CN109497390A - A kind of feed molasses special mildewproof agent and its preparation method and application - Google Patents
A kind of feed molasses special mildewproof agent and its preparation method and application Download PDFInfo
- Publication number
- CN109497390A CN109497390A CN201811628616.8A CN201811628616A CN109497390A CN 109497390 A CN109497390 A CN 109497390A CN 201811628616 A CN201811628616 A CN 201811628616A CN 109497390 A CN109497390 A CN 109497390A
- Authority
- CN
- China
- Prior art keywords
- molasses
- feed
- special mildewproof
- mildewproof agent
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 235000013379 molasses Nutrition 0.000 title claims abstract description 52
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- XBDQKXXYIPTUBI-UHFFFAOYSA-N dimethylselenoniopropionate Natural products CCC(O)=O XBDQKXXYIPTUBI-UHFFFAOYSA-N 0.000 claims abstract description 38
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 28
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- CHHHXKFHOYLYRE-UHFFFAOYSA-M 2,4-Hexadienoic acid, potassium salt (1:1), (2E,4E)- Chemical compound [K+].CC=CC=CC([O-])=O CHHHXKFHOYLYRE-UHFFFAOYSA-M 0.000 claims abstract description 20
- BEFDCLMNVWHSGT-UHFFFAOYSA-N ethenylcyclopentane Chemical compound C=CC1CCCC1 BEFDCLMNVWHSGT-UHFFFAOYSA-N 0.000 claims abstract description 20
- 235000010241 potassium sorbate Nutrition 0.000 claims abstract description 20
- 239000004302 potassium sorbate Substances 0.000 claims abstract description 20
- 229940069338 potassium sorbate Drugs 0.000 claims abstract description 20
- 235000010199 sorbic acid Nutrition 0.000 claims abstract description 20
- 239000004334 sorbic acid Substances 0.000 claims abstract description 20
- 229940075582 sorbic acid Drugs 0.000 claims abstract description 20
- 235000019260 propionic acid Nutrition 0.000 claims abstract description 19
- IUVKMZGDUIUOCP-BTNSXGMBSA-N quinbolone Chemical compound O([C@H]1CC[C@H]2[C@H]3[C@@H]([C@]4(C=CC(=O)C=C4CC3)C)CC[C@@]21C)C1=CCCC1 IUVKMZGDUIUOCP-BTNSXGMBSA-N 0.000 claims abstract description 19
- 239000004288 Sodium dehydroacetate Substances 0.000 claims abstract description 14
- 235000019259 sodium dehydroacetate Nutrition 0.000 claims abstract description 14
- 229940079839 sodium dehydroacetate Drugs 0.000 claims abstract description 14
- DSOWAKKSGYUMTF-GZOLSCHFSA-M sodium;(1e)-1-(6-methyl-2,4-dioxopyran-3-ylidene)ethanolate Chemical compound [Na+].C\C([O-])=C1/C(=O)OC(C)=CC1=O DSOWAKKSGYUMTF-GZOLSCHFSA-M 0.000 claims abstract description 14
- 229940095574 propionic acid Drugs 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 10
- 239000002994 raw material Substances 0.000 claims description 8
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims description 6
- 238000010790 dilution Methods 0.000 claims description 6
- 239000012895 dilution Substances 0.000 claims description 6
- 229910052708 sodium Inorganic materials 0.000 claims description 6
- 239000011734 sodium Substances 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 5
- 239000004287 Dehydroacetic acid Substances 0.000 claims 1
- 235000019258 dehydroacetic acid Nutrition 0.000 claims 1
- 229940061632 dehydroacetic acid Drugs 0.000 claims 1
- JEQRBTDTEKWZBW-UHFFFAOYSA-N dehydroacetic acid Chemical compound CC(=O)C1=C(O)OC(C)=CC1=O JEQRBTDTEKWZBW-UHFFFAOYSA-N 0.000 claims 1
- PGRHXDWITVMQBC-UHFFFAOYSA-N dehydroacetic acid Natural products CC(=O)C1C(=O)OC(C)=CC1=O PGRHXDWITVMQBC-UHFFFAOYSA-N 0.000 claims 1
- 239000007788 liquid Substances 0.000 abstract description 13
- 230000003449 preventive effect Effects 0.000 abstract description 10
- 238000004519 manufacturing process Methods 0.000 abstract description 7
- 239000000654 additive Substances 0.000 abstract description 2
- 230000000996 additive effect Effects 0.000 abstract description 2
- 230000015572 biosynthetic process Effects 0.000 abstract description 2
- 150000001875 compounds Chemical class 0.000 abstract description 2
- 238000004090 dissolution Methods 0.000 abstract description 2
- 239000003112 inhibitor Substances 0.000 description 8
- 238000003860 storage Methods 0.000 description 8
