CN109504308A - A kind of preparation method of open air mine mechanism film on surface - Google Patents
A kind of preparation method of open air mine mechanism film on surface Download PDFInfo
- Publication number
- CN109504308A CN109504308A CN201811427850.4A CN201811427850A CN109504308A CN 109504308 A CN109504308 A CN 109504308A CN 201811427850 A CN201811427850 A CN 201811427850A CN 109504308 A CN109504308 A CN 109504308A
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- Prior art keywords
- parts
- added
- microwave treatment
- buffering adhesive
- mine mechanism
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/30—Adhesives in the form of films or foils characterised by the adhesive composition
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J195/00—Adhesives based on bituminous materials, e.g. asphalt, tar, pitch
- C09J195/005—Aqueous compositions, e.g. emulsions
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J7/00—Adhesives in the form of films or foils
- C09J7/20—Adhesives in the form of films or foils characterised by their carriers
- C09J7/22—Plastics; Metallised plastics
- C09J7/25—Plastics; Metallised plastics based on macromolecular compounds obtained otherwise than by reactions involving only carbon-to-carbon unsaturated bonds
- C09J7/255—Polyesters
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2467/00—Presence of polyester
- C09J2467/006—Presence of polyester in the substrate
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J2495/00—Presence of bitume
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of preparation methods of outdoor mine mechanism film on surface, include the following steps: that (1) prepares buffering adhesive: to emulsified asphalt and white carbon black be added in the mixed solution of formaldehyde and ethyl alcohol in the ratio of 4:1, microwave treatment being used using reaction kettle mixed at high speed to form afterwards;Simultaneously microwave treatment when sweet potato starch and tributyl citrate is added to get material A;It to Brazil wax is added in the mixture of paraffin and gasoline, is heated to adding bentonite, glass fiber powder and graphite powder after being completely melt, equally using microwave treatment 20-25min to get material B;Pad pasting provided by the invention is for adhering to mine mechanism surface outdoors; mechanical equipment is protected; pad pasting is made of PET film and buffering adhesive; buffering adhesive has preferable elasticity and plasticity; shock resistance can voluntarily restore through sunlight irradiation at blastic deformation, and compactness is high; adhesiveness is strong, will not fall off because of equipment Long-term Vibration.It is anticorrosive, anti-aging.
Description
Technical field
The present invention relates to outdoor mine mechanism field, the system of specifically a kind of open air mine mechanism film on surface
Preparation Method.
Background technique
Outdoor mine mechanism refers to operation outdoors, and specializes in the machinery of mining, ore dressing, mine locating.Mining machine
Tool equipment is generally used for processing ore, and low-quality ore is made to have utility value.Separate valuable mineral with gangue.Including visiting
Mine machinery, mining machine and benficiation machinery.Since outdoor mine mechanism working environment is severe, and come into contacts with ore,
The protective layer of equipment surface is subject to various impacts and is damaged, such as the shock of slungshot or colliding with for other tools.In turn
Equipment is caused to be corroded, plant maintenance frequency and difficulty are larger.
Summary of the invention
It is above-mentioned to solve the purpose of the present invention is to provide a kind of preparation method of outdoor mine mechanism film on surface
The problem of being proposed in background technique.
To achieve the above object, the invention provides the following technical scheme:
A kind of preparation method of open air mine mechanism film on surface, includes the following steps:
(1) buffering adhesive is prepared: to emulsified asphalt and white carbon black with the mixed solution of addition formaldehyde and ethyl alcohol in the ratio of 4:1
In, using reaction kettle mixed at high speed to form afterwards using the microwave treatment 20-25min of frequency 3500MHz, power 500W;
Simultaneously microwave treatment when sweet potato starch and tributyl citrate is added to get material A;
To Brazil wax is added in the mixture of paraffin and gasoline, it is heated to adding bentonite, glass after being completely melt
Glass fiber powder and graphite powder, the same microwave treatment 20-25min for using frequency 3500MHz, power 500W is to get material B;
Material B, elasticator (elasticizer), plasticizer are added into material A and is passed through reducibility gas, is filled using gas and agitating device
Divide after mixing, is warming up to 60-70 degrees Celsius, and keep the temperature 5-7h;
(2) raw material after cooling in step (1) is taken out and is heated to 80~85 DEG C, using the stirring of high speed centrifugation blender
10-15 minutes, 75 DEG C are then cooled to, constant temperature persistently stirs;
(3) it is pumped into while stirring buffering adhesive in high steam spray gun, through high pressure draught in a manner of uniformly strafing
PET film surface is directly acted on, the adhesive layer with a thickness of 5~5.5mm is formed;
(4) adhesive layer density is handled: the PET film for being coated with buffering adhesive is placed in 65 DEG C of greenhouse, and is applied to pitch
Layer surface sprays atomized water humidification;Then greenhouse is warming up to 72 DEG C up to pad pasting;
As a further solution of the present invention: raw materials used weight proportion in the step (1) are as follows:
30-40 parts of emulsified asphalt, 8-12 parts of white carbon black, 8-12 parts of paraffin, 0.5-0.8 parts of gasoline, bentonite 0.5-0.8
Part, 7-9 parts of sweet potato starch, 1-1.5 parts of elasticator (elasticizer), 1-2 parts of glass fiber powder, 5-8 parts of Brazil wax, formalin 10-14
Part, 2-3 parts of plasticizer, 1-1.9 parts of tributyl citrate, 0.08-0.12 parts of graphite powder.
