CN109485783A - A kind of high gloss gloss oil is with water soluble acrylic resin and preparation method thereof - Google Patents
A kind of high gloss gloss oil is with water soluble acrylic resin and preparation method thereof Download PDFInfo
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- CN109485783A CN109485783A CN201811238031.5A CN201811238031A CN109485783A CN 109485783 A CN109485783 A CN 109485783A CN 201811238031 A CN201811238031 A CN 201811238031A CN 109485783 A CN109485783 A CN 109485783A
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F2/00—Processes of polymerisation
- C08F2/44—Polymerisation in the presence of compounding ingredients, e.g. plasticisers, dyestuffs, fillers
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/10—Esters; Ether-esters
- C08K5/11—Esters; Ether-esters of acyclic polycarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/13—Phenols; Phenolates
- C08K5/134—Phenols containing ester groups
- C08K5/1345—Carboxylic esters of phenolcarboxylic acids
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
- C09D133/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, the oxygen atom being present only as part of the carboxyl radical
- C09D133/062—Copolymers with monomers not covered by C09D133/06
- C09D133/066—Copolymers with monomers not covered by C09D133/06 containing -OH groups
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/14—Paints containing biocides, e.g. fungicides, insecticides or pesticides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/63—Additives non-macromolecular organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08F—MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08F220/00—Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
- C08F220/02—Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
- C08F220/10—Esters
- C08F220/12—Esters of monohydric alcohols or phenols
- C08F220/16—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms
- C08F220/18—Esters of monohydric alcohols or phenols of phenols or of alcohols containing two or more carbon atoms with acrylic or methacrylic acids
- C08F220/1804—C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Plant Pathology (AREA)
- Addition Polymer Or Copolymer, Post-Treatments, Or Chemical Modifications (AREA)
Abstract
A kind of high gloss gloss oil is comprised the following components in parts by weight: 8.8 ~ 9.2 parts of acrylic acid with water soluble acrylic resin；18 ~ 17 parts of hydroxy-ethyl acrylate；5.2 ~ 6 parts of methacrylic acid -2- hydroxy methacrylate；37 ~ 40 parts of butyl acrylate；14 ~ 15 parts of methyl methacrylate；23 ~ 25 parts of styrene；11 ~ 13 parts of tertiary ethylene carbonate；2.9 ~ 3.1 parts of perbenzoic acid spy butyl ester；43 ~ 45 parts of solvent.Preparation method involved in the present invention, comprising the following steps: solvent is placed in reaction vessel by A., is stirred and is heated；B. it after monomer being mixed, is added drop-wise in the reaction vessel in step A, time for adding 2 ~ 8 hours, is stirred to react；C. stop heating after completion of dropwise addition, and continue stirring 1 ~ 2 hour, when system temperature is down to 65 ~ 85 DEG C, pour out reaction solution, gloss oil uses water soluble acrylic resin.The present invention improves the stability of system, prepared gloss oil glossiness is high, and mechanical property is good by the optimization to component；Gloss oil simultaneously in the application is simple with the preparation method of water soluble acrylic resin, and process costs are low.
Description
Technical field
Auto body coatings technical field of the present invention, and in particular to a kind of high gloss gloss oil is with water-soluble acrylic tree
Rouge, while the invention further relates to the preparation methods of the water soluble acrylic resin.
Background technique
Car paint just refers to the coating being painted on the various types of vehicles such as car vehicle body and components, refers generally to the painting of new car
Material and auxiliary material and vehicle repairing coating.Wherein, can be divided by coating form: water paint, solvent based coating, powder apply
Material；It can be divided by working procedure: priming paint, middle paint, finishing coat, finishing varnish etc.；Can be divided by construction method: brush coating, spraying apply
Material, roll coat enamel, dip-coating paint, electrophoretic coating etc..
In solvent based coating, high solids coatings and low-solid content coating can be divided by its solid content height, the two
VOC content one low one is high, adapts to different environmental protection standard and area and uses, the mainstream demand of developed country is VOC content at present
Low high solids coatings.Because of its expensive price and almost, the characteristic of Diamond Search is still within the primary stage to powdery paints, now
Mainly on high-end vehicle.In contrast, at present water paint due to its environmental-friendly property, the market demand be in by
The trend that year rises, US and European account for the 70% of water paint market in the demand to water paint in 2015.
