CN109511666A - Plant growth regualting composition and its application as plant growth regulator - Google Patents

Plant growth regualting composition and its application as plant growth regulator Download PDF

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Publication number
CN109511666A
CN109511666A CN201811521180.2A CN201811521180A CN109511666A CN 109511666 A CN109511666 A CN 109511666A CN 201811521180 A CN201811521180 A CN 201811521180A CN 109511666 A CN109511666 A CN 109511666A
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plant growth
composition
snacethyl
trinexan
iron
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陈黎明
王乐天
郭素春
任勇
王迎春
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NANJING BAITE BIOTECHNOLOGICAL ENGINEERING Co Ltd
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NANJING BAITE BIOTECHNOLOGICAL ENGINEERING Co Ltd
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/90Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having two or more relevant hetero rings, condensed among themselves or with a common carbocyclic ring system
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/12Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing the group, wherein Cn means a carbon skeleton not containing a ring; Thio analogues thereof
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N37/00Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids
    • A01N37/42Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom having three bonds to hetero atoms with at the most two bonds to halogen, e.g. carboxylic acids containing within the same carbon skeleton a carboxylic group or a thio analogue, or a derivative thereof, and a carbon atom having only two bonds to hetero atoms with at the most one bond to halogen, e.g. keto-carboxylic acids

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention provides a kind of plant growth regualting composition, it includes the first active component and the second active component, first active component is chlorin iron, second active component selects TrinexAN_SNacethyl or diethyl aminoethyl hexanoate, in the composition, the content of chlorin iron and TrinexAN_SNacethyl ratio is 1:20~10:1, and the content ratio of chlorin iron and diethyl aminoethyl hexanoate is 1:20~10:1.The preparation dosage form of this composition is soluble powder, water dispersible granules, wettable powder, aqua or soluble liquid.The present invention, which gives application of the composition as plant growth regulator, TrinexAN_SNacethyl or diethyl aminoethyl hexanoate and chlorin iron compounded combination, has the function of synergy, has expanded chlorin iron in the application in plant growth regulator field.

Description

Plant growth regualting composition and its application as plant growth regulator
Technical field
The invention belongs to agriculturally useful compositions technical fields, are related to a kind of plant growth regualting composition, in particular to a kind of The plant growth regualting composition of the iron containing chlorin.The present invention gives this composition as plant growth regulator Using.
Background technique
Life in growing process, as the nutrients such as micro physiological activator and sunlight, temperature, moisture to plant Length plays an important role, these trace active objects, and there play the role of to the growth and development for adjusting plant to be special.It is various endogenous micro- Amount active material is often referred to as plant hormone, such as auxin, gibberellin, the basic element of cell division, rather than endogenic additional activity Substance is then referred to as plant growth regulator.
The application of plant growth regulating substance is one of modern age plant physiology and agrotechnical major progress, although planting Object endogenous growth adjusts active material and shows strong activity at much lower concentrations (1 μm of ol/L of <), but its content is atomic, difficult To extract preparation, thus it is at high price, and therefore, the endogenic growth regulatory substance of non-plant becomes the emphasis of research.
Plant growth regulator have it is natural extract and artificial synthesized two major classes, answered currently, having to surpass hundred kinds of products and put goods on the market With, it has also become improve and improve agricultural output quality an important technology method (Fu Hualong etc., plant growth regulator Research and application, biological processing, 2008 (6) 4:7~12).Plant growth regulator generally have low concentration promote and it is high Concentration inhibits the characteristic of plant growth, and must can be brought into normal play effect with narrow dosage range use, this causes actually to answer With there are many restrictions and inconvenience;Plant endogenous sex hormone has natural metabolic pathway and mode, is not easy to put aside, with its phase Than, exogenous synthesis class plant growth regulator used at present, dosage higher concentration is bigger than normal and metabolic pathway is unclear, Chemical property is stablized, and the residual more or residual period is long, and with the continuous expansion of application range, residue problem has caused people's Pay much attention to (Zhao Min etc., safety of the plant growth regulator to crops and environment, environment and health magazine, 2007 (24) 5:370~372), China it has been specified that, any pollution-free food production process, the form for not being able to fertilizer and pesticide uses (People's Republic of China's agricultural industry criteria NY-T393-2000 green food pesticide makes chemically synthesized plant growth regulator Use criterion;NY-T394-2000 green food Fertilizer application criterion).Research, exploitation dosage is small, property is stable, easy to use Plant growth regulator has become the development trend in the field, and nontoxic, without side-effects and do not influence plant eubolism approach Highly effective and safe product with mode is the priority and difficulty of plant growth regulator research.
