CN109467846A - A kind of wear-resisting resistance to migration high resiliency foot pad material - Google Patents
A kind of wear-resisting resistance to migration high resiliency foot pad material Download PDFInfo
- Publication number
- CN109467846A CN109467846A CN201811298417.5A CN201811298417A CN109467846A CN 109467846 A CN109467846 A CN 109467846A CN 201811298417 A CN201811298417 A CN 201811298417A CN 109467846 A CN109467846 A CN 109467846A
- Authority
- CN
- China
- Prior art keywords
- foot pad
- parts
- wear
- high resiliency
- resisting resistance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
- C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
- C08L27/06—Homopolymers or copolymers of vinyl chloride
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Footwear And Its Accessory, Manufacturing Method And Apparatuses (AREA)
Abstract
The invention discloses a kind of wear-resisting resistance to migration high resiliency foot pad materials, are made of the raw material of following parts by weight: polyvinyl chloride, methyl hydrogen silicone resin, allyl glycidyl ether, vinyl ester resin, toluene, nitrile rubber, n-butyl cholroacetate, buttress rubber, plasticizer, anti-aging agent, stabilizer, promotor, crosslinking agent, carbon black, snake mountain flour, illite powder, sorbierite, chloroplatinic acid, ethyl alcohol.The wear-resisting resistance to migration high resiliency foot pad material of disclosure of the invention, have the characteristics that be laid with light, novel appearance, and there is good wearability, antiskid, waterproofness, and toughness, stiffness and the elasticity of appropriateness, whole texture is good, and cold-resistant, ageing-resistant, folding, good permeability, rubber and plastic mixing, cost is reduced, there is artificial leather texture.
Description
Technical field
The invention belongs to technical field of polymer materials, and in particular to a kind of wear-resisting resistance to migration high resiliency foot pad material.
Background technique
Foot pad be include one of important accessories of sphere of life such as automobile interior decoration, household interior trim, be seen everywhere, and application is wide
It is general, there is application in terms of the sides such as bathroom, automobile, entry, track train, bed steps, foot pad is as daily necessities in life
Every aspect, effect mainly protect base from wearing and staiing.Foot pad pad, which is asked, to be conveniently replaceable and cleans, thus living must
Spare unit, this is one of the outstanding advantages that foot pad has.Currently on the market, divide from material, mainly include plastic foot pad and fabric
Foot pad and corium foot pad.Plastics mat generallys use the techniques such as molding, plastic uptake, removes bound edge from；Fabric mat then mainly has needle thorn
Two class of flannelette and tufting flannelette, it is most of to be punched bound edge again for plane.Its cost and class sort from high to low, are followed successively by true
Skin, tufting, needle pierce plastics.The above material respectively has advantage and disadvantage, and in different applications.
Footbed product capability and performance directly affects the safety of the users such as automobile driver, train passenger,
2 months 2010 Toyota Motor Corporation because pedal pad product causes safety accident carried out it is great recall, because bath mat slide
Caused by contingency it is also commonplace, baby bed foot of ladder pads the unhealthful weight for also causing people extensively of volatile contaminant
Depending on and deep thinking.Currently, in the market, if automobile foot pad encloses wire foot pad using flocking, PVC, plasticizer is easy to migrate, and product is not
It is wear-resisting, and dust spot is not easily cleaned, product quality is irregular, and ichthyosauru mixes pearl, bathroom PVC, PE foot pad, elastic comfort
Poor, when temperature is low, body-sensing is harder, presses against foot, and skid resistance is bad, and fabric foot pad again because of water suction, hide dirt and receive by Yi Zisheng bacterium
Dirt, not easy to clean and use, is not used widely, part foot pad embodies a concentrated expression of the safety problem of safety, smell etc.
Also another consumer's worry, and the comfortable high-grade corium foot pad of elasticity, and higher cost, and cannot get the extensive of ordinary consumer
Using.
