CN109494311A - Substrate and preparation method thereof, display panel - Google Patents

Substrate and preparation method thereof, display panel Download PDF

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Publication number
CN109494311A
CN109494311A CN201811367369.0A CN201811367369A CN109494311A CN 109494311 A CN109494311 A CN 109494311A CN 201811367369 A CN201811367369 A CN 201811367369A CN 109494311 A CN109494311 A CN 109494311A
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substrate
layer
absorbing agent
water absorbing
electrode
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CN201811367369.0A
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CN109494311B (en
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罗程远
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BOE Technology Group Co Ltd
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BOE Technology Group Co Ltd
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    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K50/00Organic light-emitting devices
    • H10K50/80Constructional details
    • H10K50/84Passivation; Containers; Encapsulations
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K59/00Integrated devices, or assemblies of multiple devices, comprising at least one organic light-emitting element covered by group H10K50/00
    • HELECTRICITY
    • H10SEMICONDUCTOR DEVICES; ELECTRIC SOLID-STATE DEVICES NOT OTHERWISE PROVIDED FOR
    • H10KORGANIC ELECTRIC SOLID-STATE DEVICES
    • H10K71/00Manufacture or treatment specially adapted for the organic devices covered by this subclass

Abstract

The present invention provides a kind of substrate and preparation method thereof, display panel, is related to field of display technology, can improve because water absorbing agent enters inside OLED device, cause particle contamination, thus the problem of influencing the service life of OLED device.The substrate marks off viewing area, and the substrate includes substrate, and first electrode over the substrate and electroluminescence layer is arranged, and the first electrode is arranged in the electroluminescence layer far from the one side of substrate;The substrate further includes the first electrode the is arranged in water absorbing agent barrier layer far from the one side of substrate, and the water absorbing agent barrier layer is located at the viewing area;The water absorbing agent barrier layer, which is used to obstruct, is located at water absorbing agent of the water absorbing agent barrier layer far from the one side of substrate through the water absorbing agent barrier layer.

Description

Substrate and preparation method thereof, display panel
Technical field
The present invention relates to field of display technology more particularly to substrate and preparation method thereof, display panel.
Background technique
OLED (Organic Light-Emitting Diode, organic electroluminescent LED) display device is due to having Thin, light, wide viewing angle actively shines, continuously adjustable, at low cost, the high colour gamut of luminescent color, high contrast, fast response time, energy consumption It is small, driving voltage is low, operating temperature range is wide, simple production process, luminous efficiency are high and can Flexible Displays the advantages that, arranged For the next-generation display technology with development prospect, but still there are some problems demands to solve.
Since OLED device is under the action of steam and oxygen, it may appear that the phenomenon that corrosion and damage, therefore, selection is preferable Packaged type is particularly important for OLED device.In traditional handicraft, often in packaging plastic be added water absorbing agent (or be drying Agent), Lai Zengqiang packaging effect.But water absorbing agent is generally the powder such as calcium oxide (CaO), magnesia (MgO), barium monoxide (BaO) Particle chemosorbent or gel physical absorbent, water absorbing agent is after glue material solidification since diffusion can enter OLED device (including cathode, anode, light emitting functional layer etc.) is internal, causes particle (Particle) to pollute, to influence making for OLED device Use the service life.
Summary of the invention
The embodiment of the present invention provides a kind of substrate and preparation method thereof, display panel, can improve because water absorbing agent enters Inside OLED device, particle contamination is caused, thus the problem of influencing the service life of OLED device.
In order to achieve the above objectives, the embodiment of the present invention adopts the following technical scheme that
On the one hand, a kind of substrate is provided, viewing area is marked off, the substrate includes substrate, is arranged over the substrate First electrode and electroluminescence layer, the first electrode are arranged in the electroluminescence layer far from the one side of substrate;The base Plate further includes the first electrode the is arranged in water absorbing agent barrier layer far from the one side of substrate, and the water absorbing agent barrier layer is located at The viewing area;The water absorbing agent barrier layer is located at the water suction of the water absorbing agent barrier layer far from the one side of substrate for obstructing Agent penetrates the water absorbing agent barrier layer.
