CN109496239A

CN109496239A - Steel for mechanical structure

Info

Publication number: CN109496239A
Application number: CN201780046552.8A
Authority: CN
Inventors: 桥村雅之; 江头诚; 藤堂尚二; 岩桥孝典
Original assignee: Nippon Steel Corp
Current assignee: Nippon Steel Corp
Priority date: 2016-07-27
Filing date: 2017-07-27
Publication date: 2019-03-19
Also published as: KR20190034273A; EP3492615A1; JP6760379B2; US20190169723A1; WO2018021452A1; EP3492615A4; JPWO2018021452A1

Abstract

The steel for mechanical structure that can obtain machinability, characteristic of getting rusty and excellent, rolling contact fatigue excellent the carburized component of hot ductility is provided.The steel for mechanical structure of present embodiment has following chemical composition: containing C:0.15% more than and less than 0.30%, Si:0.01~0.80%, Mn:0.20~2.00%, P:0.030% or less, S:0.010~0.100%, Pb:0.010~0.100%, Al:0.010~0.050%, N:0.015% or less, O:0.0005~0.0030% and Cr:0.50~2.00% in terms of quality %, surplus is Fe and impurity, and meets formula (1).The total number of specific field trash contained in steel is 40/mm²More than, the specific field trash is any one of MnS field trash, Pb field trash and complex inclusion containing MnS and Pb, and equivalent circle diameter is 5 μm or more.Mn/S >=8.0 (1) herein, substitute into the content (quality %) of respective element at each element in formula (1).

Description

Steel for mechanical structure

Technical field

The present invention relates to steel, are more specifically related to steel for mechanical structure.

Background technique

The mechanical part of the structural applications such as component for common mechanical, automobile and power transmission purposes is sometimes required that Excellent rolling contact fatigue characteristic.An example of the manufacturing method of this mechanical part is as follows.By steel for mechanical structure hot-working (hot forging Deng), manufacture intermediate.Intermediate machining (machining, grinding) is manufactured into mechanical part.According to need It wants, can also implement Surface hardening treatment to mechanical part sometimes.Surface hardening treatment is, for example, Carburization Treatment.To for manufacturing this The steel for mechanical structure of kind mechanical part, does not require nothing more than excellent hot-workability, also requires excellent machinability.

The steel for mechanical structure of excellent in machinability is also referred to as automatic steel, in JIS G 4804 (2008) (non-patent text It offers in 1) and is defined.Automatic steel is by containing Pb, to improve machinability.

Steel for mechanical structure containing Pb is for example open by Japanese Unexamined Patent Publication 2000-282172 bulletin (patent document 1).Specially Machine structural steel product documented by sharp document 1 have chemical composition below: in terms of quality % containing C:0.05~0.55%, Si:0.50~2.5%, Mn:0.01~2.00%, S:0.005~0.080%, Cr:0~2.0%, P:0.035% or less, V:0 ~0.50%, N:0.0150% or less, Al:0.04% or less, Ni:0~2.0%, Mo:0~1.5%, B:0~0.01%, Bi: 0~0.10%, Ca:0~0.05%, Pb:0~0.12%, Ti:0 more than and less than 0.04%, Zr:0 more than and less than 0.04% and Ti (%)+Zr (%): 0 more than and less than 0.04%, Te:0~0.05%, Nd:0~0.05%, Nb:0~ 0.1%, Cu:0~1.5%, Se:0~0.5%, the value for meeting fn1 shown in following formula is 100 or less, fn2's shown in following formula Value is that the value of 0 or more, fn3 shown in following formula is 3.0 or more, and surplus is Fe and impurity.In turn, in terms of area ratio, ferrite It is 160~350 that mutually shared ratio, which is 10~80%, Hv hardness, in the tissue.Wherein, fn1=100C+11Si+18Mn+32Cr + 45Mo+6V, fn2=-23C+Si (5-2Si) -4Mn+104S-3Cr-9V+10, fn3=3.2C+0.8Mn+5.2S+0.5Cr- 120N+2.6Pb+4.1Bi-0.001α²+0.13α.The symbol of element in various indicates the content of the element in terms of quality %, α Indicate the area ratio (%) of the ferritic phase in tissue.The machinability of the machine structural steel product is described in patent document 1 And excellent tenacity.

Existing technical literature

Patent document

Patent document 1: Japanese Unexamined Patent Publication 2000-282172 bulletin

Non-patent literature

Non-patent literature 1: Japan Industrial Standards Survey, standard number: JIS G 4804 (2008), title: sulphur With sulphur combined processing automatic steel steel

Summary of the invention

Problems to be solved by the invention

But the machinings such as machining can be implemented sometimes using the manufacturing equipment of automation.Utilize automation When manufacturing equipment carries out machining with first-class a large amount of intermediate to several hundred in 1 day to manufacture mechanical part, it is desirable that Excellent chip treatability.It is preferred that by being divided into fritter to be discharged with the chip of cutting discharge.In the feelings that chip continues longlyer Under condition, chip can be entangled in intermediate, and the surface for being easy the mechanical part after cutting generates flaw.Machinery is entangled in chip In the case where on component, in order to remove the chip of winding, it is also necessary to temporarily cease production line.In which case it is difficult in nothing It manufactures, is needed with the personnel for being ready for use on monitoring under people's state.In this way, chip treatability will affect the quality and manufacture of mechanical part Cost these two aspects.In turn, in the manufacturing equipment of automation, if tool wear is more, productivity can be reduced.Therefore, for Steel for mechanical structure, it is desirable that be such as able to suppress the excellent high machinability of tool wear, chip treatability.

The case where being got rusty using the machining of the manufacturing equipment of automation there is also mechanical part.In the manufacture of automation In equipment, from unattended angle, Water-soluble cutting oil is used.Therefore, machine part gets rusty sometimes.Rust is not only The reason of generating form error, and will also become the bad reason of quality when implementing plating to mechanical part.In turn, Mechanical part after cutting is equal standby for a long time in charging basket sometimes during after cutting until subsequent processing.Example Such as, machining is carried out at home, and subsequent processing is in the case where processing in another factory of other countries, after cutting Sometimes through the time in a few days~some months until implementing subsequent processing.Therefore, steel for mechanical structure is not required nothing more than and is cut Cutting property, and require the characteristic (hereinafter referred to as " characteristic of getting rusty ") for inhibiting to get rusty.

The object of the present invention is to provide: machinability, characteristic of getting rusty can be obtained and had superior hot workability, rolling contact fatigue spy The steel for mechanical structure of the excellent mechanical part of property.

The solution to the problem

Steel for mechanical structure of the invention have following chemical composition: in terms of quality % containing C:0.15% more than and less than 0.30%, Si:0.01~0.80%, Mn:0.20~2.00%, P:0.030% or less, S:0.010~0.100%, Pb: 0.010~0.100%, Al:0.010~0.050%, N:0.015% or less, O:0.0005~0.0030%, Cr:0.50~ 2.00%, Ni:0~3.50%, B:0~0.0050%, V:0~0.70%, Mo:0~0.70%, W:0~0.70%, Nb:0 with Upper and less than 0.050%, Cu:0~0.50%, Ti:0~0.100% and Ca:0~0.0030%, surplus is Fe and impurity, and Meet formula (1).In steel, the total number of specific field trash is 40/mm²More than, the specific field trash be MnS field trash, Any one of Pb field trash and the complex inclusion containing MnS and Pb, and equivalent circle diameter is 5 μm or more.

Mn/S≥8.0(1)

Herein, the content (quality %) of respective element is substituted at each element in formula (1).

The effect of invention

Steel for mechanical structure of the invention can obtain machinability, characteristic of getting rusty and have superior hot workability, rolling contact fatigue characteristic Excellent mechanical part.

Detailed description of the invention

Figure 1A is the schematic diagram for showing the S distribution in the viewing surface analyzed by EPMA.

Figure 1B is the schematic diagram for showing the Pb distribution in viewing surface being analyzed by EPMA, identical with Figure 1A.

Fig. 1 C is by the schematic diagram of the image after Figure 1A and Figure 1B synthesis.

Fig. 2 is for the schematic diagram whether being illustrated the judgment criteria that adjacent field trash is considered as 1 field trash.

Fig. 3 is the cross-sectional view of the blank cast.

Fig. 4 is the schematic diagram for illustrating the cutting test machine of cutting test.

Fig. 5 A is the perspective view of chip.

Fig. 5 B is the top view photograph figure of chip.

Fig. 6 is the main view and side view of rolling fatigue testing piece used in rolling fatigue testing.

Fig. 7 is the schematic diagram for illustrating the push type rolling fatigue testing machine of rolling fatigue testing.

