CN109503905A - A kind of high-lubricity rubber ring - Google Patents

A kind of high-lubricity rubber ring Download PDF

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Publication number
CN109503905A
CN109503905A CN201811608675.9A CN201811608675A CN109503905A CN 109503905 A CN109503905 A CN 109503905A CN 201811608675 A CN201811608675 A CN 201811608675A CN 109503905 A CN109503905 A CN 109503905A
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CN
China
Prior art keywords
parts
nitrile rubber
rubber ring
rubber
acrylonitrile content
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811608675.9A
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Chinese (zh)
Inventor
李少周
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WUXI LANXIANG PLASTIC INDUSTRY Co Ltd
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WUXI LANXIANG PLASTIC INDUSTRY Co Ltd
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Priority to CN201811608675.9A priority Critical patent/CN109503905A/en
Publication of CN109503905A publication Critical patent/CN109503905A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L9/00Compositions of homopolymers or copolymers of conjugated diene hydrocarbons
    • C08L9/02Copolymers with acrylonitrile
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06Homopolymers or copolymers of vinyl chloride
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2296Oxides; Hydroxides of metals of zinc
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The present invention discloses a kind of high-lubricity rubber ring, including rubber ring ontology, and rubber ring ontology is prepared from the following raw materials in parts by weight: 70 parts of nitrile rubber with high acrylonitrile content, 30 parts of carboxy nitrile rubber, 70 parts of Corvic, 2~4 parts of surface self-lubricating agent, 4~6 parts of sulphur, 5~8 parts of zinc oxide, 15~25 parts of white carbon black, 1~4 part of stearic acid, 2~4 parts of homogenizing agent, 2~5 parts of promotor, 1~4 part of antiaging agent;Wherein, surface self-lubricating agent is silicone oil, and the nitrile rubber with high acrylonitrile content is the high acrylonitrile nitrile rubber that acrylonitrile content is 40%~42%.The present invention is with nitrile rubber with high acrylonitrile content for main substrate, with oil resistant, wear-resisting characteristic, and part carboxy nitrile rubber is added to improve product elasticity, furthermore, the present invention is using silicone oil as surface self-lubricating agent, not only there is splendid lubricant effect, and certain plasticising, reinforcing effect can be played.