Optionally, the water absorbing agent barrier layer covers the viewing area.
Optionally, the first electrode covers the viewing area, and the water absorbing agent barrier layer is arranged including 1~15 layer stackup Graphene layer.
Optionally, every layer of graphene layer is formed by connecting by multiple sub- film layers;Wherein, in the water absorbing agent barrier layer packet In the case where including graphene layer described in multilayer, in graphene layer described in adjacent two layers, the multiple sub- film layer between any two Junction is staggered.
Optionally, the substrate further includes multiple second electricity that the electroluminescence layer is arranged in close to the one side of substrate Pole;The first electrode is transmission electrode, and each of the multiple second electrode is reflecting electrode.
Optionally, the first electrode covers the viewing area, the substrate further include setting the first electrode with Layer is filled and led up between the water absorbing agent barrier layer.
Optionally, the layer of filling and leading up is transparency conducting layer.
Optionally, it is described fill and lead up layer with a thickness of 5~10 μm.
Optionally, the material for filling and leading up layer includes conducting polymer.
Second aspect, provides a kind of preparation method of substrate, and the substrate marks off viewing area, the preparation method packet It includes: electroluminescence layer is formed on the substrate;First electrode is formed on the substrate for being formed with the electroluminescence layer;It is being formed with Water absorbing agent barrier layer is formed on the substrate of the first electrode, the water absorbing agent barrier layer is located at the viewing area;Wherein, described Water absorbing agent barrier layer, which is used to obstruct, is located at water absorbing agent of the water absorbing agent barrier layer far from the one side of substrate through the water suction Agent barrier layer.
Optionally, described to form first electrode on the substrate for being formed with the electroluminescence layer, comprising: to be formed It states and forms first electrode on the substrate of electroluminescence layer, the first electrode covers the viewing area;It is described be formed with it is described Water absorbing agent barrier layer is formed on the substrate of first electrode, comprising: the graphene layer that 1~15 layer stackup is arranged by transfer technique It is attached on the substrate for being formed with the first electrode, as the water absorbing agent barrier layer.
Optionally, described to form first electrode on the substrate for being formed with the electroluminescence layer, comprising: to be formed It states and forms first electrode on the substrate of electroluminescence layer, the first electrode covers the viewing area;It is described be formed with it is described Water absorbing agent barrier layer is formed on the substrate of first electrode, comprising: transparent lead is formed on the substrate for being formed with the first electrode Electricity fills and leads up film;The graphene layer that 1~15 layer stackup is arranged is attached to the electrically conducting transparent by transfer technique and fills and leads up film On, as the water absorbing agent barrier layer;It fills and leads up film to the electrically conducting transparent to solidify, layer is filled and led up in formation.
The third aspect provides a kind of display panel, including the described in any item substrates of first aspect;Further include and the base The cover board of plate pressing, is coated with the packaging plastic including water absorbing agent on the cover board.
The present invention provides a kind of substrate and preparation method thereof, display panel, by setting in first electrode far from one side of substrate Water absorbing agent barrier layer is set, so, when substrate is applied to display panel, is located at water absorbing agent barrier layer far from one side of substrate Water absorbing agent diffusion occurs when being moved to water absorbing agent barrier layer far from one side of substrate, under the barrier action of water absorbing agent barrier layer, Water absorbing agent can not pass through water absorbing agent barrier layer and enter inside OLED device, so as to improve because water absorbing agent enters in OLED device Portion causes particle contamination, thus the problem of influencing the service life of OLED device.
Detailed description of the invention
In order to more clearly explain the embodiment of the invention or the technical proposal in the existing technology, to embodiment or will show below There is attached drawing needed in technical description to be briefly described, it should be apparent that, the accompanying drawings in the following description is only this Some embodiments of invention for those of ordinary skill in the art without creative efforts, can be with It obtains other drawings based on these drawings.
