CN108164158A - Glass stone manufacturing process - Google Patents
Glass stone manufacturing process Download PDFInfo
- Publication number
- CN108164158A CN108164158A CN201810067288.2A CN201810067288A CN108164158A CN 108164158 A CN108164158 A CN 108164158A CN 201810067288 A CN201810067288 A CN 201810067288A CN 108164158 A CN108164158 A CN 108164158A
- Authority
- CN
- China
- Prior art keywords
- glass
- manufacturing process
- ink
- stone
- acid resin
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000011521 glass Substances 0.000 title claims abstract description 53
- 239000004575 stone Substances 0.000 title claims abstract description 28
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 25
- 239000000463 material Substances 0.000 claims abstract description 36
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 13
- 239000003085 diluting agent Substances 0.000 claims abstract description 12
- 239000000945 filler Substances 0.000 claims abstract description 12
- 239000002253 acid Substances 0.000 claims abstract description 9
- 239000011347 resin Substances 0.000 claims abstract description 9
- 229920005989 resin Polymers 0.000 claims abstract description 9
- 239000004952 Polyamide Substances 0.000 claims abstract description 8
- 239000003086 colorant Substances 0.000 claims abstract description 8
- 229920002647 polyamide Polymers 0.000 claims abstract description 8
- 239000004925 Acrylic resin Substances 0.000 claims abstract description 7
- 239000004094 surface-active agent Substances 0.000 claims abstract description 7
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims abstract description 6
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical group CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000006243 chemical reaction Methods 0.000 claims abstract description 4
- 239000005046 Chlorosilane Substances 0.000 claims abstract description 3
- KOPOQZFJUQMUML-UHFFFAOYSA-N chlorosilane Chemical compound Cl[SiH3] KOPOQZFJUQMUML-UHFFFAOYSA-N 0.000 claims abstract description 3
- 238000005496 tempering Methods 0.000 claims description 8
- 238000005516 engineering process Methods 0.000 claims description 7
- 230000001680 brushing effect Effects 0.000 claims description 5
- 239000011248 coating agent Substances 0.000 claims description 5
- 238000000576 coating method Methods 0.000 claims description 5
- 229920002521 macromolecule Polymers 0.000 claims description 5
- 229920000178 Acrylic resin Polymers 0.000 claims description 4
- 238000004140 cleaning Methods 0.000 claims description 4
- 238000000859 sublimation Methods 0.000 claims description 4
- 230000008022 sublimation Effects 0.000 claims description 4
- 150000001336 alkenes Chemical class 0.000 claims 1
- 238000000034 method Methods 0.000 claims 1
- JRZJOMJEPLMPRA-UHFFFAOYSA-N olefin Natural products CCCCCCCC=C JRZJOMJEPLMPRA-UHFFFAOYSA-N 0.000 claims 1
- 230000003373 anti-fouling effect Effects 0.000 abstract description 4
- 230000000694 effects Effects 0.000 abstract description 4
- 230000008859 change Effects 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- BLRPTPMANUNPDV-UHFFFAOYSA-N Silane Chemical compound [SiH4] BLRPTPMANUNPDV-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- 229910052782 aluminium Inorganic materials 0.000 description 1
- 239000004411 aluminium Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 229910000077 silane Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/34—Surface treatment of glass, not in the form of fibres or filaments, by coating with at least two coatings having different compositions
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/007—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C17/00—Surface treatment of glass, not in the form of fibres or filaments, by coating
- C03C17/006—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character
- C03C17/008—Surface treatment of glass, not in the form of fibres or filaments, by coating with materials of composite character comprising a mixture of materials covered by two or more of the groups C03C17/02, C03C17/06, C03C17/22 and C03C17/28
- C03C17/009—Mixtures of organic and inorganic materials, e.g. ormosils and ormocers
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D143/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
- C09D143/04—Homopolymers or copolymers of monomers containing silicon
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C2217/00—Coatings on glass
- C03C2217/40—Coatings comprising at least one inhomogeneous layer
- C03C2217/43—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase
- C03C2217/44—Coatings comprising at least one inhomogeneous layer consisting of a dispersed phase in a continuous phase characterized by the composition of the continuous phase
- C03C2217/445—Organic continuous phases
Abstract
The present invention discloses glass stone manufacturing process, and the high molecular material manufactured needed for glass stone in the glass stone manufacturing process is formed by following component according to parts by weight：Polyamide 40% 45%, organosilicon modified crylic acid resin 56% 60%, levelling agent 2% 5%, surfactant 2% 4%, filler material 27% 31%, appropriate diluent, the filler material include：Colorant accounts for host agent 15% 17% and aluminium chloride 12% 14%, and the diluent is absolute ethyl alcohol, and the organosilicon modified crylic acid resin is that polyacrylic resin adds front three chloro silane in material made of oligomer reaction.The present invention achievees the effect that stone material using industrial glass as base material, and intensity height, wearability, antifouling property and index are all better than natural stone.
