CN109548953A - A method of removing peas protein fishy smell - Google Patents

A method of removing peas protein fishy smell Download PDF

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Publication number
CN109548953A
CN109548953A CN201811619710.7A CN201811619710A CN109548953A CN 109548953 A CN109548953 A CN 109548953A CN 201811619710 A CN201811619710 A CN 201811619710A CN 109548953 A CN109548953 A CN 109548953A
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CN
China
Prior art keywords
solution
protein
fishy smell
mentioned steps
peas
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CN201811619710.7A
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Chinese (zh)
Inventor
李健
李�赫
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Beijing Technology and Business University
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Beijing Technology and Business University
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Priority to CN201811619710.7A priority Critical patent/CN109548953A/en
Publication of CN109548953A publication Critical patent/CN109548953A/en
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23JPROTEIN COMPOSITIONS FOR FOODSTUFFS; WORKING-UP PROTEINS FOR FOODSTUFFS; PHOSPHATIDE COMPOSITIONS FOR FOODSTUFFS
    • A23J3/00Working-up of proteins for foodstuffs
    • A23J3/14Vegetable proteins
    • A23J3/16Vegetable proteins from soybean
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20Removal of unwanted matter, e.g. deodorisation or detoxification
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23LFOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
    • A23L5/00Preparation or treatment of foods or foodstuffs, in general; Food or foodstuffs obtained thereby; Materials therefor
    • A23L5/20Removal of unwanted matter, e.g. deodorisation or detoxification
    • A23L5/27Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption
    • A23L5/273Removal of unwanted matter, e.g. deodorisation or detoxification by chemical treatment, by adsorption or by absorption using adsorption or absorption agents, resins, synthetic polymers, or ion exchangers
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23VINDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
    • A23V2002/00Food compositions, function of food ingredients or processes for food or foodstuffs

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  • Life Sciences & Earth Sciences (AREA)
  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Nutrition Science (AREA)
  • Engineering & Computer Science (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Biochemistry (AREA)
  • Beans For Foods Or Fodder (AREA)
  • Meat, Egg Or Seafood Products (AREA)

Abstract

The invention discloses a kind of methods for removing peas protein fishy smell, comprising the following steps: (1) peas protein is dissolved in the water, is configured to the solution that concentration is 1-10%;(2) addition pH adjusting agent adjusts the pH value of the protein solution of above-mentioned steps (1) to 4-5;(3) using the protein solution of ultrasonic physics field processing above-mentioned steps (2);(4) active carbon, stirring and adsorbing are added in the solution of above-mentioned steps (3);(5) pH adjusting agent is added into the solution of step (4) and adjusts pH value of solution to 7;(6) it is spray-dried after filtering the solution of step (5), obtains no fishy smell bean protein powder.The method of removing peas protein fishy smell provided by the invention, by adjusting solution acid alkalinity, change the foldable structure of peas protein, small molecule compound is exposed, it is handled in combination with ultrasonic physics field, break the crosslinking between albumen and small molecule, activated carbon adsorption small-molecule substance is finally utilized, to thoroughly remove fishy smell.