Fig. 1 is a kind of structural schematic diagram one of substrate provided in an embodiment of the present invention;
Fig. 2 is a kind of structural schematic diagram of water absorbing agent barrier layer provided in an embodiment of the present invention;
Fig. 3 is a kind of structural schematic diagram two of substrate provided in an embodiment of the present invention;
Fig. 4 is a kind of structural schematic diagram of display panel provided in an embodiment of the present invention;
Fig. 5 is a kind of flow chart of the preparation method of substrate provided in an embodiment of the present invention.
Appended drawing reference:
The viewing area 01-;10- substrate;20- first electrode;30- electroluminescence layer;40- water absorbing agent barrier layer;41- graphene Layer;The sub- film layer of 411-;50- second electrode;60- fills and leads up layer;70- pixel defining layer;80- packaging plastic.
Specific embodiment
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation description, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, it is obtained by those of ordinary skill in the art without making creative efforts every other Embodiment shall fall within the protection scope of the present invention.
The embodiment of the present invention provides a kind of substrate, as shown in Figure 1, marking off viewing area 01, substrate includes substrate 10, setting First electrode 20 and electroluminescence layer 30 on substrate 10, first electrode 20 are arranged in electroluminescence layer 30 far from substrate 10 1 Side;Substrate further includes that water absorbing agent barrier layer 40 of the first electrode 20 far from 10 side of substrate is arranged in, and water absorbing agent barrier layer 40 In viewing area 01;Water absorbing agent barrier layer 40, which is used to obstruct, to be penetrated positioned at water absorbing agent barrier layer 40 far from the water absorbing agent of 10 side of substrate Water absorbing agent barrier layer 40.
It should be noted that first, first electrode 20 can be transmission electrode, or reflecting electrode;It can be sun Pole, or cathode.
Second, electroluminescence layer 30 includes issuing the luminescence unit of three primary colours light in electric field action, wherein the first primary colours, Second primary colours and third primary colours can red each other, blue and green, for example, the first primary colours be red, the second primary colours be blue, Third primary colours are green, naturally it is also possible to be other combinations.Alternatively, the first primary colours, the second primary colours and third primary colours can also be mutual Certainly may be used for cyan, magenta and yellow for example, the first primary colours are cyan, the second primary colours are magenta, third primary colours are yellow To be other combinations.
Certainly, electroluminescence layer 30 can also include the luminescence unit to emit white light.
Third, can be set other light emitting functional layers between first electrode 20 and electroluminescence layer 30, the present invention is simultaneously unlimited It is set to the surface that electroluminescence layer 30 is arranged in first electrode 20.
4th, when substrate is applied to display device, cover board and substrate are sealed by packaging plastic, and in the related technology, it is Enhancing packaging effect, usually adding in packaging plastic has water absorbing agent, and the embodiment of the present invention is not tied water absorbing agent barrier layer 40 specifically The mode of structure, material and barrier water absorbing agent is defined.
For example, it may be water absorbing agent barrier layer 40 includes the material with stronger compactness, inhaled with obstructing water absorbing agent and passing through Aqua barrier layer 40;It can also be that water absorbing agent barrier layer 40 includes the material of adsorbable water absorbing agent, inhaled with obstructing water absorbing agent and passing through Aqua barrier layer 40;Either water absorbing agent barrier layer 40 includes the material that can be reacted with water absorbing agent, is worn with obstructing water absorbing agent Cross water absorbing agent barrier layer 40.
5th, water absorbing agent barrier layer 40 is located at viewing area 01, such as in some embodiments, as shown in Figure 1, water absorbing agent hinders Interlayer 40 covers entire viewing area 01;In some embodiments, viewing area 01 marks off multiple open regions, water absorbing agent barrier layer 40 It is divided into muti-piece, one open region of every piece of covering;It is, of course, also possible to be other branch's modes.
Substrate provided in an embodiment of the present invention, by the way that water absorbing agent barrier layer is arranged far from 10 side of substrate in first electrode 20 40, so, the water absorbing agent when substrate is applied to display panel, positioned at water absorbing agent barrier layer 40 far from 10 side of substrate When generation diffusion is moved to water absorbing agent barrier layer 40 far from 10 side of substrate, under the barrier action of water absorbing agent barrier layer 40, inhale Aqua can not pass through water absorbing agent barrier layer 40 and enter inside OLED device, so as to improve because water absorbing agent enters in OLED device Portion causes particle contamination, thus the problem of influencing the service life of OLED device.
