CN109479883A - Insecticidal and acaricidal composition of the one kind containing fungicide or bactericidal (virus) agent - Google Patents

Insecticidal and acaricidal composition of the one kind containing fungicide or bactericidal (virus) agent Download PDF

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CN109479883A
CN109479883A CN201811390497.7A CN201811390497A CN109479883A CN 109479883 A CN109479883 A CN 109479883A CN 201811390497 A CN201811390497 A CN 201811390497A CN 109479883 A CN109479883 A CN 109479883A
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component
agent
composition
bactericidal
virus
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CN109479883B (en
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冯聪
宋玉泉
范晓溪
张俊龙
李斌
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Shenyang Sinochem Agrochemicals R&D Co Ltd
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Shenyang Sinochem Agrochemicals R&D Co Ltd
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    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A50/00TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE in human health protection, e.g. against extreme weather
    • Y02A50/30Against vector-borne diseases, e.g. mosquito-borne, fly-borne, tick-borne or waterborne diseases whose impact is exacerbated by climate change

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Abstract

The invention belongs to field of pesticides, are related to a kind of insecticidal and acaricidal composition containing fungicide or bactericidal (virus) agent.Composition is two kinds of component A, component B active components, and the weight fraction ratio between two component of component A and component B is 1:99-99:1;Component A is selected from following structural formula compound represented A, and component B is selected from triazole bactericidal agent;The component A structure is as follows, and composition of the invention has many advantages, such as synergy obvious, save the cost, with strong points, can be used for preventing and treating a variety of pest and disease damages.

Description

Insecticidal and acaricidal composition of the one kind containing fungicide or bactericidal (virus) agent
The application is the divisional application of Chinese invention patent application, and original application date is on December 25th, 2014, application number: 201410822186.9, invention and created name: insecticidal and acaricidal composition of the one kind containing fungicide or bactericidal (virus) agent, it is public The number of opening: CN 105766924A;Since original application is there are the unicity problem that auditor points out, applicant proposes divisional application.
Technical field
The invention belongs to field of pesticides, are related to one kind and contain the desinsection of fungicide or bactericidal (virus) agent, mite killing combination Object.
Background technique
Chinese invention patent CN101875633A disclose a kind of pyrazolyl acrylonitrile compound and its control insect pest and The purposes of mite evil, wherein compound 5 (hereinafter referred to as compound A) can be used for preventing and treating various pests, harmful mite, especially have to harmful mite Control efficiency outstanding.
National facilities horticulture area accounts for the 1/4 of entire vegetable cultivation area, 410,000,000,000 yuan of the output value, accounts for vegetable up to 57,900,000 mu The 51% of the dish gross output value.And pest and disease damage often occurs simultaneously, especially causes great harm to the vegetables of Solanaceae, causes huge Economic loss, be badly in need of it is a kind of efficiently, safe Pesticidal products.
Although generally disclose in the prior art compound A or its homologue and other Mixture Use of Insecticides can produce it is additional The advantages of and effect, but the technical solution of the binary insecticidal bactericide composition containing compound A has no specific disclosure.
Summary of the invention
Present invention aims at develop a kind of insecticidal and acaricidal composition containing fungicide or bactericidal (virus) agent.
To achieve the above object, the technical solution adopted by the present invention are as follows:
Insecticidal and acaricidal composition composition of the one kind containing fungicide or bactericidal (virus) agent, composition are component A, group It is divided to two kinds of active components of B, the weight fraction ratio between two component of component A and component B is 1:100-100:1;Component A is selected from following Structural formula compound represented A, component B are selected from acid amide fungicides, dicarboximide class fungicide, methoxy acrylic Fungicide, triazole bactericidal agent, imidazoles fungicide, uh azoles fungicide, thiazoles fungicide, morpholine bactericide, pyrroles Class fungicide, miazines fungicide, quinoline (azoles) quinoline (ketone) class fungicide, carbamate fungicide, has pyridines fungicide The Phosphorus fungicide of machine, antibiotics fungicide, other class fungicide or bactericidal (virus) agent;
The active component A structure is as follows,
The acid amide fungicides are selected from flumorph (flumorph), dimethomorph (dimethomorph), efficient first frost Spirit (metalaxyl-M), benalaxyl-M (benalaxyl-M), double chlorine zarilamid (diclocymet), flusulfamide (flusulfamide), first flusulfamide (TF-991), thiophene fluorine bacterium amine (thifluzamide), tiadinil (tiadinil), fluorine Amide (flutolanil), tecloftalam (tecloftalam), ring propionyl bacterium amine (carpropamid), cyflufenamid (cyflufenamid), fenhexamid (fenhexamid), zarilamid (fenoxanil), Silthiopham (silthiopham), Furametpyr (furametpyr), pyrrole metsulfovax (penthiopyrad), mandipropamid (mandipropamid), benzoyl bacterium Amine (zoxamide), fenfuram (fenfuram) or carboxin (carboxin);
Dicarboximide class fungicide is selected from chlozolinate (chlozolinate), iprodione (iprodione) or procymidone (procymidone)
Methoxy acrylic bactericide be selected from Fluoxastrobin (azoxystrobin), dimoxystrobin (dimoxystrobin), Fluoxastrobin (fluoxastrobin), kresoxim-methyl (kresoxim-methyl), SSF 126 (metominostrobin), oxime Dimoxystrobin (orysastrobin), ZEN 90160 (picoxystrobin), pyraclostrobin (pyraclostrobin), trifloxystrobin (trifloxystrobin) Enestroburin (enestroburin) or alkene oxime amine (SYP-1620);
Triazole bactericidal agent is selected from oxygen ring azoles (aconazole), bromuconazole (bromuconazole), Cyproconazole (cyproconazole), difenoconazole (difenoconazole), olefin conversion (diniconazole), efficient olefin conversion (diniconazole-M), epoxiconazole (epoxiconazole), benzoxazole (fenbuconazole), Fluquinconazole (fluquinconazole), Flusilazole (flusilazole), Flutriafol (flutriafol), hexaconazole (hexaconazole), glyoxalin (imibenconazole), kind bacterium azoles (ipconazole), metconazole (metconazole), Nitrile bacterium azoles (myclobutanil), penconazole (penconazole), propiconazole (propiconazole), prothioconazoles (prothioconazole), simeconazoles (simeconazole), Tebuconazole (tebuconazole), tetraconazole (tetraconazole), Triadimenol (triadimenol), triticonazole (triticonazole) or bitertanol (bitertanol);