Description

A kind of high-lubricity rubber ring
Technical field
The present invention relates to Weaving device accessories field more particularly to a kind of high-lubricity rubber rings.
Background technique
Rubber ring is the important component for being located at spinning, drawing region on Weaving device, the quality of quality concerning spinning at Yarn quality, production efficiency and recruitment cost.
Spinning rubber ring must have lubricate, be wear-resisting, antistatic characteristic.The rubber used on existing Weaving device Circle, lubricity are realized generally by acid processing;However, acid treatment process is big to environmental hazard, also have to operator Injury, and acid treated rubber ring coefficient of friction is inconsistent, and then will cause between spinning products and biggish difference occur. It is badly in need of solving as a result,.
Summary of the invention
It is an object of the invention in view of the above-mentioned problems, a kind of high-lubricity rubber ring is provided, to solve existing rubber ring The short problem of poor lubricity, service life.
The purpose of the present invention is be achieved through the following technical solutions:
A kind of high-lubricity rubber ring, including rubber ring ontology, the rubber ring ontology by following parts by weight raw material It is made:
70 parts of nitrile rubber with high acrylonitrile content, 30 parts of carboxy nitrile rubber, 70 parts of Corvic, surface self-lubricating 2~4 parts of agent, 4~6 parts of sulphur, 5~8 parts of zinc oxide, 15~25 parts of white carbon black, 1~4 part of stearic acid, 2~4 parts of homogenizing agent, promote Into 2~5 parts of agent, 1~4 part of antiaging agent;Wherein, the surface self-lubricating agent is silicone oil, the high acrylonitrile content butyronitrile rubber Glue is the high acrylonitrile nitrile rubber that acrylonitrile content is 40%~42%.
As a preferred solution of the present invention, the rubber ring ontology is prepared from the following raw materials in parts by weight:
70 parts of nitrile rubber with high acrylonitrile content, 30 parts of carboxy nitrile rubber, 70 parts of Corvic, 3 parts of silicone oil, sulphur 5 parts of sulphur, 7 parts of zinc oxide, 25 parts of white carbon black, 3 parts of stearic acid, 3 parts of homogenizing agent, 4 parts of promotor, 2 parts of antiaging agent.
As a preferred solution of the present invention, it is 41% that the nitrile rubber with high acrylonitrile content, which is acrylonitrile content, High acrylonitrile nitrile rubber.
As a preferred solution of the present invention, the promotor is accelerant CZ, and its chemical name is N- cyclohexyl -2- Benzothiazole sulfenamide.
As a preferred solution of the present invention, the antiaging agent is 2-mercaptobenzimidazole.
Beneficial effects of the present invention are, the present invention, for main substrate, has oil resistant, resistance to nitrile rubber with high acrylonitrile content The characteristic of mill, and part carboxy nitrile rubber is added to improve product elasticity, and by the way that the polychlorostyrene compatible with nitrile rubber is added Vinyl, adjustable product mobile performance increase product strength, in addition, the present invention using silicone oil as surface self-lubricating agent, Not only there is splendid lubricant effect, and certain plasticising, reinforcing effect can be played, so guarantee product smoothly produce, While semi-products safe storage, so that the coefficient of friction control on rubber ring surface has preferable lubrication effect in reduced levels Fruit extends the service life of product so that spinning quality be effectively ensured.
Specific embodiment
The technical scheme of the invention is further explained by means of specific implementation.It is understood that this place The embodiment of description is used only for explaining the present invention rather than limiting the invention.
Embodiment one
In this present embodiment, a kind of high-lubricity rubber ring, including rubber ring ontology, the rubber ring ontology
It is prepared from the following raw materials in parts by weight:
70 parts of nitrile rubber with high acrylonitrile content, 30 parts of carboxy nitrile rubber, 70 parts of Corvic, surface self-lubricating 2 parts of agent, 4 parts of sulphur, 5 parts of zinc oxide, 15 parts of white carbon black, 1 part of stearic acid, 2 parts of homogenizing agent, 2 parts of promotor, 1 part of antiaging agent; Wherein, the surface self-lubricating agent is silicone oil, and the promotor is accelerant CZ, and the antiaging agent is 2- sulfydryl benzo miaow Azoles, the nitrile rubber with high acrylonitrile content are the high acrylonitrile nitrile rubbers that acrylonitrile content is 40%.
Embodiment two
In this present embodiment, a kind of high-lubricity rubber ring, including rubber ring ontology, the rubber ring ontology is by following heavy The raw material of amount number is made:
70 parts of nitrile rubber with high acrylonitrile content, 30 parts of carboxy nitrile rubber, 70 parts of Corvic, surface self-lubricating 4 parts of agent, 6 parts of sulphur, 8 parts of zinc oxide, 25 parts of white carbon black, 4 parts of stearic acid, 4 parts of homogenizing agent, 5 parts of promotor, 4 parts of antiaging agent; Wherein, the surface self-lubricating agent is silicone oil, and the promotor is accelerant CZ, and the antiaging agent is 2- sulfydryl benzo miaow Azoles, the nitrile rubber with high acrylonitrile content are the high acrylonitrile nitrile rubbers that acrylonitrile content is 42%.
Embodiment three
In this present embodiment, a kind of high-lubricity rubber ring, including rubber ring ontology, the rubber ring ontology is by following heavy The raw material of amount number is made:
70 parts of nitrile rubber with high acrylonitrile content, 30 parts of carboxy nitrile rubber, 70 parts of Corvic, surface self-lubricating 4 parts of agent, 5 parts of sulphur, 6 parts of zinc oxide, 20 parts of white carbon black, 2 parts of stearic acid, 3 parts of homogenizing agent, 3 parts of promotor, 3 parts of antiaging agent; Wherein, the surface self-lubricating agent is silicone oil, and the promotor is accelerant CZ, and the antiaging agent is 2- sulfydryl benzo miaow Azoles, the high acrylonitrile content butyronitrile
Rubber is the high acrylonitrile nitrile rubber that acrylonitrile content is 41%.
Example IV
In this present embodiment, a kind of high-lubricity rubber ring, including rubber ring ontology, the rubber ring ontology is by following heavy The raw material of amount number is made:
70 parts of nitrile rubber with high acrylonitrile content, 30 parts of carboxy nitrile rubber, 70 parts of Corvic, surface self-lubricating 3 parts of agent, 5 parts of sulphur, 7 parts of zinc oxide, 25 parts of white carbon black, 3 parts of stearic acid, 3 parts of homogenizing agent, 4 parts of promotor, 2 parts of antiaging agent; Wherein, the surface self-lubricating agent is silicone oil, and the promotor is accelerant CZ, and the antiaging agent is 2- sulfydryl benzo miaow Azoles.
In the present embodiment, the nitrile rubber that nitrile rubber with high acrylonitrile content is 4155 using the trade mark, is propylene The high acrylonitrile nitrile rubber that nitrile content is 42%, and its Mooney viscosity is lower, Mooney viscosity 55, is convenient for filled PVC, thus Improve processing fluidity, manufactures rubber ring ontology by using the formula of the present embodiment, the profit of rubber ring ontology can be effectively improved Slip energy and intensity greatly improve the service life of rubber ring ontology, are preferred embodiment of the invention.
The above embodiments only describe the basic principles and characteristics of the invention, and the present invention is not limited by above-described embodiment, Without departing from the spirit and scope of the present invention, the invention also has various changes and changes, and these changes and changes are all fallen Enter in scope of the claimed invention.The claimed scope of the invention is defined by the following claims.