Chlorin iron has excellent plant growth regulating activity, and has apparent external chlorophyllase suppression in vivo Production is used.Chemical structure and its work of the applicant in patent applied for CN102285992B, to chlorin iron It has been described later in detail for plant growth regulating activity ingredient in application.Chlorin iron, that is, patent of present patent application Chlorin iron in CN102285992B.
TrinexAN_SNacethyl is cyclohexane-carboxylic acid plant growth regulator, belongs to gibberellic acid synthetic inhibitor, red by reducing The content of mould acid, to control crop prosperous growth.TrinexAN_SNacethyl imposes on leaf portion, can be transferred on the branch of growth, reduces the elongation of internode. It is applied on cereal crop, sugarcane, rape, castor-oil plant, rice, sunflower and rye grass, can obviously inhibit to grow.In cereal Class crop, winter rape postemergence application can prevent the yield rate that lodges and improve.Currently, TrinexAN_SNacethyl is all individually to make on crop With preparation is also single dose, and preparation type is mostly missible oil, has used a large amount of toluene, dimethylbenzene, benzene and the difficult polarity decomposed organic Solvent etc., organic solvent used are larger to human body and environmental injury.In practical applications, TrinexAN_SNacethyl single dose shows as effect early period It is unobvious.
Diethyl aminoethyl hexanoate, chemical name: diethylamino ethanol caproate is American scientist in the latest find nineties, is had The high energy plant growth regulator of wide spectrum and breakthrough effect.Diethyl aminoethyl hexanoate can improve plant inner chlorophyll, protein, nucleic acid and contain Amount improves light and rate, improves the vigor of peroxidase and nitrate reductase, improves the metabolism of plant carbon, nitrogen, enhances plant Absorption to water, fertilizer adjusts the balance of plant internal water, to improve the drought resisting of plant, winter resistance.Physiological performance is to promote Cell division and elongation, growth, the differentiation of tachyauxesis point promote germination, promote tiller and branch, promote root system development And bud differentiation, delay plant senesecence, budding bloom ahead of time, improve fruit-setting rate, promote early ripening of the crops, improves crop yield, changes Kind crop quality.After existing diethyl aminoethyl hexanoate is all machined to diethyl aminoethyl hexanoate citrate in actual use as plant growth regulator Various dosage forms are reprocessed into, main dosage form is that diethyl aminoethyl hexanoate citrate wettable powder product and diethyl aminoethyl hexanoate citrate aqua produce Product.But diethyl aminoethyl hexanoate citrate wants high with respect to diethyl aminoethyl hexanoate in processing cost, and diethyl aminoethyl hexanoate citrate wettable powder is to packet Material requirement is stringenter, if the improper easy moisture absorption agglomeration of selection is to influence to use.
Summary of the invention
The technical problem to be solved in the present invention: chlorin iron is as a kind of plant growth tune with novel mechanism of action Active constituent is saved, application study also predominantly stays in the experimental study stage.Based on this, in order to promote chlorin iron in agricultural Application on industry field, in conjunction with the verification experimental verification data of early period, the present invention is by chlorin iron and common plant growth regulator Compounding, provide a kind of plant growth regualting composition of iron containing chlorin.
To achieve the goals above, the invention adopts the following technical scheme:
A kind of plant growth regualting composition of the iron containing chlorin comprising the first active component and the second active group Point, first active component is chlorin iron, and second active component selects TrinexAN_SNacethyl or diethyl aminoethyl hexanoate, in the combination In object, the content ratio of chlorin iron and TrinexAN_SNacethyl is 1:20~10:1, and the content ratio of chlorin iron and diethyl aminoethyl hexanoate is 1:20 ~10:1.