As a further solution of the present invention: the elasticator (elasticizer) is fourth conjugated diene, pentaerythritol oleate and horse
Carry out sour glycosides, the weight ratio of three's addition is 1:1.5:1.
Compared with prior art, the beneficial effects of the present invention are: pad pasting provided by the invention is for adhering to mine outdoors
Mechanical equipment surface, protects mechanical equipment, and pad pasting is made of PET film and buffering adhesive, and buffering adhesive has preferable elasticity
And plasticity, shock resistance can voluntarily restore through sunlight irradiation at blastic deformation, compactness is high, and adhesiveness is strong, will not be long because of equipment
Phase is vibrated and falls off.The present invention can also be anticorrosive, anti-aging, and improves the comprehensive performance of product surface.
Specific embodiment
The technical scheme in the embodiments of the invention will be clearly and completely described below, it is clear that described implementation
Example is only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, this field is common
Technical staff's every other embodiment obtained without making creative work belongs to the model that the present invention protects
It encloses.
A kind of preparation method of open air mine mechanism film on surface, includes the following steps:
(1) buffering adhesive is prepared: to emulsified asphalt and white carbon black with the mixed solution of addition formaldehyde and ethyl alcohol in the ratio of 4:1
In, using reaction kettle mixed at high speed to form afterwards using the microwave treatment 20-25min of frequency 3500MHz, power 500W;
Simultaneously microwave treatment when sweet potato starch and tributyl citrate is added to get material A;
To Brazil wax is added in the mixture of paraffin and gasoline, it is heated to adding bentonite, glass after being completely melt
Glass fiber powder and graphite powder, the same microwave treatment 20-25min for using frequency 3500MHz, power 500W is to get material B;
Material B, elasticator (elasticizer), plasticizer are added into material A and is passed through reducibility gas, is filled using gas and agitating device
Divide after mixing, is warming up to 60-70 degrees Celsius, and keep the temperature 5-7h;
(2) raw material after cooling in step (1) is taken out and is heated to 80~85 DEG C, using the stirring of high speed centrifugation blender
10-15 minutes, 75 DEG C are then cooled to, constant temperature persistently stirs;
(3) it is pumped into while stirring buffering adhesive in high steam spray gun, through high pressure draught in a manner of uniformly strafing
PET film surface is directly acted on, the adhesive layer with a thickness of 5~5.5mm is formed;
(4) adhesive layer density is handled: the PET film for being coated with buffering adhesive is placed in 65 DEG C of greenhouse, and is applied to pitch
Layer surface sprays atomized water humidification;Then greenhouse is warming up to 72 DEG C up to pad pasting;
As a further solution of the present invention: raw materials used weight proportion in the step (1) are as follows:
30-40 parts of emulsified asphalt, 8-12 parts of white carbon black, 8-12 parts of paraffin, 0.5-0.8 parts of gasoline, bentonite 0.5-0.8
Part, 7-9 parts of sweet potato starch, 1-1.5 parts of elasticator (elasticizer), 1-2 parts of glass fiber powder, 5-8 parts of Brazil wax, formalin 10-14
Part, 2-3 parts of plasticizer, 1-1.9 parts of tributyl citrate, 0.08-0.12 parts of graphite powder.
As a further solution of the present invention: the elasticator (elasticizer) is fourth conjugated diene, pentaerythritol oleate and horse
Carry out sour glycosides, the weight ratio of three's addition is 1:1.5:1.
Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art,
It is still possible to modify the technical solutions described in the foregoing embodiments, or part of technical characteristic is carried out etc.
With replacement, all within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in this
Within the protection scope of invention.
