CN109540730A - A kind of unattended environment-friendly type insolubles content measurement device and method - Google Patents
A kind of unattended environment-friendly type insolubles content measurement device and method Download PDFInfo
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- 238000010438 heat treatment Methods 0.000 claims abstract description 42
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Abstract
The invention discloses a kind of unattended environment-friendly type insolubles content measurement device and methods, include: automatic measuring and controlling system (1), the second power device (9) for being arranged from top to bottom, condenser (10), extracting barrel (13), heating kettle, heater (16), the first power device (8) being arranged over or around second power device (9)；It further include sequentially connected vacuum plant (2), waste liquid barrel (5), returnable bottle (18), the second reagent delivery device (17)；And sequentially connected reagent bottle (6), the first reagent delivery device (7)；First dose of conveying device (7), the second reagent delivery device (17) are connect with condenser (10).The present invention solves the deficiency of insoluble object measuring device traditional in industry, realizes protection Health Status For Workers Exposed, reduces reagent consumption, realizes organized discharge.
Description
Technical field
The invention belongs to a kind of measurement device and methods, survey more particularly to a kind of unattended environment-friendly type insolubles content
Determine device and method.
Background technique
In industries such as petroleum, pitch, coal tar, many specific insolubles contents or component need anti-using corresponding reagent
Multiple extraction and determination or acquisition.The sucking of part test reagent or contact have human body to be measured compared with major injury, such as toluene insolubles；It is special
It is not carbon resistance rod binder pitch, the index is particularly important, it is necessary to carry out mass detection.
It is defined according to WHO, volatile organic compounds (VOC) refers under normal pressure, and 50 DEG C -260 DEG C of boiling point various have
Machine compound.VOC press its chemical structure, can be further divided into: alkanes, aromatic hydrocarbons, esters, aldehydes and other etc..At present
What is identified has more than 300 kinds.It is most common to have benzene,toluene,xylene, normal heptane etc..The process of VOCs overall process solution
It include: VOCs disposal of pollutants link investigation, VOCs monitoring system and total amount estimation, the establishment of overall process VOCs resolution, production
Technique source control measure customize end VOCs Treatment process scheme, regulation effect assessment and emission reduction assessment.Wherein, dirty
Dye link investigation and overall process combing control are the key that industrial enterprise VOCs regulations.Equipment leakage, Waste are arranged by scene
The pollution sections such as gas, uncontrollable discharge, wastewater collection check pollution section one by one, carry out full mistake of the VOCs from source to end
Journey combs work, and whole process controls VOCs pollution.
The carcinogenic substance inventory edit ginseng that toluene (easily system poison -3), international cancer research institution, the World Health Organization announce
It examines, toluene is in 3 class carcinogenic substance inventories.Most laboratory toluene insolubles measurement at this stage still uses traditional-handwork equipment,
Operating personnel's contact reagent is frequent, and physical impairment is big；Reagent is formed a large amount of toxic useless using can not just reuse after primary
Liquid increases capital investment；Most laboratory disposes waste liquid without related qualification and ability, therefore produces a large amount of non-tissue discharges, right
Environment is caused compared with havoc.
As every profession and trade rises pitch, coal tar etc. using lasting, to material, there has also been more strict requirements, in turn
Detection frequency is significantly increased.At present without corresponding environment-friendly type device in industry, traditional-handwork equipment, operation are still used using unit
Personnel health's damage is big, and reagent consumption is big, and non-tissue, which discharges, leads to that environmental pollution is serious, cannot achieve VOCS overall process solution party
Case；Since reagent is toxic, the degree of automation is low, Partial Jobs personnel have stronger resentment, cause test accuracy poor.Therefore
There is an urgent need to a kind of unattended environment-friendly type insolubles content measurement device and methods.
Chinese Government proposes " made in China 2025 " within 2015 simultaneously, and information technology and manufacturing technology depth are melted
It closes, with the arrival of the construction upsurge of industry internet, sensing equipment is not only to complete the function of DATA REASONING, with greater need for information
Change, it is intelligent.
