CN1095085A - Ice-soluble paraffin wax brightening agent - Google Patents
Ice-soluble paraffin wax brightening agent Download PDFInfo
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- CN1095085A CN1095085A CN 93104798 CN93104798A CN1095085A CN 1095085 A CN1095085 A CN 1095085A CN 93104798 CN93104798 CN 93104798 CN 93104798 A CN93104798 A CN 93104798A CN 1095085 A CN1095085 A CN 1095085A
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Abstract
A kind of ice-soluble paraffin wax brightening agent is by paraffin, contain aluminium anionic emulsifier, wetting ability and repellency nonionogenic tenside, silicone oil, silane, optical brightener, polymer emulsion, softening water etc. and form.Its adopts interpenetrating(polymer)networks (IPN) technology, in reactor, after heating, react, lowering the temperature, get final product this product.Can be widely used on furniture, household electrical appliances, automobile, building, leatherware, weaving, the human hair, and possess the equal above effect of organic solvent type polishing wax.Its production technique is simple, produce and non-environmental-pollution, non-corrosiveness, harmless when using this product, and raw material sources is extensive, and saves a large amount of organic solvents.
Description
The present invention relates to wax class water soluble dispersing agent.
Traditional emulsified olefin technology generally is that the softening water with 70-90 ℃ of heat temperature is a medium, and paraffin is made emulsified olefin with the anionic emulsifier (wherein containing a spot of oleic acid or grease and organic solvent) that stearic acid and sodium hydroxide reaction produce.It is a kind of oil-in-water structure of soap bag wax pattern.Product only is used for textile finishing, can not also be unsuitable for the modern textile thing as brightening agent.
During the eighties, " Cheng Shuxi is for two " of Japan adopt the mixing method that does not contain organic solvent to make the water-soluble constituent of paraffin, it is mainly by anion active agents such as paraffin, petroleum resin, dispersion agent sodium oleate, sodium stearate, Voranol EP 2001 nonionic activator, and composition such as polyvinyl alcohol, its technology is in the container of sealing, temperature be 100 ℃ mixing, and pressurization is mediated, and reaction product is an emulsion oil-in-water.It also is only to be used to do water-resisting agent, insulating compound, and film forming agent can not be as brightening agent.
The object of the present invention is to provide a kind of ice-soluble paraffin wax brightening agent, it be a kind of do not contain organic solvent can be as the water soluble wax class of brightening agent light cream.
Another object of the present invention is to provide a kind of production method of ice-soluble paraffin wax brightening agent.
Technical scheme of the present invention realizes as follows:
Raw material of the present invention is that wax class, dispersion agent class have nonionogenic tenside that contains aluminium anionic emulsifier, wetting ability and repellency etc.Scold the anti-liniment of water that silicone oil and silane derivative are arranged.Optical brightener and polymer emulsion, compositions such as sanitas, frostproofer, softening water, alkali formula essence; The per-cent of its formulation weight is:
Wax: 8-11% contains aluminium anionic emulsifier: 8-11%
Hydrophilic non-ionic surfactant: 0.3-0.8%
Repellency nonionogenic tenside: 0.3-0.8%
Silicone oil 0.3-0.8% silane derivative: 0.3-0.8%
Optical brightener: 0.4-0.6% polymer emulsion: 0.6-1.4%
Sanitas: 0.1-0.15% frostproofer: 0.2-0.6%
Softening water: 48-66% alkali formula essence is an amount of
Wherein wax can be selected for use: paraffin, polyethylene wax, ceresine, beeswax, charcoal wax etc.
Contain the aluminium anionic emulsifier: in heat temperature softening water, react with two stearic hydroxyl aluminium by sodium hydroxide and form.
Hydrophilic non-ionic surfactant can be selected for use: polyxyethylated benzene, OP-7(ethoxylation monoalkyl phenol), the OP-10(polyoxyethylene nonylphenol ether), the El(polyoxyethylenated castor oil), DS-10(polyalkylene glycol monoalkyl ether), polyxyethylated phenylate etc.
