CN109545862A - A kind of solar battery and preparation method thereof - Google Patents

A kind of solar battery and preparation method thereof Download PDF

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Publication number
CN109545862A
CN109545862A CN201811167604.XA CN201811167604A CN109545862A CN 109545862 A CN109545862 A CN 109545862A CN 201811167604 A CN201811167604 A CN 201811167604A CN 109545862 A CN109545862 A CN 109545862A
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CN
China
Prior art keywords
solar battery
main grid
frame
microns
distance
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CN201811167604.XA
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Chinese (zh)
Inventor
徐顺波
邱江南
邵辉良
陈康
付少剑
王立富
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Jiangxi Zhanyu New Energy Co Ltd
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Jiangxi Zhanyu New Energy Co Ltd
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Priority to CN201811167604.XA priority Critical patent/CN109545862A/en
Publication of CN109545862A publication Critical patent/CN109545862A/en
Pending legal-status Critical Current

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    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/02Details
    • H01L31/0224Electrodes
    • H01L31/022408Electrodes for devices characterised by at least one potential jump barrier or surface barrier
    • H01L31/022425Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
    • H01L31/022433Particular geometry of the grid contacts
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01LSEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
    • H01L31/00Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
    • H01L31/18Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
    • H01L31/1804Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof comprising only elements of Group IV of the Periodic System
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E10/00Energy generation through renewable energy sources
    • Y02E10/50Photovoltaic [PV] energy
    • Y02E10/547Monocrystalline silicon PV cells
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P70/00Climate change mitigation technologies in the production process for final industrial or consumer products
    • Y02P70/50Manufacturing or production processes characterised by the final manufactured product

Abstract

The invention discloses a kind of solar battery, the solar battery includes surface grid line;The frame of the surface grid line is waveform, and any one section of line segment is curved section on the frame.The present invention is by being changed to the design of waveform curved section for frame S broken line undaform in the prior art design, preferably avoid the intersection point of steel wire, it greatly reduces when printing in the prior art, the problem of frame line forms angle at turning and is easy network blocking, keeps slurry difficult in lower ink, causes disconnected grid, empty print, keep the surface grid line of solar battery more complete, it compares and the prior art, reduces the series resistance of solar battery, improve the efficiency of solar battery.Invention also provides a kind of production methods of solar battery with above-mentioned beneficial effect.

Description

A kind of solar battery and preparation method thereof
Technical field
The present invention relates to area of solar cell, more particularly to a kind of solar battery and preparation method thereof.
Background technique
With the development of society, more and more people start sight to be put on sustainable energy, in a variety of sustainable energy In source, since solar energy is more stable, no pollution, therefore from invention initial stage just by global attention, and especially by wide The favor of big practitioner, into after 21 century, more and more solar cell power generation technologies are developed, however, existing There are problem, i.e., the frame S broken line undaforms of existing surface grid line to design in printing process for the pattern of the surface grid line of technology, Frame lines cause the series resistance of solar battery entirety to increase, in turn the phenomenon that turning is easy to appear disconnected grid, empty print Decline the efficiency of solar battery.
Summary of the invention
The object of the present invention is to provide a kind of solar batteries and preparation method thereof, to solve printing process in the prior art The frame of middle surface grid line is easy to appear disconnected grid, empty print at turning, and the series resistance of solar battery entirety is caused to increase, into And the problem of declining the efficiency of solar battery.
In order to solve the above technical problems, the present invention provides a kind of solar battery, the solar battery includes surface grid Line;
The frame of the surface grid line is waveform, and any one section of line segment is curved section on the frame.
Optionally, in the solar battery, the range of the distance between two adjacent peaks of the frame is 250 micro- Rice is to 270 microns, including endpoint value.
Optionally, in the solar battery, the range of the width of the frame is 30 microns to 40 microns, including end Point value.
Optionally, in the solar battery, the solar battery includes time main grid, and the secondary main grid is waveform Secondary main grid;Wherein, the range of the distance between two adjacent wave crests of the waveform time main grid is 150 microns to 170 microns, Including endpoint value.
Optionally, in the solar battery, the range of the width of the secondary main grid is 20 microns to 30 microns, including Endpoint value.