Imidazoles fungicide is selected from probenazole (thiabendazole), furidazol (fuberidazole), imazalil (imazalil), efficiently press down mould side (imazalil-S), Prochloraz (prochloraz), fluorine bacterium azoles (triflumizole), cyanogen White azoles (cyazofamid), Fenamidone (fenamidone) dislike and narrow azoles (oxpoconazole) or pefurazoate (pefurazoate);
Uh azoles fungicide is selected from Famoxate (famoxadone), oxazole (XYP-Z048), hymexazol (hymexazol) or Wakil (oxadixyl);
Thiazoles fungicide is selected from Guardian (ethaboxam), Grandox fumigant (etridiazole), octhilinone (octhilinone) or benthiozole (benthiazole);
Morpholine bactericide is selected from dodemorph (dodemorph), butadiene morpholine (fenpropimorph) or 13 Quinoline (tridemorph);
Pyroles fungicide is selected from fenpiclonil (fenpiclonil) or fludioxonil (fludioxonil);
Pyridines fungicide is selected from fluazinam (fluazinam), pyrifenox (pyrifenox), ring pyridine bacterium amine (ICI- A0858), Boscalid (boscalid), fluopicolide (fluopicolide) or pyridine bacterium amine (PEIP);
Miazines fungicide is selected from cyprodinil (cyprodinil), fluorine mepanipyrim (diflumetorim), ferimzone (ferimzone), mepanipyrim (mepanipyrim), pyrimethanil (pyrimethanil), Fenarimol (fenarimol) or Nuarimol (nuarimol);
Quinoline (azoles) quinoline (ketone) class fungicide is selected from dithianon (dithianon), ethoxyquin (ethoxyquin), 8- hydroxyl Base quinoline (8-hydroxyquinoline sulfate), the third oxygen quinoline (proquinazid) or quinoxyfen (quinoxyfen);
Carbamate fungicide is selected from diethofencarb (diethofencarb), iprovalicarb (iprovalicarb), benzene Metsulfovax (benthiavalicarb-isopropyl), Propamocarb (propamocarb) or methasulfocarb (methasulfocarb);
Organic phosphorus type disinfectant is selected from edifenphos (edifenphos), different rice blast net (Iprobenfos), pyrazophos (pyrazophos) or tolelofos-methyl (tolclofos-methyl);
Antibiotics fungicide is selected from blasticidin-S (blasticidin-S), kasugarnycin (kasugamycin), more anti-mildews Plain (polyoxins), Polyoxin (Polyoxorim), Pseudomycin or Myxothiazol;
Other class fungicide are selected from valida (validamycin), jinggangmeisu (jinggangmycin), streptomysin (streptomycin), metalaxyl (metalaxyl), furalaxyl (furalaxyl), M 9834 (benalaxyl), ofurace (ofurace), mebenil (Mepronil), carbendazim (carbendazim), benomyl (benomyl), thiophanate-methyl (thiophanate-methyl), triazolone (tridimefon), bupirimate (bupirimate), dimethirimol (dimethirimol), ethirimol (ethirimol), difoltan (captafol), captan (captan), folpet (folpet), vinclozolin (vinclozolin), fluoromide (fluoroimide), dimethachlon (dimethachlon), Bravo (chlorothalonil), Isoprothiolane (isoprothiolane), kitazine (EBP), leaf are withered Azoles (bismerthiazol), pentachloronitrobenzene (quintozene), thiram (thiram), Mancozeb (mancozeb), third Gloomy zinc (propineb), phosethyl-Al (fosetyl-aluminium), sulphur (sulfur), Bordeaux mixture (Bordeaux Mixture), copper sulphate (copper sulphate), copper oxychloride (copper oxychloride), cuprous oxide (cuprous oxide) or Kocide SD (copper hydroxide);
Bactericidal (virus) agent is selected from Acibenzolar (acibenzolar), metrafenone (metrafenone), Pencycuron (pencycuron), Bethoxazin, diclomezin (diclomezine), fenpropidin (fenpropidin), Rabcide (phthalide), pyroquilon (pyroquilon), volution bacterium amine (spiroxamine), tricyclazole (tricyclazole), piperazine Amine spirit (triforine), cymoxanil (cymoxanil), dodine (dodine), the pungent salt of biguanides (guazatine), iminoctadine (iminoctadine), botran (dicloran), benzene flusulfamide (dichlofluanid), toluene flusulfamide (tolylfluanid), Zopfiellin, K-281 (OK-9601), fenaminosulf (fenaminosulf), oxolinic acide (oxolinic acid), probenazole (probenazole) or bronopol (bronopol).
The composition is preferably that component A is compound A, and component B is selected from Fluoxastrobin, flumorph, Tebuconazole, maneb Zinc, metalaxyl, kasugarnycin, thiophanate-methyl, carbendazim or fludioxonil, the number of two kinds of active components are 1:100-100:1.
It is compound A that the composition, which is more preferably component A, and component B is selected from thiophanate-methyl, Tebuconazole or Fluoxastrobin; The weight fraction ratio of two kinds of active components is optimized for 1:50-50:1.
Composition of the invention can be provided in finished product preparation form.Therefore, the invention also includes a kind of dosage forms Insecticidal and acaricidal composition.Using composition as active component, missible oil, suspending agent, water-dispersible granules, water and milk are made as needed Agent, soluble liquid, wettable powder, oil-suspending agent etc..The cumulative amount of the active component of composition exists in preparation Between 0.5%-95%, preferably cumulative amount is between 1%-85%.The content of active component depends in composition of the invention Amount of application when being used alone, also depends on mixed ratio and synergistic effect degree.The optimum range of active component content according to The preparation type of composition and it is different.
The preparation of composition finished product preparation of the invention can be prepared by common processing method, i.e., by active material and liquid After carrier (solvent) or solid carrier mixing, one or more of surfactants such as emulsifier is added, dispersing agent, wetting agent, glues Mixture, stabilizer and defoaming agent etc..Contain at least one carrier and at least one surfactant in usual composition.Various In the case of, it should be ensured that present composition active component is uniformly distributed.
Missible oil usually contains 10~50% active component, and 2~20% emulsifiers, 0~20% other additives are for example Stabilizer, bleeding agent etc. and solvent (also containing cosolvent when necessary).
Suspending agent usually needs to be sanded, to obtain stable non-deposited flowable product.Usually contain 5 in suspending agent~ 75% active component, 5~15% dispersing agents, 4~10% antifreezing agents, 0~10% other additives for example defoaming agent, preservative, Stabilizer, bleeding agent and thickener and liquid-carrier surplus.
Water-dispersible granules are usually made 10~100 international standard sieve mesh (1.676~0.152mm) particle, can pass through It squeezes, prepared by dipping or Spray granulation method.Usual water-dispersible granules contain 0.5~75% active component and 5~20% Surfactant such as stabilizer, wetting dispersing agent, disintegrating agent and adhesive and inert carrier surplus.
Wettable powder usually contains 10~85% active component, other than solid inert carrier, usually contain 3~ 10% dispersing agent, can also containing 0~10% stabilizer and (or) other additives, such as bleeding agent or sticker.
Aqueous emulsion is to mix raw medicine, organic solvent, surfactant to form oily phase;Water, antifreezing agent are mixed, At homogeneous aqueous phase.Oily phase, usual effective component is added in water phase with high-shear emulsion machine high speed shear oil phase, while slowly 1~60%, surfactant 5~20%, antifreezing agent 2~10%, water surplus.
Microemulsion is to mix raw medicine, organic solvent, surfactant, water, at homogeneous aqueous phase.Usually have Imitate ingredient 1~50%, surfactant 10~40%, antifreezing agent 2~10%, water surplus.
Soluble liquid is to mix active component, organic solvent, surfactant, at transparent and homogeneous liquid. Usual effective component 1~50%, surfactant 6~20%, organic solvent surplus.