Specific embodiment

The inventors of the present invention implement investigation and research to the machinability, characteristic of getting rusty and hot-workability of steel for mechanical structure. Its result thinks, if the steel for mechanical structure with following chemical composition, then has and obtains excellent machinability and excellent heat The possibility of excellent rolling contact fatigue characteristic is obtained after processability, Carburization Treatment: containing C:0.15% or more and small in terms of quality % In 0.30%, Si:0.01~0.80%, Mn:0.20~2.00%, P:0.030% or less, S:0.010~0.100%, Pb: 0.010~0.100%, Al:0.010~0.050%, N:0.015% or less, O:0.0005~0.0030%, Cr:0.50~ 2.00%, Ni:0~3.50%, B:0~0.0050%, V:0~0.70%, Mo:0~0.70%, W:0~0.70%, Nb:0 with Above and less than 0.050%, Cu:0~0.50%, Ti:0~0.100% and Ca:0~0.0030%, surplus is Fe and impurity.

Mn in steel generates MnS in conjunction with S.MnS is divided into MnS field trash and MnS precipitate according to its generating process.MnS Field trash crystallization in the molten steel before solidification.And MnS precipitate is then precipitated in steel after solidification.MnS field trash is in molten steel It generates.Therefore, the size of MnS field trash tends to get bigger compared with the MnS precipitate generated after solidification.

On the other hand, the Pb in steel is not solid-solubilized in steel substantially, is existed in the form of Pb field trash (Pb particle).MnS folder Sundries and Pb field trash can improve the machinability of steel.

In turn, there are in the case where Mn and Pb in steel, Mn and Pb will form other than above-mentioned MnS field trash, Pb field trash Complex inclusion (hereinafter also referred to as " complex inclusion ") containing MnS and Pb.Complex inclusion refer to containing MnS and Pb and Surplus is the field trash of impurity.More specifically, complex inclusion is adjoined each other by MnS and Pb sometimes and is constituted, also sometimes Pb It is dissolved in MnS and forms complex inclusion.In the present specification, " MnS field trash ", " Pb field trash ", " complex inclusion " Method documented by project by aftermentioned " number TN and RA measuring method " determines.In the present specification, MnS field trash It is containing Mn and S and without the field trash of Pb.Pb field trash is the field trash for forming and being free of Mn by Pb and impurity.Duplex impurity Object is the field trash containing Mn, S and Pb.

MnS field trash is known as the field trash for improving machinability.On the other hand, the fusing point of Pb field trash is less than The fusing point of MnS field trash.Therefore, Pb field trash plays lubricating action in cutting, as a result improves the machinability of steel.

In turn, it is believed that complex inclusion can improve the machinability of steel compared with MnS field trash and Pb field trash monomer.Multiple When being cracked around co-clip sundries, the Pb of liquefied can be invaded in the crackle of opening.The development of crackle is promoted as a result, Machinability improves.Therefore, if not only generating MnS field trash and Pb field trash, also generating complex inclusion, machinability can be into One step improves.

Think that the mechanism for generating complex inclusion is as follows.For Pb, liquid phase is easier to move than solid phase.Therefore, multiple Co-clip sundries is almost impossible solidified by steel after the MnS precipitate that generates generate, but pass through the steel for being attached to Pb before solidification It is generated on the MnS field trash generated in water.Therefore, in order to generate a large amount of complex inclusion, compared to generating after solidification MnS precipitate, it is generally desirable to a large amount of MnS field trash is generated in molten steel.

As described above, in order to improve the machinability of steel, as long as largely generating MnS field trash, Pb field trash and duplex impurity Object.As described above, MnS field trash is generated in molten steel by crystallization.In turn, as described above, MnS field trash is more, The complex inclusion of generation is more.It is therefore contemplated that if crystallizing a large amount of MnS field trash in molten steel, the machinability meeting of steel It improves.

On the other hand, the steel for mechanical structure containing MnS field trash, MnS precipitate, Pb field trash and complex inclusion holds Easily get rusty.However, up to the present, the rusting mechanism of steel for mechanical structure is not yet studied in detail.Therefore, the inventors of the present invention couple The mechanism got rusty is investigated and has been studied.As a result, the inventors of the present invention obtain following opinion.

MnS field trash, MnS precipitate, Pb field trash and complex inclusion itself can become the starting point of rust.Here, for The complexity got rusty more depends on compared with the size of MnS field trash, MnS precipitate, Pb field trash and complex inclusion In the total number of MnS field trash, MnS precipitate, Pb field trash and complex inclusion.Specifically, MnS field trash, MnS are precipitated The total number of object, Pb field trash and complex inclusion more increases, and steel more gets rusty easily.Based on the above opinion, the inventors of the present invention think To in order to inhibit to get rusty while obtaining excellent machinability, reducing MnS field trash, MnS precipitate, Pb field trash and compound The total number of field trash is effective.Therefore, the inventors of the present invention, which have studied, reduces MnS field trash, MnS precipitate, Pb field trash With the method for the total number of complex inclusion.

As described above, being easy growth (coarsening) in molten steel by the MnS field trash that the crystallization in molten steel generates.Cause This, the size of MnS field trash is greater than the MnS precipitate that generation is precipitated in steel after solidification.That is, MnS precipitate ratio MnS field trash is more imperceptibly precipitated.Therefore, the case where making MnS field trash crystallization is assumed in the steel of Mn content and S content constant When with the case where MnS precipitate is precipitated, the number of the MnS precipitate generated by precipitation can be significantly more than through crystallization The number of the MnS field trash of generation.It therefore, can be by analysing MnS field trash in molten steel in order to improve the characteristic of getting rusty of steel Crystalline substance simultaneously grows (coarsening) to inhibit the precipitation of MnS precipitate.

In order to inhibit the precipitation of MnS precipitate by making MnS field trash crystallization and growth in molten steel, thus in result The upper total number for reducing MnS field trash, MnS precipitate, Pb field trash and complex inclusion, as long as sufficiently being mentioned compared with S content High Mn content.If Mn content is sufficiently high compared with S content, it is easy to generate coarse MnS field trash in molten steel.This In the case of, since the crystallization of coarse MnS field trash can consume S, the solid solution S amount in steel after solidification is reduced.It therefore, can be with Inhibit the precipitation of MnS precipitate, it is possible to reduce the total number of MnS field trash, MnS precipitate, Pb field trash and complex inclusion. As a result, it is possible to obtain excellent characteristic of getting rusty.

Specifically, Mn content and S content meet following formula (1).

Mn/S≥8.0(1)

Wherein, the content (quality %) of respective element is substituted at each element symbol in formula (1).

It is defined as F1=Mn/S.When F1 is less than 8.0, MnS field trash is difficult to the abundant crystallization in molten steel.Therefore, after solidification Steel in solid solution S amount cannot be substantially reduced, fine MnS precipitate can be largely generated after solidification.In this case, due to The total number of MnS field trash, MnS precipitate, Pb field trash and complex inclusion, therefore the characteristic drop of getting rusty of steel are not can be reduced It is low.On the other hand, when F1 is 8.0 or more, Mn content is sufficiently high compared with S content.In this case, by using appropriate Manufacturing method, MnS field trash abundant crystallization and can be grown in molten steel.As a result, solidification after steel in solid solution S amount sufficiently subtract It is few, the precipitation of the MnS precipitate in steel after being able to suppress solidification.Therefore, MnS field trash can be substantially reduced, MnS is precipitated The total number of object, Pb field trash and complex inclusion, the characteristic raising of getting rusty of steel.

Here, any one of MnS field trash, Pb field trash and complex inclusion will be belonged to and equivalent circle diameter is 5 μm Above field trash is defined as " specific field trash ".In the present specification, equivalent circle diameter refers to: in microstructure observation, The area of observed field trash or precipitate is converted into the diameter of a circle with bowlder of the same area.In such case Under, in the present embodiment, with above-mentioned chemical composition and meet formula (1) steel for mechanical structure in, specific field trash Total number is also 40/mm²More than.

If the specific field trash in steel is 40/mm²More than, then coarse MnS field trash can abundant crystallization, can press down The generation of MnS precipitate processed.As a result, MnS field trash, MnS precipitate, the Pb folder for becoming the starting point got rusty can be substantially reduced The total number of sundries and complex inclusion.Therefore, excellent machinability and excellent characteristic of getting rusty can be taken into account.On the other hand, If the specific field trash in steel is less than 40/mm², then MnS field trash cannot abundant crystallization, MnS precipitate largely generates.It is tied Fruit is able to suppress the generation of MnS precipitate.As a result, the MnS field trash for becoming the starting point got rusty, MnS analysis cannot be substantially reduced The total number of object, Pb field trash and complex inclusion out.Although cannot be obtained as a result, excellent machinability can be obtained Obtain characteristic of adequately getting rusty.