- 238000006356 dehydrogenation reaction Methods 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 235000021419 vinegar Nutrition 0.000 description 4
- 239000000052 vinegar Substances 0.000 description 4
- 238000006243 chemical reaction Methods 0.000 description 3
- 238000000034 method Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000007787 solid Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 1
- WPYMKLBDIGXBTP-UHFFFAOYSA-N benzoic acid Chemical compound OC(=O)C1=CC=CC=C1 WPYMKLBDIGXBTP-UHFFFAOYSA-N 0.000 description 1
- 229960004365 benzoic acid Drugs 0.000 description 1
- 230000000903 blocking effect Effects 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 238000000855 fermentation Methods 0.000 description 1
- 230000004151 fermentation Effects 0.000 description 1
- 235000019629 palatability Nutrition 0.000 description 1
- 239000000243 solution Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 230000009466 transformation Effects 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23L—FOODS, FOODSTUFFS, OR NON-ALCOHOLIC BEVERAGES, NOT COVERED BY SUBCLASSES A21D OR A23B-A23J; THEIR PREPARATION OR TREATMENT, e.g. COOKING, MODIFICATION OF NUTRITIVE QUALITIES, PHYSICAL TREATMENT; PRESERVATION OF FOODS OR FOODSTUFFS, IN GENERAL
- A23L3/00—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs
- A23L3/34—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals
- A23L3/3454—Preservation of foods or foodstuffs, in general, e.g. pasteurising, sterilising, specially adapted for foods or foodstuffs by treatment with chemicals in the form of liquids or solids
- A23L3/3463—Organic compounds; Microorganisms; Enzymes
- A23L3/3481—Organic compounds containing oxygen
- A23L3/3508—Organic compounds containing oxygen containing carboxyl groups
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23K—FODDER
- A23K10/00—Animal feeding-stuffs
- A23K10/30—Animal feeding-stuffs from material of plant origin, e.g. roots, seeds or hay; from material of fungal origin, e.g. mushrooms
- A23K10/33—Animal feeding-stuffs from material of plant origin, e.g. roots, seeds or hay; from material of fungal origin, e.g. mushrooms from molasses
-
- A—HUMAN NECESSITIES
- A23—FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
- A23V—INDEXING SCHEME RELATING TO FOODS, FOODSTUFFS OR NON-ALCOHOLIC BEVERAGES AND LACTIC OR PROPIONIC ACID BACTERIA USED IN FOODSTUFFS OR FOOD PREPARATION
- A23V2002/00—Food compositions, function of food ingredients or processes for food or foodstuffs
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P60/00—Technologies relating to agriculture, livestock or agroalimentary industries
- Y02P60/80—Food processing, e.g. use of renewable energies or variable speed drives in handling, conveying or stacking
- Y02P60/87—Re-use of by-products of food processing for fodder production
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Polymers & Plastics (AREA)
- Food Science & Technology (AREA)
- Health & Medical Sciences (AREA)
- Botany (AREA)
- Physiology (AREA)
- Animal Husbandry (AREA)
- Zoology (AREA)
- Mycology (AREA)
- Molecular Biology (AREA)
- Biotechnology (AREA)
- Microbiology (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Nutrition Science (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
- Fodder In General (AREA)
Abstract
The present invention discloses a kind of feed molasses special mildewproof agent comprising following component and its weight percent: propionic acid 50-80%;Potassium sorbate 5-20%;Sorbic acid 5-20%;Sodium dehydroacetate 0-20%;Water 1~20%.The present invention also provides the above-mentioned feed preparation method and application of molasses special mildewproof agent.The present invention compounds dissolution by propionic acid, potassium sorbate, sorbic acid, sodium dehydroacetate and water by a certain percentage, forms a kind of liquid mildew preventive.It can be good at dissolving sorbic acid, potassium sorbate, sodium dehydroacetate by propionic acid, water, the liquid fluidity of formation is good.While molasses are diluted with water, this liquid mildew preventive is added by certain additive amount, the shelf-life can meet and exceed no diluted molasses shelf-life, fully meet the production needs of feed factory, while extend the feed shelf-life.
