CN109537290A - 一种纺织品远红外整理剂及其制备方法 - Google Patents
一种纺织品远红外整理剂及其制备方法 Download PDFInfo
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- GNMQOUGYKPVJRR-UHFFFAOYSA-N nickel(III) oxide Inorganic materials [O-2].[O-2].[O-2].[Ni+3].[Ni+3] GNMQOUGYKPVJRR-UHFFFAOYSA-N 0.000 description 1
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/37—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/564—Polyureas, polyurethanes or other polymers having ureide or urethane links; Precondensation products forming them
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- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/44—Oxides or hydroxides of elements of Groups 2 or 12 of the Periodic Table; Zincates; Cadmates
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- D06M11/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising
- D06M11/32—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond
- D06M11/36—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with inorganic substances or complexes thereof; Such treatment combined with mechanical treatment, e.g. mercerising with oxygen, ozone, ozonides, oxides, hydroxides or percompounds; Salts derived from anions with an amphoteric element-oxygen bond with oxides, hydroxides or mixed oxides; with salts derived from anions with an amphoteric element-oxygen bond
- D06M11/46—Oxides or hydroxides of elements of Groups 4 or 14 of the Periodic Table; Titanates; Zirconates; Stannates; Plumbates
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- D06M13/00—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment
- D06M13/322—Treating fibres, threads, yarns, fabrics or fibrous goods made from such materials, with non-macromolecular organic compounds; Such treatment combined with mechanical treatment with compounds containing nitrogen
- D06M13/402—Amides imides, sulfamic acids
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- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
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- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
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Abstract
本发明公开了一种纺织品远红外整理剂及其制备方法,其特征在于:包括,包括,水性聚氨酯、环氧树脂、陶瓷粉、ZnO、TiO2、聚丙烯酸钠、聚乙烯醇Z‑200、异氰酸酯、N‑羟甲基丙烯酰胺、去离子水;其中,以质量份数计,所述水性聚氨酯为20~22份,所述环氧树脂为5~6份,陶瓷粉为10~12份、所述ZnO为5~7份,TiO2为3~5份,所述聚丙烯酸钠为4~6份,所述聚乙烯醇Z‑200为1~2份,所述异氰酸酯为1~2份,所述N‑羟甲基丙烯酰胺为1~2份,所述去离子水100~102份。本发明采用陶瓷粉、ZnO和TiO2特定组合,制备出高性能、稳定性优良的整理剂,能够赋予纺织品优良的远红外保健、防紫外线、杀菌、除臭和净化空气的性能。
Description
技术领域
本发明涉及制衣领域,具体涉及一种纺织品远红外整理剂及其制备方法。
背景技术
随着人们对衣着轻暖舒适、保健美观的需求日渐强烈,多功能化纺织品越来越受到人们的青睐,远红外纺织符合当今人们对健康舒适的普遍遍求,具有较好的商业价值和发展前景。目前制作远红外纺织品的途径有在纺织品中加入远红外纤维,也有在纺织品的后整理中进行,即在纺织品后整理中加入远红外纳米颗粒,其种类有氧化物、碳化物、氮化物、硼化物、硅化物及其他物质,如碳粉、云母、CrB、Ni2O3等。
当前国内远红外纺织品的制备存在这成本较高、制备工艺复杂以及纺织品功能化单一的问题,因此产业内急需一种能够赋予纺织品多能化整理液,在赋予纺织品优良的远红外保健、防紫外线的同时,还具有杀菌除臭、净化空气性能,以及实现织物耐洗、柔软特性,以利于产业化应用。
发明内容
本部分的目的在于概述本发明的实施例的一些方面以及简要介绍一些较佳实施例。在本部分以及本申请的说明书摘要和发明名称中可能会做些简化或省略以避免使本部分、说明书摘要和发明名称的目的模糊,而这种简化或省略不能用于限制本发明的范围。
鉴于上述和/或现有纺织品远红外整理剂中存在的问题,提出了本发明。
因此,本发明其中一个目的是,克服现有纺织品远红外整理剂的不足,提供一种纺织品远红外整理剂。
为解决上述技术问题,根据本发明的一个方面,本发明提供了如下技术方案:一种纺织品远红外整理剂,其特征在于:包括,水性聚氨酯、环氧树脂、陶瓷粉、ZnO、TiO2、聚丙烯酸钠、聚乙烯醇Z-200、异氰酸酯、N-羟甲基丙烯酰胺、去离子水;其中,
以质量份数计,所述水性聚氨酯为20~22份,所述环氧树脂为5~6份,陶瓷粉为10~12份、所述ZnO为5~7份,TiO2为3~5份,所述聚丙烯酸钠为4~6份,所述聚乙烯醇Z-200为1~2份,所述异氰酸酯为1~2份,所述N-羟甲基丙烯酰胺为1~2份,所述去离子水100~102份。