Claims (5)

1. a kind of high-lubricity rubber ring, including rubber ring ontology, it is characterised in that: the rubber ring ontology is by following parts by weight Several raw materials are made:
70 parts of nitrile rubber with high acrylonitrile content, 30 parts of carboxy nitrile rubber, 70 parts of Corvic, surface self-lubricating agent 2 ~4 parts, 4~6 parts of sulphur, 5~8 parts of zinc oxide, 15~25 parts of white carbon black, 1~4 part of stearic acid, 2~4 parts of homogenizing agent, promotor 2~5 parts, 1~4 part of antiaging agent;Wherein, the surface self-lubricating agent is silicone oil, and the nitrile rubber with high acrylonitrile content is The high acrylonitrile nitrile rubber that acrylonitrile content is 40%~42%.
2. a kind of high-lubricity rubber ring according to claim 1, it is characterised in that: the rubber ring ontology is by following heavy The raw material of amount number is made:
70 parts of nitrile rubber with high acrylonitrile content, 30 parts of carboxy nitrile rubber, 70 parts of Corvic, 3 parts of silicone oil, sulphur 5 Part, 7 parts of zinc oxide, 25 parts of white carbon black, 3 parts of stearic acid, 3 parts of homogenizing agent, 4 parts of promotor, 2 parts of antiaging agent.
3. a kind of high-lubricity rubber ring according to claim 2, it is characterised in that: the high acrylonitrile content butyronitrile rubber Glue is the high acrylonitrile nitrile rubber that acrylonitrile content is 41%.
4. a kind of high-lubricity rubber ring according to claim 3, it is characterised in that: the promotor is accelerant CZ.
5. a kind of high-lubricity rubber ring according to claim 4, it is characterised in that: the antiaging agent is 2- sulfydryl benzene And imidazoles.
CN201811608675.9A 2018-12-27 2018-12-27 A kind of high-lubricity rubber ring Pending CN109503905A (en)

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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110028715A (en) * 2019-05-06 2019-07-19 无锡二橡胶股份有限公司 A kind of factory formula of anti-jitter, tear-proof spinning apron
CN110885482A (en) * 2019-12-16 2020-03-17 江苏冠联新材料科技股份有限公司 NBR (nitrile-butadiene rubber) material for high-strength super-wear-resistant rubber roll
CN111087663A (en) * 2019-12-30 2020-05-01 长沙中京机械有限公司 Wear-resistant nitrile rubber composition and application thereof

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* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103819769A (en) * 2014-02-24 2014-05-28 无锡二橡胶股份有限公司 Production formula of high-abrasion high-draft high-speed spinning rubber ring
CN104962071A (en) * 2015-07-25 2015-10-07 长泰鑫润橡塑有限公司 Sealing rubber ring
CN107522919A (en) * 2017-08-11 2017-12-29 宁国市润丰金属制品有限公司 A kind of rubber seal with good ageing-resistant performance
CN108546376A (en) * 2018-05-07 2018-09-18 陈丽 The preparation method of cable jacket composite material

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103819769A (en) * 2014-02-24 2014-05-28 无锡二橡胶股份有限公司 Production formula of high-abrasion high-draft high-speed spinning rubber ring
CN104962071A (en) * 2015-07-25 2015-10-07 长泰鑫润橡塑有限公司 Sealing rubber ring
CN107522919A (en) * 2017-08-11 2017-12-29 宁国市润丰金属制品有限公司 A kind of rubber seal with good ageing-resistant performance
CN108546376A (en) * 2018-05-07 2018-09-18 陈丽 The preparation method of cable jacket composite material

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林詠兰等: "《聚氯乙烯塑料成型加工》", 31 August 1983, 上海科学技术出版社 *
王俊英等: ""丁腈橡胶微观结构和主要成分对胶辊胶圈纺纱性能的影响"", 《纺织器材》 *
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Cited By (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110028715A (en) * 2019-05-06 2019-07-19 无锡二橡胶股份有限公司 A kind of factory formula of anti-jitter, tear-proof spinning apron
CN110885482A (en) * 2019-12-16 2020-03-17 江苏冠联新材料科技股份有限公司 NBR (nitrile-butadiene rubber) material for high-strength super-wear-resistant rubber roll
CN111087663A (en) * 2019-12-30 2020-05-01 长沙中京机械有限公司 Wear-resistant nitrile rubber composition and application thereof

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Application publication date: 20190322