Description
Technical field
The invention belongs to Midew preventive for feed preparation fields, and in particular to a kind of the feed agent of molasses special mildewproof and its preparation
Methods and applications.
Background technique
Molasses are widely applied in feed due to its high performance-price ratio (energy is high, palatability is good, price is low).But by
In its viscosity height, poor fluidity is very inconvenient in use, in order to improve its mobility, feed factory use when
Hou Douhui inside adds moisture, dilutes Related Component.But after moisture is added, molasses it is easy to appear fermentation and go mouldy again,
Especially summer just will appear denaturalization phenomenon in short-term class.
Feed factory is typically now exactly ready-to-use mode by the way of, but this has very big drawback, one, production
Process complications;Two, it needs individually to increase equipment;Three, equipment is easy to appear blocking.Due to above, there are also parts
Then existing composite mildew inhibitor in the market or single mould inhibitor are added in dilution, reaches using dilution is concentrated for feed factory
To the purpose to extend the shelf life, but its effect is not apparent.
The mould inhibitor that can be added in diluted molasses at present must be liquid or the Midew preventive for feed that can be dissolved in water entirely.
But feed currently on the market is with liquid mildew preventive generally all added with water-retaining agent, and water-retaining agent is entirely wave in molasses solubles
Take, while without the characteristic for sugar, anti-mold effect is unobvious.And solid mould inhibitor (such as potassium sorbate, double second of whole soln water
Sour sodium), predissolve, complex procedures are needed before use, while effect is not very good.Other solid mould inhibitor raw material (such as benzene
Formic acid, sorbic acid etc.), it cannot be dissolved into molasses solubles, anti-mold effect is very faint, guarantees the quality so as to cause diluted molasses solubles
Phase is short, apt to deteriorate.
Summary of the invention
In order to solve the problems, such as that short grade of diluted molasses solubles shelf-life in the prior art, the present invention provide a kind of feed use
Molasses special mildewproof agent and its preparation method and application, add the shelf-life after the mould inhibitor can meet and exceed it is not diluted
The molasses shelf-life, the production needs of feed factory are fully met, while extending the feed shelf-life.
To achieve the above object, the present invention adopts the following technical scheme:
The first purpose of the invention is to provide a kind of molasses special mildewproof agent of feed comprising following component and its again
Measure percentage:
Further, the feed molasses special mildewproof agent includes following component and its weight percent:
Further, the feed molasses special mildewproof agent includes following component and its weight percent:
A second object of the present invention is to provide a kind of preparation methods of above-mentioned feed molasses special mildewproof agent, including such as
Lower step:
Step a, predetermined amounts weigh raw material: propionic acid, potassium sorbate, sorbic acid, sodium dehydroacetate, water;
Step b, the raw material of step a is stirred, until being completely dissolved, is filtered and packaged to prepare molasses special mildewproof
Agent.
Further, the step b includes:
Propionic acid and water is added in step 1) in a kettle, opens stirring, and sorbic acid, potassium sorbate, dehydrogenation vinegar is then added
Sour sodium;
Step 2), stirring and dissolving, temperature 50 C is hereinafter, until be completely dissolved;
Step 3) after cooling to 30 DEG C, is filtered and packaged to prepare molasses special mildewproof agent.
Contain the above-mentioned feed molasses dilution of molasses special mildewproof agent third object of the present invention is to provide a kind of.
Further, the content of the molasses special mildewproof agent is 0.1~0.5wt%.
Fourth object of the present invention, which is a kind of above-mentioned feed, is extending molasses or feed is guaranteed the quality with the agent of molasses special mildewproof
Interim application.
Compared with prior art, the present invention at least has the following beneficial effects:
The present invention compounds dissolution by propionic acid, potassium sorbate, sorbic acid, sodium dehydroacetate and water by a certain percentage, is formed
A kind of liquid mildew preventive.It can be good at dissolving sorbic acid, potassium sorbate, sodium dehydroacetate, the liquid of formation by propionic acid, water
Good fluidity.While molasses are diluted with water, this liquid mildew preventive is added by certain additive amount, the shelf-life can reach
It arrives and is more than no diluted molasses shelf-life, fully meet the production needs of feed factory, while extending the feed shelf-life.