Gloss oil is used to brush on the surface of paint object, increases the glossiness on surface, while increasing the solar heat protection of paint, preventing
Damp, anti-wiping ability.Gloss oil is to have for the film forming agent in gloss oil to the filming performance of gloss oil, glossiness with acrylic resin
It has a major impact, therefore the suitable acrylic resin of selection helps to improve the performance of gloss oil.
Water-base resin uses water or solvent as decentralized medium, generally comprises water-soluble resin, aqueous emulsion resin, water-base resin
Three kinds of dispersion, three kinds of resins all have the characteristics of colourless, tasteless, transparent feel is strong and nontoxic, low VOC, only solvent
With the difference of the mode of dispersion, there is higher requirement to the glossiness of gloss oil currently on the market, therefore the application is to high gloss
Gloss oil is studied with water soluble acrylic resin.
Summary of the invention
For the above deficiency in the prior art, the present invention provides a kind of high gloss gloss oil with water-soluble acrylic tree
Rouge, while the invention further relates to the gloss oil preparation methods of water soluble acrylic resin.
In order to solve the above-mentioned technical problem, the present invention is addressed by following technical proposals.
A kind of high gloss gloss oil is comprised the following components in parts by weight with water soluble acrylic resin: acrylic acid 8.8~
9.2 part；18~17 parts of hydroxy-ethyl acrylate；5.2~6 parts of methacrylic acid -2- hydroxy methacrylate；37~40 parts of butyl acrylate；
14~15 parts of methyl methacrylate；23~25 parts of styrene；11~13 parts of tertiary ethylene carbonate；Perbenzoic acid spy's butyl ester
2.9~3.1 parts；43~45 parts of solvent.
In preferred scheme, the gloss oil in the application is comprised the following components in parts by weight with water soluble acrylic resin: third
9.04 parts of olefin(e) acid；16.44 parts of hydroxy-ethyl acrylate；5.6 parts of methacrylic acid -2- hydroxy methacrylate；38.22 parts of butyl acrylate；
14.59 parts of methyl methacrylate；24.45 parts of styrene；12 parts of tertiary ethylene carbonate；Perbenzoic acid spy butyl ester 3.08
Part；44.18 parts of solvent.
In preferred scheme, gloss oil in the application further includes the component of following parts by weight with water soluble acrylic resin:
0.8~1.3 part of tributyl citrate, 1.1~1.4 parts of phenyl salicylate.
In preferred scheme, the solvent is butyl glycol ether or butyl.
A kind of preparation method of water soluble acrylic resin of high gloss gloss oil involved in the present invention, including following step
Rapid: solvent is placed in reaction vessel by A., is stirred and heated to 120~130 DEG C, the solvent is butyl glycol ether or diethyl two
Alcohol butyl ether；B. by acrylic acid, hydroxy-ethyl acrylate, methacrylic acid -2- hydroxy methacrylate, butyl acrylate, methyl methacrylate
After ester, styrene, tertiary ethylene carbonate, the mixing of perbenzoic acid spy's butyl ester, it is added drop-wise in the reaction vessel in step A, drips
It 2~8 hours between added-time, is stirred to react, 120~130 DEG C of reaction temperature；C. after completion of dropwise addition stop heating, and continue stirring 1~
2 hours, when system temperature is down to 65~85 DEG C, reaction solution is poured out, gloss oil is obtained and uses water soluble acrylic resin.
In preferred scheme, in step B, reaction temperature is 125 DEG C.
In preferred scheme, the material in preparation process is with following parts by weight: 8.8~9.2 parts of acrylic acid；Acrylic acid hydroxyl
18~17 parts of ethyl ester；5.2~6 parts of methacrylic acid -2- hydroxy methacrylate；37~40 parts of butyl acrylate；Methyl methacrylate
14~15 parts；23~25 parts of styrene；11~13 parts of tertiary ethylene carbonate；2.9~3.1 parts of perbenzoic acid spy butyl ester；It is molten
43~45 parts of agent.
In preferred scheme, the material in preparation process further includes 0.8~1.3 parts by weight of tributyl citrate, salicylic acid
1.1~1.4 parts by weight of phenyl ester, the tributyl citrate, phenyl salicylate are added drop-wise in solvent after mixing with raw material.