Current unattended environment-friendly type toluene insolubles content testing device and method at home and abroad also without Engineering Projects or
The problem of mature experience or technology can be applied directly, still category blank, be current precision equipment and intelligence manufacture urgent need to resolve.
Summary of the invention
Aiming at the shortcomings of the prior art, the present invention provides a kind of unattended environment-friendly type insoluble matter measurement dress
It sets.It solves still to use traditional-handwork equipment, operating personnel using unit without corresponding automation environment-friendly type device in current industry
Health cost is big, and reagent consumption is big, and non-tissue, which discharges, leads to that environmental pollution is serious, and emission can not carry out automatic and accurate monitoring；
Larger to operator's health damage since reagent is toxic, the degree of automation is low, data precision is low.
The present invention is achieved by the following technical solutions.
A kind of unattended environment-friendly type insolubles content measurement device characterized by comprising automatic measuring and controlling system (1),
The second power device (9) for being arranged from top to bottom, condenser (10), extracting barrel (13), heating kettle, heater (16), setting exist
The first power device (8) over or around second power device (9)；
It further include sequentially connected vacuum plant (2), waste liquid barrel (5), returnable bottle (18), the second reagent delivery device
(17)；
And sequentially connected reagent bottle (6), the first reagent delivery device (7)；
First dose of conveying device (7), the second reagent delivery device (17) are connect with condenser (10)；The heating
Pot connect with waste liquid barrel (5), between equipped with second solenoid valve (20), for control between heating kettle and waste liquid barrel channel opening or
It closes；The automatic measuring and controlling system (1) is used for control, the data processing of whole device.
Further, the extracting barrel (13) includes the upper shell being isolated and lower shell and side wall pipeline, siphon
Pipe, upper shell and lower shell are connected to by being located at the side wall pipeline of side, and side wall of the upper shell close to bottom is provided with siphon
Pipe, the siphon pipe lower end are located above heating kettle.
Further, agitating shaft (11) are equipped with inside the condenser.
Further, the first solenoid valve (19) are equipped between the waste liquid barrel (5) and returnable bottle (18), for controlling back
Channel between bottle (18) and waste liquid barrel (5) is received to open or close.
Further, the heating kettle includes interior heating kettle (14) and additional hot pot (15), interior heating kettle (14) peace
Loaded in additional hot pot (15), for holding remaining soluble matter after reagent and reagent recycling.
Further, the additional hot pot (15), for the thermal energy of heater (16) to be transferred to interior heating kettle (14),
Heat reagent；The additional hot pot (15) is set to below extracting barrel (13), is tightly connected with extracting barrel (13), and pass through pipeline
It is connect with waste liquid barrel (5).
Further, it is equipped with groove below the condenser (10), solvent can be kept in, the condenser (10) is used for will
It has instilled after Evaporation of reagent gas cooling and again in filter cylinder (12) or by the second reagent delivery device (17) by reclaim reagent
It is delivered in returnable bottle (18).
Further, it is provided with recovery tube in the sidewall locations in the upper shell of the extracting barrel (13) close to bottom, returned
The other end of closed tube is connected with the second reagent delivery device (17).
Further, liquid level sensor (4) are provided in the waste liquid barrel (5), for measuring waste liquid barrel (15) interior liquid
Amount.
Further, reagent delivery device is peristaltic pump or motor.
Further, first power device (8) drives the second power device (9) and condenser (10) combination to move
It is dynamic.
It further, further include third power device, first power device (8) drives condenser (10) mobile, the
Two power devices move under the drive of third power device.
Further, second power device (9) drives agitating shaft (11) rotary motion.
Further, the returnable bottle (18) measures reclaim reagent for storing, it includes: returnable bottle main body passes
Sensor, bottle cap.