Water dispersible oil suspending agent is that active component, surfactant, oil based vehicle are added in sand mill and are sanded, until grain Diameter is qualified, usual effective component 2~60%, surfactant 6~20%, oil based vehicle surplus.
Aqueous dispersion liquid and emulsion are (as being diluted with water missible oil of the invention, wettable powder or concentrate obtain Composition) it is also within the scope of the invention.Above-mentioned emulsion can be water-in-oil type or oil-in-water type, can have thick Paste-like consistency.
The preparation of composition finished product preparation of the invention can (liquid be solid using well known to those skilled in the art Body) carrier and various auxiliary agents.For example including but be not limited to following each substances.
Suitable liquid-carrier or solvent can be water, various aromatic hydrocarbons, aliphatic hydrocarbon, ketone, ethers etc., such as toluene, diformazan Benzene, acetone, cyclohexanone, acetonitrile, benzene, hexamethylene, isopropanol, ethylene glycol, sorbierite, methanol, ethyl alcohol, butanol, dimethyl formyl Amine, dimethyl sulfoxide, N- methyl-pyrrolidon, tributyl phosphate, methyl iso-butyl ketone (MIBK), naphthalane, machine oil, petroleum ether, oleic acid first One or more of ester, methylated soya oil or the molten fiber of methyl etc..The mixture of different liquids is often applicable.
Suitable solid carrier includes natural or synthesis clay and silicate, and the solid carrier suitable for pulvis includes The White Carbon black that naturally occurs, rock dust, chalk, quartz, clay, montmorillonite, sodium sulphate, white carbon black, silica, diatom Soil, float stone, gypsum, talcum, bentonite, kaolin, attapulgite, precipitated calcium carbonate, clay and the minerals of synthesis ground (such as microdispersed silicic acid or aluminium oxide).Suitable particulate vector include broken and classification natural rock such as calcite, Marble, float stone, sepiolite and dolomite and the synthesis particle made of the powder of organic matter and inorganic matter.
Suitable co-solvents are methanol, phenol, isoamyl alcohol, dimethyl sulfoxide, tributyl phosphate, ethyl acetate, butanone, diformazan One in base formamide, dimethyl sulfoxide, N- methyl-pyrrolidon, methyl oleate, methyl iso-butyl ketone (MIBK), the molten fiber of methyl etc. Kind is several.
Suitable emulsifier can be ethoxylated castor oil, polyoxyethylene (n20) phenethyl phenolic group oleic acid ester, alkyl virtue Base polyoxyethylene poly-oxygen propylene aether, alkylaryl formaldehyde resin polyoxyethylene ether, triphenyl vinyl phenol polyoxyethylene (n20) ether phosphorus It is acidified triethanolamine salt, castor oil polyoxyethylene ether, alkyl vinyl aryl phenyl ether (YUS-SC3), diphenyl phenolic group polyoxy second Alkene (n18) ether formaldehyde condensation products, the different thionic acid calcium of oleic acid, agriculture breast AEO-3, agriculture breast 0201B, agriculture breast 0203B, agriculture breast T-20, agriculture breast T-85, agriculture breast S-80, agriculture breast 507#, agriculture breast 100#, agriculture breast 36#, agriculture breast 500#, agriculture breast 600#, Nongru-700 #, agriculture breast 1601#, Agriculture breast OX-2681, agriculture breast OX-8686, agriculture breast OX-690, agriculture breast 2201#, agriculture breast NP-7, agriculture breast OX-635, agriculture breast OX-653, Agriculture breast YUS-A51G, agriculture breast YUS-135B, agriculture breast YUS-2011CX, agriculture breast YUS-D625, agriculture breast YUS-D3020, agriculture breast YUS- A41B, agriculture breast YUS-D935, agriculture breast YUS-CP120, agriculture breast YUS-A41B, agriculture breast NP-10, agriculture breast NP-15 etc..
Suitable dispersing agent can for sodium lignin sulfonate, calcium lignosulfonate, alkyl naphthalene sulfonic acid condensation polymer sodium salt, poly- Carboxylate dispersants GY-D800, polycarboxylate salt dispersant GY-D04, polycarboxylate salt dispersant GY-D02, naphthalene sulfonate formaldehyde contracting Close object, naphtholsulfonic acid formaldehyde condensation products sodium salt, condensation compound of methyl naphthalene sulfonic acid and formaldehyde, alkyl-diethylene glycol ether-sodium sulfonate, N- first Base-oleoyl-sodium taurocholate, methanonaphthalene sodium sulfonate, oleic acid methylaminoethyl sodium sulfonate, epoxidized polyether, divides detergent LS Powder SP-28F, dispersing agent SP-SC3, profit dispersing agent D909S, alkyl aryl polyoxyethylene ether, dodecyl polyoxyethylene are reached Ether phosphate, polyaryl phenol polyethenoxy ether, to tertbutyl ether, piperonyl butoxide, alkamide taurine salt, alkyl naphthalene sulfonic acid Salt formaldehyde condensation products (NNO), ethylene oxide-propylene oxide block copolymer APES formaldehyde condensation product, N- first Base-fatty acyl group-sodium taurocholate, APES formaldehyde condensation product, nekal (Nekal BX), two fourths Base naphthalene sulfonic acid-formaldehyde condensation product, alkylphenol polyoxyethylene ether formaldehyde condensate sulfate, alkylphenol-polyethenoxy based phosphates, Dispersing agent YUS-NV1203, dispersing agent YUS-NV1420, dispersing agent YUS-WG4, dispersing agent YUS-TG285, dispersing agent YUS- WP1, dispersing agent YUS-110, dispersing agent YUS-EP60P, dispersing agent YUS-CH1100, dispersing agent SP-OF3468, dispersing agent SP- OF3472, dispersing agent SP-2728, dispersing agent SP-SC29, dispersing agent Supragil MNS/90, dispersing agent Soprophor FD, Dispersing agent YUS-FS1, dispersing agent YUS-PQ100, dispersing agent YUS-WG5, YUS-D935 etc..
Suitable wetting agent can be sodium sulphate, Morwet EFW, wetting agent Igepal BC/10, wetting agent GEROPONL-WET/P, wetting agent Rhodasurf 860/p, wetting agent SP-SC3266, wetting agent YUS-LXC, wetting agent YUS-204, isopropyl naphthalene sulfonate, alkylol polyoxyethylene base ether sodium sulfate, alkylphenol-polyethenoxy base ether formaldehyde condensation products Sulfate, sldium lauryl sulfate, neopelex, lauryl sodium sulfate, calcium dodecyl benzene sulfonate, alkylnaphthalene sulphur Sour sodium fatty alcohol polyoxyethylene ether, alkylphenol-polyethenoxy base ether etc..
Suitable thickener can be (such as carbonyl methylol alcohol, polyvinyl alcohol, the polyvinyl acetate) or natural water of synthesis Soluble polymer (such as xanthan gum, gelatin, gum arabic, polyvinylpyrrolidone, aluminium-magnesium silicate, polyvinyl alcohol, poly- second two Alcohol, phenolic resin, shellac, methylcellulose, soluble starch, carboxymethyl cellulose and sodium alginate etc.), with powder, particle Or latex form is added in preparation.
