CN109503124A - A kind of crack resistence porous brick and preparation method thereof - Google Patents
A kind of crack resistence porous brick and preparation method thereof Download PDFInfo
- Publication number
- CN109503124A CN109503124A CN201910013867.3A CN201910013867A CN109503124A CN 109503124 A CN109503124 A CN 109503124A CN 201910013867 A CN201910013867 A CN 201910013867A CN 109503124 A CN109503124 A CN 109503124A
- Authority
- CN
- China
- Prior art keywords
- porous brick
- crack resistence
- preparation
- clinker
- clay
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/1321—Waste slurries, e.g. harbour sludge, industrial muds
- C04B33/1322—Red mud
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B33/00—Clay-wares
- C04B33/02—Preparing or treating the raw materials individually or as batches
- C04B33/13—Compounding ingredients
- C04B33/132—Waste materials; Refuse; Residues
- C04B33/135—Combustion residues, e.g. fly ash, incineration waste
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P40/00—Technologies relating to the processing of minerals
- Y02P40/60—Production of ceramic materials or ceramic elements, e.g. substitution of clay or shale by alternative raw materials, e.g. ashes
Abstract
The present invention relates to the technical fields of house bearing bricks can be recycled waste resource more particularly to a kind of crack resistence porous brick and preparation method thereof, reduce the waste of resource, and porous brick quality can be improved, and reduce cracking, prolong the service life;Raw material including following percentage: red mud 30%-40%, gangue 25%-35%, clinker 15%-20%, clay 12%-18% and adhesive 1%-3%;Preparation method includes the following steps: (1) crushing grinding;(2) screening removal of impurities;(3) material mixes;(4) mixed material ripening: is imported in aging bunker to the ripening carried out 3-5 days;(5) extrusion forming: the material after ageing is reused after blender is stirred, by single lead screw ex truding briquetting machine extrusion molding, obtains porous brick blank;(6) drying and processing: obtained porous brick blank is subjected to drying and processing, makes water content≤5.5% therein;(7) calcination process;(8) it post-processes.
Description
Technical field
The present invention relates to the technical fields of construction material, more particularly to a kind of crack resistence porous brick and preparation method thereof.
Background technique
It is well known that porous brick refers to using clay, shale, flyash as primary raw material, it is porous made of being formed, being roasted
Brick, hole ratio are equal to or more than 15%, and pass is circular hole or non-circular hole, the size in hole is small and quantity more than be known as porous brick, it is main
To be suitable for bearing wall.
Porous brick, hollow brick are compared with traditional solid brick, but building weight reduction 1/3 or so, save fuel 10-
20%, firing rate is high, save the cost, improves service efficiency, can improve the heat-insulated and sound insulation turned it is new more can, there is good warp
Ji meaning, but it is primary raw material that existing porous brick, which mostly uses clay, shale etc., greatly destroys ecological environment, therefore,
How using waste resource production porous brick, achieving the purpose that economize on resources to be to continue with is solved the problems, such as, and existing porous
Brick is easy cracking when in use, and service life is lower.
Gangue is the solid waste discharged during coal mining process and coal washing, be one kind in coalification course with coal seam companion
A kind of lower, harder than the coal black and gray rock of raw phosphorus content;After gas generator gasified raw material coal, solid residue is obtained,
We are known as clinker or ashes, and clinker itself is slightly with or without hydraulic gelling property, but it is existing for the levigate later moisture
In the case of, especially under the conditions of steam curing, participates in calcium hydroxide or other hydroxide chemically react.And generate tool
There is the compound of hydraulic gelling property.So it can be used to be usually used in producing cinder or cinder concrete is big as construction material
Clinker can also be used to repair the roads or make the heat preservation in house, acoustic material by pattern plate etc.;Red mud is that aluminium industry extracts aluminium oxide
When the pollution waste residue that is discharged, also known as red soil, from refining the industrial solid wastes being discharged after aluminium oxide in bauxite.It is a large amount of red
Mud sufficiently effective cannot utilize, and can only stack by the stockyard of large area, occupy a large amount of soils, also cause sternly to environment
The pollution of weight.About 70,000,000 tons of the red mud that the whole world generates every year, the red mud that China generates every year is 30,000,000 tons or more, largely
The generation of red mud causes various influences directly or indirectly to the production of the mankind, life, so subtracting to greatest extent
The yield and harm of few red mud, realize by all kinds of means, the recycling of quantity greatly it is extremely urgent.