Compared with prior art, the invention has the following advantages: providing a kind of high gloss gloss oil water solubility
Acrylic resin improves the stability of system, prepared gloss oil glossiness is high, mechanical property by the optimization to component
It is good；Gloss oil simultaneously in the application is simple with the preparation method of water soluble acrylic resin, and process costs are low.
Specific embodiment
Present invention is further described in detail With reference to embodiment.
A kind of high gloss gloss oil involved in the present invention is with water soluble acrylic resin, the group including following parts by weight
Point: 8.8~9.2 parts of acrylic acid；18~17 parts of hydroxy-ethyl acrylate；5.2~6 parts of methacrylic acid -2- hydroxy methacrylate；Acrylic acid
37~40 parts of butyl ester；14~15 parts of methyl methacrylate；23~25 parts of styrene；11~13 parts of tertiary ethylene carbonate；Peroxide
Change 2.9~3.1 parts of benzoic acid spy butyl ester；43~45 parts of solvent.
Further include the component of following parts by weight in the application, in preferred scheme, in raw material: tributyl citrate 0.8~
1.3 parts, 1.1~1.4 parts of phenyl salicylate；Solvent in the application is butyl glycol ether or butyl.
The gloss oil preparation method of water soluble acrylic resin is further related in the application, comprising the following steps: A. will be molten
Agent is placed in reaction vessel, is stirred and heated to 120~130 DEG C；B. by acrylic acid, hydroxy-ethyl acrylate, methacrylic acid -2-
Hydroxy methacrylate, butyl acrylate, methyl methacrylate, styrene, tertiary ethylene carbonate, the mixing of perbenzoic acid spy's butyl ester
Afterwards, it is added drop-wise in the reaction vessel in step A, time for adding 2~8 hours, is stirred to react, 120~130 DEG C of reaction temperature；C.
Stop heating after completion of dropwise addition, and continue stirring 1~2 hour, when system temperature is down to 65~85 DEG C, pours out reaction solution, obtain
Water soluble acrylic resin is used to gloss oil.
Following table 1 is the embodiment and comparative example in the present invention.
Table 1
Gloss oil described herein with water soluble acrylic resin refer to a variety of different structures acrylate and
The mixture of other substances.Solvent for use is butyl glycol ether in above embodiments 1-4, comparative example 1,2；Above embodiments 5-6,
In comparative example 3 solvent for use be butyl, butyl glycol ether and butyl in reaction monomer and polymerization
The dissolubility of body is good, goes on smoothly reaction.The above prepared water soluble acrylic resin is transparency liquid.
Following table 2 is some physical for water soluble acrylic resin's prepared by the embodiment and comparative example in the present invention
Matter.
Table 2
In the application, polymerization reaction is carried out using a variety of different monomers, makes prepared acrylic resin stereochemical structure
Abundant, system stability is strong, wherein the stability and dispersibility of system can be enhanced in the tributyl citrate added, improves and saves
Service life；Phenyl salicylate can also improve the uvioresistant performance of system as stabilizer and preservative, improve its service life.The application
Middle acrylic resin solid content is high, so that product is had good richness, hardness of film and flexibility, while having good face
Expect wetability, general inorganic pigment (such as titanium white) does not need additionally to add dispersing agent, and wetting flow leveling is good.
In the gloss oil product of later period preparation, property stability, stereochemical structure is strong, and glossiness is high, can dramatically increase film forming
Intensity afterwards improves its mechanical performance, anti-friction performance.
Following table 3 is the testing result of gloss oil prepared by embodiment 1-6 and comparative example 1-4.
Table 3
The process of prepared gloss oil is identical in above table, above as can be seen that in the application in embodiment 1-6
Water soluble acrylic resin prepared by gloss oil, indices meet the requirements, and very high glossiness are all had, so that object
Surface ornamental value is high.In the above comparative example 1 and 2, the methacrylic acid -2- hydroxy methacrylate of cancellation and making for tertiary ethylene carbonate
With the actual performance of oil polish prepared by the two is slightly worse than embodiment 1-6, bad mechanical property after oil polish film forming, same
Etc. be easily broken under the scrapings of conditions, collision, generate scratch, protection effect is poor；Comparative example 3 increases the use of hydroxy-ethyl acrylate
Amount, color brightness decreases after prepared oil polish forms a film, and aesthetic feeling is slightly worse.
