CN109518061A - A kind of corrosion-resistant metal alloys material and its production method - Google Patents

A kind of corrosion-resistant metal alloys material and its production method Download PDF

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Publication number
CN109518061A
CN109518061A CN201811261493.9A CN201811261493A CN109518061A CN 109518061 A CN109518061 A CN 109518061A CN 201811261493 A CN201811261493 A CN 201811261493A CN 109518061 A CN109518061 A CN 109518061A
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China
Prior art keywords
parts
corrosion
metal alloys
resistant metal
silicon dioxide
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CN201811261493.9A
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Chinese (zh)
Inventor
姚成立
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Anhui Haili Machinery Manufacturing Co Ltd
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Anhui Haili Machinery Manufacturing Co Ltd
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Application filed by Anhui Haili Machinery Manufacturing Co Ltd filed Critical Anhui Haili Machinery Manufacturing Co Ltd
Priority to CN201811261493.9A priority Critical patent/CN109518061A/en
Publication of CN109518061A publication Critical patent/CN109518061A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • C22C30/02Alloys containing less than 50% by weight of each constituent containing copper
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C30/00Alloys containing less than 50% by weight of each constituent
    • C22C30/06Alloys containing less than 50% by weight of each constituent containing zinc
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0005Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with at least one oxide and at least one of carbides, nitrides, borides or silicides as the main non-metallic constituents
    • CCHEMISTRY; METALLURGY
    • C22METALLURGY; FERROUS OR NON-FERROUS ALLOYS; TREATMENT OF ALLOYS OR NON-FERROUS METALS
    • C22CALLOYS
    • C22C32/00Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ
    • C22C32/0094Non-ferrous alloys containing at least 5% by weight but less than 50% by weight of oxides, carbides, borides, nitrides, silicides or other metal compounds, e.g. oxynitrides, sulfides, whether added as such or formed in situ with organic materials as the main non-metallic constituent, e.g. resin

Abstract

The invention discloses a kind of corrosion-resistant metal alloys material and its production methods, are made of the raw material of following parts by weight: 18-26 parts of iron, 12-18 parts of copper, 6-12 parts of aluminium, 6-10 parts of magnesium, 10-14 parts of zinc, 8-13 parts of sodium, 7-13 parts of manganese, 8-14 parts of zirconium, 4-9 parts of nickel, 3-7 parts of titanium oxide powder, 6-11 parts of silicon dioxide powder, 3-8 parts of thorium, 5-10 parts of epoxy resin, 4-8 parts of silyl ether, 3-7 parts of antioxidant, 5-10 parts of silver, 7-13 parts of boron nitride;A kind of corrosion-resistant metal alloys material of the present invention, by various metals material, melting is mixed at high temperature, alloy material obtained, it can be applied to machine components manufacturing field, obtained part is particularly suitable for working in acid or alkali environment, such as in seawater, the service life is long.

