CN1095390A - Fumigation mildew-proof moth-proof paint and its application - Google Patents
Fumigation mildew-proof moth-proof paint and its application Download PDFInfo
- Publication number
- CN1095390A CN1095390A CN 93112439 CN93112439A CN1095390A CN 1095390 A CN1095390 A CN 1095390A CN 93112439 CN93112439 CN 93112439 CN 93112439 A CN93112439 A CN 93112439A CN 1095390 A CN1095390 A CN 1095390A
- Authority
- CN
- China
- Prior art keywords
- moth
- mould
- coating
- mildew
- fumigation
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 238000003958 fumigation Methods 0.000 title claims abstract description 10
- 239000003973 paint Substances 0.000 title 1
- 239000011248 coating agent Substances 0.000 claims abstract description 34
- 238000000576 coating method Methods 0.000 claims abstract description 34
- 239000002316 fumigant Substances 0.000 claims abstract description 18
- 239000000945 filler Substances 0.000 claims abstract description 9
- OCJBOOLMMGQPQU-UHFFFAOYSA-N 1,4-dichlorobenzene Chemical compound ClC1=CC=C(Cl)C=C1 OCJBOOLMMGQPQU-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000002904 solvent Substances 0.000 claims abstract description 8
- 238000002844 melting Methods 0.000 claims abstract description 7
- 230000001046 anti-mould Effects 0.000 claims description 26
- 239000002546 antimould Substances 0.000 claims description 26
- WQRWNOKNRHCLHV-TWGQIWQCSA-N (z)-2-bromo-3-phenylprop-2-enal Chemical group O=CC(/Br)=C/C1=CC=CC=C1 WQRWNOKNRHCLHV-TWGQIWQCSA-N 0.000 claims description 12
- 239000003112 inhibitor Substances 0.000 claims description 8
- TUAMRELNJMMDMT-UHFFFAOYSA-N 3,5-xylenol Chemical compound CC1=CC(C)=CC(O)=C1 TUAMRELNJMMDMT-UHFFFAOYSA-N 0.000 claims description 6
- 239000004902 Softening Agent Substances 0.000 claims description 6
- 239000013530 defoamer Substances 0.000 claims description 6
- 239000003981 vehicle Substances 0.000 claims description 6
- 239000003292 glue Substances 0.000 claims description 5
- LLEMOWNGBBNAJR-UHFFFAOYSA-N biphenyl-2-ol Chemical compound OC1=CC=CC=C1C1=CC=CC=C1 LLEMOWNGBBNAJR-UHFFFAOYSA-N 0.000 claims description 4
- 239000000460 chlorine Substances 0.000 claims description 4
- 229910052801 chlorine Inorganic materials 0.000 claims description 4
- 235000010292 orthophenyl phenol Nutrition 0.000 claims description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 9
- 239000003795 chemical substances by application Substances 0.000 abstract description 4
- 238000000034 method Methods 0.000 abstract description 4
- 238000003756 stirring Methods 0.000 abstract description 4
- 238000012856 packing Methods 0.000 abstract description 3
- 238000010438 heat treatment Methods 0.000 abstract description 2
- 239000004014 plasticizer Substances 0.000 abstract description 2
- 239000002518 antifoaming agent Substances 0.000 abstract 1
- 230000008018 melting Effects 0.000 abstract 1
- TZCXTZWJZNENPQ-UHFFFAOYSA-L barium sulfate Chemical group [Ba+2].[O-]S([O-])(=O)=O TZCXTZWJZNENPQ-UHFFFAOYSA-L 0.000 description 8
- DKPFZGUDAPQIHT-UHFFFAOYSA-N butyl acetate Chemical group CCCCOC(C)=O DKPFZGUDAPQIHT-UHFFFAOYSA-N 0.000 description 7
- 230000000694 effects Effects 0.000 description 6
- 239000000976 ink Substances 0.000 description 5
- POAOYUHQDCAZBD-UHFFFAOYSA-N 2-butoxyethanol Chemical compound CCCCOCCO POAOYUHQDCAZBD-UHFFFAOYSA-N 0.000 description 4
- LRHPLDYGYMQRHN-UHFFFAOYSA-N N-Butanol Chemical compound CCCCO LRHPLDYGYMQRHN-UHFFFAOYSA-N 0.000 description 4
- 235000012204 lemonade/lime carbonate Nutrition 0.000 description 4