Above as can be seen that in the application, by the selection of raw material components, the optimization of component proportion, so that prepared
Water soluble acrylic resin's superior performance, stability is good, prepared by gloss oil good mechanical property, protectiveness is strong, while gloss
It spends, effect is beautiful after film forming, and perception is beautiful.
The above provides a kind of high gloss gloss oil in the present invention with water soluble acrylic resin, by component
Optimization, improve the stability of system, prepared gloss oil glossiness is high, and mechanical property is good；Gloss oil in the application simultaneously
Simple with the preparation method of water soluble acrylic resin, process costs are low.
Protection scope of the present invention includes but is not limited to embodiment of above, and protection scope of the present invention is with claims
Subject to, replacement, deformation, the improvement that those skilled in the art that any pair of this technology is made is readily apparent that each fall within of the invention
Protection scope.
Claims (8)
1. a kind of high gloss gloss oil is with water soluble acrylic resin, which is characterized in that comprise the following components in parts by weight:
8.8 ~ 9.2 parts of acrylic acid；
18 ~ 17 parts of hydroxy-ethyl acrylate；
5.2 ~ 6 parts of methacrylic acid -2- hydroxy methacrylate；
37 ~ 40 parts of butyl acrylate；
14 ~ 15 parts of methyl methacrylate；
23 ~ 25 parts of styrene；
11 ~ 13 parts of tertiary ethylene carbonate；
2.9 ~ 3.1 parts of perbenzoic acid spy butyl ester；
43 ~ 45 parts of solvent.
2. a kind of high gloss gloss oil according to claim 1 is with water soluble acrylic resin, which is characterized in that including with
The component of lower parts by weight:
9.04 parts of acrylic acid；
16.44 parts of hydroxy-ethyl acrylate；
5.6 parts of methacrylic acid -2- hydroxy methacrylate；
38.22 parts of butyl acrylate；
14.59 parts of methyl methacrylate；
24.45 parts of styrene；
12 parts of tertiary ethylene carbonate；
3.08 parts of perbenzoic acid spy butyl ester；
44.18 parts of solvent.
3. a kind of high gloss gloss oil according to claim 1 is with water soluble acrylic resin, which is characterized in that further include
The component of following parts by weight:
0.8 ~ 1.3 part of tributyl citrate；
1.1 ~ 1.4 parts of phenyl salicylate.
4. a kind of high gloss gloss oil according to any one of claims 1 to 3 is existed with water soluble acrylic resin, feature
In the solvent is butyl glycol ether or butyl.
5. a kind of high gloss gloss oil preparation method of water soluble acrylic resin, which comprises the following steps:
Solvent is placed in reaction vessel, is stirred and heated to 120 ~ 130 DEG C, the solvent is butyl glycol ether or diethylene glycol
Butyl ether；
By acrylic acid, hydroxy-ethyl acrylate, methacrylic acid -2- hydroxy methacrylate, butyl acrylate, methyl methacrylate, benzene
After ethylene, tertiary ethylene carbonate, the mixing of perbenzoic acid spy's butyl ester, it is added drop-wise in the reaction vessel in step A, time for adding
It 2 ~ 8 hours, is stirred to react, 120 ~ 130 DEG C of reaction temperature；
Stop heating after completion of dropwise addition, and continue stirring 1 ~ 2 hour, when system temperature is down to 65 ~ 85 DEG C, pours out reaction solution,
It obtains gloss oil and uses water soluble acrylic resin.
6. a kind of preparation method of the high gloss gloss oil according to claim 4 with water soluble acrylic resin, feature
It is, in step B, reaction temperature is 125 DEG C.
7. a kind of preparation method of the high gloss gloss oil according to claim 4 with water soluble acrylic resin, feature
It is, the material in preparation process has following parts by weight:
8.8 ~ 9.2 parts of acrylic acid；
18 ~ 17 parts of hydroxy-ethyl acrylate；
5.2 ~ 6 parts of methacrylic acid -2- hydroxy methacrylate；
37 ~ 40 parts of butyl acrylate；
14 ~ 15 parts of methyl methacrylate；
23 ~ 25 parts of styrene；
11 ~ 13 parts of tertiary ethylene carbonate；
2.9 ~ 3.1 parts of perbenzoic acid spy butyl ester；
43 ~ 45 parts of solvent.
