CN109505158A - A kind of reactive dye ink for digital inking printing - Google Patents
A kind of reactive dye ink for digital inking printing Download PDFInfo
- Publication number
- CN109505158A CN109505158A CN201811492527.5A CN201811492527A CN109505158A CN 109505158 A CN109505158 A CN 109505158A CN 201811492527 A CN201811492527 A CN 201811492527A CN 109505158 A CN109505158 A CN 109505158A
- Authority
- CN
- China
- Prior art keywords
- reactive dye
- dye ink
- digital inking
- inking printing
- printing
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/32—Inkjet printing inks characterised by colouring agents
- C09D11/322—Pigment inks
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/36—Inkjet printing inks based on non-aqueous solvents
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/30—Inkjet printing inks
- C09D11/38—Inkjet printing inks characterised by non-macromolecular additives other than solvents, pigments or dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/38—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using reactive dyes
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/445—Use of auxiliary substances before, during or after dyeing or printing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/64—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders using compositions containing low-molecular-weight organic compounds without sulfate or sulfonate groups
- D06P1/651—Compounds without nitrogen
- D06P1/65106—Oxygen-containing compounds
- D06P1/65118—Compounds containing hydroxyl groups
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P1/00—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed
- D06P1/44—General processes of dyeing or printing textiles, or general processes of dyeing leather, furs, or solid macromolecular substances in any form, classified according to the dyes, pigments, or auxiliary substances employed using insoluble pigments or auxiliary substances, e.g. binders
- D06P1/673—Inorganic compounds
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06P—DYEING OR PRINTING TEXTILES; DYEING LEATHER, FURS OR SOLID MACROMOLECULAR SUBSTANCES IN ANY FORM
- D06P5/00—Other features in dyeing or printing textiles, or dyeing leather, furs, or solid macromolecular substances in any form
- D06P5/30—Ink jet printing
Landscapes
- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention discloses a kind of reactive dye inks for digital inking printing, including reactive pigment colorant, phthalein amine, ethylene glycol, glycerine, diglycol, ethyl alcohol, nano-graphite, glycerol, defoaming agent, viscosity modifier, PH regulator, surface tension modifier, metal ion chelation agent, fungicide, dispersing agent and deionized water etc. in oneself.The present invention is used for digital inking printing, and performance is stablized, and can store 6~8 months under room temperature, the color fastness of resistance to dry friction >=4 grade, moisture-proof colorfastness to rubbing >=3 grade, color fastness to water (staining, discoloration) >=4 grades, light fastness >=6 grade, not facile hydrolysis, printing is smooth, and using effect is good.
Description
Technical field
The present invention relates to digital ink-jet fabric stamp field, in particular to a kind of activity dye for digital inking printing
Expect ink.
Background technique
Ink-jet printing ink is the main consumptive material of digital inking printing production, and exploitation ink-jet printing ink has become propulsion spray
Ink-printed technology develops essential component part, and promotes the research hotspot of ink-jet printed technology development.And activity dye
The chromatography of material is wide, lovely luster, has excellent performance, strong applicability, but the reactive dye of domestic enterprise's production at present are mainly used for passing
The rotary scream printing technique of system, seldom promising digital ink-jet printed kind specially developed, activity it is ink-jet printed with dyestuff at home
There are no satisfactory kind, the requirement for preparing ink is often not achieved in performance.The influence factor of drop mass is many, such as
What improves the hot spot that applicability of the reactive dye ink in ink-jet printed is current research.
Summary of the invention
In order to solve the above technical problems, leading to the present invention provides a kind of reactive dye ink for digital inking printing
It crosses and ink composition is improved, solve existing reactive dye ink in the viscosity of ink, surface tension, stability, color
The undesirable problem of depth and moisture retention etc. comprehensive performance.
In order to achieve the above objectives, technical scheme is as follows: a kind of reactive dye ink for digital inking printing
Water, including the following substance measured by mass percentage:
As a preferred solution of the present invention, the defoaming agent is N-Methyl pyrrolidone.
As a preferred solution of the present invention, the viscosity modifier is PVP K-30.
As a preferred solution of the present invention, the PH regulator is triethanolamine, ammonium hydroxide, one in sodium citrate
Kind.
