CN109485269A - A kind of glass spar making method - Google Patents
A kind of glass spar making method Download PDFInfo
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- CN109485269A CN109485269A CN201811411256.6A CN201811411256A CN109485269A CN 109485269 A CN109485269 A CN 109485269A CN 201811411256 A CN201811411256 A CN 201811411256A CN 109485269 A CN109485269 A CN 109485269A
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- glass
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- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/02—Surface treatment of glass, not in the form of fibres or filaments, by coating with glass
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L83/00—Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing silicon with or without sulfur, nitrogen, oxygen or carbon only; Compositions of derivatives of such polymers
- C08L83/10—Block- or graft-copolymers containing polysiloxane sequences
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/20—Oxides; Hydroxides
- C08K3/22—Oxides; Hydroxides of metals
- C08K2003/2217—Oxides; Hydroxides of metals of magnesium
- C08K2003/222—Magnesia, i.e. magnesium oxide
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Geochemistry & Mineralogy (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- General Chemical & Material Sciences (AREA)
- Materials Engineering (AREA)
- Polymers & Plastics (AREA)
- Medicinal Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Inorganic Chemistry (AREA)
- Composite Materials (AREA)
- Surface Treatment Of Glass (AREA)
- Application Of Or Painting With Fluid Materials (AREA)
Abstract
The present invention relates to ornament materials manufacturing method more particularly to a kind of glass spar making methods.It includes high molecular material needed for high-temperature glaze ink and manufacture glass stone；The high-temperature glaze ink includes that following component is configured according to weight: glass base glaze 45-55%, coloring powder 25-30%, varnish 20-25%, high-speed stirred are made；High molecular material needed for the manufacture glass stone includes host agent and diluent, the mass ratio of the two is 5:4~2:1, wherein, host agent includes the substance of following mass fraction: organic siliconresin 30-35%, modifying epoxy resin by organosilicon 50-60%, fluorine silicon resin 5-8%, levelling agent 1-2%, surfactant 1-2%, defoaming agent 1.5-2.5%, filling colorant 22%-27%；The filling colorant includes: that colorant accounts for host agent 17%-20% and aluminium oxide 5%-7%.The present invention achievees the effect that stone material as substrate using industrial glass, and intensity height, wearability, weatherability, antifouling hydrophobicity performance and index are all better than natural stone.
Description
Technical field
The present invention relates to ornament materials manufacturing method more particularly to a kind of glass spar making methods.
Background technique
Natural stone is a kind of non-renewable raw material, and damages in exploitation to environment that existing market occurs similar
Product, the mode of a kind of paster and silk-screen is made in glass bottom surface, and this glass makes figure line lose original texture, and weather resistance
Difference is not easy to be used for a long time, and another kind is by air brushing Heat-resisting Inorganic Coating glass surface, the disadvantage is that rough surface, does not prevent
Dirt, color saturation is low, the distortion of figure line.And above two technology can not accomplish figure line on the surrounding of glass, be formed not
Stone pattern pattern can be directly made in glass surface and surrounding by complete natural stone effect, the present invention, and have it is excellent wear-resisting and
Scratch resistance, weather-proof hydrophobicity performance is especially good, and color saturation is high, and figure line is fine and smooth beautiful.The present invention overcomes well
State all defect.
Summary of the invention
In view of the above problems, it is an object of that present invention to provide a kind of glass spar making method, the present invention is with industry
Glass is substrate to achieve the effect that stone material, and intensity height, wearability, anti-pollution and index are all better than natural stone.
The first object of the present invention is to provide a kind of glass stone comprising high score needed for high-temperature glaze ink and manufacture glass stone
Sub- material；The high-temperature glaze ink includes that following component is configured according to weight: glass base glaze 45-55%, coloring powder 25-
30%, varnish 20-25%, high-speed stirred is made；High molecular material needed for the manufacture glass stone includes host agent and dilution
Agent, the mass ratio of the two are 5:4~2:1, wherein host agent includes the substance of following mass fraction: organic siliconresin 30-35%,
Modifying epoxy resin by organosilicon 50-60%, fluorine silicon resin 5-8%, levelling agent 1-2%, surfactant 1-2%, defoaming agent
1.5-2.5%, filling colorant 22%-27%.