Specific embodiment
The present invention provides a kind of feed molasses special mildewproof agent comprising following component and its weight percent: propionic acid
50-80%;Potassium sorbate 5-20%;Sorbic acid 5-20%;Sodium dehydroacetate 0-20%;Water 1~20%.The present invention also provides upper
State the raw preparation method and application of feed molasses special mildewproof agent.
With reference to embodiment, the specific embodiment of the present invention is further described.Following embodiment is only used for more
Add and clearly demonstrate technical solution of the present invention, and not intended to limit the protection scope of the present invention.
Embodiment 1
1, it is formulated: propionic acid 70%;Water 5%;Sorbic acid 5%;Potassium sorbate 10%;Sodium dehydroacetate 10%;
2, production technology: output 1000KG
A, related raw material is accurately weighed by formula, 700 kilograms of propionic acid, 50 kilograms of water, 50 kilograms of sorbic acid, potassium sorbate
100 kilograms, 100 kilograms of sodium dehydroacetate;
B, propionic acid and water are added in 1000L reaction kettle, opens stirring, sorbic acid, potassium sorbate, dehydrogenation vinegar is then added
Sour sodium;
C, stirring and dissolving, temperature 50 C is hereinafter, until be completely dissolved;
D, it after cooling to 30 DEG C, filters and packages.
Embodiment 2
1, it is formulated: propionic acid 50%;Water 10%;Sorbic acid 12%;Potassium sorbate 8%;Sodium dehydroacetate 20%;
2, production technology: output 1000KG
A, related raw material is accurately weighed by formula, 500 kilograms of propionic acid, 100 kilograms of water, sorbic acid 120 kg, potassium sorbate
80 kilograms, 200 kilograms of sodium dehydroacetate;
B, propionic acid and water are added in 1000L reaction kettle, opens stirring, sorbic acid, potassium sorbate, dehydrogenation vinegar is then added
Sour sodium;
C, stirring and dissolving, temperature 50 C is hereinafter, until be completely dissolved;
D, it after cooling to 30 DEG C, filters and packages.
Application Example 1
1, it is formulated: propionic acid 58%;Water 4%;Sorbic acid 6%;Potassium sorbate 16%;Sodium dehydroacetate 16%;
2, production technology: output 1000KG
A, related raw material is accurately weighed by formula, 580 kilograms of propionic acid, 40 kilograms of water, 60 kilograms of sorbic acid, potassium sorbate
160 kilograms, 160 kilograms of sodium dehydroacetate;
B, propionic acid and water are added in 1000L reaction kettle, opens stirring, sorbic acid, potassium sorbate, dehydrogenation vinegar is then added
Sour sodium;
C, stirring and dissolving, temperature 50 C is hereinafter, until be completely dissolved;
D, it after cooling to 30 DEG C, filters and packages.
3, the dilution of molasses
By molasses 80%, water 20% dilutes, and the aforesaid liquid mould inhibitor of 0.2wt% is then added, is stored in storage tank;Together
When in a completely the same storage tank be added without add water molasses (storage tank specifications and models, condition of storage, storage capacity all one
It causes);One is also done by molasses 80%, water 20% dilutes, and the liquid mildew preventive in the market of 0.2t% is then added, is stored in
In tank (storage tank specifications and models, condition of storage, storage capacity are all consistent).The smell of molasses is every other day compared (with fresh molasses pair
Than and addition addition liquid mildew preventive in the market molasses), while observing whether liquid level has the more of floccule and floccule
It is few.
4, experimental conditions
By above-mentioned Application Example it is found that by experimental result, mould inhibitor of the present invention is fully able to solve very well
The problem of diluted molasses shelf-life, and its performance is better than liquid mildew preventive used in the prior art.
Specific embodiments of the present invention are described in detail above, but it is merely an example, the present invention is simultaneously unlimited
It is formed on particular embodiments described above.To those skilled in the art, any couple of present invention carries out equivalent modifications and
Substitution is also all among scope of the invention.Therefore, without departing from the spirit and scope of the invention made by equal transformation and
Modification, all should be contained within the scope of the invention.
Claims (8)
1. a kind of molasses special mildewproof agent of feed, which is characterized in that including following component and its weight percent:
2. a kind of feed according to claim 1 molasses special mildewproof agent, which is characterized in that including following component and its
Weight percent:
3. a kind of feed according to claim 2 molasses special mildewproof agent, which is characterized in that including following component and its
Weight percent:
4. a kind of preparation method of feed according to any one of claims 1 to 3 molasses special mildewproof agent, feature exist
In including the following steps:
Step a, predetermined amounts weigh raw material: propionic acid, potassium sorbate, sorbic acid, sodium dehydroacetate, water;
Step b, the raw material of step a is stirred, until being completely dissolved, is filtered and packaged to prepare molasses special mildewproof agent.