A kind of insolubles content measuring method, which comprises the following steps:
A) automatic measuring and controlling system (1) detection station state, the output order of Selection experiment classification；
B) the first power device (8) acts, and the second power device (9) and condenser (10) combination is driven to rise；
C) filter cylinder (12) containing sample is put into extracting barrel (13), the first power device drives the second power device and cold
Condenser combination decline；
D) reagent in returnable bottle (18) is delivered in extracting barrel (13) by the second reagent delivery device (17), and reagent is not
When sufficient, the reagent in reagent bottle (6) is delivered in extracting barrel (13) by the first reagent delivery device (7)；Second power device (9)
It chooses whether to start according to test type or setting；
E) heater heats reagent, and chemical vapor rises, and condenser (10) work enters condenser ditch after liquid condensation
Slot, overflow enters in filter cylinder (12) after trench fill is full, forms siphon when liquid level exceeds extracting barrel (13) siphon pipe, the step
Rapid reciprocation cycle, is dissolved by setting time or number；
F) heater stops working, and takes out filter cylinder (12), automatic measuring and controlling system (1) described in drying weighing and typing；
G) heater restarts, and steam rises, and enters condenser groove, the second reagent delivery device after gas condensation
(17) condensed fluid is delivered in returnable bottle (18).
Further, the heating kettle includes interior heating kettle and additional hot pot, and wherein step f) is specifically, heater stops
Extracting barrel (13) interior residual solvents are pumped to interior heating kettle, then taken out by work, solenoid valve (20) opening, vacuum plant (2)
Filter cylinder (12).
Further, the measuring method, which is replaced by, first carries out step g), then executes step f).
Advantageous effects of the invention,
The present invention solves the deficiency of insoluble object measuring device traditional in industry, realizes protection Health Status For Workers Exposed,
Reagent consumption is reduced, organized discharge is realized, improves test accuracy, is solved the problems, such as " data silo ", is built
Big data platform support, creates data value, the System and statistics of data, output report and prompt is realized, by finger
The judgement processing for marking data, generates directive significance to actual production.
Detailed description of the invention
Fig. 1: unattended environment-friendly type insolubles content measurement device schematic structural diagram of the first embodiment of the invention；
Fig. 2: unattended environment-friendly type insolubles content measurement device schematic structural diagram of the second embodiment of the invention.
Attached drawing mark: 1, automatic measuring and controlling system；2, vacuum plant；3, pipeline；4, liquid level sensor；5, waste liquid barrel；6, it tries
Agent bottle；7, the first reagent delivery device；8, the first power device；9, the second power device；10, condenser；11, agitating shaft；12,
Filter cylinder；13, extracting barrel；14, interior heating kettle；15, additional hot pot；16, heater；17, the second reagent delivery device；18, it recycles
Bottle；19, the first solenoid valve；20, second solenoid valve.
Specific embodiment
The following describes the present invention in detail with reference to the accompanying drawings and specific embodiments.
Embodiment 1
A kind of unattended environment-friendly type insolubles content measurement device, comprising: automatic measuring and controlling system 1 is arranged from top to bottom
The first power device 8, the second power device 9, condenser 10, extracting barrel 13, heating kettle, heater 16, the extracting barrel 13
Place filter cylinder 12 in inside；
It further include sequentially connected vacuum plant 2, waste liquid barrel 5, returnable bottle 18, the second reagent delivery device 17；
And sequentially connected reagent bottle 6, the first reagent delivery device 7；
First dose of conveying device 7, the second reagent delivery device 17 are connect with condenser 10；The heating kettle and useless
Liquid bucket 5 connect, between be equipped with second solenoid valve 20, opened or closed for controlling channel between heating kettle and waste liquid barrel；It is described
Automatic measuring and controlling system 1 is used for control, the data processing of whole device.