The filling colorant includes: that colorant accounts for host agent 17%-20% and aluminium oxide 5%-7%.
Ink needed for manufacturing glass stone in the glass stone manufacturing process is the special printing ink of heat sublimation.
The diluent is dehydrated alcohol.
The modifying epoxy resin by organosilicon is by the low molecular weight polycaprolactone siloxanes and bis-phenol base propane containing alkoxy or through base
Material made of epoxy resin condensation reaction.
The levelling agent is preferably polyester modification polydimethylsiloxane；The defoaming agent is preferably brokenly bubble polymer and poly- silicon
Oxygen alkane；The surfactant is preferably hydroxyl modification dimethyl silicone polymer.
The second object of the present invention is to provide a kind of glass Preparation Method made of stones, the specific steps are that:
One: required high-temperature glaze ink material is formed by following component according to parts by weight: glass base glaze 45-55%,
Coloring powder 25-30%, varnish 20-25%, high-speed stirred are made；The required special printing ink of glass stone pattern heat sublimation passes through
On dedicated transfer paper or transfer film, high molecular material needed for glass stone is matched by following component according to weight for printing or air brushing
It sets: organic siliconresin 30-35%, modifying epoxy resin by organosilicon 50-60%, fluorine silicon resin 5-8%, levelling agent 1-2%,
Surfactant 1-2%, defoaming agent 1.5-2.5%, fill colorant 22%-27%, appropriate diluent, and the filler material includes:
Colorant accounts for host agent 17%-20% and aluminium oxide 5%-7%, is made in reaction pot high-speed stirred；
Two: glass baseplate being processed as required, silk-screen or roll printing need on glass high temperature ink, into glass reinforced plastic
Change the molding of furnace tempering；
Three: being basic color with glaze ink color, in the surrounding of glass and ink surface spraying one using burned glaze ink as bottom
The layer laggard oven of high-molecular coating is 10 minutes roasting in 110-200 degree temperature, places 24 hours to dry；
Four: choosing figure line dedicated heat sublimation ink air brushing or the printing technology of needs, be imprinted on and copy printing paper or copy print
On film；
Five: after the printed ink surface copied printing paper or copy die is attached to the macromolecule raw material face of glass, entering back into dedicated
The distillation of vacuum hot material copy to vacuumize 90-120 seconds with 180-200 degree temperature in printing apparatus and come out of the stove；
Six: paper or film being separated with glass after coming out of the stove, then are fully completed after cleaning treatment.
Another embodiment of the present invention, glass base glaze described in above-mentioned specific method 50%, coloring powder 28% are adjusted the most
Black oil 22%；The organic siliconresin 30%, modifying epoxy resin by organosilicon 60%, fluorine silicon resin 5.5%, levelling agent 2%, table
Face activating agent 1%, defoaming agent 1.5% fill colorant 22%, appropriate diluent.
Another embodiment of the present invention, glass base glaze described in above-mentioned specific method 55%, coloring powder 25% are adjusted the most
Black oil 20%；Organic siliconresin 35%, modifying epoxy resin by organosilicon 55%, fluorine silicon resin 8%, levelling agent 1, surfactant
1%, defoaming agent 1% fills colorant 27%, appropriate diluent.