Summary of the invention
In order to solve the above technical problems, the present invention, which provides one kind, can be recycled waste resource, resource is reduced
Waste, and porous brick quality can be improved, reduces cracking, the crack resistence porous brick to prolong the service life and its preparation side
Method.
A kind of crack resistence porous brick of the invention, the raw material including following percentage:
A kind of crack resistence porous brick of the invention, it is preferred that the raw material including following percentage:
A kind of crack resistence porous brick of the invention, having a size of 240mm*115mm*90mm.
A kind of preparation method of crack resistence porous brick of the invention, comprising the following steps:
(1) crushing grinding: gangue, clinker and clay are subjected to multiple stage crushing milled processed, reduces its granularity, obtains
The abrasive flour of each raw material;
(2) screening process, removal screening removal of impurities: are carried out to the gangue, clinker and clay abrasive powder obtained after grinding
The wherein biggish part of particle;
(3) material mixes: the abrasive flour of gangue, clinker and clay after screening is added in blender, and to its
Middle addition red mud and adhesive, are eventually adding water, and starting blender is stirred mixing to the material of its inside;
(4) mixed material ripening: is imported in aging bunker to the ripening carried out 3-5 days;
(5) extrusion forming: the material after ageing is reused after blender is stirred, is squeezed out by single lead screw ex truding briquetting machine
Molding, obtains porous brick blank;
(6) drying and processing: obtained porous brick blank is subjected to drying and processing, makes water content≤5.5% therein;
(7) calcination process: the porous brick blank after drying and processing is sent into agglomerating plant and carries out calcination process, is obtained more
Hole brick;
(8) it post-processes: the porous brick that calcination process obtains being modified, and stacking.
A kind of preparation method of crack resistence porous brick of the invention, revolving speed is 1.4m/s- in blender in the step (3)
1.7m/s。
A kind of preparation method of crack resistence porous brick of the invention obtains the aqueous of material after the middle mixing of the step (4)
Measuring is 13%-14%, and temperature >=10 DEG C of the ripening of mixed material.
A kind of preparation method of crack resistence porous brick of the invention, the maturing temperature in the step (7) is 900 DEG C-
1100℃。
A kind of preparation method of crack resistence porous brick of the invention, the calcining time in the step (7) be 45min ±
2min。
Compared with prior art the invention has the benefit that a kind of crack resistence porous brick of the invention uses red mud, coal
The waste materials such as spoil and clinker reduce the usage amount of clay as raw material, can be to solid while having saved clay resource
Waste is reused, so as to reduce the waste of resource, and by carrying out ripening to mixed material,
The moisture in stock chart face can be made to penetrate into particle, interpenetrating the moisture between material, to reach moisture unanimously uniform,
Raw material physical property is improved, the porous brick plasticity made is good, and easily molded, crackle is few, and compactness is good, and it is not easy to crack, so as to
To improve porous brick quality, cracking is reduced, is prolonged the service life.And using a kind of raw material of crack resistence porous brick of the invention
Proportion can be also used for production hollow brick and standard brick.
Specific embodiment
With reference to embodiment, the embodiment of the present invention is furthur described in detail.Following embodiment is used for
Illustrate the present invention, but is not intended to limit the scope of the invention.
Embodiment 1
Gangue, clinker and clay are subjected to multiple stage crushing milled processed, reduces its granularity, obtains the grinding of each raw material
Powder carries out screening process to the gangue, clinker and clay abrasive powder obtained after grinding, removes the wherein biggish portion of particle
Point, the abrasive flour of gangue 25%, clinker 20% and clay 12% after screening is added in blender, and is added thereto
Red mud 40% and adhesive 3% are eventually adding water, and starting blender is stirred mixing to the material of its inside, and revolving speed is
1.4m/s-1.7m/s, and the mixed material that obtained water content is 13%-14% is imported in aging bunker and is carried out 3-5 days
Ripening, temperature >=10 DEG C of ripening reuse the material after ageing after blender is stirred, by squeezing
Pressing machine extrusion molding obtains porous brick blank, and obtained porous brick blank is carried out drying and processing, makes water content therein
≤ 5.5%, the porous brick blank after drying and processing is sent into agglomerating plant and carries out calcination process at 900 DEG C -1100 DEG C
45min ± 2min obtains the porous brick having a size of 240mm*115mm*90mm, repairs to the porous brick that calcination process obtains
It is whole, and stacking.
Porous brick made from the present embodiment, cracking rate≤2.4% in use.