It is always desirable with the comfortable smooth inexpensive substitute of corium foot pad elasticity, it is required that wearability
It is superior to natural skin foot pad with waterproofness, has the characteristics that be laid with light, novel appearance, and there is good wearability, anti-skidding
Move, waterproofness, and appropriateness toughness and stiffening property the features such as.If foot pad needs stamp and spraying, should also have and post-process material
Expect the preferable feature of bond properties.Currently, either what type of mat, prevents it elastic, practicability in sliding, increase
Method can be attributed to two kinds: first is that changing the frictional force that physical appearance increases the mat back side and carpeting surface；Second is that will
Mat is fixed on matrix.If anti-skidding back applies, fabric is compound, fixation is anti-skidding etc., production cost is not only increased with upper type, and
And aggravated the burden of cleaning, mobile portability, foot pad itself has removable, the outstanding advantages of waterproof easy cleaning instead by
It significantly limits, anti-skidding processing is put the cart before the horse from effect.
Chinese patent " CN105059164A " discloses a kind of automatic foot-mat material, includes flame-retardant modified vinyl chloride；It is described
Flame-retardant modified vinyl chloride is provided with one layer of high Breathable nonwoven on one side, and another side is provided with one layer of melamine foam；This hair
It is bright that there are the excellent properties such as self-cleaning high ventilative, high damping, high decontamination, the anti-peculiar smell of height, light-weight, it drives comfortably to increase
Degree is provided with high Breathable nonwoven on one side, and non-woven fabrics water absorption rate is high, easily shelters evil people and countenance evil practices, long-time service may have smelly
Itself advantage of taste, foot pad easy cleaning is weakened, and limits its extensive use instead.
As those skilled in the art, it would be highly desirable to develop that corresponding comfort level is high, low in cost, wear-resisting antiskid, fire retardant elastic
Foot pad material that is excellent, preventing old resistance to migration, easy cleaning.
Summary of the invention
The purpose of the present invention is being directed to existing problem, a kind of wear-resisting resistance to migration high resiliency foot pad material is provided.
The invention is realized by the following technical scheme:
A kind of wear-resisting resistance to migration high resiliency foot pad material, is made of the raw material of following parts by weight: 116 ~ 119 parts of polyvinyl chloride,
37 ~ 45 parts of methyl hydrogen silicone resin, 33 ~ 47 parts of allyl glycidyl ether, 33 ~ 47 parts of vinyl ester resin, toluene 43 ~ 64
Part, 7 ~ 13 parts of nitrile rubber, 13 ~ 21 parts of n-butyl cholroacetate, 5 ~ 7 parts of buttress rubber, 19 ~ 33 parts of plasticizer,
0.5 ~ 1.5 part of anti-aging agent, 1 ~ 3 part of stabilizer, 0.4 ~ 0.7 part of promotor, 0.5 ~ 2 part of crosslinking agent, 23 ~ 34 parts of carbon black, serpentine
13 ~ 21 parts of powder, 13 ~ 26 parts of illite powder, 0.3 ~ 1.5 part of sorbierite, 0.01 ~ 0.1 part of chloroplatinic acid, 2 ~ 5 parts of ethyl alcohol.
A kind of preparation method of wear-resisting resistance to migration high resiliency foot pad material, includes the following steps: each original of (1) precise
Material, in a kettle, be added methyl hydrogen silicone resin, the allyl glycidyl ether of total amount half, total amount half toluene, stir
Mix down and be heated to 65 DEG C, keep 10 ~ 15min, after being cooled to 45 DEG C, chloroplatinic acid is dissolved in the solution formed after ethyl alcohol, dropwise plus
Enter in reaction kettle, be heated to 110 ~ 115 DEG C, after being stirred to react 20 ~ 30min, adds remaining allyl glycidyl ether, residue
Toluene, vinyl ester resin stir 30 ~ 40min of lower heating, then are warming up to 115 ~ 120 DEG C and continue after stirring 1h, 100 DEG C of dryings
1h obtains epoxy-modified hydrogeneous silicone resin；(2) by epoxy-modified hydrogeneous silicone resin, n-butyl cholroacetate, butyronitrile
Rubber, buttress rubber are plasticated respectively puts into 3 ~ 7min of mixer mixing after 5 ~ 10min, puts into anti-aging agent, obtains just refining glue；(3) will
Plasticizer is added after mixing and after 60 ~ 65 DEG C of temperature arrival in load weighted polyvinyl chloride, stabilizer, sorbierite, and stirring is extremely
Powder is smooth, after not viscous group, adds carbon black, snake mountain flour, illite powder row and is sufficiently mixed, obtains mixture；(4) by mixture
Put into mixer the 3 ~ 5min of mixing that pressurizes at 115 ~ 130 DEG C with first refining glue, pressure is cooled at 80 DEG C, be added promotor and
Crosslinking agent, after turning refining uniformly, slice；(5) sheet material being kneaded is hot-forming in compression molding agent, molding temperature is set as
150 DEG C ~ 165 DEG C, molding pressure is 16 ~ 25MPa；(6) after the foot pad after cutting vulcanization, surface silk is carried out to the foot pad after vulcanization
Print, stamp, spraying, wire drawing process to get.