5. the feed according to claim 4 preparation method of molasses special mildewproof agent, which is characterized in that the step b
Include:
Propionic acid and water is added in step 1) in a kettle, opens stirring, and sorbic acid, potassium sorbate, dehydroacetic acid is then added
Sodium;
Step 2), stirring and dissolving, temperature 50 C is hereinafter, until be completely dissolved;
Step 3) after cooling to 30 DEG C, is filtered and packaged to prepare molasses special mildewproof agent.
6. a kind of contain the feed according to any one of claims 1 to 3 molasses dilution of molasses special mildewproof agent.
7. molasses dilution according to claim 6, which is characterized in that the content of the molasses special mildewproof agent is 0.1
~0.5wt%.
8. a kind of feed according to any one of claims 1 to 3 is extending molasses or feed guarantor with the agent of molasses special mildewproof
The interim application of matter.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811628616.8A CN109497390A (en) | 2018-12-28 | 2018-12-28 | A kind of feed molasses special mildewproof agent and its preparation method and application |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201811628616.8A CN109497390A (en) | 2018-12-28 | 2018-12-28 | A kind of feed molasses special mildewproof agent and its preparation method and application |
Publications (1)
Publication Number | Publication Date |
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CN109497390A true CN109497390A (en) | 2019-03-22 |
Family
ID=65755703
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201811628616.8A Pending CN109497390A (en) | 2018-12-28 | 2018-12-28 | A kind of feed molasses special mildewproof agent and its preparation method and application |
Country Status (1)
Country | Link |
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CN (1) | CN109497390A (en) |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN110050886A (en) * | 2019-05-15 | 2019-07-26 | 北京波尔莱特饲料有限公司 | A kind of dry and wet mixing complete feed of long shelf-life and preparation method thereof |
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---|---|---|---|---|
AT502601A1 (en) * | 2003-03-11 | 2007-04-15 | Tulln Zuckerforschung Gmbh | METHOD FOR PRODUCING SUGAR OR SUGAR-CONTAINING PRODUCTS FROM SUGAR-CONTAINING VEGETABLE RAW MATERIALS |
CN103168974A (en) * | 2013-03-25 | 2013-06-26 | 重庆民泰香料化工有限责任公司 | Liquid mildewproof agent for feed and method for avoiding mildew of feed |
CN103442597A (en) * | 2011-02-24 | 2013-12-11 | 百事可乐公司 | Reduction of sorbic acid precipitation |
CN104994751A (en) * | 2013-01-31 | 2015-10-21 | 百事可乐公司 | Stabilizing sorbic acid or benzoic acid in syrups and finished beverages |
CN108935983A (en) * | 2018-06-20 | 2018-12-07 | 刘吉生 | A kind of milk cow fully mixed diet additive |
-
2018
- 2018-12-28 CN CN201811628616.8A patent/CN109497390A/en active Pending
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AT502601A1 (en) * | 2003-03-11 | 2007-04-15 | Tulln Zuckerforschung Gmbh | METHOD FOR PRODUCING SUGAR OR SUGAR-CONTAINING PRODUCTS FROM SUGAR-CONTAINING VEGETABLE RAW MATERIALS |
CN103442597A (en) * | 2011-02-24 | 2013-12-11 | 百事可乐公司 | Reduction of sorbic acid precipitation |
CN104994751A (en) * | 2013-01-31 | 2015-10-21 | 百事可乐公司 | Stabilizing sorbic acid or benzoic acid in syrups and finished beverages |
CN103168974A (en) * | 2013-03-25 | 2013-06-26 | 重庆民泰香料化工有限责任公司 | Liquid mildewproof agent for feed and method for avoiding mildew of feed |
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Title |
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CN110050886A (en) * | 2019-05-15 | 2019-07-26 | 北京波尔莱特饲料有限公司 | A kind of dry and wet mixing complete feed of long shelf-life and preparation method thereof |
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PB01 | Publication | ||
PB01 | Publication | ||
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RJ01 | Rejection of invention patent application after publication | ||
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Application publication date: 20190322 |