Description

A method of removing peas protein fishy smell
Technical field
The present invention relates to the manufacture field of peas protein more particularly to a kind of methods for removing peas protein fishy smell.
Background technique
Currently, in recent years, with the transformation of consumption pattern, vegetable protein beverage is received with the concept of " natural " " health " Extensive concern.Compared with conventional animal dairy produce, vegetable protein beverage have it is cheap, saturated fat levels are few, do not tend to have The advantages that antibiotic and residue of veterinary drug.Nowadays, more and more consumers more favors vegetable protein beverage.
Yield of beans is big, and contains protein abundance, is the important raw material sources of most important vegetable protein beverage.So And peas protein has special beany flavor, product often has bad hair flavor, needs to add correlation in process of production Screening agent is made into the flavors protein beverage such as chocolate, vanilla, to cover bad flavor.The presence of beany flavor seriously constrains production The expansion of product category.Therefore, the eliminating fishy smell technology for studying peas protein facilitates the application range for expanding peas protein.
The generation of beans fishy smell is mainly by the volatile small molecules material composition such as aldehydes, ketones and alcohols, these objects Matter may be from beans itself or the in process unsaturated fatty enzymatic oxidation of beans.The beans identified at present is waved Volatile material has more than 70 kinds, and wherein content is higher hexanal, trans- 2- hexenoic aldehyde, acetic acid, 2-HEPTANONE and 4- ethylo benzene formaldehyde, These compounds present cut the taste of green grass respectively, give birth to taste, mushroom, tart flavour, semen armeniacae amarae taste and acid, and common group of these substances At beany flavor.
It is reported at present to take off awake method, it can be summarized as the method by physical heating or solvent, make small molecule Substance volatilization or dissolution remove (CN101731441A), however the small-molecule substances such as aldehydes present in beans, many and beans egg White combination can not thoroughly remove beany flavor by heating or solvent processing, and after forming product, small molecular protein compound will Volatile materials can be discharged again, and since the threshold value of fishy smell substance is extremely low, as long as there is remaining, fishy smell will exist.It in addition is logical The activity for reducing enzyme is crossed, fat oxidation is reduced and forms fishy smell substance, this method cannot remove already existing fishy smell substance.? There is the method (CN102232425A) by microbial fermentation, fishy smell substance of degrading, but new flavor can be also generated simultaneously, it is uncomfortable Symphysis produces tasteless protein product.
Summary of the invention
For overcome the deficiencies in the prior art, the purpose of the present invention is to provide a kind of sides for removing peas protein fishy smell Method, method is simple and convenient, easy to use, is suitble to industrialized batch production.
The purpose of the present invention adopts the following technical scheme that realization:
A method of removing peas protein fishy smell, comprising the following steps:
(1) peas protein is dissolved in the water, is configured to the solution that concentration is 1-10%;
(2) addition pH adjusting agent adjusts the pH value of the protein solution of above-mentioned steps (1) to 4-5;
(3) using the protein solution of ultrasonic physics field processing above-mentioned steps (2);
(4) active carbon, stirring and adsorbing are added in the solution of above-mentioned steps (3);
(5) pH adjusting agent is added into the solution of step (4) and adjusts pH value of solution to 7;
(6) it is spray-dried after filtering the solution of step (5), obtains no fishy smell bean protein powder.
Further, the beans in the step (1) be soybean, pea, chick-pea, mung bean, red bean, semen viciae fabae, hyacinth bean or One of kidney bean.
Further, the pH adjusting agent in the step (2) is hydrochloric acid solution, and the pH adjusting agent in above-mentioned steps (5) is Sodium hydroxide solution.
Further, ultrasonic physics field is 20-25kHz in above-mentioned steps (3), and the processing time is 10-20min.
Further, ultrasonic physics field is 20kHz in above-mentioned steps (3), and the processing time is 15min.
Further, the dosage of active carbon is 2-8%, stirring and adsorbing 5-30min in above-mentioned steps (4).
Further, the dosage of active carbon is 5% in above-mentioned steps (4), stirring and adsorbing 10min.
Further, above-mentioned steps (6) are filtered into using plate-frame filtering or micro-filtration.
Further, the pH of protein solution is 4.5 after adjusting in the step (2).
Compared with prior art, the beneficial effects of the present invention are: the present invention to provide a kind of side for removing peas protein fishy smell Method changes the foldable structure of peas protein by adjusting solution acid alkalinity, exposes small molecule compound sufficiently, in combination with The processing of ultrasonic physics field, breaks the crosslinking between albumen and small molecule, activated carbon adsorption small-molecule substance is finally utilized, thus thorough The removal fishy smell at bottom.
Specific embodiment