For top-emitting OLED, the top electrode as light-emitting surface OLED must have good light transmission rate.Currently, top What transmitting transparent electrode used is mostly the materials such as thin metal, ITO, IZO, wherein metal is since transmitance is poor, conduct after thinning Broad-area electrode use be easy to cause resistance to increase, and is unfavorable for the exploitation of large-size device.ITO (Indium Tin Oxide, indium Tin-oxide), the high material of transparencies such as IZO (Indium Zinc Oxide, indium-zinc oxide), the electric conductivity of itself It is weaker than metal.Therefore in the related technology, using metal as auxiliary electrode, non-luminous region is produced on using the method for photoetching, is mentioned The overall conductivity of high top emitting transparent electrode reaches the low-resistance effect of drop.But this photoetching technique needs complicated work Skill, is related to multiple tracks mask plate and exposure process, and since it needs high temperature, photoresist the process characteristics such as to wash away, can be to OLED The electroluminescence layer 30 of device damages, and is not suitable as volume production means.It is also existing that auxiliary electrode is made on encapsulation cover plate There is one of technology to increase a kind of mode of electrode conductivuty, it can be to avoid being deposited in the first manufacture craft using this kind of mode The problem of.But auxiliary electrode relies on encapsulation cover plate, and component cases thickness is caused to become larger, and is unfavorable for the thinning of display device.
Based on this, in some embodiments, as shown in Figure 1, first electrode 20 covers viewing area 01, as shown in Fig. 2, water suction Agent barrier layer 40 include 1~15 layer stackup setting graphene layer 41 (Fig. 2 with include 5 layer stackups be arranged graphene layer 41 be Example).
Wherein, graphene is conductive material, when surface of the first electrode 20 far from substrate 10 is arranged in graphene layer 41, or When being provided with conductive layer between person's first electrode 20 and graphene layer 41, graphene layer 41 and first electrode 20 are connected.
Further, since single-layer graphene layer 41 is easily broken, it includes multilayer stone that water absorbing agent barrier layer 40 can be made in the present invention Black alkene layer 41.
Herein, on the one hand, since the compactness of graphene layer 41 is stronger, so that when water absorbing agent barrier layer 40 includes graphene When layer 41, water absorbing agent can effectively be obstructed, prevent water-absorbing agent OLED device from generating damage;On the other hand, graphite Alkene layer 41 has preferable flexibility, is applicable to flexible display panels;In another aspect, graphene layer 41 is conductive layer, it can be with First electrode 20 is connected, as auxiliary electrode, it is not necessary that auxiliary electrode, and the light of graphene layer 41 is separately provided in display panel Transmitance reaches 95% or so, will not influence light transmission rate.
In order to guarantee the barriering effect to water absorbing agent, in some embodiments, as shown in Fig. 2, every layer of graphene layer 41 by Multiple sub- film layers 411 are formed by connecting;Wherein, in the case where water absorbing agent barrier layer 40 includes multiple graphene layers 41, adjacent two In layer graphene layer 41, the junction between any two of multiple sub- film layers 411 is staggered.
Herein, since graphene layer 41 is a planar structure, the connection type between sub- film layer 411 for example may be used To be splicing, it is also possible to overlap or other connection types.
Each layer of graphene layer 41 includes multiple sub- film layers 411, and multiple sub- film layers 411 are connected as a planar structure, more The shape of a sub- film layer 411 may be the same or different.For example, the rectangle that every sub- film layer 411 is 200mm × 200mm, Multiple sub- film layers 411 are connected as a planar structure.
Each layer of graphene layer 41 has multiple junctions formed when being connected by sub- film layer 411 two-by-two, is located at adjacent two Junction in layer graphene layer 41 is staggered.
In some embodiments, as shown in figure 3, substrate further includes that electroluminescence layer 30 is arranged in close to 10 side of substrate Multiple second electrodes 50;First electrode 20 is transmission electrode, and each of multiple second electrodes 50 are reflecting electrode.