Optionally, in the solar battery, the stripe shape of the stripe shape of the frame and the secondary main grid is full The following formula of foot:
Wherein, for x expression stripe shape in the plane along x-axis with a distance from origin, y indicates stripe shape in the plane along y For axis with a distance from origin, A is the amplitude of the stripe shape;Distance of the λ between described two adjacent peaks.
Optionally, in the solar battery, the surface grid line of the solar battery includes main grid, and the main grid is Two long sides are wavy main grid.
Optionally, in the solar battery, in two long sides of the main grid between two adjacent peaks of any bar The range of distance be 125 microns to 135 microns, including endpoint value;The range of the spacing of two long sides of the main grid is 0.65 millimeter to 0.75 millimeter, including endpoint value.
Optionally, in the solar battery, the stripe shape of two long sides of the main grid meets following formula:
Wherein, x indicate stripe shape in the plane along x-axis with a distance from origin, y1Indicate the shape of the first long side flat On face along y-axis with a distance from origin, y2Indicate the shape of the second long side in the plane along y-axis with a distance from origin, A is the side The amplitude of the stripe shape of edge line, λ are the distance between two adjacent peaks of the long side;M is the spacing of two long sides, Also referred to as design wave is wide.
The present invention also provides a kind of sun by the production method of battery, comprising:
In silicon crystal substrate surface, doped layer is set;
By printing surface grid line in the silicon crystal substrate two sides through overdoping without net netting version, the solar-electricity is obtained Pond;Wherein, it is described without net netting version include wavy frame pattern, any one section of line segment is song on the frame pattern Line segment.
Solar battery provided by the present invention, the solar battery include surface grid line;The side of the surface grid line Frame is waveform, and any one section of line segment is curved section on the frame.The present invention is by rolling over frame S in the prior art The design of line undaform is changed to the design of waveform curved section, preferably avoids the intersection point of steel wire, greatly reduces in existing skill When printing in art, frame line keeps slurry difficult in lower ink, disconnected grid, void is caused to print in the easy network blocking of turning formation angle Problem keeps the surface grid line of solar battery more complete, that is, compares and the prior art, reduces the series electrical of solar battery Resistance, improves the efficiency of solar battery.
Detailed description of the invention
It, below will be to embodiment or existing for the clearer technical solution for illustrating the embodiment of the present invention or the prior art Attached drawing needed in technical description is briefly described, it should be apparent that, the accompanying drawings in the following description is only this hair Bright some embodiments for those of ordinary skill in the art without creative efforts, can be with root Other attached drawings are obtained according to these attached drawings.
Fig. 1 is the structural schematic diagram of the frame of surface grid line provided by a kind of specific embodiment of the invention;
Fig. 2 is the structural schematic diagram of the secondary main grid of surface grid line provided by another specific embodiment of the invention;
Fig. 3 is the structural schematic diagram of the main grid of surface grid line provided by another specific embodiment of the invention;
Fig. 4 is the structural representation of surface grid line provided by another specific embodiment of the invention overlooked under visual angle Figure;
Fig. 5 is that the secondary main grid of surface grid line provided by another specific embodiment of the invention and frame lines correspond to Shape image;
Fig. 6 is the corresponding shape image of main grid of surface grid line provided by another specific embodiment of the invention;
Fig. 7 is the process signal of the production method for the solar battery that another specific embodiment of the invention provides Figure.
Specific embodiment
It to avoid ambiguity, need to state in advance, heretofore described secondary main grid, be the anti-electroluminescent of solar battery It tests disconnected grid and shunts grid.
Solar battery technology has attracted the concern of numerous personnel as the pollution-free power-generating technology favored at present, But current solar battery, due to its surface, grid line is easy occur the phenomenon that disconnected grid, empty print in printing, leads to the finished product sun Energy battery surface grid line part is disabled, and electric current cannot pass through, that is, increase the series resistance of battery itself, battery is made to exist Itself consumes more power in real work, influences the efficiency of battery.
The frame of the surface grid line of solar battery in the prior art use S broken line undulated design, i.e., waveform by Straight line is constituted, and is only on the corner connected with camber line, and this design can avoid frame line from forming folder in turning to a certain extent Angle is easy network blocking, but effect need further to be promoted.