Claims (3)
1. a kind of preparation method of open air mine mechanism film on surface, characterized by the following steps:
(1) buffering adhesive is prepared: to emulsified asphalt and white carbon black to be added in the ratio of 4:1 in the mixed solution of formaldehyde and ethyl alcohol,
Using reaction kettle mixed at high speed to form afterwards using the microwave treatment 20-25min of frequency 3500MHz, power 500W;Simultaneously
Microwave treatment when sweet potato starch and tributyl citrate is added to get material A;
To Brazil wax is added in the mixture of paraffin and gasoline, it is heated to adding bentonite, glass fibers after being completely melt
Powder and graphite powder are tieed up, the same microwave treatment 20-25min for using frequency 3500MHz, power 500W is to get material B;
Material B, elasticator (elasticizer), plasticizer are added into material A and is passed through reducibility gas, it is sufficiently mixed using gas and agitating device
After closing uniformly, it is warming up to 60-70 degrees Celsius, and keep the temperature 5-7h;
(2) raw material after cooling in step (1) is taken out and is heated to 80~85 DEG C, 10- is stirred using high speed centrifugation blender
15 minutes, 75 DEG C are then cooled to, constant temperature persistently stirs;
(3) it is pumped into while stirring buffering adhesive in high steam spray gun, it is direct in a manner of uniformly strafing high pressure draught
PET film surface is acted on, the adhesive layer with a thickness of 5~5.5mm is formed;
(4) adhesive layer density is handled: the PET film for being coated with buffering adhesive is placed in 65 DEG C of greenhouse, and to bituminous coating table
Spray atomized water humidification in face;Then greenhouse is warming up to 72 DEG C up to pad pasting.
2. the preparation method of open air mine mechanism film on surface according to claim 1, it is characterised in that: the step
Suddenly weight proportion raw materials used in (1) are as follows:
It is 30-40 parts of emulsified asphalt, 8-12 parts of white carbon black, 8-12 parts of paraffin, 0.5-0.8 parts of gasoline, 0.5-0.8 parts of bentonite, sweet
7-9 portions of sweet potato starch, 1-2 parts of glass fiber powder, 5-8 parts of Brazil wax, 10-14 parts of formalin, increases 1-1.5 parts of elasticator (elasticizer)
Mould agent 2-3 parts, 1-1.9 parts of tributyl citrate, 0.08-0.12 parts of graphite powder.
3. the preparation method of open air mine mechanism film on surface according to claim 1, it is characterised in that: described
Elasticator (elasticizer) is fourth conjugated diene, pentaerythritol oleate and maleic acid glycosides, and the weight ratio of three's addition is 1:1.5:1.
Priority Applications (1)
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CN201811427850.4A CN109504308A (en) | 2018-11-27 | 2018-11-27 | A kind of preparation method of open air mine mechanism film on surface |
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CN201811427850.4A CN109504308A (en) | 2018-11-27 | 2018-11-27 | A kind of preparation method of open air mine mechanism film on surface |
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Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011057807A (en) * | 2009-09-09 | 2011-03-24 | Shizuoka Rekisei Kogyo Kk | Breathable buffer sheet with self-adhesive layer and method for waterproofing composite coating film using breathable buffer sheet with self-adhesive layer |
CN105925193A (en) * | 2016-06-02 | 2016-09-07 | 安徽安重水电设备有限公司 | Preparation method for asphalt paint applied to outdoor mining machinery |
CN105925194A (en) * | 2016-06-02 | 2016-09-07 | 安徽安重水电设备有限公司 | Asphalt paint applied to outdoor mining machinery |
CN106065295A (en) * | 2016-06-02 | 2016-11-02 | 安徽安重水电设备有限公司 | A kind of preparation method of outdoor mine mechanism film on surface |
CN107227126A (en) * | 2017-07-12 | 2017-10-03 | 合肥轻风飏电气科技有限责任公司 | A kind of film on surface of mining machinery and preparation method thereof |
-
2018
- 2018-11-27 CN CN201811427850.4A patent/CN109504308A/en active Pending
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2011057807A (en) * | 2009-09-09 | 2011-03-24 | Shizuoka Rekisei Kogyo Kk | Breathable buffer sheet with self-adhesive layer and method for waterproofing composite coating film using breathable buffer sheet with self-adhesive layer |
CN105925193A (en) * | 2016-06-02 | 2016-09-07 | 安徽安重水电设备有限公司 | Preparation method for asphalt paint applied to outdoor mining machinery |
CN105925194A (en) * | 2016-06-02 | 2016-09-07 | 安徽安重水电设备有限公司 | Asphalt paint applied to outdoor mining machinery |
CN106065295A (en) * | 2016-06-02 | 2016-11-02 | 安徽安重水电设备有限公司 | A kind of preparation method of outdoor mine mechanism film on surface |
CN107227126A (en) * | 2017-07-12 | 2017-10-03 | 合肥轻风飏电气科技有限责任公司 | A kind of film on surface of mining machinery and preparation method thereof |
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Application publication date: 20190322 |