CN109497058A - A kind of glyphosate synergist of effects enhancing and dose reducing - Google Patents
A kind of glyphosate synergist of effects enhancing and dose reducing Download PDFInfo
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- CN109497058A CN109497058A CN201811471916.XA CN201811471916A CN109497058A CN 109497058 A CN109497058 A CN 109497058A CN 201811471916 A CN201811471916 A CN 201811471916A CN 109497058 A CN109497058 A CN 109497058A
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- Prior art keywords
- glyphosate
- dose reducing
- synergist
- effects enhancing
- reducing according
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Classifications
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- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/30—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests characterised by the surfactants
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/24—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing ingredients to enhance the sticking of the active ingredients
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/18—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds
- A01N57/20—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-carbon bonds containing acyclic or cycloaliphatic radicals
Abstract
The invention discloses a kind of glyphosate synergists of effects enhancing and dose reducing, belong to technical field of pesticide, and the present invention has many advantages, such as that the good compatibility of builder, synergy are obvious and are substantially reduced herbicide dosage.The glyphosate synergist of the effects enhancing and dose reducing includes the component of following weight percent meter: photoinitiator 0.5-10%, and surfactant 10-40%, prepolymer 5-20%, polysiloxanes 5-20%, pH adjusting agent 1-10%, organic solvent 1-10%, surplus is water.
Description
Technical field
The invention belongs to technical field of pesticide, and in particular to a kind of glyphosate synergist of effects enhancing and dose reducing.
Background technique
In recent years, due to long-term a large amount of uses of the pernicious variation of weather conditions and farmland chemical pesticide, agricultural pests pair
The resistance of chemical pesticide rises comparatively fast, causes the preventive effect of chemical pesticide poor, the utilization rate of chemical pesticide is low, while seriously polluted
Ecological environment.Insecticides adjuvant is the general name of the used various adjuvants in addition to effective ingredient in chemical pesticide processing dosage form.
Auxiliary agent itself is indispensable additive without bioactivity, but in novel form formula or in application, adds the master of auxiliary agent
Syllabus is to improve drug effect, reduces pesticide dosage, and save the cost reduces residual of the pesticide on crops and the dirt to environment
Dye.
Pesticide synergistic agent is the compound of a kind of basic inactive, but it is mixed with chemical pesticide when, chemistry can be improved
The surface tension of pesticide improves spread, dispersion and permeability etc., is conducive to wetting of the chemical pesticide medical fluid in plant leaf surface, paving
Exhibition, infiltration and absorption, can be improved chemical pesticide bioactivity, extend drug effect validity period, improve pesticide utilization rate, and it is residual to reduce pesticide
It stays, reduces cost, while achieving the purpose that preserve the ecological environment.
Synergist is mainly in herbicide aqua at present: tallow amine ethoxy compound, fatty alcohol polyoxyethylene ether,
Alkyl polyglycoside, organic silicon and other compounds.However existing aqua builder product there are compositions single, aqua synergy
Agent effect is unobvious, quick-acting is poor, aqua builder remains high, difficult to degrade, synergist unfriendly to environment and formulation products
Compatibility performance it is poor, even influence pesticidal preparations physicochemical property, cause aqua formulation products to be layered and flocculent undissolved substance occur etc.
Problem.
The synergist of glyphosate more focuses on the effect promoting of glyphosate at present, improves the herbicide effect of herbicide, still
In actual use, peasant household will increase the usage amount of pesticide usually to reach better herbicidal effect, therefore in addition synergist
To improve herbicidal effect meaning and little.And excessive use pesticide causes more to pollute to environment.
It is lost since glyphosate can largely drip during sprinkling from target, only least a portion of medical fluid can be attached to
On target, simultaneously because the influence of the environmental factors such as wind, rainwater, the medical fluid being attached on target is also easy by the leaching loss that hangs, because
This improves medical fluid the main reason for the adhesion strength on target is to improve drug effect.But target adhesion strength is improved in conventional synergist
Biggish macromolecule raw material of some viscositys etc. need to be added, while can also improve the viscosity of synergist, when use has certain tired
Difficulty, therefore a kind of auxiliary agent with effects enhancing and dose reducing is developed to reduce the usage amount of pesticide, drug effect is improved, current country one is more met
The developing direction that control two subtracts.