In addition, the main grid of the surface grid line of solar battery in the prior art is designed using edge line, due to winding displacement Difficulty, main grid edge are easy to appear the phenomenon that causing main grid to be broken by steel wire detent, due to main grid be broken, make electric current collection by Resistance, the whole series resistance of solar battery obviously rise.
In addition, the secondary main grid of the surface grid line of solar battery in the prior art uses linear design, set using straight line Meter secondary main grid print when, position once appears in the intersection point of the steel wire netting wire, due to steel wire intersection point area coverage compared with Greatly, the case where slurry is stopped by steel wire intersection point when easily occurring in printing, and lower leakage has some setbacks, finally obtained secondary main grid is caused to go out Now break grid, shows the phenomenon that blacking in electroluminescent test, so that electric current collection is obstructed, the whole series electrical of solar battery Resistance is obvious to be risen.
In order to enable those skilled in the art to better understand the solution of the present invention, with reference to the accompanying drawings and detailed description The present invention is described in further detail.Obviously, described embodiments are only a part of the embodiments of the present invention, rather than Whole embodiments.Based on the embodiments of the present invention, those of ordinary skill in the art are not making creative work premise Under every other embodiment obtained, shall fall within the protection scope of the present invention.
Core of the invention is to provide a kind of solar battery, the structural representation of the surface grid line of specific embodiment one Figure is as shown in Figure 1, comprising:
The solar battery includes surface grid line;
The frame 1 of the surface grid line is waveform, and any one section of line segment is curved section on the frame 1.
Above-mentioned solar battery includes monocrystalline silicon battery and polycrystal silicon cell.
It is significant to note that by theory deduction and practice examining, it is best to achieve the effect that, above-mentioned frame 1 Distance range between two adjacent peaks is 250 microns to 270 microns, including endpoint value, such as 250.0 microns, 260.0 microns or Any of 270.0 microns.
Above-mentioned wave crest refers in the shape of frame 1, using an amplitude direction of wave-like as positive direction, in the pros The point all higher than the point of its two sides upwards.
It should be noted that selecting a value in the distance range between above-mentioned adjacent peaks as real to guarantee effect After the use value of border, maximum allowable there are 10 microns of errors, for example, if selecting the distance between above-mentioned 1 adjacent peaks of frame It is 260.0 microns, then the frame line of the surface grid line of this solar battery, the maximum distance between adjacent peaks is no more than 270.0 microns, minimum distance cannot be less than 250.0 microns.
It further notes that, best to achieve the effect that by theory deduction and practice examining, above-mentioned frame 1 Width range be 30 microns to 40 microns, including endpoint value, such as any of 30.0 microns, 35.0 microns or 40.0 microns.
Equally, to guarantee effect, after a selected value is used as actual use value in the width range of above-mentioned frame 1, most The error of big 2 microns of permission, for example, if selecting the width of above-mentioned frame 1 is 35.0 microns, the table of this solar battery The width of the frame line of face grid line, for the widest part no more than 37.0 microns, most narrow place cannot be less than 33.0 microns.
Solar battery provided by the present invention, the solar battery include surface grid line;The side of the surface grid line Frame 1 is waveform, and any one section of line segment is curved section on the frame 1.The present invention is by by frame S in the prior art The design of broken line undaform is changed to the design of waveform curved section, preferably avoids the intersection point of steel wire, greatly reduces existing When printing in technology, frame line forms angle at turning and is easy network blocking, keeps slurry difficult in lower ink, causes disconnected grid, empty print The problem of, keep the surface grid line of solar battery more complete, that is, compare and the prior art, reduces the series electrical of solar battery Resistance, improves the efficiency of solar battery.
On the basis of above-mentioned specific embodiment, further to the secondary main grid 2 of the surface grid line of above-mentioned solar battery It improves, obtains specific embodiment two, the structural schematic diagram of the secondary main grid 2 of surface grid line is as shown in Figure 2, comprising:
The solar battery includes surface grid line;
The frame 1 of the surface grid line is waveform, and any one section of line segment is curved section on the frame 1;
The solar battery includes time main grid 2, and the secondary main grid 2 is waveform time main grid 2.