Beneficial effects of the present invention:
Contain modifying epoxy resin by organosilicon, organic siliconresin and fluorine in polymer material main composition of the present invention
These three substances of silicone resin, they can perfectly mix crosslinking, and the high molecular material of synthesis has outstanding physics function,
In, modifying epoxy resin by organosilicon and glass have excellent crosslinking function, can strong bond in glass surface, and epoxy resin is logical
Cross that condensation reaction is modified, the performances such as flexibility, hardness, weatherability and double thin functions of resin itself are highly improved；
It is the surface tension of organic siliconresin low (water repelling anti-fouling), viscosity-temperature coefficient small (high-low temperature resistant), compressibility high (film surface hardness is high), resistance to
Oxidation (performance is stablized)；Fluorine silicon resin has excellent resistance to bond, antiultraviolet, excellent chemical resistance.Nanoscale
Aluminium has unique hardness and superior abrasion resistance, and glass stone, which is made, using above-mentioned material synthesis high molecular material has excellent object
Characteristic is managed, is that simple glass epoxy coating or polyurethane (PU) coating can not compare.The present invention is using industrial glass as substrate
Achieving the effect that stone material, intensity height, wearability, anti-pollution and index are all better than natural stone, compared with other production technologies,
Its manufacturing process high degree of automation, production efficiency and high yield rate create an aesthetic feeling and are suitable for industrial application, and yield is high, cost
It reduces, yield rate is able to satisfy the diversified demand in market 90% or more.
Specific embodiment
The present invention is described further below with reference to embodiment.
A kind of glass stone comprising high molecular material needed for high-temperature glaze ink and manufacture glass stone；The high-temperature glaze ink packet
Include following component to configure according to weight: ink needed for manufacturing glass stone in the glass stone manufacturing process is that heat sublimation is special
Printing ink.Glass base glaze 45-55%, coloring powder 25-30%, varnish 20-25%, high-speed stirred are made；The manufacture glass
High molecular material needed for glass stone is configured by following component according to weight: organic siliconresin 30-35%, organic silicon modified epoxy
Oxygen resin 50-60%, fluorine silicon resin 5-8%, levelling agent 1-2%, surfactant 1-2%, defoaming agent 1.5-2.5%, filling
Colorant 22%-27%, appropriate diluent.
The filling colorant includes: that colorant accounts for host agent 17%-20% and aluminium oxide 5%-7%.
Ink needed for manufacturing glass stone in the glass stone manufacturing process is the special printing ink of heat sublimation.
The diluent is dehydrated alcohol.
The modifying epoxy resin by organosilicon is by the low molecular weight polycaprolactone siloxanes and bis-phenol base propane containing alkoxy or through base
Material made of epoxy resin condensation reaction.
The levelling agent is preferably polyester modification polydimethylsiloxane；The defoaming agent is preferably brokenly bubble polymer and poly- silicon
Oxygen alkane, the surfactant are preferably hydroxyl modification dimethyl silicone polymer.
Embodiment 1:
A kind of glass Preparation Method made of stones, the specific steps are that:
One: required high-temperature glaze ink material being formed by following component according to parts by weight: glass base glaze 50%, coloring
Powder 28%, varnish 22%, high-speed stirred is made；The required special printing ink of glass stone pattern heat sublimation passes through printing or air brushing
On dedicated transfer paper or transfer film, high molecular material needed for glass stone is configured by following component according to weight: being had
Machine silicone resin 30%, modifying epoxy resin by organosilicon 60%, fluorine silicon resin 5.5%, levelling agent 2%, disappear at surfactant 1%
Infusion 1.5% fills colorant 22%, appropriate diluent, and the filling colorant includes: that colorant accounts for host agent 17% and aluminium oxide 5%,
In reaction pot high-speed stirring mixing；
Two: glass baseplate being processed as required, silk-screen or roll printing need on glass high temperature ink, into glass reinforced plastic
Change the molding of furnace tempering；
Three: being basic color with glaze ink color, in the surrounding of glass and ink surface spraying one using burned glaze ink as bottom
The layer laggard oven of high-molecular coating is 10 minutes roasting in 200 degree of temperature, places 24 hours to dry；
Four: choosing figure line dedicated heat sublimation ink air brushing or the printing technology of needs, be imprinted on and copy printing paper or copy print
On film；
Five: after the printed ink surface copied printing paper or copy die is attached to the macromolecule raw material face of glass, entering back into dedicated
The distillation of vacuum hot material copy to vacuumize 120 seconds with 180 degree temperature in printing apparatus and come out of the stove；
Six: paper or film being separated with glass after coming out of the stove, then are fully completed after cleaning treatment.