The repellency nonionogenic tenside can be selected for use: sulfo-succinic acid dibutyl ester sodium, glyceryl stearate, Diethylene Glycol mono-laurate, diethylene glycol monostearate etc.
Silicone oil can be selected for use: the dimethyl-silicon wet goods.
The silane derivative class can be selected for use: alkyl trichlorosilane, aminosiloxane, methyl-monosilane etc.
Optical brightener can be selected for use: sulfonated fatty acid alkyl ester, toluol sulfonamide, orthotoluene sulfonamide, p-Xylol sulphonamide etc.
Polymer emulsion can be selected for use: Polyurethane emulsion, acrylonitrile emulsion, vinylformic acid vinylbenzene have light emulsion, chlorine that light emulsion etc. is arranged partially.
Technology characteristics of the present invention is to adopt interpenetrating polymer networks (IPN) technology.The nonionogenic tenside of wax, silicone oil, silane, caustic lye of soda, wetting ability and the repellency of above-mentioned formula ratio and the softening water that accounts for formula ratio 25% are entered the enamel reaction still that has return channel and agitating vane, begin when being warmed up to 70 ℃ to stir, be warmed up to 90 ℃ again, reacted about 30 minutes, this moment, reaction was the pre-emulsion reaction of above reactant; Because of its product particle diameter is also very thick, also claim the gala reactant.
Again two stearic acid hydroxyl aluminium are entered reactor with 20 fens clock times with the technology that is sprinkled into approximately, be warming up to 95-100 ℃, this moment, thicker state appearred in reactant, kept about 45 minutes, the reaction product in this stage is two stearic acid hydroxyl aluminium and sodium hydroxide reaction, the anion active agent of the water-containing type aluminium hydroxide that produces, and be combined into the structure of (IPN) with the nonionogenic tenside of wetting ability and repellency, form the blend micella, impel above half emulsification to become complete emulsification, reached the fineness requirement of brightening agent.
Again optical brightener and polymer emulsion and the softening water that accounts for formula ratio 25% are added reactor, reaction is about 20 minutes about 95 ℃, the reaction in this stage is things such as the aluminium hydroxide reaction in optical brightener and the above product, play enhanced shine, polymer emulsion can play the effect that helps dispersion, stablizes, helps light.
Repellency nonionogenic tenside and silicone oil, silane reaction, its function are to increase product scolding water, anti-wiping, refuse pickup etc. after application.Also have froth breaking, stabilization.
Last again the softening water of sanitas, frostproofer and surplus 50% is entered reactor, be cooled to 40 ℃ and enter alkali formula essence, promptly get product.
But another feature of the present invention is the production bulk product, and the softening water that is about to surplus 50% in the end operation stage does not enter, and makes product directly enter block packing.When the user uses, melt, can use after the cooling, can save Packing Fee in a large number like this, also be convenient to keeping with about 95 ℃ warm boiling water.
When using product of the present invention, it is clean that the face of will being embrocated is earlier wiped (washing) clearly, to local spot, can embrocate removing with this an amount of product earlier, treat clean, drying after, embrocate this product with banister brush again, should be even when embrocating, treat that moisture content is evaporated completely after, use clean cotton yarn (cloth) to polish again and get final product.
Advantage of the present invention is:
The present invention has the equal above effect with organic solvent type light cream, can save organic solvent in a large number.If in 60,000 tons of national market annual requirements, can save organic solvent (as: kerosene, 200 every year
#Solvent oil) 4.2 ten thousand ton.
The present invention and polymer emulsion brightening agent ratio, have be widely used, cost is low, of high quality and at a reasonable price, that packing keeping is used is convenient.
The present invention is used for human hair, can reduce environmental pollution.(with solvent-borne type hair light cream ratio) protection hair, scalp.
The present invention is used for the yarn fabric finishing composition, can increase softness, anti-wrinkling, bright, scold performance such as water, adaptation modern needs.
Production technique of the present invention is simple, equipment requirements is general, produce and the equal non-environmental-pollution of product application, and the starting material wide material sources, product is nontoxic, free from extraneous odour, non-corrosiveness, and is safe in utilization, reliable.