The difference of present embodiment and above-mentioned specific embodiment is that present embodiment is further to above-mentioned The shape of the secondary main grid 2 of solar battery limits, and other structures are identical as above-mentioned specific embodiment, no longer opens up herein It opens and repeats.
It should be noted that pass through theory deduction and practice examining, and it is best to achieve the effect that, the two of above-mentioned secondary main grid 2 Distance range between a adjacent peaks is 150 microns to 170 microns, including endpoint value, such as 150.0 microns, 160.0 microns or Any of 170.0 microns.
The wave crest of secondary main grid 2 defines the definition for please referring to the wave crest of one frame 1 of specific embodiment, and details are not described herein.
It should be noted that selecting a value in the distance range between above-mentioned adjacent peaks as real to guarantee effect After the use value of border, maximum allowable there are 10 microns of errors, for example, if between above-mentioned secondary 2 adjacent peaks of main grid of selection away from From being 160.0 microns, then 2 shape of secondary main grid of the surface grid line of this solar battery, the maximum distance between adjacent peaks cannot More than 170.0 microns, minimum distance cannot be less than 150.0 microns.
Further, best to achieve the effect that by theory deduction and practice examining, the width of above-mentioned secondary main grid 2 Range is 20 microns to 30 microns, including endpoint value, such as any of 20.0 microns, 25.0 microns or 30.0 microns.
Equally, to guarantee effect, a value is selected in the range of the width of above-mentioned secondary main grid 2 and is used as actual use value Afterwards, maximum allowable 2 microns of error exists, for example, this is too if selecting the width of above-mentioned secondary main grid 2 is 25.0 microns The width maximum of the secondary main grid 2 of the surface grid line of positive energy battery cannot be greater than 27.0 microns, cannot be less than at width minimum 23.0 microns.
Present embodiment uses wavy secondary main grid 2 and designs, and can largely avoid the steel of steel wire Silk intersection point, there is a situation where network blockings to be greatly reduced when so that black under slurry, efficiently solves and a little asks to disconnected grid are shone with what is blacked Topic, is conducive to the collection of electric current, reduces the series resistance of solar battery.
On the basis of above-mentioned specific embodiment, further to the main grid 3 of the surface grid line of above-mentioned solar battery into Row improves, and obtains specific embodiment three, the structural schematic diagram of the main grid 3 of surface grid line is as shown in Figure 3, comprising:
The solar battery includes surface grid line;
The frame 1 of the surface grid line is waveform, and any one section of line segment is curved section on the frame 1;
The solar battery includes time main grid 2, and the secondary main grid 2 is waveform time main grid 2;
The surface grid line of the solar battery includes main grid 3, and the main grid 3 is that two long sides are wavy main grid 3。
The difference of present embodiment and above-mentioned specific embodiment is that present embodiment is further to above-mentioned The shape of the main grid 3 of solar battery limits, and other structures are identical as above-mentioned specific embodiment, not reinflated herein It repeats.
It should be noted that pass through theory deduction and practice examining, and it is best to achieve the effect that, two of above-mentioned main grid 3 The range of distance in long side between two adjacent peaks of any bar is 125 microns to 135 microns, including endpoint value, such as 125.0 Any of micron, 130.0 microns or 135.0 microns.
The definition of the wave crest of any bar please refers to the wave of one frame 1 of specific embodiment in two long sides of above-mentioned main grid 3 The definition at peak, details are not described herein.
It should be noted that selecting a value in the distance range between above-mentioned adjacent peaks as real to guarantee effect After the use value of border, maximum allowable there are 10 microns of errors, for example, if selecting any in two long sides of above-mentioned main grid 3 Distance between the adjacent peaks of item is 135.0 microns, then appoints in two long sides of the main grid 3 of the surface grid line of this solar battery One shape, for the maximum distance between adjacent peaks no more than 145.0 microns, minimum distance cannot be less than 125.0 microns.
It further notes that, best to achieve the effect that by theory deduction and practice examining, above-mentioned main grid 3 The ranges of spacing of two long sides be 0.65 millimeter to 0.75 millimeter, including endpoint value, such as 0.650 millimeter, 0.700 millimeter or Any of 0.750 millimeter.