The steel for mechanical structure for the present embodiment completed by the above opinion has following chemical composition: in terms of quality % Containing C:0.15% more than and less than 0.30%, Si:0.01~0.80%, Mn:0.20~2.00%, P:0.030% or less, S: 0.010~0.100%, Pb:0.010~0.100%, Al:0.010~0.050%, N:0.015% or less, O:0.0005~ 0.0030%, Cr:0.50~2.00%, Ni:0~3.50%, B:0~0.0050%, V:0~0.70%, Mo:0~0.70%, W:0~0.70%, Nb:0 more than and less than 0.050%, Cu:0~0.50%, Ti:0~0.100% and Ca:0~ 0.0030%, surplus is Fe and impurity, and meets formula (1).In steel, the total number of specific field trash is 40/mm²More than, The specific field trash is any one of MnS field trash, Pb field trash and complex inclusion containing MnS and Pb, and round Equivalent diameter is 5 μm or more.

Mn/S≥8.0(1)

The chemical composition of above-mentioned steel for mechanical structure can containing selected from by Ni:0.02~3.50%, B:0.0005~ 0.0050%, V:0.05~0.70%, Mo:0.05~0.70%, W:0.05~0.70%, Nb:0.001% more than and less than 0.050%, one kind or two or more in the group that Cu:0.05~0.50% and Ti:0.003~0.100% are formed.

The chemical composition of above-mentioned steel for mechanical structure can contain Ca:0.0001~0.0030%.

In above-mentioned steel for mechanical structure, complex inclusion relative to specific field trash number ratio can for 40% with On.

The steel for mechanical structure of present embodiment is described in detail below.Unless otherwise stated, chemical composition In " % " indicate quality %.

[chemical composition]

The chemical composition of the steel for mechanical structure of present embodiment contains following element.

C:0.15% is more than and less than 0.30%

The intensity of carbon (C) raising steel.In the case where manufacturing component using steel for mechanical structure, steel for mechanical structure is forged Afterwards, implement Carburization Treatment sometimes.In this case, C improves the intensity on the surface layer of steel.C content is if it is less than 0.15%, then Steel is unable to get enough intensity.In soft steel, chip continues when cutting, is wrapped in tool, on material, makes it sometimes It is damaged.C content is if it is less than 0.15%, then the cutting resistance of steel can also improve.On the other hand, C content is if it is 0.30% More than, then the hardness of the core of the component after Carburization Treatment improves, and the toughness on surface layer is reduced relative to the harmony of intensity.Cause This, C content is 0.15% more than and less than 0.30%.The preferred lower limit of C content is 0.16%, more preferable 0.18%.C content Preferred upper limit is 0.25%, more preferable 0.23%.

Si:0.01~0.80%

Silicon (Si) makes steel-deoxidizing.In deoxidation treatment, by adding Si after adding Mn, Si can change oxide Property.Specifically, the oxide modifying based on Mn can be the oxide based on Si by the Si being added in molten steel.? After adding Si, by adding Al, the composite oxides containing Si and Al can be generated in steel.Composite oxides can become MnS The core of field trash crystallization.Therefore, composite oxides can improve the characteristic of getting rusty of steel.Si further increases temper softening resistance, mentions It is high-intensitive.If Si content less than 0.01%, cannot obtain said effect.

On the other hand, Si is ferrite generating elements.If Si content is more than 0.80%, the surface layer of steel may decarburization. The case where if Si content is more than 0.80%, and there are also ferrite ratios to get higher, strength reduction.Therefore, Si content be 0.01~ 0.80%.The preferred lower limit of Si content for improving temper softening resistance is 0.10%, more preferably 0.20%.For inhibiting The preferred upper limit of the Si content of ferrite ratio is 0.70%, more preferably 0.50%.

Mn:0.20~2.00%

Manganese (Mn) generates MnS field trash and the complex inclusion containing MnS and Pb, improves the machinability of steel.

Mn can also make steel-deoxidizing.Deoxidizing capacity ratio Si, Al of Mn is weak.Therefore, Mn can largely be contained.It is not deposited in molten steel In the case where other strong deoxidant elements, the oxide based on Mn can be generated in molten steel.Later, it is added into molten steel When his strong deoxidant element (Si, Al), the Mn in oxide is discharged in molten steel, and oxide is modified.Hereinafter, will be modified Oxide is known as composite oxides.The Mn in molten steel is discharged to from oxide, and MnS field trash is formed in conjunction with S.It needs to illustrate It is that the core of MnS field trash crystallization is easily become by the composite oxides that the modification of oxide generates.Therefore, it is generating again In the case where closing oxide, the crystallization of MnS field trash is promoted.It is also easy to generate by the MnS field trash that crystallization generates multiple Co-clip sundries.

When Mn content is less than 0.20%, MnS field trash is difficult to abundant crystallization.Therefore, it is largely generated in steel after solidification MnS precipitate.In this case, the total number of MnS field trash, MnS precipitate, Pb field trash and complex inclusion increases. Therefore, the characteristic reduction of getting rusty of steel.On the other hand, if Mn content is more than 2.00%, the hardenability of steel becomes excessively high, knot Fruit, the hardness of steel become excessively high.In this case, the machinability of steel reduces.In this case, the hot-workability of steel can also It reduces.Therefore, Mn content is 0.20~2.00%.The preferred lower limit of Mn content is 0.50%.The preferred upper limit of Mn content is 1.50%, more preferably 1.20%.

P:0.030% or less

Phosphorus (P) inevitably contains.P keeps steel brittle, improves machinability.On the other hand, if P content is more than 0.030%, Then hot ductility reduces.In this case, rolling flaw etc. can be generated, productivity reduces.Therefore, P content be 0.030% with Under.The preferred lower limit of P content for improving machinability is 0.005%.In this case, at machinability, especially chip Rationality improves.The preferred upper limit of P content is 0.015%.

S:0.010~0.100%

Sulphur (S) generates MnS in steel, improves machinability.MnS can especially inhibit tool wear.If S content is less than 0.010%, then MnS will not abundant crystallization, it is difficult to generate the complex inclusion containing MnS and Pb.As a result, characteristic drop of getting rusty It is low.On the other hand, if S content is more than that 0.100%, S is segregated in grain boundaries, the hot-workability of steel embrittlement, steel is reduced.Therefore, S Content is 0.010~0.100%.In machinability and mechanical property, the preferred lower limit of S content when preferential mechanical property is 0.015%, preferred upper limit 0.030%.The preferred lower limit of S content when preferential machinability is 0.030%, and preferred upper limit is 0.050%.

Pb:0.010~0.100%

Lead (Pb) is individually created Pb field trash (Pb particle), improves the machinability of steel.Pb can also give birth in conjunction with MnS field trash At complex inclusion, the machinability of steel is improved, especially raising chip treatability.If Pb content cannot get less than 0.010% Said effect.On the other hand, if Pb content is more than 0.100%, although machinability improves, steel embrittlement.As a result, the heat of steel Processability reduces.If Pb content is more than that 0.100%, Pb field trash can also excessively increase, therefore, the characteristic drop of getting rusty of steel It is low.Therefore, Pb content is 0.010~0.100%.For promoting the generation of complex inclusion, improving the Pb content of machinability Preferred lower limit is 0.020%, more preferably 0.025%.The preferred upper limit of Pb content for improving characteristic of getting rusty is 0.050%.

Al:0.010~0.050%

Aluminium (Al) makes steel-deoxidizing.In steel for mechanical structure of the invention, hole and the surface flaw are generated when in order to inhibit solidification Defect implements the deoxidation for utilizing Al calmness.As it is explained in detail hereinafter, if the addition Al progress deoxidation after molten steel relays Mn, Si, in steel Oxide be modified, generate the composite oxides containing Si and Al.Composite oxides easily become the crystallization of MnS field trash Core.Therefore, MnS field trash will disperse, crystallization and be easy growth, coarsening, also, be easy generate contain the compound of MnS and Pb Field trash.In this case, the machinability of steel improves.Fine MnS can be also inhibited to be precipitated when the dispersion of MnS field trash, crystallization The precipitation of object.In this case, the total number of MnS field trash, MnS precipitate, Pb field trash and complex inclusion increases.Cause This, the characteristic raising of getting rusty of steel.Al can also form AlN in conjunction with N, inhibit the coarse of the austenite grains in various heat treatments Change.If Al content less than 0.010%, cannot obtain said effect.