Automatic measuring and controlling system 1 is logic control of the invention, receives the control instruction and the various sensings of acquisition of whole system
Device signal, determination data, data processing and the control output of each power device, each power device can be pneumatic, electric
Dynamic, hydraulic etc., but not limited to this；Each combination power plant direction can be level, vertically, rotation, but not limited to this；
The vacuum plant 2 can be vacuum pump, venturi, vacuum generator etc. for providing a system to required negative pressure power,
But not limited to this；The waste liquid barrel 5 is collected the waste liquid of test generation for automatic gauge and is sealed；The reagent bottle
6, the standard reagent that test uses is provided；The extracting barrel 13 is installed on 10 lower section of condenser, takes out needed for reacting as test
Device is mentioned, is formed and extracts siphon dissolved samples repeatedly；The heater 16 is installed on additional 15 lower section of hot pot or surrounding, is used for
Thermal energy needed for heating reagent is provided；The present invention can be used for toluene insolubles assay, but be not limited to toluene insolubles content
Measurement.
Further, the extracting barrel 13 includes the upper shell and lower shell that are isolated and side wall pipeline, siphon pipe,
Upper shell is connected to lower shell by being located at the side wall pipeline of side, and side wall of the upper shell close to bottom is provided with siphon pipe,
The siphon pipe lower end is located above heating kettle.
Further, agitating shaft 11 is equipped with inside the condenser.
Further, the first solenoid valve 19 is equipped between the waste liquid barrel 5 and returnable bottle 18, for controlling returnable bottle 18
Channel opens or closes between waste liquid barrel 5.
Further, the heating kettle includes interior heating kettle 14 and additional hot pot 15, and the interior heating kettle 14 is installed on outer
In heating kettle 15, for holding remaining soluble matter after reagent and reagent recycling.
Further, the additional hot pot 15 is heated for the thermal energy of heater 16 to be transferred to interior heating kettle 14
Reagent；The additional hot pot 15 is set to 13 lower section of extracting barrel, is tightly connected with extracting barrel 13, and pass through pipeline and waste liquid barrel 5
Connection, between be equipped with second solenoid valve 20, opened or closed for controlling channel between heating kettle and waste liquid barrel；
Further, it being equipped with groove below the condenser 10, solvent capable of being kept in, the condenser 10 is for will evaporate
After reagent gas is cooling and instills in filter cylinder 12 again or reclaim reagent is delivered to by recycling by the second reagent delivery device 17
In bottle 18.
Further, it is provided with liquid level sensor 4 in the waste liquid barrel 5, for measuring amount of liquid in waste liquid barrel 15.
Further, reagent delivery device is peristaltic pump or motor.
Further, first power device 8 drives the second power device 9 and the combination movement of condenser 10.
Further, second power device 9 drives 11 rotary motion of agitating shaft.
Further, the returnable bottle 18 measures reclaim reagent for storing, it includes: returnable bottle main body, sensing
Device, bottle cap.
First power device 8 is installed on the top of the second power device 9, for driving the second power device 9 and cold
The assemblys such as condenser 10 are moved up and down or are moved forward and backward or the mode of moving in rotation etc..