Equally, to guarantee effect, selecting a value in the spacing range of two long sides of above-mentioned main grid 3 and be used as actually makes After value, maximum allowable 0.03 millimeter of error, for example, if selecting the spacing of two long sides of above-mentioned main grid 3 is 0.700 Millimeter, then the spacing maximum of two long sides of the main grid 3 of the surface grid line of this solar battery cannot be greater than 0.730 millimeter, It minimum place cannot be less than 0.670 millimeter.
Without any connection between the waveform of two long sides of above-mentioned main grid 3, above-mentioned two long side can be asymmetric.
Above-mentioned main grid 3 can be solid construction, can also be part hollow structure, the long side of hollow space is above-mentioned wave Shape.
The straight line of two long sides of the main grid 3 of above-mentioned surface grid line from the prior art is modified to by this specific embodiment Wave, there is a situation where network blockings to be greatly reduced when so that black under slurry in printing process, improve in halftone manufacturing process because Main grid 3 caused by steel wire detent prints crack, improves the final printing quality of surface grid line, reduces solar battery Series resistance.
A kind of top view of the surface grid line for solar battery that present embodiment provides is as shown in Figure 4.
On the basis of above-mentioned specific embodiment, further to the secondary main grid 2 of the surface grid line of above-mentioned solar battery It is improved with frame 1, obtains specific embodiment four, the secondary main grid 2 of surface grid line and the stripe shape schematic diagram of frame 1 As shown in Figure 5, comprising:
The solar battery includes surface grid line;
The frame 1 of the surface grid line is waveform, and any one section of line segment is curved section on the frame 1;
The solar battery includes time main grid 2, and the secondary main grid 2 is waveform time main grid 2;
The surface grid line of the solar battery includes main grid 3, and the main grid 3 is that two long sides are wavy main grid 3
The stripe shape of the stripe shape of the frame 1 and the secondary main grid 2 meets following formula:
Wherein, for x expression stripe shape in the plane along x-axis with a distance from origin, y indicates stripe shape in the plane along y For axis with a distance from origin, A is the amplitude of the stripe shape;Distance of the λ between described two adjacent peaks.
The difference of present embodiment and above-mentioned specific embodiment is that present embodiment is further to above-mentioned The secondary main grid 2 of solar battery and the stripe shape of frame 1 limit, other structures with above-mentioned specific embodiment phase Together, not reinflated herein to repeat.
Two mutually perpendicular directions therefore can be Fig. 5 in the plane for above-mentioned surface grid line for above-mentioned x-axis and y-axis In trigonometric function image regard as overlook visual angle under above-mentioned frame 1 or secondary main grid 2 shape.
Present embodiment uses surface grid line of the wave of trigonometric function shape as above-mentioned solar battery Secondary main grid 2 and frame 1 stripe shape, make finally obtained above-mentioned secondary main grid 2 and frame 1 more evenly, and using this is specific The trigonometric function shape that embodiment provides prints surface grid line, and calculation amount is small, and parameter input is more convenient.
On the basis of above-mentioned specific embodiment, further to the main grid 3 of the surface grid line of above-mentioned solar battery into Row improves, and obtains specific embodiment five, the stripe shape schematic diagram of the main grid 3 of surface grid line is as shown in Figure 6, comprising:
The solar battery includes surface grid line;
The frame 1 of the surface grid line is waveform, and any one section of line segment is curved section on the frame 1;
The solar battery includes time main grid 2, and the secondary main grid 2 is waveform time main grid 2;
The surface grid line of the solar battery includes main grid 3, and the main grid 3 is that two long sides are wavy main grid 3
The stripe shape of the stripe shape of the frame 1 and the secondary main grid 2 meets following formula:
Wherein, for x expression stripe shape in the plane along x-axis with a distance from origin, y indicates stripe shape in the plane along y For axis with a distance from origin, A is the amplitude of the stripe shape;Distance of the λ between described two adjacent peaks;
The stripe shape of two long sides of the main grid 3 meets following formula:
Wherein, x indicate stripe shape in the plane along x-axis with a distance from origin, y1Indicate the shape of the first long side flat On face along y-axis with a distance from origin, y2Indicate the shape of the second long side in the plane along y-axis with a distance from origin, A is the side The amplitude of the stripe shape of edge line, λ are the distance between two adjacent peaks of the long side;M is the spacing of two long sides, Also referred to as design wave is wide.