On the other hand, it if Al content is more than 0.050%, is easy to generate coarse composite oxides.It is generated in steel thick When big composite oxides, it is easy to generate surface blemish on steel.When generating coarse composite oxides in steel, the fatigue of steel Intensity can also reduce.If Al content is more than 0.050%, deoxidation can also be carried out excessively, the oxygen amount decline in molten steel.In this feelings Under condition, it is difficult to form MnS field trash, machinability (especially inhibition tool wear) decline of steel.In this case, it is also difficult to The complex inclusion that Pb is combined on MnS field trash is generated, Pb field trash individually largely remains in steel.As a result, MnS The total number increase of field trash, MnS precipitate, Pb field trash and complex inclusion, characteristic of getting rusty decline.Therefore, Al content is 0.010~0.050%.In order to further obtain by AlN generation bring inhibit coarse grains effect, Al content it is excellent Selecting lower limit is 0.015%, more preferably 0.020%.The preferred upper limit of Al content is 0.035%.The Al mentioned in this specification Content refers to the content of the molten Al (sol.Al) of acid.

N:0.015% or less

Nitrogen (N) inevitably contains.N forms AlN in conjunction with Al, inhibits the coarse of austenite grains when heat treatment Change, improves the intensity of steel.On the other hand, when N content is more than 0.015%, the cutting resistance of steel is improved, machinability decline.If N contains Amount is more than 0.015%, then hot-workability can also decline.Therefore, N content is 0.015% or less.The preferred lower limit of N content is 0.002%, more preferably 0.004%.The preferred upper limit of N content is 0.012%, more preferably 0.008%.It is mentioned in this specification To N content refer to the content of total N (t-N).

O:0.0005~0.0030%

Oxygen (O) is embodied not only in oxide, is also included in MnS field trash.O generates the crystallization for becoming MnS field trash The composite oxides of core.If O content, less than 0.0005%, the production quantity of composite oxides is insufficient, and MnS field trash is difficult in steel Crystallization in water.In this case, the machinability decline of steel.In this case, it can also largely generate after solidification fine MnS precipitate.As a result, the total number increase of MnS field trash, MnS precipitate, Pb field trash and complex inclusion, spy of getting rusty Property decline.O content then can also generate coarse alumina series oxide, accelerate the mill of cutting element if it exceeds 0.0030% Damage, therefore the machinability of steel reduces.Therefore, O content is 0.0005~0.0030%.In order to further increase steel machinability and The characteristic of getting rusty of steel, the preferred lower limit of O content are 0.0007%, more preferably 0.0010%.The preferred upper limit of O content is 0.0025%, more preferably 0.0020%.The O content that this specification is mentioned refers to the content of total oxygen (t-O).

Cr:0.50~2.00%

Chromium (Cr) is solid-solution in steel, is improved the hardenability and temper softening resistance of steel, is improved the intensity of steel.As a result, steel Rolling contact fatigue characteristic improve.Cr can also deepen case depth when implementing the Carburization Treatment as Surface hardening treatment.Cr Content is then unable to get said effect if it is less than 0.50%.On the other hand, Cr content is if it exceeds 2.00%, then hardenability Become excessively high, generate over-cooling structure (martensite) when cooling, steel becomes really up to the mark.In this case, the machinability of steel reduces.Cr Content is if it exceeds 2.00%, then there is also austenites also to stabilize at low temperature, the situation of steel embrittlement.Therefore, Cr content is 0.50~2.00%.The preferred lower limit of Cr content is 0.70%, more preferable 0.90%.The preferred upper limit of Cr content be 1.80%, More preferable 1.60%.

The surplus of the chemical composition of the steel for mechanical structure of present embodiment is Fe and impurity.Here, impurity refers to: industry It is mixed into from the ore, waste material or manufacturing environment etc. as raw material when manufacturing steel for mechanical structure and is being not present embodiment Steel for mechanical structure allows existing substance in the range of bringing adverse effect.

[about arbitrary element]

The chemical composition of the steel for mechanical structure of present embodiment can further containing selected from by Ni, B, V, Mo, W, Nb, It is one kind or two or more in the group of Cu and Ti composition.

Ni:0~3.50%

Nickel (Ni) is arbitrary element, can not contained.In the case of containing, Ni is solid-solution in steel to improve the quenching of steel Property, improve the intensity of steel.Ni also improves the ductility of matrix.In turn, Ni can improve the toughness of steel.In turn, Ni improves the corrosion resistant of steel Corrosion.As long as said effect can be obtained to a certain extent containing a small amount of Ni.On the other hand, if Ni content is more than 3.50%, then retained austenite largely remains.In this case, due to stress-induced phase transformation, a part of retained austenite phase Become martensite, the ductility of steel reduces.Therefore, Ni content is 0~3.50%.

In order to stablize acquisition said effect, the preferred lower limit of Ni content is 0.02%, more preferably 0.05%.In order into one Step inhibits retained austenite, and the preferred upper limit of Ni content is 2.50%, more preferably 2.00%.When preferential toughness, Ni content Preferred lower limit is 0.20%.It should be noted that Ni keeps Cu innoxious and improves toughness.In the case that steel contains Cu, Ni content Preferred lower limit be Cu content more than.

B:0~0.0050%

Boron (B) is arbitrary element, can not contained.In the case of containing, B improves the hardenability of steel, improves the strong of steel Degree.B also inhibits P, S for reducing toughness to cyrystal boundary segregation, improves fracture characteristics.As long as, can be in certain journey containing a small amount of B Said effect is obtained on degree.On the other hand, if B content is more than that 0.0050%, BN largely generates to steel embrittlement.Therefore, B contains Amount is 0~0.0050%.Containing element, that is, Ti or Nb is generated as nitride, the preferred lower limit of B content is 0.0005%.The preferred upper limit of B content is 0.0020%.

V:0~0.70%

Vanadium (V) is arbitrary element, can not contained.In the case of containing, V is in tempering and when nitrogen treatment with V carbon The form of compound, V nitride or V carbonitride is precipitated, and improves the intensity of steel.V precipitate (V carbide, V nitride and V carbon Nitride) coarsening that can also inhibit austenite grains, improves the toughness of steel.It is soft that V can also be solid-solution in raising steel belt roof bolt in steel Esd resistance.As long as said effect can be obtained to a certain extent containing a small amount of V.

On the other hand, if V content is more than 0.70%, in A₃Or more can also generate V precipitate.In A₃Or more generate V precipitate be difficult to be solid-solution in steel, and remain in steel as undissolved precipitate.In the undissolved remaining situation of precipitate, V amount is dissolved to reduce.Therefore, steel belt roof bolt softening resistance declines.In the undissolved remaining situation of precipitate, also it is difficult to by later Heat treatment fine V precipitate is precipitated.In this case, the intensity decline of steel.Therefore, V content is 0~0.70%. In order to stablize acquisition said effect, the preferred lower limit of V content is 0.05%, more preferably 0.10%.The preferred upper limit of V content is 0.50%, more preferably 0.30%.

Mo:0~0.70%

Molybdenum (Mo) is arbitrary element, can not contained.In the case of containing, Mo is in tempering, nitrogen treatment etc. in A₁Point It is precipitated in the form of Mo carbide in heat treatment in a low temperature of below.Therefore, the intensity of steel and temper softening resistance improve.Mo It is also solid-solution in steel, to improve the hardenability of steel.As long as said effect can be obtained to a certain extent containing a small amount of Mo. On the other hand, if Mo content is more than 0.70%, the hardenability of steel becomes excessively high.In this case, before rolling, wire drawing It is easy to generate over-cooling structure in softening heat treatment etc..Therefore, Mo content is 0~0.70%.

In order to stablize acquisition said effect, the preferred lower limit of Mo content is 0.05%, more preferably 0.10%, further excellent It is selected as 0.15%.In order to which the microscopic structure in steel stably obtains ferrite, pearlite and bainite, the preferred upper limit of Mo content It is 0.40%, more preferably 0.30%.

W:0~0.70%

Tungsten (W) is arbitrary element, can not contained.In the case of containing, W is precipitated in the form of W carbide in steel, Improve the intensity and temper softening resistance of steel.W carbide is in A₃Or less in a low temperature of generate.Therefore, W be different from V or Nb, Ti etc., it is not easy to generate undissolved precipitate.As a result, W carbide improves the intensity and temper softening of steel by precipitation strength Resistance.W can also be solid-solution in the hardenability that steel is improved in steel, improve the intensity of steel.As long as containing a small amount of W, so that it may Said effect is obtained to a certain extent.

On the other hand, it if W content is more than 0.70%, is easy to generate over-cooling structure, the hot-workability decline of steel.Therefore, W Content is 0~0.70%.Steel belt roof bolt softening resistance is improved in order to stablize, the preferred lower limit of W content is 0.05%, more preferably 0.10%.In order to stably obtain ferrite, pearlite and bainite in the microscopic structure of steel, the preferred upper limit of W content is 0.40%, more preferably 0.30%.

W and Mo does not allow nitride easily generated.Therefore, these elements can not improve steel belt roof bolt with being influenced by N content Softening resistance.In order to obtain high temper softening resistance, the preferred total content of W and Mo are 0.10~0.30%.