Notification number is CN102396449B, and the day for announcing is that on 07 03rd, 2013 Chinese patent literature discloses a kind of grass
Sweet phosphine ammonium salt aqua builder, it is characterised in that: the component including following weight percent meter: 120,000 basic sodium sulfonates
25-35%, cetyl trimethylammonium bromide 10-15%, alkyl glycosides 6-10%, lecithin 10-15%, organic silicon defoamer
AF-9000 0.005-0.1% and surplus are deionized water.
The patent passes through 120,000 basic sodium sulfonates, cetyl trimethylammonium bromide, alkyl glycosides, lecithin, organic
The compounding of silicon defoaming agent AF-9000 and deionized water are realized and reduce ammonium glyphosate aqua dosage and increase herbicidal effect, still
The compatibility of the builder is bad, synergy is unobvious and reduces the disadvantages of herbicide dosage is small, adhesion strength is insufficient.
Summary of the invention
Present invention seek to address that above-mentioned the deficiencies in the prior art, it is good that the present invention provides a kind of adhesion strength, good compatibility, use
The glyphosate synergist of effects enhancing and dose reducing that is convenient, improving glyphosate drug effect and enough reduction glyphosate dosages.It is light-initiated by adding
Agent and prepolymer enable medical fluid to encounter the spontaneous carry out polymerization reaction of illumination after spraying, improve the viscosity of medical fluid, thus
Drug effect is improved, the dosage of glyphosate is reduced.
The purpose of the present invention is what is be achieved through the following technical solutions:
A kind of glyphosate synergist of effects enhancing and dose reducing, it is characterised in that: the component including following weight percent meter:
Photoinitiator 0.5-10%
Surfactant 10-40%
Prepolymer 5-20%
Polysiloxanes 5-20%
PH adjusting agent 1-10%
Organic solvent 1-10%
Surplus is water.
Preferably, the photoinitiator is styrax, benzoin dimethylether, benzoin ethyl ether, benzoin isopropyl ether, rests in peace
Fragrant butyl ether, diphenylethan, α, alpha, alpha-dimethyl oxygroup-α-phenyl acetophenone, α, α-diethoxy acetophenone, alpha-hydroxyalkyl benzophenone,
α-amine alkyl phenones, aroyl phosphine oxide, bis(benzoylphenyl) phosphine oxide, benzophenone, 2,4 dihydroxyl benzophenone,
Michler's keton, thio propoxyl group thioxanthone, isopropyl thioxanthone, diaryl iodonium salt, triaryl salt compounded of iodine, alkyl iodide
One of salt, isopropylbenzene cyclopentadienyl iron hexafluorophosphate are a variety of.
Preferably, the surfactant is aliphatic acid polyethenoxy ether, fatty alcohol polyoxyethylene ether, alkyl glycosides, sweet tea
One or more of dish alkali, alkoxylated alkylamines.
Preferably, the polysiloxanes is dimethyl polysiloxane, trisiloxanes polyethers, tetramethyl tetraphenyl trimerization silicon oxygen
One or more of alkane.
Preferably, the prepolymer is epoxy acrylate, urethane acrylate, polyether acrylate, polyester third
One of olefin(e) acid ester, acrylic resin are a variety of.
Preferably, the pH adjusting agent is ethanol amine, diethanol, triethanolamine, sodium hydroxide, potassium hydroxide, phosphoric acid, grass
One of acid, citric acid, sulfuric acid are a variety of.
Preferably, the solvent is vegetable oil, ethyl alcohol, ethylene glycol, propylene glycol, glycerine, N-Methyl pyrrolidone, N- pungent
Base pyrrolidones, N ,-N-dimethylformamide, N ,-N dimethyl acetamide, N, one of-N dimethyl decyl amide or a variety of.
Preferably, the component including following weight percent meter:
Photoinitiator 1-5%
Surfactant 20-30%
Prepolymer 10-20%
Polysiloxanes 5-10%
PH adjusting agent 1-5%
Organic solvent 3-5%
Surplus is water.
Preferably, the component including following weight percent meter:
Photoinitiator 3%
Surfactant 30%
Prepolymer 15%
Polysiloxanes 10%
PH adjusting agent 3%
Organic solvent 5%
Surplus is water.
The technical program has the beneficial effect that:
1, the present invention passes through addition photoinitiator and prepolymer.Photoinitiator is that a kind of light-sensitive catalyst is mixed with prepolymer
Afterwards, it can be generated free radicals under the action of ultraviolet light, make interreaction between prepolymer, crosslinking dimerization is macromolecule chemical combination
Object can be improved deposition of the glyphosate on weeds, reduce the loss of effective component, simultaneously to increase the viscosity of medical fluid
Absorption and conduction of the weeds to herbicide can be significantly improved, so as to improve product drug effect.