Suitable defoaming agent is GPE, silicone, the fatty alcohol of C8~10, phosphoric acid ester, the saturated fat acids of C10~20 (such as capric acid) and amide.
Suitable adhesive can be polyvinyl alcohol, polyvinyl acetate, xanthan gum, gelatin, carboxymethyl cellulose and sea Mosanom etc..
Aerosol can be made when for preventing and treating city pest, needing that propellant is added wherein, bait formulation can also be made Composition, except containing in addition to active component, also containing it is one or more suitable for the foodstuff of insect's food-taking, optional attractant and Optional wetting agent.
The invention also includes the present compositions to be prepared into Insecticiding-miticiding preparation control agriculture and forestry injurious insect or urban health insect Purposes.It is particularly adapted to prevent and treat a variety of important agricultural insect pests, disease.
It prevents and treats in one embodiment, which is used to prevent and treat the disease of Mastigomycotina.Specific kind of nonexhaustive Soft rotten, the continuous corruption of eggplant melon of citing including but not limited to seedling blight of rice, Achlya spp, radish root-rot, samping off, root rot, fruits and vegetables, Hawthorn root rot, tree peony epidemic disease, tobacco black shank, the late blight of potato, pineapple heart rot, tomato late blight, citrus brown rot epidemic disease Disease, capsicum epidemic disease, red core disease of strawberry, melon epidemic disease, lily basal stem rot, lichee frost epidemic disease (mould) disease, potato blight, white blister, Tobacco downy mildew, Chinese cabbage downy mildew, downy mildew Pseudoperonospora downy mildew of cucurbits, downy mildew of garpe, downy mildew of lettuce, composite family Downy mildew, the downy mildew of millet, cabbage clubroot, powdery scab of potato, shot hole, maize brown spot, straw rust, turfgrass rust Disease, rust of pear, rose rust, Bean rust disease, jujube tree rust, flax rust, wheat loose smut, wheat flag smut, rice Leaf smut, wheat bunt, jowar dissipate black powder fringe disease, Kernel Smut of Rice, arrowhead smut, fruit tree felt fungus, peanut Purple root rot (Helicobasidium mompa) etc..
It prevents and treats in another embodiment, which is used to prevent and treat the disease of Ascomycotina.It is specific kind of non exhaustive Property citing include but is not limited to peach leaf-curl, swollen leaf disease, withes broom, citrus rot disease, grapevine anthracnose, leaf spot, peanut Black spot, the cercospora brown spot of peanut, black rot of grape, Pear scab, Guo Heixing bacterium, scab of apple, Cereal powdery mildew, cruciate flower Section's powdery mildew, it is barley (apple, grape, melon, beans) powdery mildew, fruit tree powdery mildew, sweet potato black rot, sugarcane pineapple disease, withered Wither disease, head blight, bakanae disease of rice, fruit tree anthracnose, citrus branch bar bleeding disease, peach bleeding disease, grapevine anthracnose, black points, Apple (pears) scab, root rotof flax, Kidney bean stem rot, sclerotinia sclerotiorum, cucumber timberrot, (pear tree, apple, peach, Lee, A variety of fruit trees such as apricot) ring spot, hawthorn (citrus) Sooty mould etc..
It prevents and treats in another embodiment, which is used to prevent and treat the disease of Deuteromycotina.It is specific kind of non exhaustive Property citing include but is not limited to Apple brown rot, gray mold, fruit red rot, cotton Leucoplakia, cineraria powdery mildew, the moon Season powdery mildew, rubber tree powdery mildew, rice blast, green mold of citrus, cotton verticillium wilt, eggplant verticillium wilt, oriental cherry brown spot, cloves Brown spot, sweet osmanthus leaf spot, cuckoo leaf spot fungi, the cercospora brown spot of peanut, leaf spot of peanut, beet cercospora leaf spot, carnation tikka Disease, Chinese juniper leaf blight, cotton zonate leaf spot disease, apple peels and cores (Phomopisis vexans), apple marssonina leaf spot, almond root decomposing disease, Early blight of tomato, Alternaria alternate, radish blackspot, wheat rice black points, pear scab, scab of cucumber, barley cecospora spot, The leaf blight of corn, rice samping off, rice seedling blight, root rot of beets, the sheath and culm blight of rice, southern blight, wilt disease, the shaddock base of a fruit are rotten Disease, mango blossom-end rot, citrus (black, yellow) blossom-end rot, cucumber fusarium axysporum, false smut, grapevine anthracnose, citrus scab, Solanaceous vegetable shot hole, shaddock shot hole, Peanut Scab, bacterial spot of pepper, apple marssonina leaf spot, peach cherry tikka shothole disease, the moon Season alternaria, loquat leaf blight, snake eye disease, wild cabbage class balck shank, cotton brown spot, spot disease, apple (pears) ring spot, eggplant Phomopisis vexans, stem wilt, wheat glume blotch, spot blight, Fungus of Pear Canker Disease, cotton boll black fruit, the thick pinta of sorghum, melon gummy stem blight, Cucumber blight dis-ease etc..
It prevents and treats in another embodiment, which is used to prevent and treat the disease of Zygomycotina.It is specific kind of non exhaustive Property citing include but is not limited to soft rot, blossom rot etc..
It prevents and treats in another embodiment, which is used to prevent and treat the disease of bacterial disease.It is specific kind of non exhaustive Property citing include but is not limited to rice bacterial stripe, bacterial blight of rice, rape black rot, cotton angular leaf spot, c itrus canker Disease, soybean bacterial plaque exanthema, Xanthomonas camp stris P V. campestris, peach (Lee, apricot, nectarine, cherry etc.) Bacterial septicaemia syndrome, sugarcane top burn Disease (informal voucher disease), beans bacterial epidemic disease, bacterial wilt, paddy bacterial brown spot, Pseudomonas panici Stapp, rape are bacillary Black spot, melon bacterial angular leaf spot, beans bacterial angular leaf spot, bacterial blight of soybean, the bacillary spot blight of beet, sesame Numb bacterial angular leaf spot, Tobacco Angular Leaf Spot Disease, wildfire, mulberry bacterial epidemic disease, fire blight of pear, carrot soft rot bacterium, horse Bell potato soft rot, blakleg of potato, rape soft rot, sunflower Bacterial stalk rot, solanaceous vegetable soft rot, rice base are rotten Disease, corn stalk rot disease, melon bacterial wilt disease, rosaceous plant root knot, pears root knot, Apple crown gall, citrus Huanglong Disease, Citrus fruit disease (yellow blight, yellow few disease), potato scabies disease, potato scab, corn wilt disease etc..