It can also include multiple thin film transistor (TFT)s in substrate, each thin film transistor (TFT) connects a second electrode 50.Work as base When plate is applied to display panel, display panel is top emission type display panel.
In order to avoid directly when 20 surface of first electrode forms water absorbing agent barrier layer 40, water absorbing agent barrier layer 40 can break It splits, in some embodiments, as shown in figure 3, first electrode 20 covers viewing area 01, substrate further includes being arranged in first electrode 20 Layer 60 is filled and led up between water absorbing agent barrier layer 40.
Wherein, the material for filling and leading up layer 60 can be conductive material, or insulating materials, the material for filling and leading up layer 60 can be with For opaque material, substrate is suitable for bottom emitting type display panel, and the material for filling and leading up layer 60 may be transparent material, and substrate is suitable For bottom emitting type display panel and top emission type display panel.
As shown in figure 3, providing a kind of specific board structure, thin film transistor (TFT), pixel circle are successively formed on substrate 10 Given layer 70, second electrode 50, light emitting functional layer, first electrode 20.The height of pixel defining layer 70 is generally relatively high, leads to first 20 flatness of electrode is poor.
Herein, it is filled using filling and leading up at the position of 60 pairs of open region of layer, can prevent from forming water absorbing agent barrier layer 40 When, water absorbing agent barrier layer 40 is broken.
In some embodiments, filling and leading up layer 60 is transparency conducting layer.
Graphene layer 41 is conductive layer, and filling and leading up layer 60 is conductive layer, and first electrode 20 fills and leads up 41 layers of layer 60, graphene layer Folded setting.So, graphene layer 41 can be connected with first electrode 20, as auxiliary electrode, be not necessarily in display panel independent Auxiliary electrode is set, and the light transmission rate of graphene layer 41 reaches 95% or so, filling and leading up layer 60 is transparent material, be will not influence Light transmission rate.
In some embodiments, the material for filling and leading up layer 60 includes conducting polymer.
Illustratively, the material for filling and leading up layer 60 is inorganic-organic nanocomposite, and material of main part includes polyethylene, gathers Styrene, polyacrylic acid, polyacrylate, polyamide, polyimides, polycarbonate, urethane acrylate, gathers polypropylene The mixture of the formation such as ester, polysiloxanes, polysilazane.Quantum dot, the nano wire, nanometer that radius is 1nm-10nm can be adulterated Stick, specific material be, for example, arsenic pentafluoride (AsF5), hexafluoro-antimonic acid (SbF6), iron chloride (FeCl3), tin tetrachloride (SnCl4), Silver perchlorate (AgCLO4) etc..The additives such as iodine (I2), bromine (Br2) can also be adulterated.For example, can be with dopant material than total material The volume ratio that the volume ratio of material is 20%~40% is mixed in main polymer.
In some embodiments, fill and lead up layer 60 with a thickness of 5~10 μm.
For example, can be 6 μm, 7 μm, 8 μm, 9 μm.
The embodiment of the present invention also provides a kind of display panel, as shown in figure 4, including aforesaid substrate, further includes and substrate pressure The cover board of conjunction is coated with the packaging plastic 80 including water absorbing agent on cover board.
The coating method of packaging plastic 80 can refer to the relevant technologies, and packaging plastic 80 can be uv-curing type resin glue or heat Solidified resin glue.The material of packaging plastic 80, such as may include: epoxy resin, Glycidyl Acrylate, glycidyl Propyl ester, methyl methacrylate, ethyl methacrylate, n-BMA, methyl polyacrylic acid 6,7- epoxy heptyl ester, The homopolymer or melamine resin, unsaturated polyester resin, organosilicon of the monomers such as methacrylic acid -2- hydroxy methacrylate The copolymers such as resin, furane resins.
Water absorbing agent for example may include the liquid driers such as the desiccant particles such as CaO, MgO, BaO or glycerol, diethylene glycol (DEG).
Above-mentioned display panel specifically can be OLED display, OLED TV, Digital Frame, mobile phone, tablet computer, navigation Instrument etc. has the product or component of any display function.