2, the present invention can reduce the dosage of glyphosate, improve the utilization rate of glyphosate, reduce product use cost, reduce
Residual of the pesticide in plant and soil.
3, the builder good compatibility that the present invention prepares can be applied to glyphosate as formula addition or logical mixed auxiliary agent
In formulation products.
Specific embodiment
It is further illustrated below by several specific embodiments and realizes the object of the invention technical solution, need to illustrate
It is that claimed technical solution includes but is not limited to following embodiment.
Embodiment 1
Take benzoin dimethylether 0.5%, fatty alcohol polyoxyethylene ether 40%, trisiloxanes polyethers 5%, epoxy acrylate 5%, diethyl
Alcohol 10%, N-Methyl pyrrolidone 10%, then plus 29.5% water, be uniformly mixed and can be prepared by herbicide special synergistic auxiliary agent
1。
Embodiment 2
Take benzoin isobutyl ether 10%, alkyl glycosides 10%, tetramethyl tetraphenyl cyclotrisiloxane 20%, urethane acrylate 20%,
Sodium hydroxide 1%, N ,-N-dimethylformamide 1% add 38% water, are uniformly mixed and can be prepared by the dedicated increasing of herbicide
Imitate auxiliary agent 2.
Embodiment 3
Take alpha-hydroxyalkyl benzophenone 5.25%, glycine betaine 25%, trisiloxanes polyethers 12.5%, polyether acrylate 12.5%, three ethyl alcohol
Amine 5.5%, N ,-N dimethyl decyl amide 5.5%, add 34.75% water, are uniformly mixed and can be prepared by the dedicated increasing of herbicide
Imitate auxiliary agent 3.
Embodiment 4
Take benzophenone 5%, alkoxylated alkylamines 20%, dimethyl polysiloxane 10%, polyether acrylate 10%, potassium hydroxide
5%, vegetable oil 5% adds 45% water, is uniformly mixed and can be prepared by herbicide special synergistic auxiliary agent 4.
Embodiment 5
Take diaryl iodonium salt 2%, Michler's keton 1%, alkyl glycosides 15%, glycine betaine 10%, tetramethyl tetraphenyl cyclotrisiloxane
10%, dimethyl polysiloxane 5%, acrylic resin 5%, urethane acrylate 2.5%, ethanol amine 2%, citric acid 1%, N- methyl
Pyrrolidones 2%, ethyl alcohol 1%, add 43.5% water, are uniformly mixed and can be prepared by herbicide special synergistic auxiliary agent 5.
Embodiment 6
Take isopropyl thioxanthone 1%, benzoin dimethylether 1%, benzoin ethyl ether 1%, aliphatic acid polyethenoxy ether 10%, fatty acid
Polyoxyethylene ether 10%, fatty alcohol polyoxyethylene ether 10%, trisiloxanes polyethers 10%, polyester acrylate 15%, triethanolamine 3%,
N-octylpyrrolidone 5% adds 34% water, is uniformly mixed and can be prepared by herbicide special synergistic auxiliary agent 6.
Embodiment 7
The present invention and the prior art data table of comparisons:
Processing 1-3 is commercially available 41% glyphosate isopropylamine salt water solution product, and processing 4-9 is the herbicide for adding 30% embodiment 1-6
41% glyphosate isopropylamine salt water solution of special assistant is handled.Test sample viscosity after each processing sample preparation is good, then by sample
It is placed in the place of direct sunlight, after placing 1 hour, is being carried out.
Processing 10-13 is commercially available 200g/L gyphosate solution product, and the herbicide that processing 14-25 is embodiment 1-6 is dedicated
Auxiliary agent uses the processing of Different adding amount；Handling the herbicide special assistant that 27-53 is embodiment 1-6 reduces herbicide dosage
Processing；Processing 26 is clear water control treatment.Each experimental plot 100m2, each cell water consumption is 4.5L, and cell is arranged at random
Column.After application 7 days, 14 days, investigate citrus orchard weeds respectively and prevent and kill off situation.
Strain number investigation is carried out after investigational agent after 7 days and 14 days, investigates each treatment region survival weeds strain number, statistic record.Medicine
It is as follows to imitate calculation formula:
And with the new multipole of Deng Kenshi
Poor (DMRT) method analyzes the significance of difference.