Use range of the present invention is wide, and car, leatherware, furniture, building, yarn fabric etc. all can use.
Embodiment 1: automobile, aircraft, steamer multifunctional water-soluble paraffin light cream
Paraffin: 6% polyethylene wax: 4%
Dimethyl silicone oil: 1.2% METHYL TRICHLORO SILANE: 0.8%
Alkyl trichlorosilane: 0.4% caustic lye of soda (e) 12 milliliters of 10 ° of B '
Polyxyethylated benzene: 0.8% sulfo-succinic acid dibutyl ester sodium: 1.6%
Two stearic acid hydroxyl aluminium: 10% acrylonitrile emulsion: 4.1%
Sulfonated fatty acid alkyl ester: 0.6% sanitas: 0.1%
Frostproofer: 0.4% softening water: 50% alkali formula essence is an amount of
Embodiment 2: leather series multifunctional water-soluble paraffin light cream.
Paraffin: 6% beeswax: 0.4% ceresine: 3.6%
Dimethyl silicone oil: 1.2% aminosiloxane: 0.8%
(10 ° of B ' are 12 milliliters of op-7:0.6% e) for caustic lye of soda
Glyceryl stearate: 1% pair of stearic acid hydroxyl aluminium: 10%
Toluol sulfonamide: 0.8% acrylonitrile emulsion: 7.2%
Sanitas: 0.1% frostproofer: 0.4%
Softening water: 57% alkali formula essence is an amount of
Embodiment 3: furniture, household electrical appliances, bicycle use multifunctional water-soluble paraffin light quantity cream
Paraffin: 7% ceresine, 2.8% beeswax: 0.2%
Dimethyl silicone oil: 1% methyl-monosilane: 1%
(10 ° of B ' are 12 milliliters of OP-10:0.8% e) for sodium hydroxide
Diethylene Glycol mono-laurate: 0.8% stearic acid hydroxyl aluminium: 10%
Orthotoluene sulfonamide: 0.8% vinylformic acid styrene emulsion: 4.4%
Sanitas: 0.1% deicing fluid: 0.4% softening water: 57% alkali formula essence is an amount of
Embodiment 4: ice-soluble paraffin wax brightening agent for building.
Paraffin: 6% ceresine: 2% charcoal wax: 2%
Dimethyl silicone oil: 1.6% alkyl trichlorosilane: 4%
(10 ° of B ' are 12 milliliters of DS-10:0.6% e) for caustic lye of soda
Sodium docusate: 1.4% pair of stearic acid hydroxyl aluminium: 10%
The p-Xylol sulphonamide: 0.8% chlorine has the light emulsion partially: 4.6%
Sanitas: 0.1% frostproofer: 0.4%
Softening water: 58.1% alkali formula essence is an amount of
Embodiment 5: yarn fabric finishing composition multifunctional water-soluble paraffin light cream.
Paraffin: 6% ceresine: 4%
(10 ° of B ' are 12 milliliters of EL:0.8% e) for caustic lye of soda
Dimethyl silicone oil: 1.6% METHYL TRICHLORO SILANE: 0.8%
Aminosiloxane: 1.2% pair of stearic acid hydroxyl aluminium: 10%
Sulfonated fatty acid alkyl ester: 1% Polyurethane emulsion: 6.6%
Sanitas: 0.1% frostproofer: 0.4%
Softening water: 55.5% alkali formula essence is an amount of.
Embodiment 6: human hair multifunctional water-soluble paraffin light quantity cream.