After the present apparatus is powered, each section mechanism starts co-ordination.1 detection station state of automatic measuring and controlling system, confirmation are each
System is in normal Standby station；Starting starts；Automatic measuring and controlling system 1 is exported according to Selection experiment classification and is ordered；First power
Device 8 acts, and the combinations such as the second power device 9 and condenser 10 is driven to rise；Operating personnel is manually by the filter cylinder containing sample
12 are put into extractor 13；The movement of first power device 8 drives the combinations decline such as the second power device 9 and condenser 10；Second
Reagent in returnable bottle 18 is delivered in extracting barrel 13 by reagent delivery device 17, when reagent deficiency, the first reagent delivery device
7 are delivered to the reagent in reagent bottle 6 in extracting barrel 13；Second power device 9 chooses whether to open according to test type or setting
It is dynamic, if starting will drive 11 stirred sample of agitating shaft；Heater 16 works, and heats reagent；Chemical vapor rises；10 work of condenser
Make, condenser groove is entered after liquid condensation, overflow enters in filter cylinder 12 after trench fill is full, when liquid level exceeds 13 rainbow of extracting barrel
Siphon is formed when suction pipe, which is dissolved by setting time or number；Solenoid valve 19 is closed；Vacuum plant 2
Residual solvents in extracting barrel 13 are pumped to interior heating kettle 14 by work, solenoid valve 20, and filter cylinder 12 carries out prebake；Heater 16
It stops working, temperature is reduced to set temperature, program alarm, device prompts sampling；Taking-up filter cylinder 12 is put into baking oven and wants by standard
Ask drying；Heater restarting, steam rise, and enter condenser groove, the second reagent delivery device (17) after gas condensation
Condensed fluid is delivered in returnable bottle (18)；Quality is weighed after being cooled to room temperature from taking-up filter cylinder in baking oven and typing is surveyed automatically
Control system；Automatic measuring and controlling system is calculated according to the collected data, is counted, is analyzed and exported as a result, insolubles content measures
Complete and by amount of reagent, waste liquid quantum of output, collected the data such as waste liquid amount and be uploaded to specified host computer, realize closed loop prison
Control；This description is illustrated to conventional detection process, is not the restriction to the present apparatus, all equivalent streams for the present apparatus
The variation of journey or sub-process, if this method is using first sampling, the mode conversion of recycling reagent is first reclaim reagent, then is sampled
Mode is all within the scope of the present invention.
The following describes the present invention in detail with reference to the accompanying drawings and specific embodiments.
A kind of unattended environment-friendly type insolubles content measurement device, comprising: automatic measuring and controlling system 1 is arranged from top to bottom
The first power device 8, the second power device 9, condenser 10, extracting barrel 13, heating kettle, heater 16, the extracting barrel 13
Place filter cylinder 12 in inside；
It further include sequentially connected vacuum plant 2, waste liquid barrel 5, returnable bottle 18, the second reagent delivery device 17；
And sequentially connected reagent bottle 6, the first reagent delivery device 7；
First dose of conveying device 7, the second reagent delivery device 17 are connect with condenser 10；The heating kettle and useless
Liquid bucket 5 connect, between be equipped with second solenoid valve 20, opened or closed for controlling channel between heating kettle and waste liquid barrel；It is described
Automatic measuring and controlling system 1 is used for control, the data processing of whole device.
Automatic measuring and controlling system 1 is logic control of the invention, receives the control instruction and the various sensings of acquisition of whole system
Device signal, determination data, data processing and the control output of each power device, each power device can be pneumatic, electric
Dynamic, hydraulic etc., but not limited to this；Each combination power plant direction can be level, vertically, rotation, but not limited to this；
The vacuum plant 2 can be vacuum pump, venturi, vacuum generator etc. for providing a system to required negative pressure power,
But not limited to this；The waste liquid barrel 5 is collected the waste liquid of test generation for automatic gauge and is sealed；The reagent bottle
6, the standard reagent that test uses is provided；The extracting barrel 13 is installed on 10 lower section of condenser, takes out needed for reacting as test
Device is mentioned, is formed and extracts siphon dissolved samples repeatedly；The heater 16 is installed on additional 15 lower section of hot pot or surrounding, is used for
Thermal energy needed for heating reagent is provided；The present invention can be used for toluene insolubles assay, but be not limited to toluene insolubles content
Measurement.
Embodiment 2
Not having groove below the condenser 10, the extracting barrel 13 includes the upper shell and lower shell being isolated, with
And side wall pipeline, siphon pipe, recycling pipe fitting, upper shell is connected to lower shell by being located at the side wall pipeline of side, in upper cylinder
Side wall of the body close to bottom is provided with siphon pipe and recycling pipe fitting, and the siphon pipe lower end is located above heating kettle, described
Recycling pipe fitting is connect by pipeline with the first conveying device 7 and the second conveying device 17.