作为本发明所述纺织品远红外整理剂的一种优选方案,其中:所述水性聚氨酯为20份,所述环氧树脂为5份,陶瓷粉为12份、所述ZnO为6份,TiO2为4份,所述聚丙烯酸钠为4份,所述聚乙烯醇Z-200为2份,所述异氰酸酯为2份,所述N-羟甲基丙烯酰胺为1份,所述去离子水100份。
作为本发明所述纺织品远红外整理剂的一种优选方案,其中:所述ZnO,其粒径大小为20nm。
作为本发明所述纺织品远红外整理剂的一种优选方案,其中:所述TiO2,其粒径大小为25nm。
本发明另一个目的是,提供一种纺织品远红外整理剂的制备方法。
为解决上述技术问题,根据本发明的一个方面,本发明提供了如下技术方案:一种纺织品远红外整理剂的制备方法,其特征在于:包括,取1~2份聚丙烯酸钠置于容器内,加入去离子水50~51份,再加入3~5份粒径大小为25nm的TiO2,超声处理得到纳米TiO2乳液,备用;称取1~2份聚丙烯酸钠置于容器内,加入去离子水50~51份,然后再加入5~7份粒径大小为20nm的ZnO,超声处理得到纳米ZnO乳液,备用;取20~22份水性聚氨酯和5~6份环氧树脂于容器内,搅拌均匀后,缓慢加入10~12份陶瓷粉,混合均匀后得混合液,将所述纳米TiO2乳液、所述纳米ZnO乳液依次缓慢加入混合液体后,再加入1~2份聚乙烯醇Z-200、1~2份异氰酸酯和1~2份N-羟甲基丙烯酰胺,机械搅拌处理后得织物远红外整理剂。
作为本发明所述纺织品远红外整理剂制备方法的一种优选方案,其中:所述超声处理得到纳米TiO2乳液,超声处理时间为25min~30min,超声温度为35~40℃。
作为本发明所述纺织品远红外整理剂制备方法的一种优选方案,其中:所述超声处理得到纳米ZnO乳液,超声处理时间为30min~35min,超声温度为32~38℃。
作为本发明所述纺织品远红外整理剂制备方法的一种优选方案,其中:所述超声处理,超声频率为25KHz,超声功率为600W。
作为本发明所述纺织品远红外整理剂制备方法的一种优选方案,其中:所述机械搅拌处理后得织物远红外整理剂,机械搅拌时间为28min~32min,机械搅拌转速为100~120rpm,机械搅拌处理温度为30~35℃。
作为本发明所述纺织品远红外整理剂制备方法的一种优选方案,其中:所述机械搅拌处理时间为30min,所述机械搅拌转速为100rpm,所述机械搅拌处理温度为30℃。
本发明有益效果:
(1)本发明将陶瓷粉、纳米TiO2、ZnO作为主要添加剂,提供整理剂远红外保健、防紫外线的功能;同时,聚丙烯酸钠作为分散剂,能够将纳米TiO2均匀分散在水中;水性聚氨酯、环氧树脂和聚乙烯醇Z-200牢固地将纳米TiO2和陶瓷粉粘附在织物表面,异氰酸酯和N-羟甲基是作为固化剂,对水性聚氨酯、环氧树脂进行固化,在织物表面形成一层薄状膜结构,在赋予织物耐水性的性能的同时,使得纺织品具有良好的柔软性。
(2)本发明制备的整理液对纺织品进行整理后,在纺织品表面形成一层薄状的膜结构,使得纺织品具有良好的柔软性。且制备的整理液具有生物相容性,可自行降解,整理液制备流程短,适合工业化生产需求。
具体实施方式
为使本发明的上述目的、特征和优点能够更加明显易懂,下面结合说明书实施例对本发明的具体实施方式做详细的说明。
在下面的描述中阐述了很多具体细节以便于充分理解本发明,但是本发明还可以采用其他不同于在此描述的其它方式来实施,本领域技术人员可以在不违背本发明内涵的情况下做类似推广,因此本发明不受下面公开的具体实施例的限制。
其次,此处所称的“一个实施例”或“实施例”是指可包含于本发明至少一个实现方式中的特定特征、结构或特性。在本说明书中不同地方出现的“在一个实施例中”并非均指同一个实施例,也不是单独的或选择性的与其他实施例互相排斥的实施例。