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 description 4
- MNAHQWDCXOHBHK-UHFFFAOYSA-N 1-phenylpropane-1,1-diol Chemical compound CCC(O)(O)C1=CC=CC=C1 MNAHQWDCXOHBHK-UHFFFAOYSA-N 0.000 description 3
- 125000000118 dimethyl group Chemical group [H]C([H])([H])* 0.000 description 3
- 239000000839 emulsion Substances 0.000 description 3
- 229920003987 resole Polymers 0.000 description 3
- 241000228212 Aspergillus Species 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 2
- UFWIBTONFRDIAS-UHFFFAOYSA-N Naphthalene Chemical compound C1=CC=CC2=CC=CC=C21 UFWIBTONFRDIAS-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 210000002189 macula lutea Anatomy 0.000 description 2
- 244000005700 microbiome Species 0.000 description 2
- 238000007650 screen-printing Methods 0.000 description 2
- 230000001988 toxicity Effects 0.000 description 2
- 231100000419 toxicity Toxicity 0.000 description 2
- DSSYKIVIOFKYAU-XCBNKYQSSA-N (R)-camphor Chemical compound C1C[C@@]2(C)C(=O)C[C@@H]1C2(C)C DSSYKIVIOFKYAU-XCBNKYQSSA-N 0.000 description 1
- QPVRKFOKCKORDP-UHFFFAOYSA-N 1,3-dimethylcyclohexa-2,4-dien-1-ol Chemical compound CC1=CC(C)(O)CC=C1 QPVRKFOKCKORDP-UHFFFAOYSA-N 0.000 description 1
- 241000194107 Bacillus megaterium Species 0.000 description 1
- 244000025254 Cannabis sativa Species 0.000 description 1
- 241001515917 Chaetomium globosum Species 0.000 description 1
- 241000723346 Cinnamomum camphora Species 0.000 description 1
- 241001149956 Cladosporium herbarum Species 0.000 description 1
- 241001236817 Paecilomyces <Clavicipitaceae> Species 0.000 description 1
- 241000228153 Penicillium citrinum Species 0.000 description 1
- 241000589540 Pseudomonas fluorescens Species 0.000 description 1
- 241000191967 Staphylococcus aureus Species 0.000 description 1
- 230000001154 acute effect Effects 0.000 description 1
- 229920000180 alkyd Polymers 0.000 description 1
- 229960000846 camphor Drugs 0.000 description 1
- 229930008380 camphor Natural products 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- DOIRQSBPFJWKBE-UHFFFAOYSA-N dibutyl phthalate Chemical compound CCCCOC(=O)C1=CC=CC=C1C(=O)OCCCC DOIRQSBPFJWKBE-UHFFFAOYSA-N 0.000 description 1
- 210000003743 erythrocyte Anatomy 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- FUZZWVXGSFPDMH-UHFFFAOYSA-N hexanoic acid Chemical compound CCCCCC(O)=O FUZZWVXGSFPDMH-UHFFFAOYSA-N 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 230000005764 inhibitory process Effects 0.000 description 1
- 230000000968 intestinal effect Effects 0.000 description 1
- 239000007788 liquid Substances 0.000 description 1
- 210000004185 liver Anatomy 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 239000006187 pill Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 239000002023 wood Substances 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
- Paper (AREA)
Abstract
A kind of coating for fumigation, mildew and moth proofing, especially suitable for coating on the surface of packing paper, film, finished bag and various cards to make mildew and moth proofing card, mildew and moth proofing bag, paper and film. It is made up by using fumigant mildew-proofing agent, 1, 4-dichlorobenzene, filler, connecting material, solvent, plasticizer and defoaming agent through the processes of heating, stirring and melting according to a certain proportion. The invention solves the problems that the use occasions are small and clothes sometimes generate yellow spots in the prior art, and provides convenience for properly storing articles and avoiding mildew and moth damage for families and large shops.
