 hours, obtains anti-skidding painting
Material.
The application method of non-skid coating of the present invention: it is directly coated on ground or road surface, after room temperature curing, can reach pole
Good dry state and hygrometric state antiskid effect.
Inventive principle description:
The present invention obtains the formulation for coating material by a large number of experiments, and coating is coated on ground or road surface, and in room temperature curing
Afterwards, there is following special construction:
1, surface forms micro- sodium composite construction, the i.e. microstructure of class gecko's toes skin to the coating after hardening, from
And it is provided with good nonslip properties；
2, simultaneously, the addition of polyglutamic acid, aristolochic acid, rosin acid further improves the antiskid effect of coating surface,
Polyglutamic acid, aristolochic acid, rosin acid pass through the van der Waals interaction of a large amount of hydrogen bonds and higher-strength, so that coating surface is to pole
Property and the surfaces of apolar surfaces all there is good wear-resisting effect.
Compared with prior art, the invention has the advantages that
Non-skid coating provided by the invention can directly be coated on ground or road surface, after room temperature curing, can reach fabulous do
State and hygrometric state antiskid effect.Compared with existing coating with the same function, paint slip-resistance of the invention improve 5 times with
On.
Specific embodiment
The present invention is described in detail combined with specific embodiments below.Following embodiment will be helpful to the technology of this field
Personnel further understand the present invention, but the invention is not limited in any way.It should be pointed out that the ordinary skill of this field
For personnel, without departing from the inventive concept of the premise, various modifications and improvements can be made.These belong to the present invention
Protection scope.
Embodiment 1
Non-skid coating is made of the raw material components of following weight ratio:
4 parts of triethanolamine；10 parts of magnesium hydroxide；1 part of bishydroxymethyl propionic acid；6 parts of polyglutamic acid；3 parts of atoleine；Horse
1 part of acid of pocket bell；8 parts of rosin acid；3 parts of carbon black；10 parts of silicone acrylic emulsion；10 parts of polyaminoester emulsion；44 parts of distilled water.
The magnesium hydroxide partial size is at 10-20 microns；The number-average molecular weight of polyglutamic acid is in 50000-100000；Carbon black
Partial size is at 10-30 nanometers；Silicone acrylic emulsion solid content is 40%；Polyaminoester emulsion solid content is 40%.
The preparation method of the non-skid coating, in turn includes the following steps:
(1) each raw material component is taken by the weight ratio；
(2) magnesium hydroxide, carbon black are added in silicone acrylic emulsion, persistently stir 1 hour, obtains mixture one；
(3) rosin acid, aristolochic acid, polyglutamic acid are added in atoleine, persistently stir 1 hour, obtains mixture
Two；
(4) triethanolamine, bishydroxymethyl propionic acid, polyaminoester emulsion are added in distilled water, persistently stir 1 hour, obtains
To mixture three；
(5) mixture two is added in mixture one, is persistently stirred 1 hour；It is then sonicated 10 minutes, obtains mixture
Four；
(6) mixture four is added in mixture three, is persistently stirred 1 hour；It grinds again 3 hours, obtains non-skid coating.
Embodiment 2
Non-skid coating is made of the raw material components of following weight ratio:
6 parts of triethanolamine；16 parts of magnesium hydroxide；3 parts of bishydroxymethyl propionic acid；8 parts of polyglutamic acid；5 parts of atoleine；Horse
3 parts of acid of pocket bell；10 parts of rosin acid；5 parts of carbon black；12 parts of silicone acrylic emulsion；12 parts of polyaminoester emulsion；20 parts of distilled water.
The magnesium hydroxide partial size is at 20-30 microns；The number-average molecular weight of polyglutamic acid is in 100000-150000；Carbon black
Partial size at 30-50 nanometers；Silicone acrylic emulsion solid content is 60%；Polyaminoester emulsion solid content is 60%.
The preparation method of the non-skid coating, in turn includes the following steps:
(1) each raw material component is taken by the weight ratio；
(2) magnesium hydroxide, carbon black are added in silicone acrylic emulsion, persistently stir 3 hours, obtains mixture one；
(3) rosin acid, aristolochic acid, polyglutamic acid are added in atoleine, persistently stir 3 hours, obtains mixture
Two；
(4) triethanolamine, bishydroxymethyl propionic acid, polyaminoester emulsion are added in distilled water, persistently stir 3 hours, obtains
To mixture three；
(5) mixture two is added in mixture one, is persistently stirred 3 hours；It is then sonicated 30 minutes, obtains mixture
Four；
(6) mixture four is added in mixture three, is persistently stirred 3 hours；It grinds again 5 hours, obtains non-skid coating.
Embodiment 3
Non-skid coating is made of the raw material components of following weight ratio:
5 parts of triethanolamine；13 parts of magnesium hydroxide；2 parts of bishydroxymethyl propionic acid；7 parts of polyglutamic acid；4 parts of atoleine；Horse
2 parts of acid of pocket bell；9 parts of rosin acid；4 parts of carbon black；11 parts of silicone acrylic emulsion；11 parts of polyaminoester emulsion；32 parts of distilled water.
The magnesium hydroxide partial size is at 15-25 microns；The number-average molecular weight of polyglutamic acid is in 75000-125000；Carbon black
Partial size is at 25-40 nanometers；Silicone acrylic emulsion solid content is 50%；Polyaminoester emulsion solid content is 50%.