Description

A kind of corrosion-resistant metal alloys material and its production method
Technical field
The invention belongs to hydraulic drive fields, and in particular to a kind of corrosion-resistant metal alloys material and its production method.
Background technique
Alloy material is by two or more metal and metal or nonmetallic synthesized tool by certain methods There is the substance of metallic character, uniform liquid solidification is obtained by melting and is obtained, according to the number of component, is divided into binary conjunction Gold, ternary alloy three-partalloy, multicomponent alloy, alloy are even macroscopic, the multiple elements chemical substance containing metallic element, generally have metal special Property, any element, which can be used, makees alloying element, and what is be largely added is still that component alloy is most basic, independent urstoff, closes The structure and property of constituent play the role of the performance of alloy conclusive in gold, meanwhile, variation, that is, alloy of alloy structure Middle relative populations, the size of crystal grain, the variation of character and distribution have very big influence to the metallicity of alloy, therefore, benefit With the combination of various elements to form a variety of different alloy phases, it can satisfy different practical need using suitable processing It asks.
Alloy is relative to single metal product, and there are many natural advantages, and than great, plasticity is strong etc., it is existing some Alloy product, intensity is relatively low, and manufacturing process is complicated, and finished product is expensive, is unfavorable for promoting the use of on a large scale, some Intensity height, good corrosion resistance, good mechanical property alloy material, be only used for single special dimension, versatility is poor.
Summary of the invention
The purpose of the present invention is to solve the above-mentioned problems, provides a kind of corrosion-resistant metal alloys material.
To achieve the goals above, the present invention is achieved by the following technical solutions: a kind of corrosion-resistant metal alloys material Material forms: 18-26 parts of iron, 12-18 parts of copper, 6-12 parts of aluminium, 6-10 parts of magnesium, zinc 10-14 according to the parts by weight of following raw material Part, 8-13 parts of sodium, 7-13 parts of manganese, 8-14 parts of zirconium, 4-9 parts of nickel, 3-7 parts of titanium oxide powder, 6-11 parts of silicon dioxide powder, 3-8 parts of thorium, 5-10 parts of epoxy resin, 4-8 parts of silyl ether, 3-7 parts of antioxidant, 5-10 parts of silver, 7-13 parts of boron nitride.
Further, a kind of corrosion-resistant metal alloys material forms: iron 20-23 according to the parts by weight of following raw material Part, 14-16 parts of copper, 8-11 parts of aluminium, 7-9 parts of magnesium, 11-13 parts of zinc, 9-12 parts of sodium, 8-11 parts of manganese, 9-11 parts of zirconium, 5-7 parts of nickel, oxygen Change titanium valve 4-6 parts, 7-10 parts of silicon dioxide powder, 4-7 parts of thorium, 6-9 parts of epoxy resin, 5-7 parts of silyl ether, antioxidant 4-6 Part, 6-9 parts of silver, 9-11 parts of boron nitride.
Further, a kind of corrosion-resistant metal alloys material is formed according to the parts by weight of following raw material: 22 parts of iron, 15 parts of copper, 10 parts of aluminium, 8 parts of magnesium, 12 parts of zinc, 11 parts of sodium, 9 parts of manganese, 10 parts of zirconium, 6 parts of nickel, 5 parts of titanium oxide powder, silicon dioxide powder 8 Part, 6 parts of thorium, 7 parts of epoxy resin, 6 parts of silyl ether, 5 parts of antioxidant, 7 parts, 10 parts of boron nitride of silver.
Further, a kind of corrosion-resistant metal alloys material, the titanium oxide powder, silicon dioxide powder cross 80 meshes.
Further, a kind of production method of corrosion-resistant metal alloys material, includes the following steps: the ratio Iron, copper, aluminium, magnesium, zinc, sodium, manganese, zirconium, nickel are put into boiler, are heated to 1700-1800 DEG C, melt it sufficiently, keep 15- 25min is cooled to 1000-1200 DEG C, and titanium oxide powder, silicon dioxide powder, thorium, silver, the boron nitride of corresponding ratio is added, keeps its complete Full-fusing keeps 10-15min, then is cooled to 400-600 DEG C, and epoxy resin, silyl ether, the antioxygen of corresponding ratio is added Agent, sufficiently merge, obtain fusant, be poured into mold to get.