Embodiment 2:
One: required high-temperature glaze ink material being formed by following component according to parts by weight: glass base glaze 55%, coloring
Powder 25%, varnish 20%, high-speed stirred is made；The required special printing ink of glass stone pattern heat sublimation passes through printing or air brushing
On dedicated transfer paper or transfer film, high molecular material needed for glass stone is configured by following component according to weight: being had
Machine silicone resin 35%, modifying epoxy resin by organosilicon 55%, fluorine silicon resin 8%, levelling agent 1, surfactant 1%, defoaming agent
1%, colorant 27%, appropriate diluent are filled, the filler material includes: that colorant accounts for host agent 20% and aluminium oxide 7%, in reaction pot
High-speed stirred is made；
Two: glass baseplate being processed as required, silk-screen or roll printing need on glass high temperature ink, into glass reinforced plastic
Change the molding of furnace tempering；
Three: being basic color with glaze ink color, in the surrounding of glass and ink surface spraying one using burned glaze ink as bottom
The layer laggard oven of high-molecular coating is 10 minutes roasting in 110 degree of temperature, places 24 hours to dry；
Four: choosing figure line dedicated heat sublimation ink air brushing or the printing technology of needs, be imprinted on and copy printing paper or copy print
On film；
Five: after the printed ink surface copied printing paper or copy die is attached to the macromolecule raw material face of glass, entering back into dedicated
The distillation of vacuum hot material copy to vacuumize 110 seconds with 200 degree of temperature in printing apparatus and come out of the stove；
Six: paper or film being separated with glass after coming out of the stove, then are fully completed after cleaning treatment.
Contain modifying epoxy resin by organosilicon, organic siliconresin and fluorine in polymer material main composition of the present invention
These three substances of silicone resin, they can perfectly mix crosslinking, and the high molecular material of synthesis has outstanding physics function,
In, modifying epoxy resin by organosilicon and glass have excellent crosslinking function, can strong bond in glass surface, and epoxy resin is logical
Cross that condensation reaction is modified, the performances such as flexibility, hardness, weatherability and double thin functions of resin itself are highly improved；
It is the surface tension of organic siliconresin low (water repelling anti-fouling), viscosity-temperature coefficient small (high-low temperature resistant), compressibility high (film surface hardness is high), resistance to
Oxidation (performance is stablized)；Fluorine silicon resin has excellent resistance to bond, antiultraviolet, excellent chemical resistance.Nanoscale
Aluminium has unique hardness and superior abrasion resistance, and glass stone, which is made, using above-mentioned material synthesis high molecular material has excellent object
Characteristic is managed, is that simple glass epoxy coating or polyurethane (PU) coating can not compare.
Comparative example 1
One: glass baseplate being processed as required, silk-screen or roll printing need on glass high temperature ink, into glass reinforced plastic
Change the molding of furnace tempering；
Two: being basic color, surrounding and the common ring of ink surface in glass with glaze ink color using burned glaze ink as bottom
Oxygen glass coating (host agent epoxy resin) laggard oven is 10 minutes roasting in 110-200 degree temperature, places 24 hours to dry；
Three: choosing figure line dedicated heat sublimation ink air brushing or the printing technology of needs, be imprinted on and copy printing paper or copy print
On film；
Four: after the printed ink surface copied printing paper or copy die is attached to glass coating face face, entering back into dedicated vacuum
Hot material distillation is copied to be vacuumized 90-120 seconds in printing apparatus with 180-200 degree temperature and be come out of the stove；
Five: paper or film being separated with glass after coming out of the stove, then are fully completed after cleaning treatment.