Embodiment 2
Gangue, clinker and clay are subjected to multiple stage crushing milled processed, reduces its granularity, obtains the grinding of each raw material
Powder carries out screening process to the gangue, clinker and clay abrasive powder obtained after grinding, removes the wherein biggish portion of particle
Point, the abrasive flour of gangue 27%, clinker 19% and clay 13.5% after screening is added in blender, and thereto plus
Enter red mud 38% and bonding 2.5%, be eventually adding water, starting blender is stirred mixing to the material of its inside, and revolving speed is
1.4m/s-1.7m/s, and the mixed material that obtained water content is 13%-14% is imported in aging bunker and is carried out 3-5 days
Ripening, temperature >=10 DEG C of ripening reuse the material after ageing after blender is stirred, by squeezing
Pressing machine extrusion molding obtains porous brick blank, and obtained porous brick blank is carried out drying and processing, makes water content therein
≤ 5.5%, the porous brick blank after drying and processing is sent into agglomerating plant and carries out calcination process at 900 DEG C -1100 DEG C
45min ± 2min obtains the porous brick having a size of 240mm*115mm*90mm, repairs to the porous brick that calcination process obtains
It is whole, and stacking.
Porous brick made from the present embodiment, cracking rate≤1.9% in use.
Embodiment 3
Gangue, clinker and clay are subjected to multiple stage crushing milled processed, reduces its granularity, obtains the grinding of each raw material
Powder carries out screening process to the gangue, clinker and clay abrasive powder obtained after grinding, removes the wherein biggish portion of particle
Point, the abrasive flour of gangue 30%, clinker 18% and clay 15% after screening is added in blender, and is added thereto
Red mud 35% and adhesive 2% are eventually adding water, and starting blender is stirred mixing to the material of its inside, and revolving speed is
1.4m/s-1.7m/s, and the mixed material that obtained water content is 13%-14% is imported in aging bunker and is carried out 3-5 days
Ripening, temperature >=10 DEG C of ripening reuse the material after ageing after blender is stirred, by squeezing
Pressing machine extrusion molding obtains porous brick blank, and obtained porous brick blank is carried out drying and processing, makes water content therein
≤ 5.5%, the porous brick blank after drying and processing is sent into agglomerating plant and carries out calcination process at 900 DEG C -1100 DEG C
45min ± 2min obtains the porous brick having a size of 240mm*115mm*90mm, repairs to the porous brick that calcination process obtains
It is whole, and stacking.
Porous brick made from the present embodiment, cracking rate≤0.8% in use.
Embodiment 4
Gangue, clinker and clay are subjected to multiple stage crushing milled processed, reduces its granularity, obtains the grinding of each raw material
Powder carries out screening process to the gangue, clinker and clay abrasive powder obtained after grinding, removes the wherein biggish portion of particle
Point, the abrasive flour of gangue 33%, clinker 19% and clay 16% after screening is added in blender, and is added thereto
Red mud 30% and adhesive 3% are eventually adding water, and starting blender is stirred mixing to the material of its inside, and revolving speed is
1.4m/s-1.7m/s, and the mixed material that obtained water content is 13%-14% is imported in aging bunker and is carried out 3-5 days
Ripening, temperature >=10 DEG C of ripening reuse the material after ageing after blender is stirred, by squeezing
Pressing machine extrusion molding obtains porous brick blank, and obtained porous brick blank is carried out drying and processing, makes water content therein
≤ 5.5%, the porous brick blank after drying and processing is sent into agglomerating plant and carries out calcination process at 900 DEG C -1100 DEG C
45min ± 2min obtains the porous brick having a size of 240mm*115mm*90mm, repairs to the porous brick that calcination process obtains
It is whole, and stacking.
Porous brick made from the present embodiment, cracking rate≤2.2% in use.
Embodiment 5
Gangue, clinker and clay are subjected to multiple stage crushing milled processed, reduces its granularity, obtains the grinding of each raw material
Powder carries out screening process to the gangue, clinker and clay abrasive powder obtained after grinding, removes the wherein biggish portion of particle
Point, the abrasive flour of gangue 35%, clinker 17% and clay 13% after screening is added in blender, and is added thereto
Red mud 33.5% and adhesive 1.5%, are eventually adding water, and starting blender is stirred mixing, revolving speed to the material of its inside
For 1.4m/s-1.7m/s, and the mixed material that obtained water content is 13%-14% is imported in aging bunker and carries out 3-5
Material after ageing is reused after blender is stirred, is passed through by it ripening, temperature >=10 DEG C of ripening
Single lead screw ex truding briquetting machine extrusion molding obtains porous brick blank, and obtained porous brick blank is carried out drying and processing, is made therein aqueous
Porous brick blank after drying and processing is sent into agglomerating plant and carries out calcination process at 900 DEG C -1100 DEG C by amount≤5.5%
45min ± 2min obtains the porous brick having a size of 240mm*115mm*90mm, repairs to the porous brick that calcination process obtains
It is whole, and stacking.