Nb:0 is more than and less than 0.050%

Niobium (Nb) is arbitrary element, can not contained.In the case of containing, Nb generate Nb nitride, Nb carbide or Nb carbonitride inhibits the coarsening of austenite grains in quenching, when normalizing.Nb also improves the strong of steel by precipitation strength Degree.As long as said effect can be obtained to a certain extent containing a small amount of Nb.On the other hand, if Nb content is more than 0.050%, then non-Solid solution precipitation object can be generated, the toughness of steel reduces.If Nb content is more than 0.050%, it is also easy to generate The hot-workability of cold tissue, steel reduces.Therefore, Nb content is 0 more than and less than 0.050%.In order to stablize acquisition said effect, The preferred lower limit of Nb content is 0.001%, more preferably 0.005%.The preferred upper limit of Nb content is 0.030%, more preferably 0.015%.

Cu:0~0.50%

Copper (Cu) is arbitrary element, can not contained.In the case of containing, Cu prevents decarburization.Cu is also mentioned as Ni Highly corrosion resistant.As long as said effect can be obtained to a certain extent containing a small amount of Cu.On the other hand, if Cu content is super 0.50% is crossed, then steel embrittlement, is easy to produce roll mark.Therefore, Cu content is 0~0.50%.In order to stablize acquisition said effect, Cu The preferred lower limit of content is 0.05%, more preferably 0.10%.Containing 0.30% or more Cu when, if Ni content contains higher than Cu Amount, then can maintain hot ductility.

Ti:0~0.100%

Titanium (Ti) is arbitrary element, can not contained.In the case of containing, Ti generates nitride, carbide or carbon nitrogen Compound inhibits the coarsening of austenite grains in quenching, when normalizing.Ti also improves the intensity of steel by precipitation strength.Ti is also It can make steel-deoxidizing.In the case where containing B, Ti can also maintain solid solution B amount in conjunction with solid solution N.In this case, it quenches Property improve.As long as said effect can be obtained to a certain extent containing a small amount of Ti.

On the other hand, Ti generates above-mentioned nitride and sulfide, therefore influences MnS field trash and complex inclusion.Specifically For, if the crystallization amount that Ti content is more than 0.100%, MnS field trash is reduced, the generation of complex inclusion is also reduced.At this In the case of kind, the characteristic reduction of getting rusty of steel.If Ti too high levels, nitride and sulfide can be also generated, fatigue strength reduces. Therefore, Ti content is 0~0.100%.In order to effectively obtain said effect, the preferred lower limit of Ti content is 0.003%.Especially When containing B, in order to reduce solid solution N, the preferred lower limit of Ti content is 0.005%.In order to improve corrosion resistance, Ti content it is excellent It chooses and is limited to 0.090%, more preferably 0.085%.

The steel for mechanical structure of present embodiment can also contain Ca.

Ca:0~0.0030%

Calcium (Ca) is arbitrary element, can not contained.In the case of containing, Ca generates CaS or (Mn, Ca) S, thus MnS field trash spheroidizing reduces tool wear amount.As a result, the machinability of steel improves.As long as containing a small amount of Ca, so that it may Said effect is obtained to a certain extent.On the other hand, if Ca content is more than 0.0030%, oxide system field trash is coarse Change, the fatigue strength of steel reduces.Therefore, Ca content is 0~0.0030%.In order to further increase machinability, Ca content it is excellent Selecting lower limit is 0.0001%.Compared with machinability in the case where preferential fatigue strength, the preferred upper limit of Ca content is 0.0015%, More preferably 0.0003%.

[[about formula (1)]

The chemical composition of the steel for mechanical structure of present embodiment also meets formula (1).

Mn/S≥8.0(1)

Define F1=Mn/S.F1 indicates the Mn content relative to S content.If F1 is difficult to fill less than 8.0, MnS field trash Analysis is brilliant.Therefore, the solid solution S amount in the steel after solidification cannot be reduced sufficiently, and fine MnS can be largely generated after solidification and is precipitated Object.In this case, since the total number of MnS field trash, MnS precipitate, Pb field trash and complex inclusion can not be reduced, Therefore the characteristic reduction of getting rusty of steel.In the case that solid solution S amount in steel after solidification cannot be reduced sufficiently, the solid solution S after solidification Grain boundaries can also be remained in.As a result, the hot-workability of steel can reduce sometimes.

On the other hand, if F1 is 8.0 or more, Mn content is sufficiently high compared with S content.In this case, MnS is mingled with Object abundant crystallization and is grown in molten steel.As a result, solidification after steel in solid solution S amount be substantially reduced, after solidification being inhibited Steel in MnS precipitate precipitation.Therefore, can be substantially reduced MnS field trash in steel, MnS precipitate, Pb field trash and The total number of complex inclusion improves the characteristic of getting rusty of steel.In order to improve the characteristic of getting rusty of steel, the preferred lower limit of F1 is 10.0, More preferably 20.0.

[microscopic structure about steel]

The microscopic structure of steel for mechanical structure of the invention is mainly made of ferrite, pearlite and bainite.It is specific and It says, the gross area rate of ferrite, pearlite and bainite in the microscopic structure of the steel for mechanical structure of above-mentioned chemical composition is 99% or more.

The gross area rate of ferrite, pearlite and bainite in microscopic structure can measure by the following method.Slave Tool structural steel collecting sample.For example, when steel for mechanical structure is bar steel or wire rod, from cross section (with axially vertical face) Central portion (the hereinafter referred to as portion R/2) collecting sample of the radius R of middle connected surfaces and central axis.The cross section of the sample in the portion R/2 In (surface), using the surface of the central axis perpendicular to steel for mechanical structure as viewing surface.After grinding viewing surface, with 3% nitric acid second Alcohol (nital) is etched it.With the viewing surface after 200 times of optical microphotograph sem observation etching, generate any 5 visual fields photograph image.

In each visual field, the contrast of phase each for ferrite, pearlite, bainite etc., each phase is different.Therefore, base Each phase is determined in contrast.In determining phase, the gross area (μ of ferrite in each visual field, pearlite and bainite is found out m²).The gross area of each visual field of adduction, finds out the ratio of the gross area relative to all visual fields in all visual fields (5 visual fields).It will The ratio found out is defined as the gross area rate (%) of ferrite, pearlite and bainite.

[the number TN of specific field trash]

For steel for mechanical structure of the invention, in steel, for MnS field trash, Pb field trash and contain MnS's and Pb The total number TN for the field trash (that is, specific field trash) that any one of complex inclusion and equivalent circle diameter are 5 μm or more is 40/mm²More than.

If the quantity TN of specific field trash is 40/mm²More than, then the coarse MnS that equivalent circle diameter is 5 μm or more is mingled with The abundant crystallization of object is substantially reduced the total of MnS field trash, MnS precipitate, Pb field trash and complex inclusion as a result, realizing Number.Therefore, excellent machinability and excellent characteristic of getting rusty can be taken into account.On the other hand, if specific field trash in steel Number TN is less than 40/mm², then equivalent circle diameter be 5 μm or more coarse MnS field trash will not abundant crystallization, as a result, not The total number of MnS field trash, MnS precipitate, Pb field trash and complex inclusion can be substantially reduced.It is thus impossible to obtain sufficiently Characteristic of getting rusty.The preferred lower limit of the number TN of specific field trash is 80/mm², more preferably 150/mm².Specific field trash Number TN preferred upper limit be 300/mm².It should be noted that for specific field trash equivalent circle diameter the upper limit simultaneously It is not particularly limited, for example, 200 μm.

[in specific field trash, the ratio between number of complex inclusion (recombination rate) RA]

Preferably, the total number (a/mm for the complex inclusion that equivalent circle diameter is 5 μm or more²) relative to specific folder Number (a/mm of sundries²) the ratio between (hereinafter also referred to " recombination rate ") RA be 40% or more.

As described above, MnS field trash, MnS precipitate, Pb field trash and complex inclusion total number more increase, steel is got over It gets rusty easily.Here, MnS field trash and the complex inclusion that Pb field trash generates are more, MnS field trash, MnS analysis more can be reduced The total number of object, Pb field trash and complex inclusion out.The total number of the Pb field trash in steel can especially be reduced.Pb is mingled with Object is particularly susceptible reduction and gets rusty characteristic.If recombination rate is 40% or more, MnS field trash, MnS precipitate, Pb can be reduced The total number of field trash and complex inclusion, also, can also reduce the number of the Pb field trash of individualism.As a result, steel Characteristic of getting rusty further increase.It is therefore preferable that recombination rate RA is 40% or more.In this case, it can further mention The characteristic of getting rusty of Gao Gang.The more preferable lower limit of recombination rate RA is 60%, further preferably 75%.