The difference of present embodiment and above-mentioned specific embodiment is that present embodiment is further to above-mentioned The stripe shape of the main grid 3 of solar battery limits, and other structures are identical as above-mentioned specific embodiment, herein no longer Expansion repeats.
Two mutually perpendicular directions therefore can be Fig. 6 in the plane for above-mentioned surface grid line for above-mentioned x-axis and y-axis In trigonometric function image regard as overlook visual angle under above-mentioned main grid 3 shape, it is significant to note that, in practical application In, the distance M between two long sides of above-mentioned main grid 3 is much larger than the amplitude of above-mentioned long side itself.
Further, the phase of above-mentioned two long sides can be different, are expressed as follows with formula:
Wherein, b indicates the phase difference of the shape of an above-mentioned long side and the shape of another long side.
Present embodiment uses surface grid line of the wave of trigonometric function shape as above-mentioned solar battery Main grid 3 long side stripe shape, make the long side of finally obtained above-mentioned main grid 3 more evenly, and use this specific embodiment party The trigonometric function shape that formula provides prints surface grid line, and calculation amount is small, and parameter input is more convenient.
The present invention also provides a kind of sun by the production method of battery, referred to as specific embodiment six, steps flow chart Figure as shown in fig. 7, comprises:
Step S101: doped layer is set in silicon crystal substrate surface;
Step S102: by printing surface grid line in the silicon crystal substrate two sides through overdoping without net netting version, institute is obtained State solar battery;Wherein, it is described without net netting version include wavy frame pattern, any one section on the frame pattern Line segment is curved section.
It is above-mentioned without net netting version include 380 mesh, 400 mesh, 430 mesh, 480 mesh and more high mesh number screen cloth, it is above-mentioned without net tie The mesh design requirement of halftone is controlled in 1 lattice to 3 grid mesh.
The present embodiment is suitable for 101 lines, 106 lines, 110 lines, 112 lines and more close grid designs.
Since the surface grid line of above-mentioned solar battery is by above-mentioned without the obtained surface grid line of net netting version printing, because This frame 1 of surface grid line obtained by the above-mentioned frame pattern without in net netting version, any one section of line segment is on frame 1 Curved section.
Further, above-mentioned without net netting version may include waveform time main grid pattern.
Further, above-mentioned without net netting version may include two long sides is wavy main grid pattern.
Further, the stripe shape of above-mentioned frame pattern and above-mentioned waveform time main grid pattern meets following formula:
Wherein, for x expression stripe shape in the plane along x-axis with a distance from origin, y indicates stripe shape in the plane along y For axis with a distance from origin, A is the amplitude of the stripe shape;Distance of the λ between described two adjacent peaks.
Further, above-mentioned two long sides are that two long side stripe shapes satisfaction of wavy main grid pattern is as follows Formula:
Wherein, x indicate stripe shape in the plane along x-axis with a distance from origin, y1Indicate the shape of the first long side flat On face along y-axis with a distance from origin, y2Indicate the shape of the second long side in the plane along y-axis with a distance from origin, A is the side The amplitude of the stripe shape of edge line, λ are the distance between two adjacent peaks of the long side;M is the spacing of two long sides, Also referred to as design wave is wide.
Before the design parameter of above-mentioned each pattern can refer in specific embodiment corresponding construction data, it is no longer superfluous herein It states.
The production method of solar battery provided by the present invention, by the way that doped layer is arranged in silicon crystal substrate surface;It is logical It crosses and prints surface grid line in the silicon crystal substrate two sides through overdoping without net netting version, obtain the solar battery;Wherein, institute Stating without net netting version includes wavy frame pattern, and any one section of line segment is curved section on the frame pattern.This hair It is bright to be designed by the way that frame S broken line undaform in the prior art design is changed to waveform curved section, preferably avoid steel wire The intersection point of net greatly reduces when printing in the prior art, and frame line forms angle at turning and is easy network blocking, and slurry is made to exist It is difficult when lower ink, disconnected grid, empty the problem of printing are caused, keeps the surface grid line of finally obtained solar battery more complete, that is, compares With the prior art, the series resistance of solar battery is reduced, improves the efficiency of solar battery.