It prevents and treats in another embodiment, which is used to prevent and treat the disease of virosis.Specific kind of nonexhaustive is lifted Example includes but is not limited to banana bunchy top disease, mung bean yellow mosaic, melon leaf curl, capsicum (tomato, tobacco, melon) Qu Ye Disease, capsicum (tomato) tomato yellow leaf curl China, pumpkin yellow mosaic, tomato yellow leaf curl disease, tomato leaf curl, yellow stunt of wheat, Tobacco yellow dwarf, Kidney bean yellow dwarf, wheat dwarf wilt, beet curly-top, dayflower yellow mottle virus, cauliflower mosaic The short disease of poison, corn rough dwarf, Rice Gall Dwarf In Guangdong Province, rice cluster, fractilinea oryzae black streaked dwarf virus of rice, rice dwarf virus disease, water Cercosporiosis of rice poison stripe disease, rice yellowtop (wise jaundice yellow dwarf), grape cork disease, rice tungro disease virus Disease, bean mosaic virus section, cowpea mosaic virus, potato mosaic, rye grass mosaic disease, wheat shuttle streak mosaic disease, barley Yellow mosaic, Bromoviridae, masaic of tomato, cucumber mosaic virus, beet yellows virus are sick, beet yellows virus is sick, Citrus tristeza virus disease, wheat yellow leaf virus disease, beet yellow stunt virus disease, mosaic virus, cucumber mosaic virus, peach mosaic, Apple mosaic, lily necrosis pinta, lily ring spot etc..
It prevents and treats in another embodiment, pest of the combination for anti-Orthoptera of curing the disease.Specific kind of nonexhaustive Citing includes but is not limited to Asiatic migrotory locust, reading room management, Ban Tui locust section, Chinese rice grasshopper, Patanga japonica (l.Bol.), single thorn mole cricket, east Mole cricket, Gryllotalpa unispina, African mole cricket, Taiwan mole cricket;
It prevents and treats in another embodiment, pest of the combination for anti-Thysanoptera of curing the disease.Specific kind of nonexhaustive Citing includes but is not limited to rice thrips, onion thrips, greenhouse thrips, haplothrips aculeatus, Testa Tritici thrips, end Taeniothrips spp, onion thrips, flower Thrips, golden thistle horse, Sugarcane Thrips, yellow thrips;
It prevents and treats in another embodiment, pest of the combination for anti-Homoptera of curing the disease.Specific kind of nonexhaustive Citing include but is not limited to Trialeurodes vaporariorum Westwood, rice green leafhopper, Erythroneura subrufa, green leaf hopper, chlorita biguttula, Siberian elm leaf cicada, smaller green leaf hopper, India chlorita biguttula, spot clothing plant hopper, brown paddy plant hopper, white backed planthopper, small brown rice planthopper, pear sucker, diaphorina citri, Aleurocanthus spiniferus, the flat angle of sugarcane Plant hopper, cotten aphid, green bugs, grain aphid, soybean aphid, Aphis medicaginis, black peach aphid, kaoliang aphid, radish aphid, sugar cane cottony aphid, apple are continuous Aphid, icerya purchasi, Pseudaulacaspis pentagona, unaspis shield kuwana, san jose scale, wax insect, ceroplastes rubens, Didesmococcus koreanus Borchs, cotton pearl a red-spotted lizard, sugarcane mealybug, length White a red-spotted lizard, white peach scale, apricot ball heavily fortified point a red-spotted lizard, Ceroplastes japonicus Green, persimmon suede a red-spotted lizard, chaff piece a red-spotted lizard, chaff scale, brown round a red-spotted lizard, heap wax powder a red-spotted lizard;
It prevents and treats in another embodiment, pest of the combination for anti-Semiptera of curing the disease.Specific kind of nonexhaustive Citing includes but is not limited to pear lace bug, banana lace bug, thin corner piece stinkbug, Orius minutus, slender rice bug, big Leptocorisa spp, paddy fly, rice Brown stinkbug, scotinophora lurida, green rice bug, green plant bug, alfalfa plant bug, black striped plant bug, wheat root fleahopper, adelphocoris taeniophorus, tarnished plant bug, lichee Stinkbug;
It prevents and treats in another embodiment, pest of the combination for anti-Lepidoptera of curing the disease.Specific kind of nonexhaustive Citing include but is not limited to rain moth, casemaking clothes moth, oriental moth, brown slug moth, thosea siensis, gelechiid, pink bollworm, oriental tobacco budworm, brachmia triannuella, Diamondback moth, eating-core bean worm, small heart-eating peach worm, hemp Grapholita spp, oriental fruit months, pear fruit borer, carpocapsa pononella, apple Spilonota lechriaspis, apple tabaniformis, macula lutea leaf roller, apple ermine moth, brown belt length leaf roller, intends small yellow leaf curl at applied perfume The brown leaf roller of moth, stain, the small hairstreak of lichee, striped rice borer, bean-pod borer, corn borer, yellow rice borer, goldrimmed moth, Oeobia undalis, cnaphalocrocis Snout moth's larva, chilotraea infuscatellus, duckweed ash snout moth's larva, duckweed snout moth's larva, snout moth's larva, Notarchaderogata, Sweet Potato snout moth's larva, some paddy snout moth's larvas, dichocrocis punctiferalis, sunflower moth, yellow snout moth's larva, Chilo infuscatellus, white snout moth's larva, leukorrhea snout moth's larva, loxostege sticticalis, armyworm, prodenia litura, three-spotted plusia, hole wing noctuid, Chenopodiaceae noctuid, jute noctuid, ramie Numb noctuid, fruit piercing moth, Chlumetia transversa Walker, lopper worm, beet armyworm, elegant noctuid, loquat yellow caterpillar, the red Jia of ramie Butterfly, a ramie Huang a kind of butterfly harmful to crop plants, rice green caterpillar, anomis flava, pink rice borer, bollworm, cotton leafroller, soybean leaf roll snout moth's larva, peach pyralid moth, ancient cooking vessel point Spark, earias fabia, earias insulana, black cutworm, big cutworm, yellow cutworm, white edge cutworm, alert line it is old Tiger steals poison moth, gypsymoth, palaearctic sweet potato, greenish brown hawk moth, straight grain rice hesperiidae, pelopidas mathias, Papilio xuthus, Common Mormon, vegetable powder Butterfly, biobelt night butterfly, Rice Leaf night butterfly, amyloid plaque snout moth, Euproctis pseudoconspersa, looper, tea bagworm, big psychid, tea bagworm, Parametrites theae, tea branch Sickle moth, wild silkworm, euproctis similis, tent caterpillar, Atrijuglans hetaohei, persimmon fruit moth, phyllocnistis citrella stainton, Erionota thorax (Linne);