The plant growth regualting composition of the iron containing chlorin can be prepared into convenient for applying in agriculture and forestry field Any dosage form.In view of chlorin iron, TrinexAN_SNacethyl, the physicochemical property of diethyl aminoethyl hexanoate and corresponding preparations dosage form use just Benefit, it is preferable that the preparation dosage form of the composition is soluble powder, water dispersible granules, wettable powder, aqua or solvable Property liquor.
When preparing aqua or soluble liquid, those of ordinary skill in the art, which are very familiar with, completes this using corresponding auxiliary agent Invention, the auxiliary agent of selection can illustrate are as follows: emulsifier such as calcium dodecyl benzene sulfonate (agriculture breast 500#), Nongru-700 # (common name: Alkyl phenol formaldehyde resin polyoxyethylene ether), agriculture breast 2201#, this disk -60# (common name: Span60), tween - 60# (common name: polyoxyethylene sorbitan stearate), TX-10 (common name: octylphenol polyethylene ethylene oxide (10) ether), agriculture Newborn 1601# (common name: triphenoethyl benzene phenol polyoxyethylene polyoxypropylene block polymer), agriculture breast 600#, one in agriculture breast 400# Kind is a variety of;It is solvent such as methanol, dimethylformamide, N-Methyl pyrrolidone, cyclohexanone, acetone, a kind of in dimethyl sulfoxide Or it is a variety of.
When preparing water dispersible granules, the auxiliary agent that those of ordinary skill in the art select can illustrate are as follows: for example poly- carboxylic of dispersing agent It is hydrochlorate, lignosulfonates, one or more in alkylnaphthalene sulfonate;Wetting agent such as alkyl sulfate, alkylsulfonate, naphthalene sulphur It is one or more in hydrochlorate;It is disintegrating agent such as ammonium sulfate, urea, sucrose, one or more in glucose;Binder such as diatomite, One of cornstarch, PVA, carboxymethyl (ethyl) cellulose family are a variety of;Filler such as diatomite, kaolin, white carbon black, light Calcium, talcum powder, attapulgite, clay are one or more.
When preparing wettable powder or soluble powder, the auxiliary agent that those of ordinary skill in the art select can illustrate are as follows: It is dispersing agent such as polycarboxylate, lignosulfonates, one or more in alkylnaphthalene sulfonate;Wetting agent such as alkyl sulfate, alkane It is one or more in base sulfonate, naphthalene sulfonate;Filler such as ammonium sulfate, urea, sucrose, glucose, diatomite, kaolin, white Carbon black, light calcium, talcum powder, attapulgite, clay are one or more.
On the other hand, the present invention gives the plant growth regualting composition answering as plant growth regulator With.
Preferred, the plant growth regulating work of the composition is applied in terms of plant growth regulating as the composition Property group be divided into chlorin iron and TrinexAN_SNacethyl, the composition is configured to solution use, in the solution, chlorin iron Concentration is 0.05~0.5mg/L, and the concentration of TrinexAN_SNacethyl is 0.01~10mg/L.
Preferred, the plant growth regulating work of the composition is applied in terms of plant growth regulating as the composition Property group be divided into chlorin iron and diethyl aminoethyl hexanoate, the composition is configured to solution use, in the solution, chlorin iron Concentration is 0.01~0.5mg/L, and the concentration of diethyl aminoethyl hexanoate is 0.01~10mg/L.
The plant growth regualting composition of the iron of the present invention containing chlorin and its in plant growth regulating field Using, at least have it is following the utility model has the advantages that
1) chlorin iron of the invention is environmentally protective, easily by plant catabolism, no people and animals' toxicity, and the low dosage of dosage It is few, it selects the plant growth regulating activities such as TrinexAN_SNacethyl or diethyl aminoethyl hexanoate ingredient as chlorin iron compounded combination ingredient, tests number According to showing that it has the function of synergy, chlorin iron has been expanded in the application in plant growth regulator field.