In the following, being described further in conjunction with specific embodiment to the present invention, it should be noted that is do not collided Under the premise of, new embodiment can be formed between various embodiments described below or between each technical characteristic in any combination.
Embodiment 1
(1) soybean protein is dissolved in the water, is configured to the solution that concentration is 2%;
(2) addition hydrochloric acid solution adjusts the pH value of the protein solution of above-mentioned steps (1) to 4.5;
(3) using the protein solution 15min of 20kHz ultrasonic physics field processing above-mentioned steps (2);
(4) 5% active carbon, stirring and adsorbing 10min are added in the solution of above-mentioned steps (3);
(5) sodium hydroxide solution is added into the solution of step (4) and adjusts pH value of solution to 7;
(6) solution of step (5) is obtained into odourless soybean albumen powder using being spray-dried after plate-frame filtering.
Embodiment 2
(1) pea protein is dissolved in the water, is configured to the solution that concentration is 5%;
(2) addition hydrochloric acid solution adjusts the pH value of the protein solution of above-mentioned steps (1) to 4;
(3) using the protein solution 20min of 22kHz ultrasonic physics field processing above-mentioned steps (2);
(4) 2% active carbon, stirring and adsorbing 20min are added in the solution of above-mentioned steps (3);
(5) sodium hydroxide solution is added into the solution of step (4) and adjusts pH value of solution to 7;
(6) by spray drying rear after the solution micro-filtration of step (5), no fishy smell Fed Protein Powder of Pea Insteal is obtained.
Embodiment 3
(1) Broad Bean Protein is dissolved in the water, is configured to the solution that concentration is 10%;
(2) addition hydrochloric acid solution adjusts the pH value of the protein solution of above-mentioned steps (1) to 5;
(3) using the protein solution 10min of 25kHz ultrasonic physics field processing above-mentioned steps (2);
(4) 8% active carbon, stirring and adsorbing 5min are added in the solution of above-mentioned steps (3);
(5) sodium hydroxide solution is added into the solution of step (4) and adjusts pH value of solution to 7;
(6) solution of step (5) is obtained into odourless soybean albumen powder using being spray-dried after plate-frame filtering.
Comparative example 1
Comparative example 1 provides a kind of difference of method and embodiment 1 for removing peas protein fishy smell are as follows: step (3) are saved, Remaining is and embodiment 1 is identical.
Comparative example 2
Comparative example 2 provide it is a kind of remove peas protein fishy smell method and embodiment 1 difference are as follows: save step (2) and (5), remaining is and embodiment 1 is identical.
Comparative example 3
Comparative example 3 provides a kind of difference of method and embodiment 1 for removing peas protein fishy smell are as follows: adjusts in step (2) PH value is 3, remaining is and embodiment 1 is identical.
Comparative example 4
Comparative example 4 provides a kind of difference of method and embodiment 1 for removing peas protein fishy smell are as follows: adjusts in step (2) PH value is 6, remaining is and embodiment 1 is identical.
To embodiment 1 to 3, the bean protein powder of comparative example 1 to 4 carries out sensory evaluation, and the results are shown in Table 1.
Table 1
Sample Beany flavor Acceptance level
Embodiment 1 It is tasteless Receive
Embodiment 2 It is tasteless Receive
Embodiment 3 There is slight beany flavor Receive
Comparative example 1 Beany flavor is strong Do not receive
Comparative example 2 Beany flavor is strong Do not receive
Comparative example 3 Beany flavor is strong Do not receive
Comparative example 4 Beany flavor is strong Do not receive
It is analyzed by gas chromatography-mass spectrography in the bean protein powder of embodiment 1 to 3 and comparative example 1 to 4 and generates fishy smell Substance, determine the variation of its content (peak area expression), the results are shown in Table 2.
Table 2
As can be seen from Table 1, for the bean protein powder handled using the method for the present invention almost without fishy smell, sensory evaluation person can be with Receive, and 4 comparative examples show strong beany flavor.It is found by gas chromatography-mass spectrometry analysis, in 3 embodiments It does not find 2-HEPTANONE, trans- -2- hexenoic aldehyde, 3- octanone, 2-Ethylhexyl Alcohol and 4- ethylo benzene formaldehyde, realizes complete removing. The content of hexanal is also reduced to 1/10th or so of comparative example.It is by comparative example 1 to 4 it can be seen that (right when saving ultrasonic field processing Ratio 1,3,4) or save after acid-base property adjusts (comparative example 2) or change the pH value (comparative example 3,4) of solution, at fishy smell Result is managed not as good as the present invention.Illustrate the method for removing peas protein fishy smell provided by the invention, by adjusting solution acid alkalinity, It is handled in combination with ultrasonic physics field, breaks the crosslinking between albumen and small molecule, finally utilize activated carbon adsorption small molecule object Matter, to thoroughly remove fishy smell.
The above embodiment is only the preferred embodiment of the present invention, and the scope of protection of the present invention is not limited thereto, The variation and replacement for any unsubstantiality that those skilled in the art is done on the basis of the present invention belong to institute of the present invention Claimed range.