It prevents and treats in another embodiment, pest of the combination for anti-coleoptera of curing the disease.Specific kind of nonexhaustive Citing includes but is not limited to beans blister beetle, Venus ground beetle, wrinkle sheath ground beetle, wheat head ground beetle, pleonomus canaliculatus, Agriotes subrittatus Motschulsky, wide back gold Needle worm, brown line wireworm, khapra beetle, attagenus piceus, the small buprestid beetle of citrus, flat headed apple borer, golden edge buprestid beetle, citrus blistering Worm, citrus slip skinworm, potato bug, potato ladybug, Chenopodiaceae ladybug, yellow meal worm, dark mealworm, red flour beetle, miscellaneous quasi- paddy It is robber, grain peat, saw-toothed grain beetle, Cryptolestes pusillus, black wrinkle gill cockchafer, clouding gill cockchafer, Anomala exoleta, verdigris different beetle, dark Dark fund tortoise, holotrichia oblita, mulberry borer, longicorn beetle, nadezhdiella cantori, pink neck longicorn, red neck longicorn, sugarcane prionid, Paralglenes fortunei, hemo longicorn beetle, brown longicorn beetle, the green longicorn of light shield, big daikon leaf beetle, daicon leaf beetle, rice root is chrysomelid, grain fish-scale is chrysomelid, sesame slices First, pernicious chrysomelid, tangerine leaf mining first, trifoliate orange leaf mining first, aulacophora femoralis, phyllotreta striolata, beet flea beetle, paddy flea beetle, Callosobruchus chinensis, pea As, broad bean weevil, sitophilus zea-mais, rice weevil, root nodule weevil, the beautiful line weevil of tea, tea seed weevil, beet weevil, Rape stem weevil, pear curculio, Apricot tiger, peach tiger, black suede scarab beetle, mesh quasi- ground first, Mongolia quasi- ground first, Lissorhoptrus oryzophilus Kuschel, Oulema oryzae, corn dicladispa armigera, sweet potato Small green nail, prominent back glycosides tortoise, light back glycosides tortoise, yellow leaf worm, banana root weevil, the double black-tape curculionids of banana;
It prevents and treats in another embodiment, pest of the combination for anti-Diptera of curing the disease.Specific kind of nonexhaustive Citing include but is not limited to wheat midge, contarinia tritici, pachydiplosis oryzae, rice midge, ricestem-fly, hydrellia griseola, rice ephydrid, Citrus fruit fly, dacus dorsalis, bactrocera tsuneonis, melonfly, wheat leaf ash latent fly, Americal rice leaf miner, Soybean stem borer, straw Fly, Hylemyia Platura Meigen, onion fly, radish fly, sorghum shoot fly, millet stem fly, Chinese milk vetch Liriomyza, duckweed midge, kmangold fly, beet root maggot, Radish fly;
It prevents and treats in another embodiment, pest of the combination for anti-Acarina of curing the disease.Specific kind of nonexhaustive Citing includes but is not limited to grain spider mite, penthaleus major duges, cotton Tetranychus cinnabarinus, vegetables tetranychid, tetranychus viennensis, the full pawl of citrus Mite, phyllocoptruta oleivora, apple tetranychus, Tetranychus urticae, goitre mite, flour mite, privet mite, Bryobia praetiosa, citrus tumor mite.
When for preventing and treating agricultural pest, it can be used for fruit tree such as apple, pears, citrus, peach, hawthorn, apricot, plum, jujube, core Peach, persimmon, longan, banana, loquat, mango, lichee etc., cereal such as wheat, rice, corn, sorghum, millet etc., cotton, oil plant are made Object such as soybean, peanut, sunflower, castor-oil plant, sesame etc., sugar crop such as beet, sugarcane etc., crudefiber crop such as jute, ramie etc., Green manure crop such as clover, duckweed, Chinese milk vetch etc., vegetables such as wild cabbage, cauliflower, Chinese cabbage, cucumber, potato, rape, eggplant, dish Beans, semen viciae fabae, mung bean, watermelon, sweet potato, tomato, capsicum, green onion, leek, garlic, ginger and flowers, tea, tobacco, mulberry tree etc..
When for preventing and treating city pest, it can be used for family, public place, office space, factory, gardens, golf , and trees, the dykes and dams etc. of termite damage occur.
The invention also includes a kind of methods for controlling insect pest, the present composition can be imposed on effective dose and need to control Pest or its growth medium on.The more suitable effective dose generally selected is 10 grams to 500 grams of per hectare, preferably effectively Dosage is 15 grams to 100 grams of per hectare.
The present invention has the advantage that
1. composition of the invention shows certain synergistic effect within a certain ratio range, the compound pair is improved The control efficiency of pest.Specifically, compound A and Fluoxastrobin, flumorph, Tebuconazole, Mancozeb, metalaxyl, kasugarnycin, first Base thiophanate, carbendazim, fludioxonil show better synergistic effect to Tetranychus cinnabarinus in the range of 1:100~100:1.
2. the present composition proposes the pest and disease damage Unifying control mode of highly efficient vegetable at protected field, effective to save About labor cost.
3. each adjuvant component has specific aim in the present composition, effectively avoids fungicide and insecticide and applying Failure or phytotoxicity phenomenon in the process, with meet agricultural and urban health field prevention and treatment pest and disease damage in terms of to pesticidal effects increasingly Improve the demand constantly updated with kind.
Specific embodiment
Following specific embodiments are for present invention be described in more detail, but the present invention is by no means limited to these examples.It is real Each component percentage composition or proportion in example is applied to be by weight.Active component in each formula is calculated with effective content, while group Closing each substance in object can prepare in a conventional manner.
Formulation Example
The preparation of embodiment 1,21% Fluoxastrobin compound A missible oil
By recipe requirements, respectively by 1 part of Fluoxastrobin, 20 parts of compound A, 5 parts of agriculture breast 0201B, 4 parts of agriculture breast YUS-135B, 2 Part agriculture breast 1601#, 10 parts of dimethylformamides, 6 parts of methanol, dimethylbenzene complement in 100% addition mixing kettle, are stirred It is even, it is dissolved by heating when necessary with hot bath, 21% Fluoxastrobin compound A missible oil can be obtained.
Can also by fungicide described in Fluoxastrobin alternative costs specification, in bactericidal (virus) agent other one Kind, form 21% new fungicide, bactericidal (virus) immunomodulator compounds A missible oil.
The preparation of embodiment 2,42% thiophanate-methyl compound A wettable powder
By recipe requirements, by 40 parts of thiophanate-methyls, 2 parts of compound A, 2 parts of lauryl sodium sulfate, 4 parts of dispersing agents Soprophor FD, 4 parts of methanonaphthalene sodium sulfonates, 4 parts of sodium lignin sulfonates, 5 parts of White Carbon blacks, diatomite complement to 100% and fill Point mixing, to get to 42% thiophanate-methyl compound A wettable powder after ultra-fine pulverizer disintegrating.
It can also be by fungicide described in thiophanate-methyl alternative costs specification, other in bactericidal (virus) agent One kind forming 42% new fungicide, bactericidal (virus) immunomodulator compounds A wettable powder.
The preparation of embodiment 3,12% flumorph compound A wettable powder
By recipe requirements, by 2 parts of flumorphs, 10 parts of compound A, 2 parts of wetting agent Igepal BC/10,4 parts of dispersing agents Supragil MNS/90,3 parts of polycarboxylate salt dispersant GY-D02,4 parts of sodium lignin sulfonates, 5 parts of White Carbon blacks, precipitated calcium carbonates It complements to 100% to be sufficiently mixed, to get to 12% flumorph compound A wettable powder after ultra-fine pulverizer disintegrating.
Can also by fungicide described in flumorph alternative costs specification, in bactericidal (virus) agent other one Kind, form 12% new fungicide, bactericidal (virus) immunomodulator compounds A wettable powder.