Particular embodiments described above has carried out further specifically the purpose of the present invention, technical scheme and beneficial effects
It is bright, it should be understood that above is only a specific embodiment of the present invention, be not intended to restrict the invention, it is all in the present invention
Spirit and principle within, any modification, equivalent substitution, improvement and etc. done, should be included in protection scope of the present invention it
It is interior.
Claims (9)
1. a kind of glyphosate synergist of effects enhancing and dose reducing, it is characterised in that: the component including following weight percent meter:
Photoinitiator 0.5-10%
Surfactant 10-40%
Prepolymer 5-20%
Polysiloxanes 5-20%
PH adjusting agent 1-10%
Organic solvent 1-10%
Surplus is water.
2. the glyphosate synergist of effects enhancing and dose reducing according to claim 1, it is characterised in that: described includes following weight hundred
Divide the component than meter:
Photoinitiator 1-5%
Surfactant 20-30%
Prepolymer 10-20%
Polysiloxanes 5-10%
PH adjusting agent 1-5%
Organic solvent 3-5%
Surplus is water.
3. the glyphosate synergist of effects enhancing and dose reducing according to claim 1, it is characterised in that: described includes following weight hundred
Divide the component than meter:
Photoinitiator 3%
Surfactant 30%
Prepolymer 15%
Polysiloxanes 10%
PH adjusting agent 3%
Organic solvent 5%
Surplus is water.
4. the glyphosate synergist of effects enhancing and dose reducing according to claim 1, it is characterised in that: the photoinitiator is to rest in peace
Perfume, benzoin dimethylether, benzoin ethyl ether, benzoin isopropyl ether, benzoin isobutyl ether, diphenylethan, α, alpha, alpha-dimethyl oxygroup-α-
Phenyl acetophenone, α, α-diethoxy acetophenone, alpha-hydroxyalkyl benzophenone, α-amine alkyl phenones, aroyl phosphine oxide, double benzene first
Aminosulfonylphenyl phosphine oxide, benzophenone, 2,4 dihydroxyl benzophenone, Michler's keton, thio propoxyl group thioxanthone, isopropyl sulphur
One of miscellaneous anthrone, diaryl iodonium salt, triaryl salt compounded of iodine, alkyl salt compounded of iodine, isopropylbenzene cyclopentadienyl iron hexafluorophosphate are more
Kind.
5. the glyphosate synergist of effects enhancing and dose reducing according to claim 1, it is characterised in that: the surfactant is rouge
One of fat acid polyoxyethylene ether, fatty alcohol polyoxyethylene ether, alkyl glycosides, glycine betaine, alkoxylated alkylamines are more
Kind.
6. the glyphosate synergist of effects enhancing and dose reducing according to claim 1, it is characterised in that: the polysiloxanes is diformazan
One or more of based polysiloxane, trisiloxanes polyethers, tetramethyl tetraphenyl cyclotrisiloxane.
7. the glyphosate synergist of effects enhancing and dose reducing according to claim 1, it is characterised in that: the prepolymer is epoxy
One of acrylate, urethane acrylate, polyether acrylate, polyester acrylate, acrylic resin are a variety of.
8. the glyphosate synergist of effects enhancing and dose reducing according to claim 1, it is characterised in that: the pH adjusting agent is ethyl alcohol
One of amine, diethanol, triethanolamine, sodium hydroxide, potassium hydroxide, phosphoric acid, oxalic acid, citric acid, sulfuric acid are a variety of.
9. the glyphosate synergist of effects enhancing and dose reducing according to claim 1, it is characterised in that: the solvent be vegetable oil,
Ethyl alcohol, ethylene glycol, propylene glycol, glycerine, N-Methyl pyrrolidone, n-octylpyrrolidone, N ,-N-dimethylformamide, N ,-N
Dimethyl acetamide, N, one of-N dimethyl decyl amide or a variety of.
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110506581A (en) * | 2019-08-30 | 2019-11-29 | 贵州省果树科学研究所 | A kind of dragon fruit antifreeze, production method and its application |
| CN113475524A (en) * | 2021-06-28 | 2021-10-08 | 江苏腾龙生物药业有限公司 | Preparation method of glyphosate isopropylamine salt aqueous solution |
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| CN110506581A (en) * | 2019-08-30 | 2019-11-29 | 贵州省果树科学研究所 | A kind of dragon fruit antifreeze, production method and its application |
| CN113475524A (en) * | 2021-06-28 | 2021-10-08 | 江苏腾龙生物药业有限公司 | Preparation method of glyphosate isopropylamine salt aqueous solution |
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