Comparative example 2
One: glass baseplate being processed as required, silk-screen or roll printing need on glass high temperature ink, into glass reinforced plastic
Change the molding of furnace tempering；
Two: using burned glaze ink as bottom, being basic color with glaze ink color, commonly gather in the surrounding of glass with ink surface
Amine rouge (PU) glass coating (host agent alkyd resin 90%, epoxy resin 10%) laggard oven is 10 minutes roasting in 110 degree of temperature, puts
24 hours are set to dry；
Three: choosing figure line dedicated heat sublimation ink air brushing or the printing technology of needs, be imprinted on and copy printing paper or copy print
On film；
Four: after the printed ink surface copied printing paper or copy die is attached to glass coating face face, entering back into dedicated vacuum
Hot material distillation is copied to be vacuumized 90-120 seconds in printing apparatus with 180-200 degree temperature and be come out of the stove；
Five: paper or film being separated with glass after coming out of the stove, then are fully completed after cleaning treatment.
Marble grain glass obtained by Examples 1 to 2 and comparative example 1~2 is done into following performance test:
Hardness test
Hardness test is carried out using 3m pencil.
Burn-in test
Sample 250*250mm is placed in ageing test box, 45 ° of temperature, humidity 80%RH, ultraviolet light is set as 360-
380wm irradiation, observes aging conditions.
Abrasion-resistant test
The surface sample 250*250mm smearing alcohol is placed on friction testing machine (friction head is 250 mesh steel wire lumps), if
Identical pressure is set, abrasion-resistant test is carried out；
Test result is shown in Table 1:
As seen from Table 1, compared with common expoxy glass coating and polyurethane (PU) glass coating, using in the present invention
High molecular material be made glass stone have excellent wear-resisting and anti-scratch ability, water repelling anti-fouling and weather resistance are good, and can be long-term
It uses.
Although the present invention has been described by way of example and in terms of the preferred embodiments, it is not intended to limit the invention, any to be familiar with this skill
The people of art can do various change and modification, therefore protection model of the invention without departing from the spirit and scope of the present invention
Enclosing subject to the definition of the claims.
Claims (9)
1. a kind of glass stone, it is characterised in that: including high molecular material needed for high-temperature glaze ink and manufacture glass stone；The high temperature
Glaze ink includes that following component is configured according to weight: glass base glaze 45-55%, coloring powder 25-30%, varnish 20-
25%, high-speed stirred is made；High molecular material needed for the manufacture glass stone includes host agent and diluent, the mass ratio of the two
For 5:4~2:1, wherein host agent includes the substance of following mass fraction: organic siliconresin 30-35%, silicon-modified epoxy tree
Rouge 50-60%, fluorine silicon resin 5-8%, levelling agent 1-2%, surfactant 1-2%, defoaming agent 1.5-2.5%, filling colorant
22%-27%.
2. a kind of glass stone according to claim 1, it is characterised in that: the filling colorant includes: that colorant accounts for host agent
17%-20% and aluminium oxide 5%-7%.
3. a kind of glass stone according to claim 1, it is characterised in that: ink needed for the manufacture glass stone is hot liter
The special printing ink of China.
4. a kind of glass stone according to claim 1, it is characterised in that: the diluent is dehydrated alcohol.
5. a kind of glass stone according to claim 1, it is characterised in that: the modifying epoxy resin by organosilicon is by containing alkane
Oxygroup or the low molecular weight polycaprolactone siloxanes through base and material made of the epoxy resin condensation reaction of bis-phenol base propane.
It makes 6. glass according to claim 1 is made of stones with high molecular material, it is characterised in that: the levelling agent changes for polyester
Property polydimethylsiloxane；The defoaming agent is brokenly bubble polymer and polysiloxanes, and the surfactant is hydroxyl modification poly- two
Methylsiloxane.