The preparation of embodiment 4,22% Tebuconazole compound A aqueous emulsion
By recipe requirements, by 20 parts of Tebuconazoles, 2 parts of compound A, 6 parts of agriculture breast OX-2681,4 parts of agriculture breast YUS-D935,5 parts Agriculture breast 2201#, 10 parts of tributyl phosphates, 5 parts of dimethyl sulfoxides, 10 parts of dimethylbenzene are added in mixing kettle, are stirred, make to dissolve At homogeneous oil phase, under high velocity agitation, excess water (complementing to 100%) is added to oily phase, favorable dispersibility can be obtained 22% Tebuconazole compound A aqueous emulsion.
Can also by fungicide described in Tebuconazole alternative costs specification, in bactericidal (virus) agent other one Kind, form 22% new fungicide, bactericidal (virus) immunomodulator compounds A aqueous emulsion.
The preparation of embodiment 5,40% kasugarnycin compound A aqueous emulsion
By recipe requirements, by 20 parts of kasugarnycin, 20 parts of compound A, 2 parts of triphenyl vinyl phenol polyoxyethylene (n20) ether phosphorus It is acidified triethanolamine salt, 6 parts of agriculture breast 1601#, 8 parts of agriculture breast YUS-D3020,8 parts of dimethyl sulfoxides, 10 parts of cyclohexanone, 5 parts of dimethylbenzene It is added in mixing kettle, is stirred, makes to be dissolved into homogeneous oil phase, under high velocity agitation, excess water (complementing to 100%) is added To oily phase, 40% kasugarnycin compound A aqueous emulsion of favorable dispersibility can be obtained.
Can also by fungicide described in kasugarnycin alternative costs specification, in bactericidal (virus) agent other one Kind, form 40% new fungicide, bactericidal (virus) immunomodulator compounds A aqueous emulsion.
Embodiment 6,51% Tebuconazole compound A water-dispersible granules
By recipe requirements, by 1 part of Tebuconazole, 50 parts of compound A, 5 parts of dispersing agent YUS-WG5,4 parts of alkyl naphthalene sulfonic acid polycondensations The sodium salt of object, 4 parts of sodium lignin sulfonates, 6 portions of soluble starches, 10 parts of sodium sulphate, bentonite complement to 100% and are added together, Co-grinding is carried out, then after adding water to mediate, is added in the pelletizer equipped with certain specification sieve and is granulated.Then again through dry Dry, screening (presses screen cloth scope), and 51% Tebuconazole compound A water-dispersible granules can be obtained.
Can also by fungicide described in Tebuconazole alternative costs specification, in bactericidal (virus) agent other one Kind, form 51% new fungicide, bactericidal (virus) immunomodulator compounds A water-dispersible granules.
Embodiment 7,24% fludioxonil compound A water-dispersible granules
By recipe requirements, by 20 parts of fludioxonils, 4 parts of compound A, 5 parts of alkylnaphthalene sulfonate formaldehyde condensation products, 5 parts of wettings Agent YUS-204,1 part of Morwet EFW, 2 parts of PEG 8000s, 15 parts of sodium sulphate, diatomite complement to 100% and are added together, Co-grinding is carried out, then after adding water to mediate, is added in the pelletizer equipped with certain specification sieve and is granulated.Then again through dry Dry, screening (presses screen cloth scope), and 24% fludioxonil compound A water-dispersible granules can be obtained.
Can also by fungicide described in fludioxonil alternative costs specification, in bactericidal (virus) agent other one Kind, form 24% new fungicide, bactericidal (virus) immunomodulator compounds A water-dispersible granules.
Embodiment 8,21% carbendazim compound A suspending agent
By recipe requirements, by 1 part of carbendazim, 20 parts of compound A, 4 parts of dispersing agent Supragil MNS/90,4 parts of agriculture breasts 0201B, 2 parts of agriculture breast 1601#, 0.1 part of xanthan gum, 0.3 part of white carbon black, 5 parts of ethylene glycol, with water 100% is complemented to, sequentially added It is mixed into blending tank, first passes through high shear and carry out coarse crushing, homogenize, be then pumped into sand mill and carry out fine grinding, use granularity The granularity of material is sanded in distribution instrument detection, and after partial size reaches standard requirements, 21% carbendazim compound is can be obtained in filtering A suspending agent.
Can also by fungicide described in carbendazim alternative costs specification, in bactericidal (virus) agent other one Kind, form 21% new fungicide, bactericidal (virus) immunomodulator compounds A suspending agent.
Embodiment 9,51% Fluoxastrobin compound A suspending agent
By recipe requirements, by 50 parts of Fluoxastrobins, 1 part of compound A, 2 parts of agriculture breast S-80,4 parts of alkylnaphthalene sulfonate formaldehyde contractings Close object, 1 part of Nongru-700 #, 3 parts of dispersing agent YUS-FS1,2 parts of agriculture breast 1601#, 0.1 part of xanthan gum, 0.2 part of white carbon black, 5 parts of second Glycol complements to 100% with water, is added sequentially to mix in blending tank, first passes through high shear and carries out coarse crushing, homogenizes, then It is pumped into sand mill and carries out fine grinding, the granularity that material is sanded, after partial size reaches standard requirements, mistake are detected with particles distribution instrument Filter, can be obtained 51% Fluoxastrobin compound A suspending agent.
Can also by fungicide described in Fluoxastrobin alternative costs specification, in bactericidal (virus) agent other one Kind, form 51% new fungicide, bactericidal (virus) immunomodulator compounds A suspending agent.
Embodiment 10,21% metalaxyl compound A microemulsion
By recipe requirements, by 1 part of metalaxyl, 20 parts of compound A, 8 parts of agriculture breast 2201#, 4 parts of agriculture breast OX-8686,8 parts of agricultures Newborn YUS-A51G, 3 parts of agriculture breast 1601#, 12 parts of dimethyl sulfoxides, 16 parts of cyclohexanone are added together, and make it dissolve into homogeneous oil phase, Surplus complements to 100% with water, under high velocity agitation, water phase is added to oily phase or oil is added to water phase, forms dispersion The good 21% metalaxyl compound A microemulsion of property.
Can also by fungicide described in metalaxyl alternative costs specification, in bactericidal (virus) agent other one Kind, form 21% new fungicide, bactericidal (virus) immunomodulator compounds A microemulsion.
Embodiment 11,21% Tebuconazole compound A soluble concentrate
By recipe requirements, by 1 part of Tebuconazole, 20 parts of compound A, 6 parts of triphenyl vinyl phenol polyoxyethylene (n20) ether phosphoric acid Change triethanolamine salt, 6 parts of agriculture breast 0201B, 3 parts of agriculture breast agriculture breast YUS-135B, 2 parts of agriculture breast 500#, 12 parts of N- methyi-pyrrofidiniums Ketone, 6 parts of tributyl phosphates, the molten fiber of methyl complement to 100% and are uniformly mixed, and are dissolved by heating, can be made with hot bath when necessary 21% Tebuconazole compound A soluble concentrate.
Can also by fungicide described in Tebuconazole alternative costs specification, in bactericidal (virus) agent other one Kind, form 21% new fungicide, bactericidal (virus) immunomodulator compounds A soluble concentrate.