Description
The present invention relates to coating, especially a kind of anti-mould, anti-moth fumigant coating.
The present invention is particularly suitable for doing wrapping paper, film, bag and card surface coating material.
In prior art, the major ingredient of anti-mould and anti-moth articles for use such as mothball, camphor spirit piece is a naphthalene, and it is mainly as mothproof, and anti-mold effect is very poor, and toxicity is big.Along with development of technology, this product certainly will will be eliminated.In scientific research process, it is found that alpha-bromo-cinnamaldehyde has good anti-mold effect, shown in tabulation:
Alpha-bromo-cinnamaldehyde is to the minimum inhibition solubility (MIC) of microorganism
Microorganism MIC (ppm)
China ink aspergillus 50
Flavus 60
Penicillium citrinum 25
Paecilomyces varioti 30
Variable color aspergillus 25
Wood mould 25
Cladosporium herbarum 25
Chaetomium globosum 50
Streptococcus aureus 25
Intestinal bacteria 75
Withered grass liver bacterium 75
Pseudomonas fluorescens 50
Bacillus megaterium 50
Alpha-bromo-cinnamaldehyde is to small white mouse acute oral LD
50Be 0.926g/kg, to the skin nonirritant, negative to marrow polychromatic erythrocyte micronucleus test.English Patent GB1402791 discloses a kind of technology that adopts alpha-bromo-cinnamaldehyde as anti-mould and moth-proof agent, it is that alpha-bromo-cinnamaldehyde is adsorbed on the filler, but, cause the concentration part of alpha-bromo-cinnamaldehyde too high or too low because the evaporation rate of alpha-bromo-cinnamaldehyde still is difficult to fine control.Too high meeting causes the clothing macula lutea, and low excessively then anti-mold effect is poor.In addition, the said products is to make sheet, and pill-type only can be used in the encloses containers such as case, cabinet.The clothing that displays for the emporium in southern coastal cities is just improper.
The objective of the invention is to overcome above-mentioned technical deficiency part, provide a kind of toxicity low, clothing is not had the anti-mould, anti-moth fumigant coating of damage.This coating is suitable for being coated in the internal skin and the various cards top layer of wrapping paper, film, finished bag, makes the anti-mould and anti-moth function not only be suitable for the protection of clothes, but also expands to fields such as book information, sensitive materials, audiovisual tape, postal materials card.
The present invention's purpose realizes by following technical proposals: a kind of anti-mould, anti-moth fumigant coating, by fumigation mould inhibitor, 1,4-dichlorobenzene, filler, low-melting ink vehicle, solvent, softening agent and defoamer are formed.
Described fumigation mould inhibitor is an alpha-bromo-cinnamaldehyde, 4-chlorine 3,5-xylenol or orthoxenol.
The weight percent of this anti-mould, anti-moth fumigant coating each component is:
Fumigation mould inhibitor 1～30%
1,4 dichlorobenzene 1～30%
Low-melting ink vehicle 10～30%
Softening agent 1～5%
Solvent 10～30%
Defoamer 0.5～3%
Filler 15～35%
The fineness of this anti-mould, anti-moth fumigant coating＜10 μ m.
In component, filler is barium sulfate and lime carbonate, and solvent is N-BUTYL ACETATE, butyl glycol ether or propyl carbinol, and softening agent is phthalic acid n-octyl, n-butyl phthalate or long-oil-length phthalic alkyd resin.