The preparation method of the non-skid coating, in turn includes the following steps:
(1) each raw material component is taken by the weight ratio；
(2) magnesium hydroxide, carbon black are added in silicone acrylic emulsion, persistently stir 2 hours, obtains mixture one；
(3) rosin acid, aristolochic acid, polyglutamic acid are added in atoleine, persistently stir 2 hours, obtains mixture
Two；
(4) triethanolamine, bishydroxymethyl propionic acid, polyaminoester emulsion are added in distilled water, persistently stir 2 hours, obtains
To mixture three；
(5) mixture two is added in mixture one, is persistently stirred 2 hours；It is then sonicated 20 minutes, obtains mixture
Four；
(6) mixture four is added in mixture three, is persistently stirred 2 hours；It grinds again 4 hours, obtains non-skid coating.
Invention effect verifying
1, the non-skid coating that will be prepared according to embodiment one to three, is denoted as sample one, sample two and sample respectively
Three.Take conventional coating: EPOXY-SEAL (SEAL KRETE), Tianjin Yu Xin development in science and technology Co., Ltd produce anti-skidding floor paint, show
It moors industry ground slab Science and Technology Ltd. and produces anti-skidding floor paint, respectively as sample four, sample five, sample six.
2, sample one to sample six is respectively coated in 304 stainless steel surfaces, at room temperature film-forming.
3,30mm × 30mm × 5mm rubber block is placed in the stainless steel surface for being coated with non-skid coating sample, pressed thereon
10kg iron block then carries out tensile test to rubber block, tests it and starts critical force (testing critical force before and after spray water respectively),
Its test result is as follows table
As can be seen from the above table, relative to common commercially available non-skid coating, present invention gained non-skid coating is shown preferably
In contrast dry state and hygrometric state non-skid property, technical effect are very significant.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited to above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring substantive content of the invention.
Claims (4)
1. a kind of non-skid coating, which is characterized in that the non-skid coating is made of the raw material components of following weight ratio:
4-6 parts of triethanolamine；10-16 parts of magnesium hydroxide；1-3 parts of bishydroxymethyl propionic acid；6-8 parts of polyglutamic acid；Atoleine
3-5 parts；1-3 parts of aristolochic acid；8-10 parts of rosin acid；3-5 parts of carbon black；10-12 parts of silicone acrylic emulsion；10-12 parts of polyaminoester emulsion；
20-44 parts of distilled water；
The silicone acrylic emulsion solid content is 40%-60%；The polyaminoester emulsion solid content is 40%-60%.
2. non-skid coating according to claim 1, which is characterized in that the magnesium hydroxide partial size is 10-30 microns.
3. non-skid coating according to claim 1, which is characterized in that the number-average molecular weight of the polyglutamic acid is 50000-
150000。
4. non-skid coating according to claim 1, which is characterized in that the partial size of the carbon black is 10-50 nanometers.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811430842.5A CN109575727A (en) | 2018-11-28 | 2018-11-28 | A kind of non-skid coating |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811430842.5A CN109575727A (en) | 2018-11-28 | 2018-11-28 | A kind of non-skid coating |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109575727A true CN109575727A (en) | 2019-04-05 |
Family
ID=65925112
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811430842.5A Pending CN109575727A (en) | 2018-11-28 | 2018-11-28 | A kind of non-skid coating |
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| Country | Link |
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| CN (1) | CN109575727A (en) |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101094698A (en) * | 2003-09-29 | 2007-12-26 | 汉莫堤克科技公司 | Biocompatible, biostable coating of medical surfaces |
| CN103479534A (en) * | 2012-06-11 | 2014-01-01 | 陶炎 | Palm antiskid liquid for sports |
| CN104194601A (en) * | 2014-08-27 | 2014-12-10 | 句容市石狮冲压件厂 | Antiskid paint for bicycle court tracks and preparation method thereof |
| CN106700497A (en) * | 2016-12-06 | 2017-05-24 | 安徽潜源教学设备有限公司 | Green and environment-friendly polyurethane plastic track and preparation method thereof |
| CN107142014A (en) * | 2017-06-06 | 2017-09-08 | 合肥月煌新型装饰材料有限公司 | A kind of ground anti-skid wearable coating and preparation method |
-
2018
- 2018-11-28 CN CN201811430842.5A patent/CN109575727A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101094698A (en) * | 2003-09-29 | 2007-12-26 | 汉莫堤克科技公司 | Biocompatible, biostable coating of medical surfaces |
| CN103479534A (en) * | 2012-06-11 | 2014-01-01 | 陶炎 | Palm antiskid liquid for sports |
| CN104194601A (en) * | 2014-08-27 | 2014-12-10 | 句容市石狮冲压件厂 | Antiskid paint for bicycle court tracks and preparation method thereof |
| CN106700497A (en) * | 2016-12-06 | 2017-05-24 | 安徽潜源教学设备有限公司 | Green and environment-friendly polyurethane plastic track and preparation method thereof |
| CN107142014A (en) * | 2017-06-06 | 2017-09-08 | 合肥月煌新型装饰材料有限公司 | A kind of ground anti-skid wearable coating and preparation method |
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Application publication date: 20190405 |
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