2) inventor passes through largely deep theory and experimental study discovery, the plant growth tune of the iron containing chlorin Section composition activity is strong, effect is good, and effect propety is wide, such as can be improved crop yield, improves crop quality.
Specific embodiment
Purpose, technical solution and its effect to facilitate the understanding of the present invention, now will in conjunction with the embodiments to the present invention do into One step elaborates.
(1) example of formulations
Example of formulations 1
The formula composition of 22% chlorin iron TrinexAN_SNacethyl aqua: 2% chlorin iron, 20% TrinexAN_SNacethyl, 1.5% ten Sodium dialkyl sulfate, 2% styrene phenol polyoxyethylene ether, 8% ethyl alcohol, deionized water are mended to 100%.Above-mentioned material is according to right Answer ratio uniformly mixed in kettle in being mixed, obtaining active constituent content is 22% chlorin iron TrinexAN_SNacethyl aqua.
Example of formulations 2
The formula composition of 6% chlorin iron TrinexAN_SNacethyl soluble liquid: 1% chlorin iron, 5% TrinexAN_SNacethyl, 2% Cyclohexanone, 2% dimethylformamide, 2% agriculture breast 600#, 4% ethyl alcohol, deionized water are mended to 100%.Above-mentioned material is according to correspondence Ratio is uniformly mixed in kettle in being mixed, and obtaining active constituent content is 6% chlorin iron TrinexAN_SNacethyl solubility liquid Agent.
Example of formulations 3
The formula composition of 2% chlorin iron diethyl aminoethyl hexanoate aqua: 0.5% chlorin iron, 1.5% diethyl aminoethyl hexanoate, 4% nitre Sour ammonium, 4%TX-10#, 2% styrene phenol polyoxyethylene ether, deionized water are mended to 100%.Above-mentioned material is according to corresponding ratio It is uniformly mixed in being mixed in kettle, obtaining active constituent content is 2% chlorin iron diethyl aminoethyl hexanoate aqua.
Example of formulations 4
The formula composition of 20% chlorin iron diethyl aminoethyl hexanoate wettable powder: 5% chlorin iron, 15% diethyl aminoethyl hexanoate, 10% potassium nitrate, 3% lauryl sodium sulfate, 3% alkylsulfonate, 8% white carbon black, 5% diatomite, kaolin mend to 100%.By above-mentioned material according in corresponding ratio investment double spiral agitator, it is crushed to after mixing by airslide disintegrating mill 500 mesh, it is 20% chlorin iron diethyl aminoethyl hexanoate wettable powder that active constituent content, which is made,.
Example of formulations 5
The formula composition of 46% chlorin iron diethyl aminoethyl hexanoate water dispersible granules: 6% chlorin iron, 40% diethyl aminoethyl hexanoate, 5% calcium chloride, 1% PA 800K, 2% polycarboxylate, 3% naphthalene sulfonate, 2% alkylsulfonate, 5% cornstarch, calcining Kaolin complements to 100%.By above-mentioned material according in corresponding ratio investment double spiral agitator, pass through air-flow after mixing Pulverizer is crushed to 800 mesh, after smashed material is uniformly mixed with 11% deionized water of its weight, by squeeze make Grain, screening, it is 46% chlorin iron diethyl aminoethyl hexanoate water dispersible granules that active constituent content, which is made,.
(2) pharmacodynamic test embodiment
Test examples 1
The present embodiment provides that wheat is resistant to lodging, simulation experiments.It is experimental field arranged in Shaanxi Province Weinan city Linwei district, experimental field Soil fertility is uniform, topsoil soils organic matter be 16.3mg/kg, full nitrogen 85mg/kg, rapid available phosphorus 28mg/kg, available potassium 180mg/kg, Preceding stubble is summer corn.Mechanical planting on October 12nd, 2016 (western 979 seed of agriculture is purchased from local market), mu application rate is 12kg. In mid-March, 2017 carries out spring irrigation, big bell mouth stage foliage-spray medicament.Medicament sprayed dose is shown in Table 1-3.Test is using random District's groups arrangement, every cell 30m2, every processing is repeated 4 times.Maturity period harvest, measures yield, result is as shown in following table 1-3.