Description
Technical field
The present invention relates to ornament materials manufacturing method more particularly to glass stone manufacturing process.
Background technology
Natural stone is a kind of non-renewable raw material, and environment is damaged in exploitation, and the present invention is directly made in glass
Glass surface and surrounding, and have excellent wear-resisting and scratch resistance, weather resistance is especially good, and color saturation is high, and figure line is fine and smooth
It is beautiful.
The mode of the similar product of existing market appearance, a kind of paster and silk-screen is made in glass bottom surface, and this glass makes figure
Line loses original texture, and weather resistance is poor, is not easy to use for a long time, and another kind is by air brushing Heat-resisting Inorganic Coating glass table
Face, the drawback is that rough surface, not antifouling, color saturation is low, the distortion of figure line.And above two technology can not do figure line
Onto the surrounding of glass, complete natural stone effect is not become, the present invention overcomes above-mentioned all defect well.
Invention content
In view of the above problems, present invention aims at glass stone manufacturing process is provided, the present invention is with industrial glass
Achieve the effect that stone material for base material, intensity height, wearability, antifouling property and index are all better than natural stone.
The present invention is in order to achieve the above object, using following scheme：
Glass stone manufacturing process, the high molecular material in the glass stone manufacturing process needed for manufacture glass stone are pressed by following component
It is formed according to parts by weight：Polyamide 40%-45%, organosilicon modified crylic acid resin 56%-60%, levelling agent 2%-5%, table
Face activating agent 2%-4%, filler material 27%-31%, appropriate diluent, the filler material include：Colorant accounts for host agent 15%-17% and chlorination
Aluminium 12%-14%, the diluent are absolute ethyl alcohol, and the organosilicon modified crylic acid resin is that polyacrylic resin adds front three chlorine
Base silane is in material made of oligomer reaction.
Further, the manufacturing method of the glass stone manufacturing process：
One：Required high molecular material is formed by following component according to parts by weight：It is polyamide 40%-45%, organic
Fluorine-silicon modified acrylic resin 56%-60%, levelling agent 2%-5%, surfactant 2%-4%, filler material 27%-31%, appropriate diluent,
Using glass as base material, it is processed into the specification and shape of needs；
Two：It is processed, silk-screen or roll printing need on glass high temperature ink is molded into glass tempering furnace tempering；
Three：Using burned ink as bottom, using ink colors as basic color, a floor height is sprayed in the surrounding of glass and ink surface
The laggard oven of molecule coating is baked 10 minutes in 110-200 degree temperature, is placed 24 hours and is waited to do；
Four：Figure line dedicated heat sublimation ink air brushing or the printing technology of needs are chosen, is imprinted on and is copied printing paper or copy on die；
Five：The ink surface of printed transfer paper or transfer film is attached to the macromolecule Tu level of glass, enters back into dedicated vacuum
Thermal transfer equipment（Or use vacuum bag）It vacuumizes and is heated 2-5 minutes with 180-200 degree temperature again；
Six：Paper or film with glass are detached after coming out of the stove, then are fully completed after cleaning treatment.
Beneficial effects of the present invention：
The present invention achievees the effect that stone material using industrial glass as base material, and intensity height, wearability, antifouling property and index are all strong
In natural stone, compared with other production technologies, manufacturing process high degree of automation, production efficiency and high yield rate, rich in beautiful
Feel and be suitable for commercial Application, yield is high, and cost reduction, yield rate can meet the diversified need in market more than 90%
It asks.
Specific embodiment
The present invention is described further with reference to embodiment.