Display panel provided by the invention includes aforesaid substrate, and beneficial effect is identical as aforesaid substrate, and details are not described herein again.
The embodiment of the present invention also provides a kind of preparation method of substrate, as shown in Figure 5, comprising:
S10, electroluminescence layer 30 is formed on substrate 10.
Wherein, specific formation process, can refer to the relevant technologies.
S20, first electrode 20 is formed on the substrate 10 for be formed with electroluminescence layer 30.
In some embodiments, step S20 includes: to form first electrode on the substrate 10 for being formed with electroluminescence layer 30 20, first electrode 20 covers viewing area 01.
S30, water absorbing agent barrier layer 40 is formed on the substrate 10 for be formed with first electrode 20, water absorbing agent barrier layer 40 is located at Viewing area 01;Wherein, water absorbing agent barrier layer 40 is located at water absorbing agent of the water absorbing agent barrier layer 40 far from 10 side of substrate for obstructing Through water absorbing agent barrier layer 40.
In some embodiments, step S30 includes: the graphene layer 41 that 1~15 layer stackup is arranged by transfer technique It is attached on the substrate 10 for being formed with first electrode 20, as water absorbing agent barrier layer 40.
For example, one layer of graphene layer 41 can be formed on the substrate, then it is transferred to using the method for mechanical stripping not solid It in the first electrode 20 of change, then repeats the above steps, forms multiple graphene layers 41, formed and absorbed water by multiple transfer printing process Agent barrier layer 40.It is also possible to that the graphene layer 41 of 1~15 layer stackup setting is formed on the substrate, then using mechanical stripping Method is transferred in first electrode 20, forms water absorbing agent barrier layer 40 by primary transfer.
In some embodiments, step S30 includes:
S31, formation electrically conducting transparent fills and leads up film on the substrate 10 for be formed with first electrode 20.
For example, can be filled and led up by way of printing in the electrically conducting transparent that the upper surface of first electrode 20 forms 5~10 μm Film is formed in open region, filler pixels inner space.
S32, it the graphene layer 41 that 1~15 layer stackup is arranged is attached to by electrically conducting transparent by transfer technique fills and leads up film On, as water absorbing agent barrier layer 40.
For example, one layer of graphene layer 41 can be formed on the substrate, then it is transferred to using the method for mechanical stripping not solid The electrically conducting transparent of change is filled and led up on film, is then repeated the above steps, and is formed multiple graphene layers 41, is passed through multiple transfer printing process shape At water absorbing agent barrier layer 40.It is also possible to that the graphene layer 41 of 1~15 layer stackup setting is formed on the substrate, then using machinery The method of removing is transferred to uncured electrically conducting transparent and fills and leads up on film, forms water absorbing agent barrier layer 40 by primary transfer.
S33, film is filled and led up to electrically conducting transparent solidifying, layer 60 is filled and led up in formation.
Solidify for example, filling and leading up film to electrically conducting transparent by ultraviolet light irradiation, layer 60 is filled and led up in formation.
The beneficial effect of the preparation method of substrate provided in an embodiment of the present invention and the beneficial effect of substrate are identical, herein not It repeats again.
A kind of preparation method of specific display panel of example sequentially forms thin film transistor (TFT), array row on substrate 10 The structures such as the anode of cloth, 1.5 μm high of pixel defining layer 70, light emitting functional layer, planar cathode.
Then planar cathode surface will adulterate the polystyrene of 40%FeCl3, I2, polypropylene miser passes through printing The electrically conducting transparent that mode forms 10 μ m-thicks fills and leads up film, fills open region inner space.
Again by way of transfer, single-layer graphene layer 41 is covered in electrically conducting transparent and is filled and led up on film, irradiating ultraviolet light Electrically conducting transparent is set to fill and lead up film hardening, layer 60 is filled and led up in formation.
Coating has the packaging plastic of water absorbing agent on the cover board, cover board and substrate is pressed, cure package glue, completes encapsulation knot Structure.