实施例1
A液:以质量份数计,取20份水性聚氨酯和5份环氧树脂于烧杯内,然后缓慢加入10份陶瓷粉,通过电动搅拌机以100rpm搅拌速度搅拌,并保持机械搅拌处理温度为30℃。
B液:称取2份聚丙烯酸钠于烧杯内,加入去离子水50份,然后再加入3份25nm的TiO2,超声处理30min(超声频率为25KHz,超声功率为600W),得到分散均匀的纳米TiO2乳液。
C液:称取2份聚丙烯酸钠于烧杯内,加入去离子水50份,然后再加入5份20nm的ZnO,超声处理30min(超声频率为25KHz,超声功率为600W),得到分散均匀的纳米ZnO乳液。
在电动搅拌机搅拌下,将B液、C液依次缓慢加入A液中,再缓慢加入1份聚乙烯醇Z-200,最后加2份异氰酸酯和1份N-羟甲基丙烯酰胺,并用电动搅拌机搅拌;其中,搅拌时间为28min,搅拌转速为100rpm,机械搅拌处理温度为30℃。
实施例2
A液:以质量份数计,取20份水性聚氨酯和5份环氧树脂于烧杯内,然后缓慢加入12份陶瓷粉,通过电动搅拌机以100rpm搅拌速度搅拌,并保持机械搅拌处理温度为30℃。
B液:称取2份聚丙烯酸钠于烧杯内,加入去离子水50份,然后再加入4份25nm的TiO2,超声处理28min(超声频率为25KHz,超声功率为600W),超声温度为38℃,得到分散均匀的纳米TiO2乳液。
C液:称取2份聚丙烯酸钠于烧杯内,加入去离子水50份,然后再加入6份20nm的ZnO,超声处理35min(超声频率为25KHz,超声功率为600W),超声温度为36℃,得到分散均匀的纳米ZnO乳液。
然后在电动搅拌机搅拌下,将B液、C液依次缓慢加入A液中,再缓慢加入2份聚乙烯醇Z-200,最后加2份异氰酸酯和1份N-羟甲基丙烯酰胺,并用电动搅拌机搅拌;其中,搅拌时间为30min,搅拌转速为100rpm,机械搅拌处理温度为30℃。
实施例3
A液:以质量份数计,取20份水性聚氨酯和6份环氧树脂于烧杯内,然后缓慢加入12份陶瓷粉,通过电动搅拌机以100rpm搅拌速度搅拌,并保持机械搅拌处理温度为30℃。
B液:称取3份聚丙烯酸钠于烧杯内,加入去离子水50份,然后再加入4份25nm的TiO2,超声处理25min(超声频率为25KHz,超声功率为600W),超声温度为40℃,得到分散均匀的纳米TiO2乳液。
C液:称取3份聚丙烯酸钠于烧杯内,加入去离子水50份,然后再加入7份20nm的ZnO,超声处理35min(超声频率为25KHz,超声功率为600W),超声温度为38℃,得到分散均匀的纳米ZnO乳液。
然后在电动搅拌机搅拌下,将B液、C液依次缓慢加入A液中,再缓慢加入1份聚乙烯醇Z-200,最后加1份异氰酸酯和2份N-羟甲基丙烯酰胺,并用电动搅拌机搅拌;其中,搅拌时间为32min,搅拌转速为120rpm,机械搅拌处理温度为35℃。
实施例4
A液:以质量份数计,取20份水性聚氨酯和5份环氧树脂于烧杯内,然后缓慢加入12份陶瓷粉,通过电动搅拌机以100rpm搅拌速度搅拌,并保持机械搅拌处理温度为30℃。
B液:称取2份聚丙烯酸钠于烧杯内,加入去离子水50份,然后再加入5份25nm的TiO2,超声处理25min(超声频率为25KHz,超声功率为600W),超声温度为40℃,得到分散均匀的纳米TiO2乳液。
C液:称取2份聚丙烯酸钠于烧杯内,加入去离子水50份,然后再加入7份20nm的ZnO,超声处理30min(超声频率为25KHz,超声功率为600W),超声温度为38℃,得到分散均匀的纳米ZnO乳液。
然后在电动搅拌机搅拌下,将B液、C液依次缓慢加入A液中,再缓慢加入1份聚乙烯醇Z-200,最后加2份异氰酸酯和1份N-羟甲基丙烯酰胺,并用电动搅拌机搅拌;其中,搅拌时间为28min,搅拌转速为120rpm,机械搅拌处理温度为35℃。