7. a kind of glass stone according to claim 1, it is characterised in that: it is described specific the preparation method comprises the following steps:
One: required high-temperature glaze ink material being formed by following component according to parts by weight: glass base glaze 45-55%, coloring
Powder 25-30%, varnish 20-25%, high-speed stirred are made；The required special printing ink of glass stone pattern heat sublimation passes through printing
Or air brushing is on dedicated transfer paper or transfer film, high molecular material needed for glass stone configured by following component according to weight and
At: organic siliconresin 30-35%, modifying epoxy resin by organosilicon 50-60%, fluorine silicon resin 5-8%, levelling agent 1-2%, surface
Activating agent 1-2%, defoaming agent 1.5-2.5% fill colorant 22%-27%, appropriate diluent, and the filling colorant includes: color
Material accounts for host agent 17%-20% and aluminium oxide 5%-7%, is made in reaction pot high-speed stirred；
Two: glass baseplate being processed as required, silk-screen or roll printing need on glass high temperature ink, into glass tempering furnace
Tempering molding；
Three: being basic color with glaze ink color using burned glaze ink as bottom, spray one layer of height in the surrounding of glass and ink surface
The laggard oven of molecule coating is 10 minutes roasting in 110-200 degree temperature, places 24 hours to dry；
Four: choosing figure line dedicated heat sublimation ink air brushing or the printing technology of needs, be imprinted on and copy printing paper or copy on die；
Five: after the printed ink surface copied printing paper or copy die is attached to the macromolecule raw material face of glass, entering back into dedicated true
Empty hot material distillation, which is copied to vacuumize 90-120 seconds in printing apparatus with 180-200 degree temperature, comes out of the stove；
Six: paper or film being separated with glass after coming out of the stove, then are fully completed after cleaning treatment.
8. a kind of glass stone according to claim 7, it is characterised in that: the glass base glaze 50%, coloring powder 28%,
Varnish 22%；The organic siliconresin 30%, modifying epoxy resin by organosilicon 60%, fluorine silicon resin 5.5%, levelling agent 2%,
Surfactant 1%, defoaming agent 1.5% fill colorant 22%, appropriate diluent.
9. a kind of glass stone according to claim 7, it is characterised in that: the glass base glaze 55%, coloring powder 25%,
Varnish 20%；Organic siliconresin 35%, modifying epoxy resin by organosilicon 55%, fluorine silicon resin 8%, levelling agent 1, surface-active
Colorant 27%, appropriate diluent are filled in agent 1%, defoaming agent 1%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811411256.6A CN109485269A (en) | 2018-11-24 | 2018-11-24 | A kind of glass spar making method |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811411256.6A CN109485269A (en) | 2018-11-24 | 2018-11-24 | A kind of glass spar making method |
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| Publication Number | Publication Date |
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| CN109485269A true CN109485269A (en) | 2019-03-19 |
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ID=65697781
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| CN201811411256.6A Pending CN109485269A (en) | 2018-11-24 | 2018-11-24 | A kind of glass spar making method |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110204203A (en) * | 2019-07-01 | 2019-09-06 | 于洪伟 | Marble glass manufacturing process |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108164158A (en) * | 2018-01-24 | 2018-06-15 | 东莞市尚艺玻璃制品有限公司 | Glass stone manufacturing process |
| CN108753165A (en) * | 2018-06-22 | 2018-11-06 | 东莞市尚艺玻璃制品有限公司 | The preparation method of glass manufacture cover gloss oil and marble grain glass |
-
2018
- 2018-11-24 CN CN201811411256.6A patent/CN109485269A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108164158A (en) * | 2018-01-24 | 2018-06-15 | 东莞市尚艺玻璃制品有限公司 | Glass stone manufacturing process |
| CN108753165A (en) * | 2018-06-22 | 2018-11-06 | 东莞市尚艺玻璃制品有限公司 | The preparation method of glass manufacture cover gloss oil and marble grain glass |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110204203A (en) * | 2019-07-01 | 2019-09-06 | 于洪伟 | Marble glass manufacturing process |
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