After the present apparatus is powered, each section mechanism starts co-ordination.1 detection station state of automatic measuring and controlling system, confirmation are each
System is in normal Standby station；Starting starts；Automatic measuring and controlling system 1 is exported according to Selection experiment classification and is ordered；First power
Device 8 acts, and the combinations such as the second power device 9 and condenser 10 is driven to rise；Operating personnel is manually by the filter cylinder containing sample
12 are put into extractor 13；The movement of first power device 8 drives the combinations decline such as the second power device 9 and condenser 10；Second
Reagent in returnable bottle 18 is delivered in extracting barrel 13 by reagent delivery device 17, when reagent deficiency, the first reagent delivery device
7 are delivered to the reagent in reagent bottle 6 in extracting barrel 13；Second power device 9 chooses whether to open according to test type or setting
It is dynamic, if starting will drive 11 stirred sample of agitating shaft；Heater 16 works, and heats reagent；Chemical vapor rises；10 work of condenser
Make, enters in filter cylinder 12 after liquid condensation, form siphon when liquid level exceeds 13 siphon pipe of extracting barrel, the step reciprocation cycle,
It is dissolved by setting time or number；Solenoid valve 19 is closed；Vacuum plant 2 works, and solenoid valve 20 will be remaining in extracting barrel 13
Solvent is pumped to interior heating kettle 14, and filter cylinder 12 carries out prebake；Heater 16 stops working, and temperature is reduced to set temperature, journey
Sequence alarm, device prompts sampling；Taking-up filter cylinder 12 is put into baking oven is dried by standard requirements；Heater restarting, steam rise,
Enter extracting barrel 13 after gas condensation, condensed fluid is delivered in returnable bottle 18, this mistake by the starting of the second reagent delivery device 17
The 13 inner condensat liquid scale of construction of journey extracting barrel will be unable to reach siphon height, complete reagent recycling；Filter cylinder is taken out from baking oven to be cooled to
Quality and typing automatic measuring and controlling system are weighed after room temperature；Automatic measuring and controlling system is calculated according to the collected data, is counted, is analyzed
And export as a result, insolubles content measurement complete and by amount of reagent, waste liquid quantum of output, collected the data such as waste liquid amount upload
To specified host computer, closed loop monitoring is realized；This description is illustrated to conventional detection process, is not the limit to the present apparatus
Fixed, the variation of all equivalent process or sub-process for the present apparatus first samples, the mode of recycling reagent as this method uses
The modes such as it is transformed to first reclaim reagent, then is sampled, is all within the scope of the present invention.
Claims (17)
1. a kind of unattended environment-friendly type insolubles content measurement device characterized by comprising automatic measuring and controlling system (1), from
The second power device (9) of top to bottm setting, condenser (10), extracting barrel (13), heating kettle, heater (16), are arranged in institute
State the first power device (8) over or around the second power device (9)；
It further include sequentially connected vacuum plant (2), waste liquid barrel (5), returnable bottle (18), the second reagent delivery device (17)；
And sequentially connected reagent bottle (6), the first reagent delivery device (7)；
First dose of conveying device (7), the second reagent delivery device (17) are connect with condenser (10)；The heating kettle with
Waste liquid barrel (5) connection, between be equipped with second solenoid valve (20), play on or off for controlling channel between heating kettle and waste liquid barrel
It closes；The automatic measuring and controlling system (1) is used for control, the data processing of whole device.
2. measurement device according to claim 1, which is characterized in that the extracting barrel (13) includes the upper shell being isolated
And lower shell and side wall pipeline, siphon pipe, upper shell is connected to lower shell by being located at the side wall pipeline of side, in upper cylinder
Side wall of the body close to bottom is provided with siphon pipe, and the siphon pipe lower end is located above heating kettle.