Table 1 sprays influence of the different plant growth regulator to Plant Height in Wheat
Table 1 is the results show that compared with clear water control, and under 0.01~0.5mg/L dosage, spraying chlorin iron single dose can There is certain inhibiting effect to Plant Height in Wheat, to the dwarfing effect of Plant Height in Wheat not as good as TrinexAN_SNacethyl or diethyl aminoethyl hexanoate;But dihydro Porphines iron is used in compounding with TrinexAN_SNacethyl or diethyl aminoethyl hexanoate, is significantly improved to the dwarfing effect of Plant Height in Wheat.In addition, being tried from field The Appearance View tested is watched, and chlorin iron is used in compounding that may advantageously facilitate wheat plant stalk sturdy with TrinexAN_SNacethyl or diethyl aminoethyl hexanoate, And have no that wheat plant lodges;The Plant Height in Wheat of clear water control group is relatively high, and has the lodging of part wheat plant.
Table 2 sprays influence of the different plant growth regulator to wheat grains per spike and mass of 1000 kernel
The investigation that spraying different plant growth regulator influences wheat grains per spike and mass of 1000 kernel the results are shown in Table 2.2 result of table It has been shown that, compared with clear water control, different plant growth regulator are applied under setting dosage, the different degrees of raising wheat of energy Grain number per spike and mass of 1000 kernel;But chlorin iron is used in compounding with TrinexAN_SNacethyl or diethyl aminoethyl hexanoate, is increased wheat grains per spike and mass of 1000 kernel Influence it is particularly evident, illustrate that chlorin iron is used in compounding with TrinexAN_SNacethyl or diethyl aminoethyl hexanoate, be conducive to nutriment lodge in it is small In wheat seed.
Table 3 sprays evaluation of the different plant growth regulator to wheat increase yield effect
It sprays different plant growth regulator and 3 the results are shown in Table to the investigation of wheat per mu yield.Table 3 is the results show that and clear water Control is compared, and different plant growth regulator are applied under setting dosage, the different degrees of raising wheat yield of energy;But dihydro Porphines iron is used in compounding with TrinexAN_SNacethyl or diethyl aminoethyl hexanoate, and it is more significant to promote effect to wheat yield.
It is comprehensive by table 1-3 it is found that chlorin iron and TrinexAN_SNacethyl, diethyl aminoethyl hexanoate are compounded in ratio listed in upper table, compared to Single dose can reduce Plant Height in Wheat, improve lodging tolerance, and dramatically increase grain number per spike and mass of 1000 kernel, improves wheat yield, obtains Obtained synergistic effect.
Test examples 2
The present embodiment provides Chinese cabbage and adjusts growth test.Breeds of Chinese cabbage is SUZHOUQING(sic).Test method uses growth of seedling Method.It selects Chinese cabbage seeds of the same size to dial in respectively in the culture dish for the 9cm size for being covered with two layers of filter paper, 20, every ware, 2 wares of every processing, are added configured medical fluid 1.5ml, and control plus distilled water, every processing are repeated 4 times.Ware lid is covered, is placed into 28 ± 1 DEG C of phjytotron investigates germination percentage after illumination 10 hours, 3 days, measure that seedling is long and root long after 6 days, calculate germination percentage and Growth rate.Test result is as shown in the following table 4 and 5.
4 Chinese cabbage seeds germination percentage measurement result of table
Table 4 the results show that compared with clear water control, apply under setting dosage, can not by different plant growth regulator With the raising Chinese cabbage seeds germination percentage of degree, wherein chlorin iron is used in compounding with TrinexAN_SNacethyl or diethyl aminoethyl hexanoate, to Chinese cabbage The influence that percentage of seedgermination improves is especially pronounced.