Porous brick made from the present embodiment, cracking rate≤2.5% in use.
The above is only a preferred embodiment of the present invention, it is noted that for the ordinary skill people of the art
For member, without departing from the technical principles of the invention, several improvements and modifications, these improvements and modifications can also be made
Also it should be regarded as protection scope of the present invention.
Claims (8)
1. a kind of crack resistence porous brick, which is characterized in that the raw material including following percentage:
2. a kind of crack resistence porous brick as described in claim 1, which is characterized in that preferred, the original including following percentage
Material:
3. a kind of crack resistence porous brick as described in any one of claim 1 and 2, which is characterized in that it is having a size of 240mm*
115mm*90mm。
4. a kind of preparation method of crack resistence porous brick, which comprises the following steps:
(1) crushing grinding: gangue, clinker and clay are subjected to multiple stage crushing milled processed, reduces its granularity, obtains each original
The abrasive flour of material;
(2) screening removal of impurities: screening process is carried out to the gangue, clinker and clay abrasive powder obtained after grinding, removal is wherein
The biggish part of particle;
(3) material mixes: the abrasive flour of gangue, clinker and clay after screening is added in blender, and thereto plus
Enter red mud and adhesive, be eventually adding water, starting blender is stirred mixing to the material of its inside;
(4) mixed material ripening: is imported in aging bunker to the ripening carried out 3-5 days;
(5) extrusion forming: the material after ageing is reused after blender is stirred, is extruded by single lead screw ex truding briquetting machine
Type obtains porous brick blank;
(6) drying and processing: obtained porous brick blank is subjected to drying and processing, makes water content≤5.5% therein;
(7) calcination process: the porous brick blank after drying and processing is sent into agglomerating plant and carries out calcination process, is obtained porous
Brick;
(8) it post-processes: the porous brick that calcination process obtains being modified, and stacking.
5. a kind of preparation method of crack resistence porous brick as claimed in claim 4, which is characterized in that stirred in the step (3)
Mixing revolving speed in machine is 1.4m/s-1.7m/s.
6. a kind of preparation method of crack resistence porous brick as claimed in claim 4, which is characterized in that mixed in the step (4)
The water content of material is obtained after conjunction as 13%-14%, and temperature >=10 DEG C of the ripening of mixed material.
7. a kind of preparation method of crack resistence porous brick as claimed in claim 4, which is characterized in that in the step (7)
Maturing temperature is 900 DEG C -1100 DEG C.
8. a kind of preparation method of crack resistence porous brick as claimed in claim 4, which is characterized in that in the step (7)
Calcining time is 45min ± 2min.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910013867.3A CN109503124A (en) | 2019-01-08 | 2019-01-08 | A kind of crack resistence porous brick and preparation method thereof |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201910013867.3A CN109503124A (en) | 2019-01-08 | 2019-01-08 | A kind of crack resistence porous brick and preparation method thereof |
Publications (1)
Publication Number | Publication Date |
---|---|
CN109503124A true CN109503124A (en) | 2019-03-22 |
Family
ID=65756243
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201910013867.3A Pending CN109503124A (en) | 2019-01-08 | 2019-01-08 | A kind of crack resistence porous brick and preparation method thereof |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN109503124A (en) |
Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2105420A1 (en) * | 2008-03-26 | 2009-09-30 | Council of Scientific&Industrial Research | A composition for building material and a process for the preparation thereof |
CN101666129A (en) * | 2009-08-04 | 2010-03-10 | 上海鑫晶山淤泥研发有限公司 | Construction waste sintering brick and production method thereof |
CN101830707A (en) * | 2010-03-29 | 2010-09-15 | 郑州市磊鑫实业有限公司 | Method for producing baked bricks from alumina red mud |
CN102503371A (en) * | 2011-10-28 | 2012-06-20 | 灵宝市华奥墙体建材有限责任公司 | Brick making method |
CN102795877A (en) * | 2012-08-29 | 2012-11-28 | 浙江嘉荣新型材料有限公司 | Energy-saving heat retaining rectangular-hole porous brick |