As a preferred solution of the present invention, the surface tension modifier is OP-10.
As a preferred solution of the present invention, the metal ion chelation agent is EDTA-2Na.
As a preferred solution of the present invention, phthalein amine, ethylene glycol, glycerine, diglycol and the second in oneself
The sum of mass percent of alcohol is 30~45%.
As a preferred solution of the present invention, the mass ratio of the ethylene glycol and glycerine is 2:3.
As a preferred solution of the present invention, the reactive dye ink pH value control is in 7.0-7.5.
As a preferred solution of the present invention, the partial size of the reactive pigment colorant is in 250~450nm.
Through the above technical solutions, the significant beneficial effect of technical solution of the present invention is: the present invention is printed for digital ink-jet
Flower, performance are stablized, and can store 6~8 months under room temperature, and for viscosity in 15~22mPas, surface tension is 40~44mN/m, fixation
Rate is 96~99%, and conductivity is 7.5~8.3mS/cm, the color fastness of resistance to dry friction >=4 grade, and moisture-proof colorfastness to rubbing >=3 grade are resistance to
Water colour fastness (staining, discoloration) >=4 grades, light fastness >=6 grade, facile hydrolysis, printing smoothness, using effect be not good.
Specific embodiment
Below in conjunction with the embodiment of the present invention, technical scheme in the embodiment of the invention is clearly and completely described,
Obviously, described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based in the present invention
Embodiment, every other embodiment obtained by those of ordinary skill in the art without making creative efforts, all
Belong to the scope of protection of the invention.
Embodiment 1
A kind of reactive dye ink for digital inking printing, including the following substance measured by mass percentage:
Wherein, the defoaming agent is N-Methyl pyrrolidone.The viscosity modifier is PVP K-30.
The PH regulator is triethanolamine.The surface tension modifier is OP-10.The metal ion chelation agent is EDTA-
2Na.The reactive dye ink pH value control is in 7.0-7.5.The partial size of the reactive pigment colorant is in 250~450nm.
Embodiment 2
A kind of reactive dye ink for digital inking printing, including the following substance measured by mass percentage:
Wherein, the defoaming agent is N-Methyl pyrrolidone.The viscosity modifier is PVP K-30.
The PH regulator is ammonium hydroxide.The surface tension modifier is OP-10.The metal ion chelation agent is EDTA-2Na.Institute
The control of reactive dye ink pH value is stated in 7.0-7.5.The partial size of the reactive pigment colorant is in 250~450nm
Embodiment 3
A kind of reactive dye ink for digital inking printing, including the following substance measured by mass percentage:
Wherein, the defoaming agent is N-Methyl pyrrolidone.The viscosity modifier is PVP K-30.
The PH regulator is sodium citrate.The surface tension modifier is OP-10.The metal ion chelation agent is EDTA-
2Na.The reactive dye ink pH value control is in 7.0-7.5.The partial size of the reactive pigment colorant is in 250~450nm.
Embodiment 4
A kind of reactive dye ink for digital inking printing, including the following substance measured by mass percentage:
Wherein, the defoaming agent is N-Methyl pyrrolidone.The viscosity modifier is PVP K-30.
The PH regulator is sodium citrate.The surface tension modifier is OP-10.The metal ion chelation agent is EDTA-
2Na.The reactive dye ink pH value control is in 7.0-7.5.The partial size of the reactive pigment colorant is in 250~450nm.
Embodiment 1- embodiment 4 is detected, measures viscosity in 15~22mPas, surface tension is 40~44mN/
M, degree of fixation is 96~99%, and conductivity is 7.5~8.3mS/cm, the color fastness of resistance to dry friction >=4 grade, and moisture-proof colorfastness to rubbing >=
3 grades, color fastness to water (staining, discoloration) >=4 grades, light fastness >=6 grade.
By above-mentioned specific embodiment, the beneficial effects of the present invention are: the present invention is using phthalein amine in oneself, ethylene glycol, the third three
The mixed solvent of alcohol, diglycol and ethyl alcohol has moisture retention good, being capable of rapid-curing cutback fixation；And nano-graphite is used, a side
Face can improve conductivity, while reactive pigment colorant can be made preferably to carry out dispersion staining, improve stability, extend and live
The shelf-life of property dye ink, and the fluency of printing can be improved.