Each embodiment in this specification is described in a progressive manner, the highlights of each of the examples are with it is other The difference of embodiment, same or similar part may refer to each other between each embodiment.For being filled disclosed in embodiment For setting, since it is corresponded to the methods disclosed in the examples, so being described relatively simple, related place is referring to method part Explanation.
Solar battery provided by the present invention and preparation method thereof is described in detail above.It is used herein A specific example illustrates the principle and implementation of the invention, and the above embodiments are only used to help understand originally The method and its core concept of invention.It should be pointed out that for those skilled in the art, not departing from this hair , can be with several improvements and modifications are made to the present invention under the premise of bright principle, these improvement and modification also fall into power of the present invention In the protection scope that benefit requires.

Claims (10)

1. a kind of solar battery, which is characterized in that the solar battery includes surface grid line;
The frame of the surface grid line is waveform, and any one section of line segment is curved section on the frame.
2. solar battery as described in claim 1, which is characterized in that distance between two adjacent peaks of the frame Range is 250 microns to 270 microns, including endpoint value.
3. solar battery as claimed in claim 2, which is characterized in that the range of the width of the frame is 30 microns to 40 Micron, including endpoint value.
4. solar battery as described in claim 1, which is characterized in that the solar battery includes time main grid, described secondary Main grid is waveform time main grid;Wherein, the range of the distance between two adjacent wave crests of the waveform time main grid is 150 micro- Rice is to 170 microns, including endpoint value.
5. solar battery as claimed in claim 4, which is characterized in that the range of the width of the secondary main grid be 20 microns extremely 30 microns, including endpoint value.
6. such as solar battery described in any one of claim 1 to 5, which is characterized in that the stripe shape of the frame and institute The stripe shape for stating time main grid meets following formula:
Wherein, x indicate stripe shape in the plane along x-axis with a distance from origin, y indicate stripe shape in the plane along y-axis from The distance of origin, A are the amplitude of the stripe shape;Distance of the λ between described two adjacent peaks.
7. solar battery as described in claim 1, which is characterized in that the surface grid line of the solar battery includes master Grid, the main grid are that two long sides are wavy main grid.
8. solar battery as claimed in claim 7, which is characterized in that two of any bar in two long sides of the main grid The range of distance between adjacent peaks is 125 microns to 135 microns, including endpoint value;The spacing of two long sides of the main grid Range be 0.65 millimeter to 0.75 millimeter, including endpoint value.
9. solar battery as claimed in claim 8, which is characterized in that the stripe shape of two long sides of the main grid meets Following formula:
Wherein, x indicate stripe shape in the plane along x-axis with a distance from origin, y1Indicate the shape of the first long side edge in the plane Y-axis is with a distance from origin, y2Indicate the shape of the second long side in the plane along y-axis with a distance from origin, A is the edge line The amplitude of stripe shape, λ are the distance between two adjacent peaks of the long side;M is the spacing of two long sides, is also referred to as set It is wide to count wave.
10. a kind of sun is by the production method of battery characterized by comprising
In silicon crystal substrate surface, doped layer is set;
By printing surface grid line in the silicon crystal substrate two sides through overdoping without net netting version, the solar battery is obtained; Wherein, it is described without net netting version include wavy frame pattern, any one section of line segment is curve on the frame pattern Section.
CN201811167604.XA 2018-10-08 2018-10-08 A kind of solar battery and preparation method thereof Pending CN109545862A (en)

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EP4099403A4 (en) * 2020-12-30 2024-03-13 Tongwei Solar Chengdu Co Ltd Solar cell and front electrode thereof, and manufacturing method

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CN206357786U (en) * 2017-01-05 2017-07-28 常州三立精图光电有限公司 Without net netting version wire casing structure and its obtained cell piece
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