[measuring method of the number TN and recombination rate RA of specific field trash]

The number TN and recombination rate RA of specific field trash can be measured by the following method.Using the above method from machinery Structural steel collecting sample.For the cross section (surface) of the sample in the portion R/2, using scanning electron microscope (SEM) with 1000 20 visual fields of multiplying power random observation again.Determine specific field trash (for MnS field trash, Pb in each visual field (referred to as viewing surface) Any one of field trash and complex inclusion, and equivalent circle diameter is 5 μm or more).Specific folder can be distinguished by contrast Sundries and other field trashes.In turn, determine by the following method respectively MnS field trash in specific field trash, Pb field trash and Complex inclusion.

In each viewing surface, the S distribution in viewing surface is obtained by Wavelength dispersion type x ray spectrometer (EPMA) and is divided with Pb The image of cloth.Figure 1A is the schematic diagram for showing the S distribution in the viewing surface obtained by EPMA analysis, and Figure 1B is to show to pass through The schematic diagram of Pb distribution in the viewing surface identical as Figure 1A that EPMA analysis obtains.

Appended drawing reference 10 in Figure 1A is region existing for S.Since S exists substantially in the form of MnS, can be considered as MnS is present in the appended drawing reference 10 of Figure 1A.Appended drawing reference 20 in Figure 1B is region existing for Pb.

As shown in Figure 1B, Pb is as shown in appended drawing reference 20A sometimes since rolling etc. is separated, along rolling direction row Column.S is also such.As shown in Fig. 2, adjacent field trash IN all has 5 μm or more in the image obtained by EPMA analysis When equivalent circle diameter, if the interval D of adjacent field trash IN is that these field trashes IN is considered as a field trash within 10 μm. It should be noted that as described above, equivalent circle diameter refers to that the area by each field trash or each precipitate is scaled with identical The diameter of a circle of the bowlder of area.Even if being defined as the field trash group of 1 field trash, equivalent circle diameter is also and field trash The identical diameter of a circle of the gross area of group.

Fig. 1 C is the image for synthesizing Figure 1B with Figure 1A.When C referring to Fig.1, Pb field trash 20 is Chong Die with MnS field trash 10, The field trash is regarded as into complex inclusion 30.On the other hand, C, MnS field trash 10 be not be overlapped with Pb field trash 20 referring to Fig.1 When (region A1, region A2 in Fig. 1 C etc.), these field trashes are determined as MnS field trash 10, Pb field trash 20.

According to the above method, MnS field trash, Pb field trash and duplex impurity are determined using flying-spot microscope and EPMA Object.The area for finding out determined each field trash finds out equivalent circle diameter of the diameter of a circle of the same area as each field trash (μm)。

In each field trash, determine that equivalent circle diameter is 5 μm or more of specific field trash.Specific field trash determined by finding out Total number (number in 20 visual fields), and be scaled every 1mm²Number TN (a/mm²).By the above method, spy is found out The number TN of clamp sundries.In turn, the complex inclusion that equivalent circle diameter is 5 μm or more in specific field trash determined by finding out Number MN (a/mm²), formula (2) based on following finds out recombination rate RA (%).

RA=MN/TN × 100 (2)

[manufacturing method]

An example of the manufacturing method of steel for mechanical structure of the invention is illustrated.In present embodiment, as machinery An example of structural steel is illustrated the manufacturing method of bar steel or wire rod.But steel for mechanical structure of the invention is not limited to Bar steel or wire rod.

An example of manufacturing method comprises the following steps: being refined to molten steel, casts to manufacture blank (slab or casting Ingot) steel process processed；Hot-working is carried out with to blank to manufacture the hot procedure of steel for mechanical structure.Below to each work Sequence is illustrated.

[steel process processed]

Steel process processed includes refining procedure and casting process.

[refining procedure]

In refining procedure, refining (primary essence is implemented to the molten iron manufactured by well known method first in converter Refining).Implement double refining to from the molten steel of converter tapping.In double refining, addition alloy implements composition adjustment, to manufacture Molten steel with above-mentioned chemical composition.

Specifically, adding Mn to from the molten steel of converter tapping.As a result, generating the oxidation based on Mn in molten steel Object.After the addition for completing Mn, the Si stronger than Mn deoxidizing capacity is added.As a result, the oxide based on Mn is modified For the oxide based on Si.After the addition for completing Si, add Al more stronger than Si deoxidizing capacity.As a result, with Si Based on oxide be modified as the composite oxides (hereinafter also referred to as " composite oxides ") containing Si and Al.

Become the crystallization core of MnS field trash by the composite oxides that above-mentioned refining procedure generates.Therefore, multiple by generating Close oxide, the abundant crystallization of MnS field trash simultaneously coarse is grown.That is, it is straight to be easy generation circle equivalent if generating composite oxides Field trash, that is, specific field trash that diameter is 5 μm or more, the number TN of specific field trash are 40/mm²More than.As a result, solidification Solid solution S amount in steel afterwards is substantially reduced, the precipitation of the MnS precipitate in steel after can inhibiting solidification.Therefore, MnS is mingled with Object, MnS precipitate, Pb field trash and complex inclusion total number can be substantially reduced, the characteristic raising of getting rusty of steel.

After implementing deoxidation treatment, implement well known except Slag treatment.After Slag treatment, implement double refining.Double refining Such as implement composite refining.For example, firstly, implementing to use LF (ladle refining furnace, Ladle Furnace) or VAD (vacuum arc Degassing, Vacuum Arc Degassing) refining treatment.In turn, it is possible to implement RH (Ruhrstahl-Hausen) vacuum is de- Gas disposal.In double refining, Mn, Si and other elements are added as needed to implement the composition adjustment of molten steel.Molten steel composition After adjustment, implement casting process.

[casting process]

Blank (slab or ingot casting) is manufactured using the molten steel manufactured by above-mentioned refining procedure.Specifically, using molten steel Slab is manufactured by continuous metal cast process.Alternatively, molten steel can be used by ingot casting method to manufacture ingot casting.Hereinafter, slab and ingot casting are united Referred to as blank.The cross-sectional area of blank mentioned here is, for example, 200~350mm × 200~600mm.

Solidification cooling RC when casting is 100 DEG C/min or less.If solidification cooling RC be 100 DEG C/min with Under, then MnS field trash abundant crystallization and is grown in molten steel.Therefore, it is easy to generate specific field trash, number TN is 40/ mm²More than.As a result, solidification after steel in solid solution S amount be substantially reduced, be able to suppress solidify after steel in MnS precipitate Precipitation.Therefore, the total number of MnS field trash, MnS precipitate, Pb field trash and complex inclusion can be substantially reduced, steel Characteristic of getting rusty improves.

On the other hand, if solidification cooling RC is more than 100 DEG C/min, MnS field trash will not abundant crystallization, in turn, MnS field trash will not be sufficiently grown.Accordingly, it is difficult to generate specific field trash, the number TN of specific field trash become smaller than 40/ mm².In this case, the solid solution S amount in steel after cannot being substantially reduced solidification, can largely generate fine MnS after solidification Precipitate.As a result, not can be reduced the total number of MnS field trash, MnS precipitate, Pb field trash and complex inclusion, therefore steel Get rusty characteristic reduction.Therefore, solidification cooling RC is 100 DEG C/min or less.

Preferred solidification cooling RC is 8 DEG C/min more than and less than 50 DEG C/min.In this case, MnS is pressed from both sides Sundries is easier crystallization and growth.In turn, it if solidification cooling RC is 8 DEG C/min more than and less than 50 DEG C/min, arrives Time until solidification is long, and it is hereby ensured that time enough to keep Pb mobile to be attached to MnS field trash in molten steel.Cause This is easy to generate the complex inclusion containing MnS and Pb, and recombination rate RA becomes 40% or more.Solidification cooling RC is more Preferred upper limit is 30 DEG C/min.The more preferable lower limit of solidification cooling RC is 10 DEG C/min, further preferably 15 DEG C/minute Clock.

Solidification cooling RC can be found out based on the blank cast.Fig. 3 is the cross-sectional view of cast blank.It will In the blank of thickness W (mm) from the surface at the point P1 of the position W/4 at blank center, it is warm from liquidus temperature to solidus Cooling velocity until degree is defined as the solidification cooling RC (DEG C/min) in casting process.It can ask by the following method Solidification cooling RC out.Blank after solidification is transversely cut.Solidification group in the cross section of blank, at measuring point P1 The Models For Secondary Dendrite Arm spacing λ 2 (μm) for the thickness direction knitted.Following formula (3), which are based on, using measured value λ 2 finds out solidification cooling rate RC (DEG C/min).

RC=(λ 2/770)^-(1/0.41)(3)

Models For Secondary Dendrite Arm spacing λ 2 depends on solidification cooling RC.It therefore, can be by measuring Models For Secondary Dendrite Arm spacing λ 2 find out solidification cooling RC.