实施例5
A液:以质量份数计,取21份水性聚氨酯和5份环氧树脂于烧杯内,然后缓慢加入12份陶瓷粉,通过电动搅拌机以100rpm搅拌速度搅拌,并保持机械搅拌处理温度为30℃。
B液:称取2份聚丙烯酸钠于烧杯内,加入去离子水50份,然后再加入5份25nm的TiO2,超声处理28min(超声频率为25KHz,超声功率为600W),超声温度为40℃,得到分散均匀的纳米TiO2乳液。
C液:称取2份聚丙烯酸钠于烧杯内,加入去离子水50份,然后再加入7份20nm的ZnO,超声处理35min(超声频率为25KHz,超声功率为600W),超声温度为38℃,得到分散均匀的纳米ZnO乳液。
然后在电动搅拌机搅拌下,将B液、C液依次缓慢加入A液中,再缓慢加入1份聚乙烯醇Z-200,最后加2份异氰酸酯和1份N-羟甲基丙烯酰胺,并用电动搅拌机搅拌;其中,搅拌时间为32min,搅拌转速为110rpm,机械搅拌处理温度为33℃。
实施例6
A液:以质量份数计,取22份水性聚氨酯和5份环氧树脂于烧杯内,然后缓慢加入12份陶瓷粉,通过电动搅拌机以100rpm搅拌速度搅拌,并保持机械搅拌处理温度为30℃。
B液:称取2份聚丙烯酸钠于烧杯内,加入去离子水51份,然后再加入5份25nm的TiO2,超声处理30min(超声频率为25KHz,超声功率为600W),超声温度为35℃,得到分散均匀的纳米TiO2乳液。
C液:称取2份聚丙烯酸钠于烧杯内,加入去离子水51份,然后再加入7份20nm的ZnO,超声处理30min(超声频率为25KHz,超声功率为600W),超声温度为38℃,得到分散均匀的纳米ZnO乳液。
然后在电动搅拌机搅拌下,将B液、C液依次缓慢加入A液中,再缓慢加入1份聚乙烯醇Z-200,最后加2份异氰酸酯和1份N-羟甲基丙烯酰胺,并用电动搅拌机搅拌;其中,搅拌时间为28min,搅拌转速为110rpm,机械搅拌处理温度为30℃。
实施例7
A液:以质量份数计,取20份水性聚氨酯和5份环氧树脂于烧杯内,然后缓慢加入5份陶瓷粉,通过电动搅拌机以100rpm搅拌速度搅拌,并保持机械搅拌处理温度为30℃。
B液:称取2份聚丙烯酸钠于烧杯内,加入去离子水50份,然后再加入3份25nm的TiO2,超声处理25min(超声频率为25KHz,超声功率为600W),超声温度为40℃,得到分散均匀的纳米TiO2乳液。
C液:称取2份聚丙烯酸钠于烧杯内,加入去离子水50份,然后再加入6份20nm的ZnO,超声处理35min(超声频率为25KHz,超声功率为600W),超声温度为38℃,得到分散均匀的纳米ZnO乳液。
然后在电动搅拌机搅拌下,将B液、C液依次缓慢加入A液中,再缓慢加入1份聚乙烯醇Z-200,最后加2份异氰酸酯和1份N-羟甲基丙烯酰胺,并用电动搅拌机搅拌;其中,搅拌时间为30min,搅拌转速为120rpm,机械搅拌处理温度为34℃。
实施例8
A液:以质量份数计,取20份水性聚氨酯和5份环氧树脂于烧杯内,然后缓慢加入2份陶瓷粉,通过电动搅拌机以100rpm搅拌速度搅拌,并保持机械搅拌处理温度为30℃。
B液:称取2份聚丙烯酸钠于烧杯内,加入去离子水50份,然后再加入3份25nm的TiO2,超声处理30min(超声频率为25KHz,超声功率为600W),超声温度为40℃,得到分散均匀的纳米TiO2乳液。
C液:称取2份聚丙烯酸钠于烧杯内,加入去离子水50份,然后再加入6份20nm的ZnO,超声处理35min(超声频率为25KHz,超声功率为600W),超声温度为32℃,得到分散均匀的纳米ZnO乳液。