This anti-mould, anti-moth fumigant coating is used for the coating of the internal skin of wrapping paper, film, bag, the coating on various cards top layer.Its glue spread is 5～7g/m
2
The present invention compared with the prior art, its advantage is: 1. alpha-bromo-cinnamaldehyde is added in the coating as mould inhibitor and fully mix and stir, make its concentration even.This coating is coated in the finished bag internal skin, and the packing clothing does not have the damage effect to clothing, has solved " mould moth gram " and has caused clothing the problem of macula lutea to occur because of the mould inhibitor density unevenness is even.2. the present invention has also adopted the 4-chlorine 3 close with the anti-mold effect of alpha-bromo-cinnamaldehyde, and 5-xylenol or orthoxenol can reduce cost, and the material choice scope increases.3. sheet, the pill shape of changing traditional anti-mould and anti-moth articles for use are liquid coating, and its range of application is enlarged.From the user, no longer be that the clothing that only limits to family is preserved, but also can expand each department store, clothes workshop to.Wrapping paper, the packing bag of clothing will change the wrapping paper that scribbles anti-mould, anti-moth fumigant coating of the present invention into, bag can play the effect to the clothing anti-mould and anti-moth as long as will pack.From applicable object, also no longer be confined to clothes, leatherware, and expand categories such as CD, tape, sensitive materials, photograph album, postal materials to.
As mentioned above, the present invention has realized the desired purpose that reaches substantially.
Embodiment one:
Prepare anti-mould, anti-moth fumigant coating in the requsst listed below
(1) batching (unit: gram)
Fumigation anti-mould and moth-proof agent alpha-bromo-cinnamaldehyde 25
1,4-dichlorobenzene 10
Filler barium sulfate 15
Lime carbonate 10
Low-melting ink vehicle Abietyl modified (dihydroxyphenyl propane) resol 20
Solvent butyl acetate 5
Butyl glycol ether 7.5
Propyl carbinol 2.5
Plasticizer phthalic acid n-octyl 4
Defoamer dimethyl silscone emulsion 1
(2) with low-melting ink vehicle and solvent heating for dissolving at high temperature
(3) add softening agent and defoamer
(4) add the fumigation anti-mould and moth-proof agent, stir fully to dissolving
(5) add filler, stir, cooling.
(6) being rolled to fineness with three-high mill is below the 10 μ m.
Embodiment two:
Batching (unit: gram)
4-chlorine 3,5-xylenol 25
1,4-dichlorobenzene 10
Barium sulfate 15
Lime carbonate 10
Abietyl modified (dihydroxyphenyl propane) resol 20
N-BUTYL ACETATE 5
Butyl glycol ether 7.5
Propyl carbinol 2.5
Phthalic acid n-octyl 4
Dimethyl silscone emulsion 1
All the other schemes are with embodiment one
Embodiment three:
Batching (unit: gram)
Orthoxenol 25
1,4-dichlorobenzene 10
Barium sulfate 15
Lime carbonate 10
Abietyl modified (dihydroxyphenyl propane) resol 20
N-BUTYL ACETATE 5
Butyl glycol ether 7.5
Propyl carbinol 2.5
Phthalic acid n-octyl 4
Dimethyl silscone emulsion 1
All the other schemes are with embodiment one.
Embodiment four
Make anti-mould and anti-moth wrapping paper, film and finished bag with above-mentioned anti-mould, anti-moth fumigant coating, the method for above-mentioned coating by roller coat, blade coating or silk screen printing is coated on wrapping paper, film and the finished bag internal skin, glue spread is 6g/m
2
Embodiment five
Make anti-mould and anti-moth stamp album, postal materials card, bookmark with above-mentioned anti-mould, anti-moth fumigant coating, by the method for roller coat, blade coating or silk screen printing, above-mentioned coating is coated in the top layer of stamp album, postal materials card, bookmark, glue spread is 7g/m
2
Claims (8)
1, a kind of anti-mould, anti-moth fumigant coating is characterized in that by fumigation mould inhibitor, 1, and 4-dichlorobenzene, filler, low-melting ink vehicle, solvent, softening agent and defoamer are formed.