Paraffin: 8% beeswax: 1% whiteruss: 3%
N-SMT salt: 1.5% hexadecanol: 5%
Caustic lye of soda: (10 ° of B ' are 12.6 milliliters of Zerols e): 10.5%
Ground walnut oil: 5.2% kojic acid: 4% antiseptic-germicide: 0.1%
Softening water: an amount of glycerine of 32% essence: 8%
Claims (9)
1, a kind of ice-soluble paraffin wax brightening agent, it is characterized in that: by wax, contain aluminium anionic emulsifier, wetting ability and repellency nonionogenic tenside, scold the water anti-wear agent, optical brightener, polymer emulsion, sanitas, frostproofer, softening water, alkali formula essence form, its weight percent is:
Wax: 8%～11% contains the aluminium anionic emulsifier: 8%～11%
Hydrophilic non-ionic surfactant: 0.3～8% repellency nonionogenic tenside: 0.3～0.8%
Silicone oil: 0.3～0.8% silane derivative: 0.3～0.8%
Optical brightener: 0.4～0.6% polymer emulsion: 0.6～1.4%
Sanitas: 0.1～0.15% frostproofer: 0.2～0.6%
Softening water: 48～66% alkali formula essence are an amount of
2, according to the multifunctional water-soluble paraffin light quantity cream of claim 1, it is characterized in that:
Wax can be selected for use: paraffin, polyethylene wax, beeswax, ceresine, charcoal wax.
Containing the aluminium anionic emulsifier selects for use: two stearic acid hydroxyl aluminium and sodium hydroxide;
Hydrophilic non-ionic surfactant can be selected for use: polyxyethylated benzene, OP-7(ethoxylation monoalkyl phenol), the OP-10(polyoxyethylene nonylphenol ether), the EL(polyoxyethylenated castor oil), DS-10(polyalkylene glycol monoalkyl ether), polyxyethylated phenylate.
The repellency nonionogenic tenside can be selected for use: sulfo-succinic acid dibutyl ester sodium, stearin, Diethylene Glycol mono-laurate, diethylene glycol monostearate.
Silicone oil can be selected for use: dimethyl silicone oil;
Silane derivative can be selected for use: alkyl trichlorosilane, aminosiloxane, methyl-monosilane;
Silicone oil can be selected for use: dimethyl silicone oil;
Silane derivative can be selected for use: alkyl trichlorosilane, aminosiloxane, methyl-monosilane;
Silicone oil can be selected for use: dimethyl silicone oil;
Silane derivative can be selected for use: alkyl trichlorosilane, aminosiloxane, methyl-monosilane;
Optical brightener can be selected for use: sulfonated fatty acid alkyl ester, toluol sulfonamide, orthotoluene sulfonamide, p-Xylol sulphonamide.Stirring polymer emulsion can select for use: Polyurethane emulsion, propionic acid nitrile emulsion, vinylformic acid styrene emulsion, chlorine meta-acid have the light emulsion.
3, a kind of method for making of ice-soluble paraffin wax brightening agent technology, it is characterized in that: the nonionogenic tenside of wax, silicone oil, silane, caustic lye of soda, wetting ability and repellency, softening water etc. are warming up in the enamel reaction still that return channel and agitating vane are arranged produce the gala reactant about 70 ℃-90 ℃, two stearic acid hydroxyl aluminium are sprinkled into 20 fens clock times heat up 90～100 ℃ in the reactor, sodium hydroxide is produced with two stearic acid hydroxyls reactions contain the aluminium anionic emulsifier; With optical brightener, polymer emulsion and account for 25% softening water and add in the reactor, optical brightener and sodium hydroxide etc. are answered again, at last sanitas, frostproofer and softening water are entered reactor, be cooled to 40 ℃ and enter alkali formula essence again.