Glass stone manufacturing process, the high molecular material in the glass stone manufacturing process needed for manufacture glass stone is by following group
Divide and formed according to parts by weight：Polyamide 40%-45%, organosilicon modified crylic acid resin 56%-60%, levelling agent 2%-
5%th, surfactant 2%-4%, filler material 27%-31%, appropriate diluent, the filler material include：Colorant accounts for host agent 15%-17%
And aluminium chloride 12%-14%, the diluent are absolute ethyl alcohol, the organosilicon modified crylic acid resin is that polyacrylic resin adds
Front three chloro silane is in material made of oligomer reaction.
Embodiment 1:
The manufacturing method of the glass stone manufacturing process：
One：Required high molecular material is formed by following component according to parts by weight：Polyamide 43%, organosilicon change
Property acrylic resin 57%, levelling agent 4%, surfactant 3%, filler material 29%, appropriate diluent, using glass as base material, processing
Into the specification and shape of needs；
Two：It is processed, silk-screen or roll printing need on glass high temperature ink is molded into glass tempering furnace tempering；
Three：Using burned ink as bottom, using ink colors as basic color, a floor height is sprayed in the surrounding of glass and ink surface
The laggard oven of molecule coating is baked 10 minutes in 110-200 degree temperature, is placed 24 hours and is waited to do；
Four：Figure line dedicated heat sublimation ink air brushing or the printing technology of needs are chosen, is imprinted on and is copied printing paper or copy on die；
Five：The ink surface of printed transfer paper or transfer film is attached to the macromolecule Tu level of glass, enters back into dedicated vacuum
Thermal transfer equipment（Or use vacuum bag）It vacuumizes and is heated 2-5 minutes with 180-200 degree temperature again；
Six：Paper or film with glass are detached after coming out of the stove, then are fully completed after cleaning treatment.
Embodiment 2：
One：Required high molecular material is formed by following component according to parts by weight：Polyamide 42%, organosilicon change
Property acrylic resin 55%, levelling agent 3%, surfactant 4%, filler material 30%, appropriate diluent, using glass as base material, processing
Into the specification and shape of needs；
Two：It is processed, silk-screen or roll printing need on glass high temperature ink is molded into glass tempering furnace tempering；
Three：Using burned ink as bottom, using ink colors as basic color, a floor height is sprayed in the surrounding of glass and ink surface
The laggard oven of molecule coating is baked 10 minutes in 110-200 degree temperature, is placed 24 hours and is waited to do；
Four：Figure line dedicated heat sublimation ink air brushing or the printing technology of needs are chosen, is imprinted on and is copied printing paper or copy on die；
Five：The ink surface of printed transfer paper or transfer film is attached to the macromolecule Tu level of glass, enters back into dedicated vacuum
Thermal transfer equipment（Or use vacuum bag）It vacuumizes and is heated 2-5 minutes with 180-200 degree temperature again；
Six：Paper or film with glass are detached after coming out of the stove, then are fully completed after cleaning treatment.
The foregoing is merely the preferred embodiments of patent of the present invention, are not intended to limit the invention patent, all at this
All any modification, equivalent and improvement made within the spirit and principle of patent of invention etc., should be included in patent of the present invention
Protection domain within.
Claims (2)
1. glass stone manufacturing process, which is characterized in that the macromolecule material needed for glass stone is manufactured in the glass stone manufacturing process
Material is formed by following component according to parts by weight：Polyamide 40%-45%, organosilicon modified crylic acid resin 56%-60%,
Levelling agent 2%-5%, surfactant 2%-4%, filler material 27%-31%, appropriate diluent, the filler material include：Colorant accounts for master
Agent 15%-17% and aluminium chloride 12%-14%, the diluent are absolute ethyl alcohol, and the organosilicon modified crylic acid resin is poly- third
Olefin(e) acid resin adds front three chloro silane in material made of oligomer reaction.