In summary the invention has the following advantages: corrosion-resistant metal alloys material prepared by the present invention, mechanical Intensity is high, performance is good, has good physics, chemical attribute, and performance is stablized, and fusing point is low, and good fluidity, shrinkage is small, crystal grain Tiny, toughness is good, soft or hard to be suitable for, and surface is smooth clean and tidy, does not have sand hole, without crackle, there is good corrosion resistance, energy Enough use for a long time are in acid or alkali environment, and such as seawater, and easy processing, durability height, use scope are wide, are able to bear biggish Load, machinability is good, can be applied to the fields such as shipbuilding.
Specific embodiment
Specific embodiment 1: a kind of corrosion-resistant metal alloys material forms: iron 18 according to the parts by weight of following raw material Part, 12 parts of copper, 6 parts of aluminium, 6 parts of magnesium, 10 parts of zinc, 8 parts of sodium, 7 parts of manganese, 8 parts of zirconium, 4 parts of nickel, 3 parts of titanium oxide powder, silicon dioxide powder 6 Part, 3 parts of thorium, 5 parts of epoxy resin, 4 parts of silyl ether, 3 parts of antioxidant, 5 parts, 7 parts of boron nitride of silver.
Titanium oxide powder, silicon dioxide powder cross 80 meshes.
A kind of production method of corrosion-resistant metal alloys material are as follows: by the iron of the ratio, copper, aluminium, magnesium, zinc, sodium, manganese, Zirconium, nickel are put into boiler, are heated to 1700 DEG C, are melted it sufficiently, and 15min is kept, and are cooled to 1000 DEG C, and corresponding ratio is added Titanium oxide powder, silicon dioxide powder, thorium, silver, boron nitride, melt it completely, keep 10min, then be cooled to 400 DEG C, be added Epoxy resin, silyl ether, the antioxidant of corresponding ratio sufficiently merge, obtain fusant, be poured into mold to get.
Specific embodiment 2: a kind of corrosion-resistant metal alloys material is formed according to the parts by weight of following raw material: 22 parts of iron, 15 parts of copper, 10 parts of aluminium, 8 parts of magnesium, 12 parts of zinc, 11 parts of sodium, 9 parts of manganese, 10 parts of zirconium, 6 parts of nickel, 5 parts of titanium oxide powder, silicon dioxide powder 8 Part, 6 parts of thorium, 7 parts of epoxy resin, 6 parts of silyl ether, 5 parts of antioxidant, 7 parts, 10 parts of boron nitride of silver.
Titanium oxide powder, silicon dioxide powder cross 80 meshes.
A kind of production method of corrosion-resistant metal alloys material are as follows: by the iron of the ratio, copper, aluminium, magnesium, zinc, sodium, manganese, Zirconium, nickel are put into boiler, are heated to 1750 DEG C, are melted it sufficiently, and 20min is kept, and are cooled to 1500 DEG C, and corresponding ratio is added Titanium oxide powder, silicon dioxide powder, thorium, silver, boron nitride, melt it completely, keep 13min, then be cooled to 500 DEG C, be added Epoxy resin, silyl ether, the antioxidant of corresponding ratio sufficiently merge, obtain fusant, be poured into mold to get.
Specific embodiment 3: a kind of corrosion-resistant metal alloys material is formed: 26 parts of iron, copper by the parts by weight of following raw material 18 parts, 12 parts of aluminium, 10 parts of magnesium, 14 parts of zinc, 13 parts of sodium, 13 parts of manganese, 14 parts of zirconium, 9 parts of nickel, 7 parts of titanium oxide powder, silicon dioxide powder 11 Part, 8 parts of thorium, 10 parts of epoxy resin, 8 parts of silyl ether, 7 parts of antioxidant, 10 parts, 13 parts of boron nitride of silver.
Titanium oxide powder, silicon dioxide powder cross 80 meshes.
A kind of production method of corrosion-resistant metal alloys material are as follows: by the iron of the ratio, copper, aluminium, magnesium, zinc, sodium, manganese, Zirconium, nickel are put into boiler, are heated to 1800 DEG C, are melted it sufficiently, and 25min is kept, and are cooled to 1200 DEG C, and corresponding ratio is added Titanium oxide powder, silicon dioxide powder, thorium, silver, boron nitride, melt it completely, keep 15min, then be cooled to 600 DEG C, be added Epoxy resin, silyl ether, the antioxidant of corresponding ratio sufficiently merge, obtain fusant, be poured into mold to get.
Embodiment provided above is better embodiment of the invention, only is used to facilitate to illustrate the present invention, not to this hair It is bright to make any form of restriction, any those of ordinary skill in the art, if not departing from the proposed skill of the present invention In the range of art feature, using the equivalent embodiment for locally changing or modifying made by disclosed technology contents, and Without departing from technical feature content of the invention, in the range of still falling within the technology of the present invention feature.