4, according to the ice-soluble paraffin wax brightening agent of claim 1 or 2, it is characterized in that: optimisation substance and weight percent:
Paraffin: 6% polyethylene wax: 4%
Dimethyl silicone oil: 1.2% METHYL TRICHLORO SILANE: 0.8%
Alkyl trichlorosilane: 0.4% liter of caustic lye of soda: (e) 12 milliliters of 10 ° of B '
Polyxyethylated benzene: 0.8% sulfo-succinic acid dibutyl ester sodium: 1.6%
The two hydroxyl aluminium of two tristearin: 10% acrylonitrile emulsion: 4.1%
Sulfonated fatty acid alkyl ester: 0.6% sanitas: 0.1%
Frostproofer: 0.4% softening water: 50% alkali formula essence is an amount of
5, according to the ice-soluble paraffin wax brightening agent of claim 1 or 2, it is characterized in that: optimisation substance and weight percent:
Paraffin: 6% beeswax: 0.4% ceresine: 3.6%
Dimethyl silicone oil: 1.2% aminosiloxane: 0.8%
Caustic lye of soda: (10 ° of B ' are 12 milliliters of oP-7:06% e)
Stearin: 1% double stearic acid aluminium: 10%
Toluol sulfonamide: 0.8% acrylonitrile emulsion: 7.2%
Sanitas: 0.1% frostproofer: 0.4%
Softening water: 57% alkali formula essence is an amount of
6, according to the ice-soluble paraffin wax brightening agent of claim 1 or 2, it is characterized in that: optimisation substance and weight percent:
Paraffin: 7% ceresine: 0.4% beeswax: 0.2%
Dimethyl silicone oil: 1% methyl-monosilane: 1%
Sodium hydroxide: (10 ° of Be) 12 milliliters of OP-10:0.8%
Single month silicon ester of Diethylene Glycol: 0.8% double stearic acid aluminium: 10%
Orthotoluene sulfonamide: 0.8% vinylformic acid styrene emulsion: 4.4%
Sanitas: 0.1% frostproofer: 0.4%
Softening water: 57% alkali formula essence is an amount of
7, according to the ice-soluble paraffin wax brightening agent of claim 1 or 2, it is characterized in that: optimisation substance and weight percent:
Paraffin: 6% ceresine: 2% charcoal wax: 2%
Dimethyl silicone oil: 1.6% alkyl trichlorosilane: 4%
(10 ° of B ' are 12 milliliters of DS-10:0.6% e) for caustic lye of soda
Sulfo-succinic acid dibutyl ester sodium: 1.4% double stearic acid aluminium: 10%
The p-Xylol sulphonamide: 0.8% chlorine has the light emulsion partially: 4.6%
Sanitas: 0.1% frostproofer: 0.4%
Softening water: 58.1% alkali formula essence is an amount of
8, according to the ice-soluble paraffin wax brightening agent of claim 1 or 2, it is characterized in that: optimisation substance and weight percent:
Paraffin: 6% ceresine: 4%
12 milliliters of EL:0.8% of caustic lye of soda (10 ° of BL)
Dimethyl silicone oil: 1.6% METHYL TRICHLORO SILANE: 0.8%
Aminosiloxane: 1.2% pair of stearic acid hydroxyl aluminium: 10%
Sulfonated fatty acid alkyl ester: 1% Polyurethane emulsion: 6.6%
Sanitas: 0.1% frostproofer: 0.4%
Softening water: 55.5% alkali formula essence is an amount of
9, according to the ice-soluble paraffin wax brightening agent of claim 1 or 2, it is characterized in that: optimisation substance and weight percent:
Paraffin: 8% beeswax: 1% whiteruss: 3%
N-stearic acid N-methyltaurine sodium salt: 1.5% hexadecanol: 5% ester
(10 ° of B ' are 12.6 milliliters of Zerols e): 10.5% for caustic lye of soda
Ground walnut oil: 5.2% kojic acid: 4% antiseptic-germicide: 0.1%
Softening water: an amount of glycerine of 32% essence: 8%
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93104798 CN1095085A (en) | 1993-04-24 | 1993-04-24 | Ice-soluble paraffin wax brightening agent |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 93104798 CN1095085A (en) | 1993-04-24 | 1993-04-24 | Ice-soluble paraffin wax brightening agent |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1095085A true CN1095085A (en) | 1994-11-16 |
Family
ID=4985374
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 93104798 Pending CN1095085A (en) | 1993-04-24 | 1993-04-24 | Ice-soluble paraffin wax brightening agent |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1095085A (en) |