然后在电动搅拌机搅拌下,将B液、C液依次缓慢加入A液中,再缓慢加入1份聚乙烯醇Z-200,最后加2份异氰酸酯和1份N-羟甲基丙烯酰胺,并用电动搅拌机搅拌;其中,搅拌时间为32min,搅拌转速为120rpm,机械搅拌处理温度为35℃。
实施例9
实施例1~8原料配比如表1所示。
表1实施例1~8中各原料配比表
1、整理方法
将纺织品置于该整理剂中浸渍15min,取出,并置于80℃真空干燥烘箱内烘燥20min冷却至室温。
将获得的纺织品浸泡在1mg/L的甲醛溶液中并置于阳光下暴露3h,取出纺织品,并测定甲醛溶液的浓度。
2、克罗值的测定
按照标准GB11048-1989测得纺织品的保温性能,试验仪器:由莱州市电子仪器有限公司生产的,仪器型号YG606LF;测定方法:参照国家标准GB11048-1989进行测定,使用恒定温差散热法,试验条件是20℃、湿度为65.8%。
3、纺织品紫外光透过率的测定
通过紫外光透过率采用紫外可见分光光度计测定,波长范围为200~800nm,扫描速率300nm/min,样品尺寸:长50mm×宽30mm×厚2mm。
4、抗菌性能测试
按GB/T 20944.3-2008《纺织品抗菌性能的评价第三部分:振荡法》进行测试;测试菌种为金黄色葡萄球菌。
由实施例1~8得到的整理剂分别整理织物后,测定指标见表2。
表2实施例1~8得到的整理剂分别整理织物后的测定指标
从表2可以看出,织物经本发明制得的整理剂整理后,克罗值最高达到0.973,紫外光透过率仅达10%,使得制得的整理剂具有较好的远红外保健、防紫外线功能外,在能够满足服用要求的同时,发明人还发现整理剂具有杀菌、除臭和净化空气的功能。可能是由于本发明添加纳米TiO2粒径很小,即25nm,具有吸收紫外线的优异性能,从而具有抗防紫外线的功能。ZnO作为一种优异的抗菌剂,纳米TiO2也具有抗菌性能,二者协同赋予织物良好的抗菌性能。陶瓷粉具有催化氧化功能,在太阳光(尤其是紫外线)照射下,生成OH-,能有效除去室内的苯、甲醛、硫化物、氨和臭味物质,并具有杀菌功能,发明人通过优化实验得出纳米ZnO、纳米TiO2、陶瓷粉的最佳配比,实现优异的杀菌、除臭和净化空气的功能。
实施例10
将实施例2制得的整理剂整理纺织品后,经不同次数水洗后按照相关国家纺织品检测标准测定的纺织品特性。(整理纺织品方法为:将纺织品置于该整理剂中浸渍15min,取出,并置于80℃真空干燥烘箱内烘燥20min冷却至室温;各特性测定参照实施例9中的方法)
洗涤耐久性测试:
用2g/L洗涤剂,采用1:30的浴比在家用洗衣机中,将整理后得到的纺织品于40℃下洗涤l0min,然后放出洗涤液,用40℃清水洗涤5min,脱水;重复以上操作,记录洗涤次数,于80℃下烘30min,然后测试其特性。
实验结果见表3。
表3洗涤对整理后得到的纺织品特性的影响
从表3中可看出,织物经过本发明制备的整理剂整理后,随着水洗次数的增加,其远红外保健功能在下降(由表中CLO值表征,即克罗值表征,CLO越大,织物保暖性越好,织物远红外功能越强。)当水洗达到50次以后,CLO依然高达0.815,织物仍具有很强的远红外保健功能,能够满足服用要求;随着水洗次数的增加,织物抗紫外线功能也在下降,当水洗达到20次以后,织物抗紫外线透过率仅为20%,仍具有一定的抗紫外线的功能,能够满足服用要求。同时可以看出,制备的织物的摩擦较小、手感优良。
实施例11
(1)在制备整理剂过程中,水性聚氨酯为20份,环氧树脂为5份,聚丙烯酸钠为2份,聚乙烯醇Z-200为2份,异氰酸酯为2份,N-羟甲基丙烯酰胺为1份,探究陶瓷粉、ZnO、TiO2添加量对整理剂性能的影响,结果见表4。
表4陶瓷粉、ZnO、TiO2添加量对整理剂性能的影响
从表4可以看出,陶瓷粉12份、ZnO 6份、TiO2 4份时,整理剂性能较佳,当缺少其中某一种物质时,其性能明显降低,表明陶瓷粉、ZnO、TiO2之间协同作用,能有效提高整理剂性能。