Embodiment 12,21% Mancozeb compound A water dispersible oil suspending agent
By recipe requirements, by 1 part of Mancozeb, 20 parts of compound A, 5 parts of dispersing agent SP-OF3468,4 parts of dispersing agent SP- OF3472,3 parts of agriculture breast 0201B, 2 parts of agriculture breast S-80,3 parts of white carbon blacks, 20 parts of methyl oleates, methylated soya oils complement to 100% is added sequentially to mix in blending tank, first pass through high shear carry out coarse crushing, homogenize, be then pumped into sand mill into Row fine grinding detects the granularity that material is sanded with particles distribution instrument, and after partial size reaches standard requirements, filtering can be obtained 21% Mancozeb compound A water dispersible oil suspending agent.
Can also by fungicide described in Mancozeb alternative costs specification, in bactericidal (virus) agent other one Kind, form 21% new fungicide, bactericidal (virus) immunomodulator compounds A water dispersible oil suspending agent.
Indoor biological activity assay
Synergism determination of composition of the embodiment 13 containing compound A to Tetranychus cinnabarinus
For examination object: Tetranychus cinnabarinus (Tetranychus cinnabarinus Boisduval), adult mite, indoor raising Sensitive strain.
Test condition: temperature: 24~26 DEG C, humidity: RH 60%, illumination: L:D=14:10
Test method: pot-spraying method is used.The sizing potting Kidney bean seedling (2 true leaves) of hot-house culture, stays a piece of true leaf, It is connected into mite 40-60 head on it.Test material is handled using Airbrush spray-on process medical fluid, is dried in the shade naturally.Blank control is first handled, Then aforesaid operations, 4 repetitions of every processing are repeated from low to high according to experimental design dosage.By treated, test worm is placed in In observation ward, routine observation test worm response situation investigates number of dead and live insects after 72h, calculates the death rate.
Evaluation uses Bliss method, and this method is to evaluate one of the classical way of mixture effect.Bliss is proposed according to it Independent joint action concept thinks, theoretical death rate P when Mixture Use of Insecticides can be calculated with following formula:
P=Pm+Pn(1-Pm)
PmFor the death rate (%) of the first active component target when concentration is m;PnIt is using concentration for the second active component The death rate (%) of target when n.
If the actual of two kinds of active component targets after being mixed with a certain concentration is greater than theoretical death rate P, Determine that two kinds of active components are used in mixed way in the case where setting concentration with synergistic effect, it is on the contrary then be antagonism.It the results are shown in Table 1.
9 medicaments such as 1 compound A of table and Fluoxastrobin are used in mixed way the synergism determination to Tetranychus cinnabarinus adult mite
To sum up, the composition shows certain synergistic effect to the synergistic effect of Tetranychus cinnabarinus bioactivity.In addition, by Contain fungicide or bactericidal (virus) agent in the composition, so it also has preventive and therapeutic effect to the Common Diseases of plant.

Claims (9)

1. insecticidal and acaricidal composition of the one kind containing fungicide or bactericidal (virus) agent, it is characterised in that: composition be component A, Two kinds of active components of component B, the weight fraction ratio between two component of component A and component B are 1:100-100:1;Component A is selected from down Structural formula compound represented A is stated, component B is selected from triazole bactericidal agent;
The component A structure is as follows:
Triazole bactericidal agent is selected from oxygen ring azoles, bromuconazole, Cyproconazole, difenoconazole, olefin conversion, efficient olefin conversion, fluorine ring Azoles, benzoxazole, Fluquinconazole, Flusilazole, Flutriafol, hexaconazole, glyoxalin, kind bacterium azoles, metconazole, nitrile bacterium azoles, penconazole, the third ring Azoles, prothioconazoles, simeconazoles, Tebuconazole, tetraconazole, Triadimenol, triticonazole or bitertanol.
2. composition described in accordance with the claim 1, it is characterised in that: the component A is compound A, and component B is selected from penta azoles Alcohol;The weight fraction ratio of two kinds of active components is 1:100-100:1.
3. composition according to claim 2, it is characterised in that: the component A is compound A, and component B is selected from penta azoles Alcohol;The weight fraction ratio of component A and B component is optimized for 20:1-50:1.
4. composition according to claim 2, it is characterised in that: the component A is compound A, and component B is selected from penta azoles Alcohol;The weight fraction ratio of component A and B component is optimized for 1:10-50:1.
5. composition described in accordance with the claim 1, it is characterised in that: composition can be configured to missible oil, suspending agent, water dispersion Property granula, aqueous emulsion, microemulsion, soluble concentrate, wettable powder or water dispersible oil suspending agent.
6. composition according to claim 5, it is characterised in that: the cumulative amount of active component is in 0.5%- in composition Between 95%.
7. composition according to claim 5, it is characterised in that: the cumulative amount of active component is in 1%- in composition Between 85%.
8. a kind of application of the insecticidal and acaricidal composition described in accordance with the claim 1 containing fungicide or bactericidal (virus) agent, It is characterized by: the composition is used to prepare insecticidal/acaricidal agent, for controlling agricultural pests or urban health insect.
9. the application of the insecticidal and acaricidal composition according to claim 8 containing fungicide or bactericidal (virus) agent, special Sign is: with effective agent meter, the composition for being prepared into insecticidal/acaricidal agent being imposed on the pest for needing to control or its growth Medium on.
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CN106719820A (en) * 2016-12-26 2017-05-31 东莞市联洲知识产权运营管理有限公司 A kind of agricultural bactericidal composition containing triazole bactericidal agent and preparation method thereof
CN110786159B (en) * 2019-11-26 2022-02-08 宾川县云福农副产品加工有限责任公司 Citrus seedling growing method
CN114431237A (en) * 2020-11-03 2022-05-06 浙江省化工研究院有限公司 Pesticide composition

Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003201280A (en) * 2001-10-24 2003-07-18 Nissan Chem Ind Ltd Acrylonitrile compound
JP2003206281A (en) * 2002-01-10 2003-07-22 Nissan Chem Ind Ltd Acrylonitrile compound
CN101367784A (en) * 2008-09-28 2009-02-18 江苏省农药研究所股份有限公司 Vinyl cyanide compounds, preparation and application thereof
CN101875633A (en) * 2009-04-29 2010-11-03 中国中化股份有限公司 Pyrazolyl acrylonitrile compound and application thereof
CN103651381A (en) * 2012-09-24 2014-03-26 中国中化股份有限公司 Acaricidal preparation and application thereof

Family Cites Families (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1227229C (en) * 1996-04-25 2005-11-16 日产化学工业株式会社 Ethylene derivatives and pest controlling agents
JP2008150302A (en) * 2006-12-15 2008-07-03 Nissan Chem Ind Ltd Insecticidal or acaricidal composition

Patent Citations (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP2003201280A (en) * 2001-10-24 2003-07-18 Nissan Chem Ind Ltd Acrylonitrile compound
JP2003206281A (en) * 2002-01-10 2003-07-22 Nissan Chem Ind Ltd Acrylonitrile compound
CN101367784A (en) * 2008-09-28 2009-02-18 江苏省农药研究所股份有限公司 Vinyl cyanide compounds, preparation and application thereof
CN101875633A (en) * 2009-04-29 2010-11-03 中国中化股份有限公司 Pyrazolyl acrylonitrile compound and application thereof
CN103651381A (en) * 2012-09-24 2014-03-26 中国中化股份有限公司 Acaricidal preparation and application thereof

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