The above description is merely a specific embodiment, but scope of protection of the present invention is not limited thereto, any Those familiar with the art in the technical scope disclosed by the present invention, can easily think of the change or the replacement, and should all contain Lid is within protection scope of the present invention.Therefore, protection scope of the present invention should be based on the protection scope of the described claims.

Claims (10)

1. a kind of substrate marks off viewing area, the substrate includes substrate, and first electrode over the substrate and electroluminescent is arranged Luminescent layer, the first electrode are arranged in the electroluminescence layer far from the one side of substrate;It is characterized in that,
The substrate further includes the first electrode the is arranged in water absorbing agent barrier layer far from the one side of substrate, the water absorbing agent Barrier layer is located at the viewing area;
The water absorbing agent barrier layer, which is used to obstruct, to be penetrated positioned at the water absorbing agent barrier layer far from the water absorbing agent of the one side of substrate The water absorbing agent barrier layer.
2. substrate according to claim 1, which is characterized in that the water absorbing agent barrier layer covers the viewing area.
3. substrate according to claim 1, which is characterized in that the first electrode covers the viewing area, the water suction Agent barrier layer includes the graphene layer of 1~15 layer stackup setting.
4. substrate according to claim 3, which is characterized in that every layer of graphene layer by multiple sub- film layers connections and At;
Wherein, in the case where the water absorbing agent barrier layer includes graphene layer described in multilayer, graphene layer described in adjacent two layers In, the junction between any two of the multiple sub- film layer is staggered.
5. substrate according to claim 1, which is characterized in that further include being arranged in the electroluminescence layer close to the lining Multiple second electrodes of bottom side;
The first electrode is transmission electrode, and each of the multiple second electrode is reflecting electrode.
6. substrate according to claim 1, which is characterized in that the first electrode covers the viewing area, the substrate It further include being arranged between the first electrode and the water absorbing agent barrier layer to fill and lead up layer.
7. substrate according to claim 6, which is characterized in that
The layer of filling and leading up is transparency conducting layer;
And/or
It is described fill and lead up layer with a thickness of 5~10 μm;
And/or
The material for filling and leading up layer includes conducting polymer.
8. a kind of preparation method of substrate, which is characterized in that the substrate marks off viewing area, and the preparation method includes:
Electroluminescence layer is formed on the substrate;
First electrode is formed on the substrate for being formed with the electroluminescence layer;
Water absorbing agent barrier layer is formed on the substrate for being formed with the first electrode, the water absorbing agent barrier layer is located at the display Area;Wherein, the water absorbing agent barrier layer is located at the water absorbing agent of the water absorbing agent barrier layer far from the one side of substrate for obstructing Through the water absorbing agent barrier layer.
9. the preparation method of substrate according to claim 8, which is characterized in that described to be formed with the electroluminescence layer Substrate on form first electrode, comprising:
First electrode is formed on the substrate for being formed with the electroluminescence layer, the first electrode covers the viewing area;
It is described that water absorbing agent barrier layer is formed on the substrate for being formed with the first electrode, comprising: by transfer technique by 1~15 The graphene layer of layer stackup setting is attached on the substrate for being formed with the first electrode, as the water absorbing agent barrier layer;
Alternatively,
It is described that water absorbing agent barrier layer is formed on the substrate for being formed with the first electrode, comprising:
Electrically conducting transparent is formed on the substrate for being formed with the first electrode fills and leads up film;
The graphene layer that 1~15 layer stackup is arranged the electrically conducting transparent is attached to by transfer technique to fill and lead up on film, as The water absorbing agent barrier layer;
It fills and leads up film to the electrically conducting transparent to solidify, layer is filled and led up in formation.
10. a kind of display panel, which is characterized in that including the described in any item substrates of claim 1-7;
Further include the cover board with substrate pressing, is coated with the packaging plastic including water absorbing agent on the cover board.
CN201811367369.0A 2018-11-16 2018-11-16 Substrate, preparation method thereof and display panel Active CN109494311B (en)

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CN116218116A (en) * 2022-12-26 2023-06-06 合肥维信诺科技有限公司 Organic packaging material and preparation method thereof, display device and preparation method thereof

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