2. the glass stone manufacturing process according to claim 1, which is characterized in that the manufacture of the glass stone manufacturing process
Method：
One：Required high molecular material is formed by following component according to parts by weight：It is polyamide 40%-45%, organic
Fluorine-silicon modified acrylic resin 56%-60%, levelling agent 2%-5%, surfactant 2%-4%, filler material 27%-31%, appropriate diluent,
Using glass as base material, it is processed into the specification and shape of needs；
Two：It is processed, silk-screen or roll printing need on glass high temperature ink is molded into glass tempering furnace tempering；
Three：Using burned ink as bottom, using ink colors as basic color, a floor height is sprayed in the surrounding of glass and ink surface
The laggard oven of molecule coating is baked 10 minutes in 110-200 degree temperature, is placed 24 hours and is waited to do；
Four：Figure line dedicated heat sublimation ink air brushing or the printing technology of needs are chosen, is imprinted on and is copied printing paper or copy on die；
Five：The ink surface of printed transfer paper or transfer film is attached to the macromolecule Tu level of glass, enters back into dedicated vacuum
Thermal transfer equipment（Or use vacuum bag）It vacuumizes and is heated 2-5 minutes with 180-200 degree temperature again；
Six：Paper or film with glass are detached after coming out of the stove, then are fully completed after cleaning treatment.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810067288.2A CN108164158A (en) | 2018-01-24 | 2018-01-24 | Glass stone manufacturing process |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810067288.2A CN108164158A (en) | 2018-01-24 | 2018-01-24 | Glass stone manufacturing process |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108164158A true CN108164158A (en) | 2018-06-15 |
Family
ID=62515875
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810067288.2A Pending CN108164158A (en) | 2018-01-24 | 2018-01-24 | Glass stone manufacturing process |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108164158A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109485269A (en) * | 2018-11-24 | 2019-03-19 | 东莞市尚艺玻璃制品有限公司 | A kind of glass spar making method |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2178720Y (en) * | 1994-03-01 | 1994-10-05 | 徐国庆 | Marble-type glass |
| CN101905620A (en) * | 2010-06-30 | 2010-12-08 | 浙江省平湖市澳妮斯洁具有限公司 | Glass printing method |
| CN102391778A (en) * | 2011-09-05 | 2012-03-28 | 北京首创纳米科技有限公司 | Colored transparent heat insulation glass coating and preparation method thereof |
| CN102719136A (en) * | 2012-05-11 | 2012-10-10 | 佛山市高明绿色德化工有限公司 | Colorful crystal glass printing ink |
| CN102825939A (en) * | 2012-08-16 | 2012-12-19 | 郑州玉海玻璃技术有限公司 | Manufacturing method of ultra-large plate glass pattern and processing equipment thereof |
| CN104804547A (en) * | 2015-04-22 | 2015-07-29 | 黎司华 | High-hardness chemicals-resistant screen printing ink |
| CN105368150A (en) * | 2015-12-14 | 2016-03-02 | 佛山市高明绿色德化工有限公司 | Water-based weather-resistant glass printing ink |
-
2018
- 2018-01-24 CN CN201810067288.2A patent/CN108164158A/en active Pending
Patent Citations (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN2178720Y (en) * | 1994-03-01 | 1994-10-05 | 徐国庆 | Marble-type glass |
| CN101905620A (en) * | 2010-06-30 | 2010-12-08 | 浙江省平湖市澳妮斯洁具有限公司 | Glass printing method |
| CN102391778A (en) * | 2011-09-05 | 2012-03-28 | 北京首创纳米科技有限公司 | Colored transparent heat insulation glass coating and preparation method thereof |
| CN102719136A (en) * | 2012-05-11 | 2012-10-10 | 佛山市高明绿色德化工有限公司 | Colorful crystal glass printing ink |
| CN102719136B (en) * | 2012-05-11 | 2016-08-17 | 佛山市高明绿色德化工有限公司 | A kind of color crystal glass ink |
| CN102825939A (en) * | 2012-08-16 | 2012-12-19 | 郑州玉海玻璃技术有限公司 | Manufacturing method of ultra-large plate glass pattern and processing equipment thereof |
| CN104804547A (en) * | 2015-04-22 | 2015-07-29 | 黎司华 | High-hardness chemicals-resistant screen printing ink |
| CN105368150A (en) * | 2015-12-14 | 2016-03-02 | 佛山市高明绿色德化工有限公司 | Water-based weather-resistant glass printing ink |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109485269A (en) * | 2018-11-24 | 2019-03-19 | 东莞市尚艺玻璃制品有限公司 | A kind of glass spar making method |
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Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180615 |
|
| RJ01 | Rejection of invention patent application after publication |