3. measurement device according to claim 2, which is characterized in that be equipped with agitating shaft (11) inside the condenser.
4. measurement device according to claim 1 or 2, which is characterized in that the waste liquid barrel (5) and returnable bottle (18) it
Between be equipped with the first solenoid valve (19), opened or closed for controlling channel between returnable bottle (18) and waste liquid barrel (5).
5. measurement device according to claim 1 or 2, which is characterized in that the heating kettle include interior heating kettle (14) and
Additional hot pot (15), the interior heating kettle (14) are installed in additional hot pot (15), residual after reagent and reagent recycling for holding
The soluble matter deposited.
6. measurement device according to claim 5, which is characterized in that the additional hot pot (15) is used for heater
(16) thermal energy is transferred to interior heating kettle (14), heats reagent；The additional hot pot (15) is set to below extracting barrel (13), with
Extracting barrel (13) is tightly connected, and is connect by pipeline with waste liquid barrel (5).
7. measurement device according to claim 6, which is characterized in that groove is equipped with below the condenser (10), it can be temporarily
Solvent is deposited, the condenser (10) is used to that second will to be instilled in filter cylinder (12) or passed through after Evaporation of reagent gas cooling and again
Reclaim reagent is delivered in returnable bottle (18) by reagent delivery device (17).
8. measurement device according to claim 6, which is characterized in that the extracting barrel (13) upper shell close to bottom
Side wall be provided with siphon pipe and recycling pipe fitting, the recycling pipe fitting pass through pipeline and the first conveying device 7 and second
Conveying device 17 connects.
9. measurement device according to claim 1, which is characterized in that be provided with liquid level sensor in the waste liquid barrel (5)
(4), for measuring waste liquid barrel (15) interior amount of liquid.
10. measurement device according to claim 1, which is characterized in that reagent delivery device is peristaltic pump or motor.
11. measurement device according to claim 1 or 2, which is characterized in that first power device (8) drives the
Two power devices (9) and condenser (10) combination movement.
12. measurement device according to claim 1 or 2, which is characterized in that it further include third power device, described first
Power device (8) drives condenser (10) mobile, and the second power device moves under the drive of third power device.
13. measurement device according to claim 2, which is characterized in that second power device (9) drives agitating shaft
(11) rotary motion.
14. measurement device according to claim 1, which is characterized in that the returnable bottle (18) is for having stored metering
Reclaim reagent, it includes: returnable bottle main body, sensor, bottle cap.
15. a kind of insolubles content measuring method of any one of -14 measurement devices according to claim 1, which is characterized in that
The following steps are included:
A) automatic measuring and controlling system (1) detection station state, the output order of Selection experiment classification；
B) the first power device (8) acts, and the second power device (9) and condenser (10) combination is driven to rise；
C) filter cylinder (12) containing sample is put into extracting barrel (13), the first power device drives the second power device and condenser
Combination decline；
D) reagent in returnable bottle (18) is delivered in extracting barrel (13) by the second reagent delivery device (17), when reagent deficiency,
Reagent in reagent bottle (6) is delivered in extracting barrel (13) by the first reagent delivery device (7)；Second power device (9) basis
Test type or setting choose whether to start；
E) heater heats reagent, and chemical vapor rises, and condenser (10) work enters condenser groove, ditch after liquid condensation
Overflow enters in filter cylinder (12) after slot filling is full, forms siphon when liquid level exceeds extracting barrel (13) siphon pipe, the step is reciprocal
Circulation, is dissolved by setting time or number；
F) heater stops working, and takes out filter cylinder (12), automatic measuring and controlling system (1) described in drying weighing and typing；
G) heater restarts, and steam rises, and condenser groove is entered after gas condensation, and the second reagent delivery device (17) will
Condensed fluid is delivered in returnable bottle (18).