(2)在制备整理剂过程中,陶瓷粉为12份、ZnO为6份,TiO2为4份,聚丙烯酸钠为2份,N-羟甲基丙烯酰胺为1份,探究水性聚氨酯、环氧树脂、异氰酸酯、N-羟甲基对整理剂性能的影响,结果见表5。
按照标准ASTMD3320-1991涂层织物耐水性测定纺织品的耐水洗。
表5水性聚氨酯、环氧树脂、异氰酸酯、N-羟甲基丙烯酰胺添加量对整
理剂性能的影响
从表5可以看出,水性聚氨酯20份、环氧树脂5份、异氰酸酯2份、N-羟甲基丙烯酰胺1份时,整理剂性能最佳;当缺少其中某一物质时,整理剂性能降低,可能由于水性聚氨酯、环氧树脂和聚乙烯醇Z-200牢固地将纳米TiO2和陶瓷粉粘附在织物表面,异氰酸酯和N-羟甲基丙烯酰胺是作为固化剂,对水性聚氨酯、环氧树脂进行固化,在织物表面形成一层薄状膜结构,赋予织物耐水性的性能,同时,发明人还发现,经本发明整理剂整理后的织物,还具有良好的柔软性。
本发明中环氧树脂,即环氧树脂E-44(6101)为普通市售产品;异氰酸酯,即单异氰酸酯为普通市售产品;聚丙烯酸钠为工业级普通市售产品;陶瓷粉、ZnO、TiO2、聚乙烯醇Z200、N-羟甲基丙烯酰胺均为普通市售产品;水性聚氨酯为阴离子型聚酯型聚氨酯,固含量为35%~45%。
本发明中水性聚氨酯作为第一载体,起承担其他添加剂的作用,将添加剂稳定的粘附在织物的表面;环氧树脂作为第二载体,起承担其他添加剂的作用,与水性聚氨酯协同将添加剂稳定的粘附在织物的表面;聚丙烯酸钠作为一种良好的分散剂,具有较小的粘性,能够将陶瓷粉、ZnO和TiO2很好的分散在水性聚氨酯水溶液中;聚乙烯醇Z-200,即改性聚乙烯醇,作为优良的粘性剂,协同树脂将各种添加剂牢固在粘附在织物表面;异氰酸酯作为固化剂,对水性聚氨酯起固化作用;N-羟甲基丙烯酰胺作为固化剂,对环氧树脂起固化作用。
本发明将陶瓷粉、纳米TiO2、ZnO作为主要添加剂,提供整理剂远红外保健、防紫外线的功能;同时,聚丙烯酸钠作为分散剂,能够将纳米TiO2均匀分散在水中;水性聚氨酯、环氧树脂和聚乙烯醇Z-200牢固地将纳米TiO2和陶瓷粉粘附在织物表面,异氰酸酯和N-羟甲基是作为固化剂,对水性聚氨酯、环氧树脂进行固化,在织物表面形成一层薄状膜结构,在赋予织物耐水性的性能的同时,使得纺织品具有良好的柔软性。发明人通过实验优选出水性聚氨酯、环氧树脂、陶瓷粉、ZnO、TiO2、聚丙烯酸钠、聚乙烯醇Z-200、异氰酸酯、N-羟甲基丙烯酰胺最佳配比,使得制得的整理剂具有较好的远红外保健、防紫外线功能外,还能赋予织物较好的耐水性和良好的柔软性。发明人发现,陶瓷粉、ZnO、TiO2之间存在协同作用,能有效提高整理剂性能,当陶瓷粉12份,ZnO 6份,TiO24份时,整理剂远红外保健性能最佳;当不添加ZnO和TiO2两种物质中的一种或二种时,整理剂远红外保健性能下降,表明ZnO和TiO2能协同陶瓷粉改善整理剂远红外保健性能。
同时,发明人还发现整理剂具有杀菌、除臭和净化空气的功能。可能由于本发明添加纳米TiO2具有吸收紫外线的优异性能,从而具有抗防紫外线的功能。ZnO作为一种优异的抗菌剂,纳米TiO2也具有抗菌性能,二者协同赋予织物良好的抗菌性能。陶瓷粉具有催化氧化功能,在太阳光(尤其是紫外线)照射下,生成OH-,能有效除去室内的苯、甲醛、硫化物、氨和臭味物质,并具有杀菌功能,陶瓷粉、ZnO、TiO2之间协同作用实现杀菌、除臭和净化空气的功能。发明人通过实验发现,纳米TiO2为25nm时,ZnO为20nm时,整理剂杀菌、除臭和净化空气的效果以及远红外保健性能最佳,当TiO2为100nm,ZnO为80nm时,整理剂杀菌、除臭和净化空气的效果以及远红外保健性能相比较差;同时,当TiO2为10nm,ZnO为10nm时,其整理剂杀菌、除臭和净化空气的效果以及远红外保健性能与纳米TiO2为25nm、ZnO为20nm时相比变化不明显,从节约成本方面考虑,纳米TiO2优选25nm,ZnO优选20nm。