Cited By (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1057786C (en) * | 1995-02-17 | 2000-10-25 | 杨延安 | Multi-function super-thin-film brightener and production technology thereof |
| CN1064065C (en) * | 1998-05-14 | 2001-04-04 | 张西华 | Multifunctional leather clothing oiling cream and its preparation |
| CN102226060A (en) * | 2011-05-19 | 2011-10-26 | 江苏力宝建材工业有限公司 | Cloud paraffin |
| CN102226061A (en) * | 2011-05-19 | 2011-10-26 | 江苏力宝建材工业有限公司 | Preparation method of cloud paraffin |
| CN102453441A (en) * | 2010-10-14 | 2012-05-16 | 中国石油化工股份有限公司 | Glazing protective agent for stone materials and preparation method thereof |
| CN103666281A (en) * | 2013-11-22 | 2014-03-26 | 南通信一服饰有限公司 | Stain removal and leather softening shoe polish |
| CN104831005A (en) * | 2015-05-12 | 2015-08-12 | 湖州吉昌丝绸有限公司 | Novel anti-cracking and anti-wrinkle agent for textile leather bag and preparation method of novel anti-cracking and anti-wrinkle agent |
| CN105062370A (en) * | 2015-07-27 | 2015-11-18 | 宋从甲 | Surface treatment coating wiping agent for appearances of musical instruments and furniture products |
| CN106318221A (en) * | 2016-08-20 | 2017-01-11 | 杨配媛 | Broad-spectrum wax glaze |
| CN107690463A (en) * | 2015-05-27 | 2018-02-13 | 3M创新有限公司 | Polishing composition with improved low-temperature characteristics |
| CN108165388A (en) * | 2017-12-11 | 2018-06-15 | 安徽省定远县劲牛球业有限公司 | A kind of football cleans agent prescription |
| CN108410274A (en) * | 2017-03-30 | 2018-08-17 | 广东驰安汽车用品科技有限公司 | A kind of aqua type solid vehicle glazing protection wax and preparation method thereof |
| CN108912926A (en) * | 2018-06-20 | 2018-11-30 | 湖南辰砾新材料有限公司 | A kind of furniture polish and preparation method thereof |
-
1993
- 1993-04-24 CN CN 93104798 patent/CN1095085A/en active Pending
Cited By (14)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1057786C (en) * | 1995-02-17 | 2000-10-25 | 杨延安 | Multi-function super-thin-film brightener and production technology thereof |
| CN1064065C (en) * | 1998-05-14 | 2001-04-04 | 张西华 | Multifunctional leather clothing oiling cream and its preparation |
| CN102453441A (en) * | 2010-10-14 | 2012-05-16 | 中国石油化工股份有限公司 | Glazing protective agent for stone materials and preparation method thereof |
| CN102453441B (en) * | 2010-10-14 | 2013-10-09 | 中国石油化工股份有限公司 | Glazing protective agent for stone materials and preparation method thereof |
| CN102226060A (en) * | 2011-05-19 | 2011-10-26 | 江苏力宝建材工业有限公司 | Cloud paraffin |
| CN102226061A (en) * | 2011-05-19 | 2011-10-26 | 江苏力宝建材工业有限公司 | Preparation method of cloud paraffin |
| CN103666281A (en) * | 2013-11-22 | 2014-03-26 | 南通信一服饰有限公司 | Stain removal and leather softening shoe polish |
| CN104831005A (en) * | 2015-05-12 | 2015-08-12 | 湖州吉昌丝绸有限公司 | Novel anti-cracking and anti-wrinkle agent for textile leather bag and preparation method of novel anti-cracking and anti-wrinkle agent |
| CN107690463A (en) * | 2015-05-27 | 2018-02-13 | 3M创新有限公司 | Polishing composition with improved low-temperature characteristics |
| CN105062370A (en) * | 2015-07-27 | 2015-11-18 | 宋从甲 | Surface treatment coating wiping agent for appearances of musical instruments and furniture products |
| CN106318221A (en) * | 2016-08-20 | 2017-01-11 | 杨配媛 | Broad-spectrum wax glaze |
| CN108410274A (en) * | 2017-03-30 | 2018-08-17 | 广东驰安汽车用品科技有限公司 | A kind of aqua type solid vehicle glazing protection wax and preparation method thereof |
| CN108165388A (en) * | 2017-12-11 | 2018-06-15 | 安徽省定远县劲牛球业有限公司 | A kind of football cleans agent prescription |
| CN108912926A (en) * | 2018-06-20 | 2018-11-30 | 湖南辰砾新材料有限公司 | A kind of furniture polish and preparation method thereof |
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| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
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