2, anti-mould, anti-moth fumigant coating according to claim 1 is characterized in that described fumigation mould inhibitor is an alpha-bromo-cinnamaldehyde, 4-chlorine 3,5-xylenol or orthoxenol.
3, anti-mould, anti-moth fumigant coating according to claim 1 and 2 is characterized in that the weight percent of each component is
Fumigation mould inhibitor 1～30%
1,4 dichlorobenzene 1～30%
Low-melting ink vehicle 10～30%
Softening agent 1～5%
Solvent 10～30%
Defoamer 0.5～3%
Filler 15～35%
4, anti-mould, anti-moth fumigant coating according to claim 3 is characterized in that the fineness＜10 μ m of described coating.
5, a kind of wrapping paper, the film of at least one described anti-mould, anti-moth fumigant coating in the claim 1～4 and bag of making thereof of having applied.
6, the wrapping paper of coating according to claim 5, film and the bag made thereof is characterized in that glue spread is 5～7g/m
2
7, a kind of card that has applied at least one described anti-mould, anti-moth fumigant coating in the claim 1～4.
8, the card of coating according to claim 7 is characterized in that glue spread is 5～7g/m
2
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93112439A CN1040011C (en) | 1993-05-19 | 1993-05-19 | Fumigation mildew-proof moth-proof paint and product coated with said paint |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93112439A CN1040011C (en) | 1993-05-19 | 1993-05-19 | Fumigation mildew-proof moth-proof paint and product coated with said paint |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1095390A true CN1095390A (en) | 1994-11-23 |
| CN1040011C CN1040011C (en) | 1998-09-30 |
Family
ID=4990052
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN93112439A Expired - Fee Related CN1040011C (en) | 1993-05-19 | 1993-05-19 | Fumigation mildew-proof moth-proof paint and product coated with said paint |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1040011C (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1085496C (en) * | 1999-09-23 | 2002-05-29 | 中国科学院上海植物生理研究所 | New slowly-releasing anti-mildew fresh-keeping method and is equipment |
| CN102326539A (en) * | 2011-07-29 | 2012-01-25 | 苏州卡奇特纺织有限公司 | Mothproofing agent for viscose cotton fabric |
| CN106634518A (en) * | 2016-12-29 | 2017-05-10 | 常德金德镭射科技股份有限公司 | Packing box |
| CN106634130A (en) * | 2016-12-29 | 2017-05-10 | 常德金德镭射科技股份有限公司 | Packaging bag |
| CN106697599A (en) * | 2016-12-29 | 2017-05-24 | 常德金德镭射科技股份有限公司 | Packaging bottle |
-
1993
- 1993-05-19 CN CN93112439A patent/CN1040011C/en not_active Expired - Fee Related
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1085496C (en) * | 1999-09-23 | 2002-05-29 | 中国科学院上海植物生理研究所 | New slowly-releasing anti-mildew fresh-keeping method and is equipment |
| CN102326539A (en) * | 2011-07-29 | 2012-01-25 | 苏州卡奇特纺织有限公司 | Mothproofing agent for viscose cotton fabric |
| CN106634518A (en) * | 2016-12-29 | 2017-05-10 | 常德金德镭射科技股份有限公司 | Packing box |
| CN106634130A (en) * | 2016-12-29 | 2017-05-10 | 常德金德镭射科技股份有限公司 | Packaging bag |
| CN106697599A (en) * | 2016-12-29 | 2017-05-24 | 常德金德镭射科技股份有限公司 | Packaging bottle |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1040011C (en) | 1998-09-30 |
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|---|---|---|---|
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C06 | Publication | ||
| PB01 | Publication | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
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