本发明采用陶瓷粉、ZnO和TiO2特定组合,制备出高性能、稳定性优良的整理剂,能够赋予纺织品优良的远红外保健、防紫外线、杀菌、除臭和净化空气性能,整理液对纺织品进行整理后,在纺织品表面形成一层薄状的膜结构,使得纺织品具有良好的柔软性。本发明制备的整理液具有生物相容性,可自行降解,整理液制备流程短,适合工业化生产需求。
应说明的是,以上实施例仅用以说明本发明的技术方案而非限制,尽管参照较佳实施例对本发明进行了详细说明,本领域的普通技术人员应当理解,可以对本发明的技术方案进行修改或者等同替换,而不脱离本发明技术方案的精神和范围,其均应涵盖在本发明的权利要求范围当中。
Claims (10)
1.一种纺织品远红外整理剂,其特征在于:包括,水性聚氨酯、环氧树脂、陶瓷粉、ZnO、TiO2、聚丙烯酸钠、聚乙烯醇Z-200、异氰酸酯、N-羟甲基丙烯酰胺、去离子水;其中,
以质量份数计,所述水性聚氨酯为20~22份,所述环氧树脂为5~6份,陶瓷粉为10~12份、所述ZnO为5~7份,TiO2为3~5份,所述聚丙烯酸钠为4~6份,所述聚乙烯醇Z-200为1~2份,所述异氰酸酯为1~2份,所述N-羟甲基丙烯酰胺为1~2份,所述去离子水100~102份。
2.根据权利要求1所述纺织品远红外整理剂,其特征在于:所述水性聚氨酯为20份,所述环氧树脂为5份,陶瓷粉为12份、所述ZnO为6份,TiO2为4份,所述聚丙烯酸钠为4份,所述聚乙烯醇Z-200为2份,所述异氰酸酯为2份,所述N-羟甲基丙烯酰胺为1份,所述去离子水100份。
3.根据权利要求1或2所述纺织品远红外整理剂,其特征在于:所述ZnO,其粒径大小为20nm。
4.根据权利要求1或2所述纺织品远红外整理剂,其特征在于:所述TiO2,其粒径大小为25nm。
5.一种纺织品远红外整理剂的制备方法,其特征在于:包括,
取1~2份聚丙烯酸钠置于容器内,加入去离子水50~51份,再加入3~5份粒径大小为25nm的TiO2,超声处理得到纳米TiO2乳液,备用;
称取1~2份聚丙烯酸钠置于容器内,加入去离子水50~51份,然后再加入5~7份粒径大小为20nm的ZnO,超声处理得到纳米ZnO乳液,备用;
取20~22份水性聚氨酯和5~6份环氧树脂于容器内,搅拌均匀后,缓慢加入10~12份陶瓷粉,混合均匀后得混合液,将所述纳米TiO2乳液、所述纳米ZnO乳液依次缓慢加入混合液体后,再加入1~2份聚乙烯醇Z-200、1~2份异氰酸酯和1~2份N-羟甲基丙烯酰胺,机械搅拌处理后得织物远红外整理剂。
6.如权利要求5所述纺织品远红外整理剂的制备方法,其特征在于:所述超声处理得到纳米TiO2乳液,超声处理时间为25min~30min。
7.如权利要求5所述纺织品远红外整理剂的制备方法,其特征在于:所述超声处理得到纳米ZnO乳液,超声处理时间为30min~35min。
8.如权利要求6或7所述纺织品远红外整理剂的制备方法,其特征在于:所述超声处理,超声频率为25KHz,超声功率为600W。
9.如权利要求5所述纺织品远红外整理剂的制备方法,其特征在于:所述机械搅拌处理后得织物远红外整理剂,机械搅拌时间为28~32min,机械搅拌转速为100~120rpm,机械搅拌处理温度为30~35℃。
10.如权利要求9所述纺织品远红外整理剂的制备方法,其特征在于:所述机械搅拌处理时间为30min,所述机械搅拌转速为100rpm,所述机械搅拌处理温度为30℃。
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