CN103030372A (en) * | 2012-12-16 | 2013-04-10 | 河南理工大学 | Bayer process red mud and gangue porous sintered brick and production method thereof |
CN108147782A (en) * | 2017-12-25 | 2018-06-12 | 合肥佳安建材有限公司 | Sintered coal gangue hollow brick and its production method |
CN108249888A (en) * | 2017-12-22 | 2018-07-06 | 广东科达洁能股份有限公司 | A kind of dedicated binding agent of sintering brick permeable to water and preparation method thereof |
-
2019
- 2019-01-08 CN CN201910013867.3A patent/CN109503124A/en active Pending
Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
EP2105420A1 (en) * | 2008-03-26 | 2009-09-30 | Council of Scientific&Industrial Research | A composition for building material and a process for the preparation thereof |
CN101666129A (en) * | 2009-08-04 | 2010-03-10 | 上海鑫晶山淤泥研发有限公司 | Construction waste sintering brick and production method thereof |
CN101830707A (en) * | 2010-03-29 | 2010-09-15 | 郑州市磊鑫实业有限公司 | Method for producing baked bricks from alumina red mud |
CN102503371A (en) * | 2011-10-28 | 2012-06-20 | 灵宝市华奥墙体建材有限责任公司 | Brick making method |
CN102795877A (en) * | 2012-08-29 | 2012-11-28 | 浙江嘉荣新型材料有限公司 | Energy-saving heat retaining rectangular-hole porous brick |
CN103030372A (en) * | 2012-12-16 | 2013-04-10 | 河南理工大学 | Bayer process red mud and gangue porous sintered brick and production method thereof |
CN108249888A (en) * | 2017-12-22 | 2018-07-06 | 广东科达洁能股份有限公司 | A kind of dedicated binding agent of sintering brick permeable to water and preparation method thereof |
CN108147782A (en) * | 2017-12-25 | 2018-06-12 | 合肥佳安建材有限公司 | Sintered coal gangue hollow brick and its production method |
Non-Patent Citations (1)
Title |
---|
株洲市革命委员会环境保护办公室: "《工业废渣综合利用》", 31 December 1975, 中国建筑工业出版社 * |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103922622B (en) | A kind of technique utilizing aluminium ash to produce aluminosulfate cement | |
CN107352928B (en) | Red mud-fly ash high-strength heat-insulation building block based on alkali excitation and preparation method thereof | |
CN102070309B (en) | Method for preparing hydraulic calcium oxide through papermaking alkali recycling causticized white sludge | |
CN101618971A (en) | Municipal sludge expanded ceramsite and preparation method thereof | |
CN102826827A (en) | Sintering pitchers brick with ceramics polishing slag serving as main material and production method of sintering pitchers brick | |
CN103641402A (en) | Baking-free brick prepared from red mud | |
CN102765928A (en) | Brick manufacturing method | |
CN103351117A (en) | Autoclaved blue brick or grey tile and manufacturing method thereof | |
CN101519282A (en) | Novel technology of vertical kiln for manufacturing cement clinker by utilizing dry acetylene sludge two-stage batching | |
CN104276808A (en) | High-strength perforated brick | |
CN113149525A (en) | Coal ash and red mud geopolymer material and preparation method thereof | |
CN103553537B (en) | Method of synthesizing magnesium silicate building material product by utilizing boron mud and coal ashes | |
CN111892381A (en) | Brick making process by utilizing solid building waste | |
CN106431203A (en) | Multi-waste-residue mixed sintered brick preparation method | |
CN105481303B (en) | It is made based on alkaline residue non-burning brick and preparation method thereof | |
CN108911608B (en) | Autoclaved sand-lime brick and preparation method thereof | |
CN104446363A (en) | Method of preparing ceramsite from manganese carbonate residues | |
CN102381864A (en) | Unburned brick prepared from main materials of red mud and magnesium slag | |
CN112919840A (en) | Waste rock resource utilization process | |
CN106892645A (en) | A kind of color bamboo fiber colliery wastes brick | |
CN104226667A (en) | Brick-concrete building slag recycling regeneration integrated apparatus and usage method thereof | |
CN109503124A (en) | A kind of crack resistence porous brick and preparation method thereof | |
CN103864306A (en) | Full-solid waste high-strength glass ceramic as well as preparation method and application thereof | |
CN111792886B (en) | Non-sintered slate tailing brick and preparation method thereof | |
CN211471245U (en) | System for preparing refractory aggregate by using aluminum profile sludge dry method |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
PB01 | Publication | ||
PB01 | Publication | ||
SE01 | Entry into force of request for substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190322 |
|
RJ01 | Rejection of invention patent application after publication |