8. a kind of preparation method of the high gloss gloss oil according to claim 6 with water soluble acrylic resin, feature
It is, in preparation process, also with the material of following parts by weight: 0.8 ~ 1.3 part of tributyl citrate, phenyl salicylate 1.1 ~
1.4 part；The tributyl citrate, phenyl salicylate are added drop-wise in solvent after mixing with raw material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811238031.5A CN109485783A (en) | 2018-10-23 | 2018-10-23 | A kind of high gloss gloss oil is with water soluble acrylic resin and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811238031.5A CN109485783A (en) | 2018-10-23 | 2018-10-23 | A kind of high gloss gloss oil is with water soluble acrylic resin and preparation method thereof |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110628354A (en) * | 2019-10-16 | 2019-12-31 | 深圳市弘海电子材料技术有限公司 | High-light-reflection cover film and manufacturing method thereof |
| CN112251087A (en) * | 2020-11-09 | 2021-01-22 | 太仓港亨得蕾实业有限公司 | Glazing oil and preparation method thereof |
| CN112266677A (en) * | 2020-10-30 | 2021-01-26 | 广州化工研究设计院有限公司 | Hydroxyl acrylic acid dispersoid and acrylic acid anticorrosive paint |
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| US6228931B1 (en) * | 1998-03-11 | 2001-05-08 | Vianova Resins Ag | Water-dilutable film-forming binders |
| JP2003020409A (en) * | 2001-07-06 | 2003-01-24 | Asahi Kasei Corp | Temperature-sensitive resin composition |
| CN101575476A (en) * | 2009-05-27 | 2009-11-11 | 彭文表 | Aqueous wear-resistant gloss oil and preparation method thereof |
| CN103205173A (en) * | 2013-04-15 | 2013-07-17 | 上海应用技术学院 | Aqueous wallpaper printing medium and preparation method thereof |
| CN106832093A (en) * | 2017-02-13 | 2017-06-13 | 汕头市金森源化工股份有限公司 | A kind of water-soluble thermoplastic acrylic resin and preparation method thereof |
| CN107216761A (en) * | 2017-07-17 | 2017-09-29 | 江苏三木化工股份有限公司 | The preparation method of the water soluble acrylic resin of high solid |
| CN107602759A (en) * | 2017-10-17 | 2018-01-19 | 武汉工程大学 | A kind of preparation method of fluorine-containing aqueous photo-curing acroleic acid esterification polyacrylate resin |
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2018
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|---|---|---|---|---|
| US6228931B1 (en) * | 1998-03-11 | 2001-05-08 | Vianova Resins Ag | Water-dilutable film-forming binders |
| JP2003020409A (en) * | 2001-07-06 | 2003-01-24 | Asahi Kasei Corp | Temperature-sensitive resin composition |
| CN101575476A (en) * | 2009-05-27 | 2009-11-11 | 彭文表 | Aqueous wear-resistant gloss oil and preparation method thereof |
| CN103205173A (en) * | 2013-04-15 | 2013-07-17 | 上海应用技术学院 | Aqueous wallpaper printing medium and preparation method thereof |
| CN106832093A (en) * | 2017-02-13 | 2017-06-13 | 汕头市金森源化工股份有限公司 | A kind of water-soluble thermoplastic acrylic resin and preparation method thereof |
| CN107216761A (en) * | 2017-07-17 | 2017-09-29 | 江苏三木化工股份有限公司 | The preparation method of the water soluble acrylic resin of high solid |
| CN107602759A (en) * | 2017-10-17 | 2018-01-19 | 武汉工程大学 | A kind of preparation method of fluorine-containing aqueous photo-curing acroleic acid esterification polyacrylate resin |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110628354A (en) * | 2019-10-16 | 2019-12-31 | 深圳市弘海电子材料技术有限公司 | High-light-reflection cover film and manufacturing method thereof |
| CN112266677A (en) * | 2020-10-30 | 2021-01-26 | 广州化工研究设计院有限公司 | Hydroxyl acrylic acid dispersoid and acrylic acid anticorrosive paint |
| CN112251087A (en) * | 2020-11-09 | 2021-01-22 | 太仓港亨得蕾实业有限公司 | Glazing oil and preparation method thereof |
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