16. insolubles content measuring method according to claim 15, which is characterized in that the heating kettle includes interior heating
Pot and additional hot pot, wherein step f) is specifically, heater stops working, and solenoid valve (20) is opened, vacuum plant (2) will extract
Cylinder (13) interior residual solvents are pumped to interior heating kettle, then take out filter cylinder (12).
17. insolubles content measuring method according to claim 16, which is characterized in that the measuring method is replaced by elder generation
Step g) is executed, then executes step f).
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| CN201811556824.1A CN109540730B (en) | 2018-12-19 | 2018-12-19 | Unmanned environment-friendly insoluble content measuring device and method |
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| CN201811556824.1A CN109540730B (en) | 2018-12-19 | 2018-12-19 | Unmanned environment-friendly insoluble content measuring device and method |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112485151A (en) * | 2020-11-10 | 2021-03-12 | 广西电网有限责任公司桂林供电局 | Automatic determination method for oil sludge precipitation of electric insulating oil |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH415118A (en) * | 1963-10-10 | 1966-06-15 | Frings Heinrich | Method and device for the quantitative determination of a component of a liquid mixture |
| JPH0921798A (en) * | 1995-05-02 | 1997-01-21 | Kaneda Kk | Asphalt extraction device and asphalt extraction test method |
| KR20020011041A (en) * | 2000-07-31 | 2002-02-07 | 박경렬 | A method and equipment for regeneration and separate recovery of waste water, waste absorbent, waste absorbent oil and waste organic solvent etc. which have been involved odor and VOCs. |
| CN103792342A (en) * | 2014-02-27 | 2014-05-14 | 北京英斯派克科技有限公司 | Toluene insoluble substance measuring device |
| CN103823023A (en) * | 2014-02-27 | 2014-05-28 | 北京英斯派克科技有限公司 | Apparatus for determining insoluble substance |
| CN103837423A (en) * | 2014-03-24 | 2014-06-04 | 北京英斯派克科技有限公司 | Device for simultaneously measuring plurality of types of insoluble substances |
| CN209640139U (en) * | 2018-12-19 | 2019-11-15 | 北京英斯派克科技有限公司 | A kind of unattended environment-friendly type insolubles content measurement device |
-
2018
- 2018-12-19 CN CN201811556824.1A patent/CN109540730B/en active Active
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CH415118A (en) * | 1963-10-10 | 1966-06-15 | Frings Heinrich | Method and device for the quantitative determination of a component of a liquid mixture |
| JPH0921798A (en) * | 1995-05-02 | 1997-01-21 | Kaneda Kk | Asphalt extraction device and asphalt extraction test method |
| KR20020011041A (en) * | 2000-07-31 | 2002-02-07 | 박경렬 | A method and equipment for regeneration and separate recovery of waste water, waste absorbent, waste absorbent oil and waste organic solvent etc. which have been involved odor and VOCs. |
| CN103792342A (en) * | 2014-02-27 | 2014-05-14 | 北京英斯派克科技有限公司 | Toluene insoluble substance measuring device |
| CN103823023A (en) * | 2014-02-27 | 2014-05-28 | 北京英斯派克科技有限公司 | Apparatus for determining insoluble substance |
| CN103837423A (en) * | 2014-03-24 | 2014-06-04 | 北京英斯派克科技有限公司 | Device for simultaneously measuring plurality of types of insoluble substances |
| CN209640139U (en) * | 2018-12-19 | 2019-11-15 | 北京英斯派克科技有限公司 | A kind of unattended environment-friendly type insolubles content measurement device |
Non-Patent Citations (1)
| Title |
|---|
| 戴红;徐歌德;刘丹;张宗才;: "皮革中二氯甲烷萃取物含量测定抽提装置的改进", 皮革科学与工程, no. 06, 28 December 2016 (2016-12-28) * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112485151A (en) * | 2020-11-10 | 2021-03-12 | 广西电网有限责任公司桂林供电局 | Automatic determination method for oil sludge precipitation of electric insulating oil |
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| CN109540730B (en) | 2024-08-20 |
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