Claims (5)

1. a kind of corrosion-resistant metal alloys material, which is characterized in that be made of the raw material as follows according to parts by weight: 18-26 parts of iron, 12-18 parts of copper, 6-12 parts of aluminium, 6-10 parts of magnesium, 10-14 parts of zinc, 8-13 parts of sodium, 7-13 parts of manganese, 8-14 parts of zirconium, 4-9 parts of nickel, oxidation 3-7 parts of titanium valve, 6-11 parts of silicon dioxide powder, 3-8 parts of thorium, 5-10 parts of epoxy resin, 4-8 parts of silyl ether, antioxidant 3-7 Part, 5-10 parts of silver, 7-13 parts of boron nitride.
2. a kind of corrosion-resistant metal alloys material according to claim 1, which is characterized in that by as follows according to parts by weight Raw material composition: 20-23 parts of iron, 14-16 parts of copper, 8-11 parts of aluminium, 7-9 parts of magnesium, 11-13 parts of zinc, 9-12 parts of sodium, 8-11 parts of manganese, zirconium 9-11 parts, 5-7 parts of nickel, 4-6 parts of titanium oxide powder, 7-10 parts of silicon dioxide powder, 4-7 parts of thorium, 6-9 parts of epoxy resin, monosilane ether 5-7 parts of base, 4-6 parts of antioxidant, 6-9 parts of silver, 9-11 parts of boron nitride.
3. a kind of corrosion-resistant metal alloys material according to claim 2, which is characterized in that by as follows according to parts by weight Raw material composition: 22 parts of iron, 15 parts of copper, 10 parts of aluminium, 8 parts of magnesium, 12 parts of zinc, 11 parts of sodium, 9 parts of manganese, 10 parts of zirconium, 6 parts of nickel, titanium oxide powder 5 parts, 8 parts of silicon dioxide powder, 6 parts of thorium, 7 parts of epoxy resin, 6 parts of silyl ether, 5 parts of antioxidant, 7 parts, 10 parts of boron nitride of silver.
4. a kind of corrosion-resistant metal alloys material according to claim 1 to 3, which is characterized in that the titanium oxide Powder, silicon dioxide powder cross 80 meshes.
5. a kind of -3 any corrosion-resistant metal alloys material producing method according to claim 1, which is characterized in that including Following steps: the iron of the ratio, copper, aluminium, magnesium, zinc, sodium, manganese, zirconium, nickel being put into boiler, are heated to 1700-1800 DEG C, It melts it sufficiently, keeps 15-25min, be cooled to 1000-1200 DEG C, titanium oxide powder, the silica of corresponding ratio is added Powder, thorium, silver, boron nitride, melt it completely, keep 10-15min, then be cooled to 400-600 DEG C, and the ring of corresponding ratio is added Oxygen resin, silyl ether, antioxidant, sufficiently merge, obtain fusant, be poured into mold to get.
CN201811261493.9A 2018-10-26 2018-10-26 A kind of corrosion-resistant metal alloys material and its production method Withdrawn CN109518061A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111243846A (en) * 2020-01-19 2020-06-05 北京工业大学 Method capable of simultaneously improving oxidation corrosion resistance of NdFeB powder and magnet
CN112008072A (en) * 2019-07-13 2020-12-01 安徽中弘鑫源机械制造股份有限公司 Intercooler air inlet pipe material and preparation method thereof
CN112251624A (en) * 2020-10-22 2021-01-22 广东顺博铝合金有限公司 Corrosion-resistant aluminum alloy material and preparation method thereof

Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN112008072A (en) * 2019-07-13 2020-12-01 安徽中弘鑫源机械制造股份有限公司 Intercooler air inlet pipe material and preparation method thereof
CN111243846A (en) * 2020-01-19 2020-06-05 北京工业大学 Method capable of simultaneously improving oxidation corrosion resistance of NdFeB powder and magnet
CN111243846B (en) * 2020-01-19 2021-12-24 北京工业大学 Method capable of simultaneously improving oxidation corrosion resistance of NdFeB powder and magnet
CN112251624A (en) * 2020-10-22 2021-01-22 广东顺博铝合金有限公司 Corrosion-resistant aluminum alloy material and preparation method thereof

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Application publication date: 20190326