[hot procedure]

Usually implement one or many hot-working in hot procedure.Blank is heated before implementing each hot-working.Later, Hot-working is implemented to blank.Hot-working is, for example, hot forging, hot rolling.In the case where implementing repeatedly hot worked situation, initial hot-working For example, breaking down or hot forging, subsequent hot-working are the finish rolling using tandem mill.In hot-rolling mill, there is the water of a pair of of horizontal roller Flat rack and vertical frames with a pair of of vertical roller are alternately arranged Cheng Yilie.Blank after hot-working passes through the public affairs such as air cooling The cooling means known cools down.

The steel for mechanical structure of present embodiment is manufactured by the above process.Steel for mechanical structure is, for example, bar steel or line Material.

Steel for mechanical structure machinability to the manufacture of top method and the excellent that gets rusty.From steel for mechanical structure to machinery The manufacture of component is for example implemented by following methods.

Steel for mechanical structure is implemented to be hot-forged, to manufacture the intermediate of basic configuration.As needed to intermediate Implement normalized treatment.In turn, intermediate is implemented to be machined.Machining for example, machining.It can also be to implementation The intermediate of machining implements modifier treatment (Q-tempering).It, can be to quenched place in the case where carrying out modifier treatment Intermediate after reason implements the machining such as machining.Mechanical part is manufactured by the above process.Cold forging can also be passed through Mechanical part is manufactured instead of being hot-forged.

Embodiment

Manufacture the molten steel with chemical composition shown in table 1.

[table 1]

Table 1

The molten steel of each test number manufactures by the following method.To the molten iron manufactured by well known method according to identical Condition carries out initial refining in converter to manufacture.

For the molten steel of the test number in addition to test number 65 and 66, after converter tapping, successively add Mn, Si, Al implements deoxidation treatment.For the molten steel of test number 65, after converter tapping, Si, Al, Mn are successively added, is implemented at deoxidation Reason.For the molten steel of test number 66, after converter tapping, Mn, Al, Si are successively added, implements deoxidation treatment.

Implement to remove Slag treatment after deoxidation treatment.After Slag treatment, implement the refining treatment for using VAD, it is true then to implement RH Empty degassing process.After RH Fruit storage, implement the final adjustment of alloying element.It is manufactured by the above process and is changed shown in table 1 Learn the molten steel of composition.

Casting is carried out to manufacture the experiment ingot casting of rectangular-shape to molten steel.The transverse shapes of ingot casting are rectangle, are 190mm×190mm.The solidification cooling RC (DEG C/min) of each test number is as shown in table 2.Measure the secondary dendrite of ingot casting Arm spacing simultaneously finds out solidification cooling RC using above-mentioned formula (3).

[table 2]

Table 2

2 hot-working is implemented to manufacture bar steel to the experiment ingot casting of manufacture.In hot-working, after implementing breaking down, Implement finish rolling (bar steel rolling).Hot forging is implemented to manufacture the bar steel that diameter is 50mm with ingot casting to the experiment of manufacture.Alternatively, right Experiment implements breaking down with ingot casting, implements finish rolling then to manufacture the bar steel that diameter is 50mm.800 is implemented to the bar steel of manufacture~ 950 DEG C of normalized treatment.Cooling means in normalized treatment is to place cooling.By the above manufacturing process, manufacturing diameter is The bar steel (steel for mechanical structure) of 50mm.

[evaluation test]

[microstructure observation]

Structure observation test film is acquired from the portion R/2 of the bar steel of each test number.It, will be with bar steel in the surface of test film Length direction (that is, rolling direction or draw direction) parallel section be defined as viewing surface.Based on the above method, iron element is found out The gross area rate (%) of body, pearlite and bainite.The gross area rate of the microscopic structure of the bar steel of each test number is 99% More than.The microscopic structure for being 99% or more for gross area rate, is shown in table 2 in the form of " F+P+B ".

[the number TN and recombination rate RA of specific field trash]

Structure observation test film is acquired from the portion R/2 of the bar steel of each test number.It, will be with bar steel in the surface of test film Length direction (that is, rolling direction or draw direction) parallel section be defined as viewing surface.For the tissue of each test number The viewing surface of observation test piece finds out specific field trash number TN (a/mm based on the above method²) and recombination rate RA (%).Show the result in table 2.

[machinability]

For machinability, evaluation utilizes the life tools characteristic and chip treatability of conventional bit.

[life tools characteristic CL1000]

The bar steel of diameter 50mm is cut off with the length of 20mm, as drifting test piece.Drifting test piece is implemented to perforate. The condition of perforation is shown in table 3.

[table 3]

Table 3

Specifically, changing drills outer circumference speed, the accumulation hole depth until drill bit is lost is measured.Drill bit uses high Fast steel straight drill.The crown R of drill bit is 3mm, burr-drill angle is 118 °.With cutting speed: 10~70m/ minutes, the amount of feeding: 0.25mm/rev, hole depth 9mm implement perforation.In the case where accumulation hole depth (hole depth × perforation number) reaches 1000mm, Utilize the punch off of a drill bit.In this case, drill bit is exchanged, the speed higher speed of drills outer circumference is made, repeats to try It tests until fracture.It will perforate and accumulate the maximum drills outer circumference speed of hole depth 1000mm and be defined as CL1000 (m/ minutes), make For the index of machinability.Show the result in column " CL1000 " of table 2.CL1000 is to be judged as in the case where 50m/ minutes or more Life tools excellent.On the other hand, in the case that CL1000 is less than 50m/ minutes, it is judged as that life tools characteristic is not excellent It is different.

[evaluation of chip treatability]

With the bar steel of defined length cutting diameter 50mm, as cutting test piece.For cutting test piece, implement Fig. 4 Shown in cylindrical turning.The condition of cylindrical turning is shown in table 4.

[table 4]

Table 4

Specifically, tool 50 uses P20 trade mark superhard alloy tool.The crown R of tool 50 is 0.4, and anterior angle is 5 °.With Cutting speed V1:250m/ minutes, feed speed V2:0.2mm/rev, depth of cut D1:2mm, length direction length of cut L1: 200mm implements cylindrical turning.After cutting periphery, incision turning is repeated in a manner of only becoming the minor diameter of D1:2mm again, it is right Test film 5 implements the Cutting experiment of 4 minutes above-mentioned conditions.

In the turning of the 1000th test film, chip shown in Fig. 5 A and Fig. 5 B is obtained.Then, to the length of chip L20, diameter D20 are determined.Following evaluation is carried out based on measurement result.It is 30mm coil below by chip diameter D20 The case where shape or even if be not coil shape, length of chip L20 be less than 50mm the case where be judged as that chip treatability is excellent Different ("○" in table 2).On the other hand, the diameter D20 that will not belong to chip is 30mm coil shape below and length of chip L20 is also that the situation of 50mm or more is judged as that chip treatability is not excellent ("×" in table 2).

[characteristic of getting rusty (corrosion resistance) evaluation test]

The bar steel of diameter 50mm is cut into the Rust Test piece of defined length by production.Identical as above-mentioned cutting test Under conditions of to Rust Test piece carry out turnery processing.Then, tap water is sprayed on cutting face on one side, test film exists on one side It is taken care of 1 hour in the atmosphere that 70%, 20 DEG C of humidity.After keeping, the cutting face of test film is observed, measures rust spot number.It will measurement As a result it is shown in " determination of getting rusty " column of table 2.Situation by rust spot less than 10 is (in table 2) and rust spot be 10 Situation ("○" in table 2) more than and less than 20 is judged as the excellent that gets rusty.It on the other hand, is 20 or more by rust spot The case where ("×" in table 2), is judged as that characteristic of getting rusty is not excellent.

[rolling fatigue testing]

The evaluation of rolling fatigue life is carried out using gloomy formula push type rolling fatigue testing.From the bar steel of each test number The portion R/2 respectively acquire 10 shown in fig. 6, diameter 60mm, thickness 5mm discoid rolling fatigue testing pieces 100.To rolling Fatigue test piece 100 implements carburizing, makes Surface hardened layer.Effective case depth is set as 0.8mm or more.

The condition of Carburization Treatment is as described below.Carry out Cp=0.7~0.8,930 DEG C × 2 hours, 870 DEG C × 1 hour Oil hardening, cleaning, 170 DEG C × 2 hours lonneals.For the rolling fatigue testing piece 100 for implementing Carburization Treatment, grinding Surface removes carburizing abnormal layer, makes effective case depth 0.7mm.Effective case depth is set as the position as HV550 Set the depth apart from surface.0.2mm or less is set as using the removal of grinding.Cp and grinding removal amount are adjusted, it is tired to adjust each rolling Hardness distribution and effective case depth in labor test film.