Claims (9)

1. a kind of method for removing peas protein fishy smell, which comprises the following steps:
(1) peas protein is dissolved in the water, is configured to the solution that concentration is 1-10%;
(2) addition pH adjusting agent adjusts the pH value of the protein solution of above-mentioned steps (1) to 4-5;
(3) using the protein solution of ultrasonic physics field processing above-mentioned steps (2);
(4) active carbon, stirring and adsorbing are added in the solution of above-mentioned steps (3);
(5) pH adjusting agent is added into the solution of step (4) and adjusts pH value of solution to 7;
(6) it is spray-dried after filtering the solution of step (5), obtains no fishy smell bean protein powder.
2. removing the method for peas protein fishy smell according to claim 1, which is characterized in that the beans in the step (1) For soybean, pea, chick-pea, mung bean, red bean, semen viciae fabae, one of hyacinth bean or kidney bean.
3. removing the method for peas protein fishy smell according to claim 1, which is characterized in that the pH tune in the step (2) Section agent is hydrochloric acid solution, and the pH adjusting agent in above-mentioned steps (5) is sodium hydroxide solution.
4. removing the method for peas protein fishy smell according to claim 1, which is characterized in that ultrasonic object in above-mentioned steps (3) Reason field is 20-25kHz, and the processing time is 10-20min.
5. removing the method for peas protein fishy smell according to claim 4, which is characterized in that ultrasonic object in above-mentioned steps (3) Reason field is 20kHz, and the processing time is 15min.
6. removing the method for peas protein fishy smell according to claim 1, which is characterized in that active carbon in above-mentioned steps (4) Dosage be 2-8%, stirring and adsorbing 5-30min.
7. removing the method for peas protein fishy smell according to claim 6, which is characterized in that active carbon in above-mentioned steps (4) Dosage be 5%, stirring and adsorbing 10min.
8. removing the method for peas protein fishy smell according to claim 1, which is characterized in that above-mentioned steps (6) are filtered into Using plate-frame filtering or micro-filtration.
9. removing the method for peas protein fishy smell according to claim 1, which is characterized in that after being adjusted in the step (2) The pH of protein solution is 4.5.
CN201811619710.7A 2018-12-28 2018-12-28 A method of removing peas protein fishy smell Pending CN109548953A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113993388A (en) * 2019-05-29 2022-01-28 罗盖特公司 Reduced flavor co-atomized legume proteins

Citations (3)

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Publication number Priority date Publication date Assignee Title
CN102907627A (en) * 2012-11-16 2013-02-06 桂仕林 Preparation technique and application of non-odor soybean
CN108041254A (en) * 2017-05-31 2018-05-18 中国农业大学 A kind of soybean protein isolate of no fishy smell high emulsibility and preparation method thereof
CN108935915A (en) * 2018-06-27 2018-12-07 山东禹王生态食业有限公司 A kind of preparation method of smellless soybean separated protein powder

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102907627A (en) * 2012-11-16 2013-02-06 桂仕林 Preparation technique and application of non-odor soybean
CN108041254A (en) * 2017-05-31 2018-05-18 中国农业大学 A kind of soybean protein isolate of no fishy smell high emulsibility and preparation method thereof
CN108935915A (en) * 2018-06-27 2018-12-07 山东禹王生态食业有限公司 A kind of preparation method of smellless soybean separated protein powder

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN113993388A (en) * 2019-05-29 2022-01-28 罗盖特公司 Reduced flavor co-atomized legume proteins

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