The foregoing description of the disclosed embodiments enables those skilled in the art to implement or use the present invention.
Various modifications to these embodiments will be readily apparent to those skilled in the art, as defined herein
General Principle can be realized in other embodiments without departing from the spirit or scope of the present invention.Therefore, of the invention
It is not intended to be limited to the embodiments shown herein, and is to fit to and the principles and novel features disclosed herein phase one
The widest scope of cause.
Claims (9)
1. a kind of reactive dye ink for digital inking printing, which is characterized in that including measure by mass percentage with
Lower substance:
2. the reactive dye ink according to claim 1 for digital inking printing, which is characterized in that the defoaming agent
For N-Methyl pyrrolidone.
3. the reactive dye ink according to claim 2 for digital inking printing, which is characterized in that the viscosity tune
Section agent is PVP K-30.
4. the reactive dye ink according to claim 2 for digital inking printing, which is characterized in that the PH is adjusted
Agent is one of triethanolamine, ammonium hydroxide, sodium citrate.
5. the reactive dye ink according to claim 2 for digital inking printing, which is characterized in that the surface
Power regulator is OP-10.
6. the reactive dye ink according to claim 2 for digital inking printing, which is characterized in that the metal from
Sub- chelating agent is EDTA-2Na.
7. the reactive dye ink according to claim 2 for digital inking printing, which is characterized in that the phthalein in oneself
The sum of mass percent of amine, ethylene glycol, glycerine, diglycol and ethyl alcohol is 30~45%.
8. the reactive dye ink according to claim 2 for digital inking printing, which is characterized in that the ethylene glycol
Mass ratio with glycerine is 2:3.
9. the reactive dye ink according to claim 2 for digital inking printing, which is characterized in that the activity face
Expect the partial size of colorant in 250~450nm.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811492527.5A CN109505158A (en) | 2018-12-07 | 2018-12-07 | A kind of reactive dye ink for digital inking printing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811492527.5A CN109505158A (en) | 2018-12-07 | 2018-12-07 | A kind of reactive dye ink for digital inking printing |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109505158A true CN109505158A (en) | 2019-03-22 |
Family
ID=65751876
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811492527.5A Withdrawn CN109505158A (en) | 2018-12-07 | 2018-12-07 | A kind of reactive dye ink for digital inking printing |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109505158A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112323514A (en) * | 2020-11-20 | 2021-02-05 | 浙江理工大学 | Low-ammonia-nitrogen urea substitute with high color-obtaining performance and active printing method thereof |
| CN114000366A (en) * | 2021-11-22 | 2022-02-01 | 广州希音国际进出口有限公司 | Ink-jet ink and preparation method and application thereof |
| CN115058152A (en) * | 2022-07-13 | 2022-09-16 | 浙江义乌科标制笔有限公司 | Cold-resistant water-based color ink and preparation method thereof |
-
2018
- 2018-12-07 CN CN201811492527.5A patent/CN109505158A/en not_active Withdrawn
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112323514A (en) * | 2020-11-20 | 2021-02-05 | 浙江理工大学 | Low-ammonia-nitrogen urea substitute with high color-obtaining performance and active printing method thereof |
| CN112323514B (en) * | 2020-11-20 | 2022-08-05 | 浙江理工大学 | Low-ammonia-nitrogen urea substitute with high color-obtaining performance and active printing method thereof |
| CN114000366A (en) * | 2021-11-22 | 2022-02-01 | 广州希音国际进出口有限公司 | Ink-jet ink and preparation method and application thereof |
| CN114000366B (en) * | 2021-11-22 | 2023-12-12 | 广州希音国际进出口有限公司 | Inkjet ink and preparation method and application thereof |
| CN115058152A (en) * | 2022-07-13 | 2022-09-16 | 浙江义乌科标制笔有限公司 | Cold-resistant water-based color ink and preparation method thereof |
| CN115058152B (en) * | 2022-07-13 | 2024-02-02 | 浙江义乌科标制笔有限公司 | Cold-resistant aqueous color ink and preparation method thereof |
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| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20190322 |