As shown in Figure 7, rolling fatigue testing piece 100 is made to be impregnated in the lubricating oil 102 of oil 70% and water 30%, lubrication Moisture in oil is evaporated due to heat release, 1 day 1 time additional 30ml water.Test surface pressure is set as 4kN and constant.Hard sphere makes Use Si₃N₄Ceramic hard sphere.The hard sphere contacted with rolling fatigue testing piece 100 is set as 3 balls, and revolving speed is set as 1200rpm.As rolling The scale of dynamic fatigue life uses " until it is general to generate the accumulation fracture obtained from plotting test result on Weibull probability paper The time (hour) of spot corrosion under rate 10% " is used as endurance life.Show the result in " rolling fatigue life " column of table 2.It rolls Fatigue life is that 4.0 hours or more situations are judged as rolling contact fatigue excellent.On the other hand, rolling fatigue life is less than 4.0 hours the case where, are judged as that rolling contact fatigue characteristic is not excellent.

[hot ductility (hot-workability) evaluation test]

Implementation uses the power on the hot tensile test of heating to evaluate hot ductility (hot-workability).Specifically, by each test The slab manufacture diameter of number is 10mm, length is 100mm and both ends are by the pole test film of screw thread process.Pass through electrified regulation Pole test film is heated to 1100 DEG C and is kept for 3 minutes.Then, pole test film is cooled to 900 DEG C by placing cooling. Implement tension test in the state that pole test film is in 900 DEG C, finds out the sectional shrinkage value (%) when fracture.For every A test number implements tension test with three pole test films, and the average value of 3 values is defined as cutting for the test number Face shrinking percentage value (%).In " hot ductility " column that sectional shrinkage value is shown in Table 2.Sectional shrinkage value is 70% or more It is excellent that situation is evaluated as hot ductility (hot-workability).On the other hand, sectional shrinkage value less than 70% the case where be evaluated as heat and prolong Property (hot-workability) is not excellent.

[test result]

In test number 1~31, chemical composition is appropriate, and F1 is 8.0 or more, appropriate, the solidification cooling RC of deoxidation sequence It is 100 DEG C/min or less.Therefore, the number TN of specific field trash is 40/mm²More than.As a result, CL1000 is 50m/ points More than clock, and excellent chip treatability is obtained.That is, having obtained excellent machinability.In turn, the evaluating characteristics that get rusty test In, rust spot is respectively less than at 20 points, has obtained excellent characteristic of getting rusty.In turn, in rolling fatigue testing, rolling fatigue life is 4.0 hours or more, excellent rolling contact fatigue characteristic is obtained.In turn, in hot ductility evaluation test, sectional shrinkage value is 70% More than, obtain excellent hot ductility.

In test number 1~7,26,30 and 31, solidification cooling RC is also 8~50 DEG C/min.Therefore, not only specific The number TN of field trash is 40/mm²More than, and recombination rate RA is 40% or more.As a result, rust spot is respectively less than at 10 points, Compared with test number 8~25 and 27~29, superior characteristic of getting rusty has been obtained.

On the other hand, in test number 32~42, chemical composition is appropriate, and F1 is 8.0 or more, and deoxidation sequence is appropriate, but solidifying Gu cooling velocity RC is more than 100 DEG C/min.Therefore, the number TN of specific field trash is less than 40/mm².As a result, can not obtain To excellent characteristic of getting rusty.

In test number 43 and 44, chemical composition is appropriate, and deoxidation sequence is appropriate, and solidification cooling RC is 100 DEG C/min Hereinafter, but F1 less than 8.0.Therefore, the number TN of specific field trash is less than 40/mm².As a result, being unable to get excellent life Rust characteristic.In turn, sectional shrinkage value is unable to get excellent hot ductility less than 70%.

In test number 45, chemical composition is appropriate, and deoxidation sequence is appropriate, but solidification cooling RC is more than 100 DEG C/minute Clock, and then F1 is less than 8.0.Therefore, the number TN of specific field trash is less than 40/mm².As a result, being unable to get excellent life Rust characteristic.In turn, sectional shrinkage value is unable to get excellent hot ductility less than 70%.

In test number 46 and 47, Mn too high levels.As a result, CL1000 is less than 50m/ minutes, it is unable to get excellent Machinability.

In test number 48 and 49, Mn content is too low.Therefore, the number TN of specific field trash is less than 40/mm².It is tied Fruit is unable to get excellent characteristic of getting rusty.In turn, sectional shrinkage value is unable to get excellent hot ductility less than 70%.

In test number 50, S too high levels.Prolong as a result, sectional shrinkage value less than 70%, is unable to get excellent heat Property.

In test number 51, S too high levels.In turn, F1 is less than 8.0.Therefore, the number TN of specific field trash is less than 40 A/mm².As a result, being unable to get excellent characteristic of getting rusty.In turn, sectional shrinkage value is unable to get excellent less than 70% Hot ductility.

In test number 52 and 53, S content is too low.Therefore, the number TN of specific field trash is less than 40/mm².It is tied Fruit is unable to get excellent characteristic of getting rusty.

In test number 54 and 55, Pb too high levels.As a result, being unable to get excellent characteristic of getting rusty.In turn, section is received Shrinkage value is unable to get excellent hot ductility less than 70%.

In test number 56 and 57, Pb content is too low.As a result, CL1000 is less than 50m/ minutes, in turn, it is unable to get excellent Different chip treatability.That is, being unable to get excellent machinability.

In test number 58, Al content is too low.Therefore, the number TN of specific field trash is less than 40/mm².As a result, nothing Method obtains excellent characteristic of getting rusty.

In test number 59, N content is excessively high.As a result, CL1000 is less than 50m/ minutes, it is unable to get excellent cutting Property.In turn, sectional shrinkage value is unable to get excellent hot ductility less than 70%.

In test number 60 and 61, O content is excessively high.As a result, CL1000 is less than 50m/ minutes, it is unable to get excellent cut Cutting property.In turn, rolling fatigue life was unable to get excellent rolling contact fatigue characteristic less than 4.0 hours.

In test number 62, O content is too low.Therefore, the number TN of specific field trash is less than 40/mm².As a result, nothing Method obtains excellent characteristic of getting rusty.In turn, CL1000 is less than 50m/ minutes, is also unable to get excellent chip treatability.That is, nothing Method obtains excellent machinability.

In test number 63, Cr too high levels.As a result, CL1000 is less than 50m/ minutes, it is unable to get excellent cutting Property.

In test number 64, Cr content is too low.As a result, rolling fatigue life was unable to get excellent less than 4.0 hours Rolling contact fatigue characteristic.

In test number 65 and 66, chemical composition is appropriate, and F1 is 8.0 or more, and solidification cooling RC is 100 DEG C/min Hereinafter, but deoxidation sequence it is inappropriate, therefore, the number TN of specific field trash is less than 40/mm².As a result, being unable to get excellent Characteristic of getting rusty.

More than, embodiments of the present invention are illustrated.But above embodiment is only intended to implement the present invention Example.Therefore, the present invention is not limited to the above embodiments, can suitably change in the range of without departing from its spirit above-mentioned Embodiment is implemented.

Description of symbols

10 MnS field trashes

20 Pb field trashes

30 complex inclusions

Claims

1. a kind of steel for mechanical structure, with following chemical composition:

Contained in terms of quality %

C:0.15% more than and less than 0.30%,

Si:0.01~0.80%,

Mn:0.20~2.00%,

P:0.030% or less,

S:0.010~0.100%,

Pb:0.010~0.100%,

Al:0.010~0.050%,

N:0.015% or less,

O:0.0005~0.0030%,

Cr:0.50~2.00%,

Ni:0~3.50%,

B:0~0.0050%,

V:0~0.70%,

Mo:0~0.70%,

W:0~0.70%,

Nb:0 more than and less than 0.050%,

Cu:0~0.50%,

The and of Ti:0~0.100%

Ca:0~0.0030%, surplus is Fe and impurity, and meets formula (1),

In steel, the total number of specific field trash is 40/mm²More than, the specific field trash is MnS field trash, Pb field trash With any one of the complex inclusion containing MnS and Pb, and equivalent circle diameter be 5 μm or more,

Mn/S≥8.0 (1)

Herein, the quality % content of respective element is substituted at each element in formula (1).

2. steel for mechanical structure according to claim 1, wherein

The chemical composition contain selected from by

Ni:0.02~3.50%,

B:0.0005~0.0050%,

V:0.05~0.70%,

Mo:0.05~0.70%,

W:0.05~0.70%,

Nb:0.001% more than and less than 0.050%,

The and of Cu:0.05~0.50%

It is one kind or two or more in the group that Ti:0.003~0.100% is formed.

3. according to claim 1 or steel for mechanical structure as claimed in claim 2, wherein

The chemical composition contains

Ca:0.0001~0.0030%.

4. steel for mechanical structure described in any one of according to claim 1~claim 3, wherein

The complex inclusion is 40% or more relative to the number ratio of the specific field trash.