Influence of the different plant growth regulator of table 5 to Chinese cabbage nutrient growth (seedling is long)
Influence (root long) of the different plant growth regulator of table 6 to Chinese cabbage nutrient growth
Table 5 and table 6 are the results show that compared with clear water control, and different plant growth regulator are applied under setting dosage, The growth of promotion Chinese cabbage that can be different degrees of, wherein chlorin iron is used in compounding with TrinexAN_SNacethyl or diethyl aminoethyl hexanoate, can be significant Promote the growth of Chinese cabbage root leaf.
Consolidated statement 4 and 5 is it is found that chlorin iron and TrinexAN_SNacethyl, diethyl aminoethyl hexanoate are compounded in ratio listed in upper table, compared to list Agent can more promote the growth and development of Chinese cabbage, improve germination percentage, improve seedling length and root long, obtain synergistic effect.
Further narration is done to the present invention above in conjunction with embodiment, but present invention is not limited to the embodiments described above, Within the knowledge of one of ordinary skill in the art, it can also make without departing from the purpose of the present invention Various change.

Claims (6)

1. a kind of plant growth regualting composition, which is characterized in that including the first active component and the second active component, described One active component is chlorin iron, and second active component selects TrinexAN_SNacethyl or diethyl aminoethyl hexanoate, in the composition, dihydro The content of porphines iron and TrinexAN_SNacethyl ratio is 1:20~10:1, and the content ratio of chlorin iron and diethyl aminoethyl hexanoate is 1:20~10:1.
2. plant growth regualting composition according to claim 1, which is characterized in that the preparation dosage form of the composition is can Soluble powder, water dispersible granules, wettable powder, aqua or soluble liquid.
3. application of the plant growth regualting composition described in claim 1 as plant growth regulator.
4. application of the composition as plant growth regulator according to claim 3, which is characterized in that the composition Plant growth regulating activity group is divided into chlorin iron and TrinexAN_SNacethyl, and the composition is configured to solution use, in the solution In, the concentration of chlorin iron is 0.05~0.5mg/L, and the concentration of TrinexAN_SNacethyl is 0.01~10mg/L.
5. application of the composition as plant growth regulator according to claim 3, which is characterized in that the composition Plant growth regulating activity group is divided into chlorin iron and diethyl aminoethyl hexanoate, and the composition is configured to solution use, in the solution In, the concentration of chlorin iron is 0.01~0.5mg/L, and the concentration of diethyl aminoethyl hexanoate is 0.01~10mg/L.
6. application of the composition as plant growth regulator according to claim 3, the composition for adjust wheat, The growth of Chinese cabbage.
CN201811521180.2A 2018-12-12 2018-12-12 Plant growth regualting composition and its application as plant growth regulator Pending CN109511666A (en)

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CN110839642A (en) * 2019-11-04 2020-02-28 南京百特生物工程有限公司 Plant growth regulating composition containing chlorin iron and application thereof
CN111194748A (en) * 2020-01-14 2020-05-26 南京百特生物工程有限公司 Composition for preparing plant growth regulator, plant growth regulator and preparation method and application thereof
CN111248217A (en) * 2020-03-29 2020-06-09 邢宇俊 Plant growth regulator composition containing chlorin iron and thidiazuron
CN113853872A (en) * 2021-09-29 2021-12-31 江苏省农业科学院 Method for promoting rice seed germination and seedling growth by utilizing chlorin iron

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Publication number Priority date Publication date Assignee Title
CN110839642A (en) * 2019-11-04 2020-02-28 南京百特生物工程有限公司 Plant growth regulating composition containing chlorin iron and application thereof
CN111194748A (en) * 2020-01-14 2020-05-26 南京百特生物工程有限公司 Composition for preparing plant growth regulator, plant growth regulator and preparation method and application thereof
CN111248217A (en) * 2020-03-29 2020-06-09 邢宇俊 Plant growth regulator composition containing chlorin iron and thidiazuron
CN113853872A (en) * 2021-09-29 2021-12-31 江苏省农业科学院 Method for promoting rice seed germination and seedling growth by utilizing chlorin iron

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