Further, the promotor is the di n butyl xanthogen disulfide, butyl dithiocarbonic acids zinc, two sulphur
Change one of or several combination of bisbenzimidazole.
Further, the n-butyl cholroacetate, butyl acrylate content accounting are that 12 ~ 14%, K value is
60 ~ 65, the polyvinyl chloride is SG-3 resin-oatmeal, and the vinyl ester resin is acrylic modified bisphenol type epoxy tree
Epoxy-type vinyl ester resin, 500 ~ 650mpas of viscosity at 25 DEG C, the hydrogeneous rate of methyl hydrogen silicone resin are 0.7-1%.
Further, the stabilizer be poly- tin glycol lauric acid-maleate, calcium benzoate, zinc ricinate its
Middle one or more combination.
Further, the plasticizer is the one of which of triacetyl glycerine, glyceryl laurate ester, cyclohexane carboxylate
Or several combinations.
Further, the illite powder is illite geopolymer powder.
Further, the anti-aging agent is 1,4 Er Benzyl base benzene, Pyrogentisinic Acid's list benzyl oxide and 2- thionaphthol according to mass fraction ratio
Complex antiager made of being compounded for 1 ~ 3:2 ~ 3:1 ~ 2.
Beneficial effects of the present invention:
Surface can be carried out to material using sorbierite agent to be modified, by physics and chemical action, filler surface is made to organise, from
And preventing filler grain from reuniting, particle is uniformly distributed with primary partical state, and filler part is with the presence of nanoparticle state, therefore
Applied to dispersibility and compatibility in composite processing system, can not only be improved, improve system liquidity and processing performance, and
And assign the preferable physical and mechanical property of product and achieve the effect that toughened and reinforced, and there are certain stabilization, lubrication, anti-corrosion effect.
Carbon black, illite powder geopolymer have good resistance to ag(e)ing, and supplementary material intensity.The addition of snake powder mountain flour improves material
Heat resistance, it is low in cost.Vinyl ester resin not only improves the corrosion resistance and heat resistance of material, also mentions and does the well-pressed of material
Property, further increase the texture of material, and with silicone resin have it is good cooperate with facilitation, improve wearability.Vinyl chloride-propylene
Butyl acrylate copolymer reduces the order of strand due to the introducing of butyl acrylate, increases Copolymer Melts mobility,
Toughness and cold resistance are improved.Butyl acrylate plays the role of internally plasticized in the copolymer, it is possible to reduce plasticizer makes
With reducing the risk of migration.Reasonable auxiliary agent collocation makes ageing-resistant, good, anti-corrosion of thermal stability of material etc. have good effect
Effect.
Epoxy-modified silicone resin is added to replace part small molecule liquid plasticizer in PVC, main purpose is by high score
Elastic body is not as the migrating of PVC, nonvolatile permanent plasticizer, to improve materials ' durability.Therefore, selected epoxy
Blending and modifying agent of the modified hydrogeneous silicone resin as PVC, has good compatibility between epoxy-modified hydrogeneous silicone resin and PVC,
And epoxy-modified hydrogeneous silicone resin, it is good with PVC compatibility containing epoxy group, and there is stabilizer function, not only improve its heat
Stability also reduces the use of stabilizer, reduces production cost.In this blend system, epoxy-modified Silicon Containing Hydrogen tree
Rouge itself is hydrogeneous to have good weatherability, and epoxy-modified hydrogeneous silicone resin and liquid plasticizer compatibility are fine, can be with
The volatilization of liquid plasticizer is reduced, the weatherability of blend is further improved, and further increases the resistance to low temperature of material,
Can improve the surface property of material, change it is smooth comfortable.
Nitrile rubber is introduced, macromolecular plasticizer can be played the role of, the volatilization of plasticizer is avoided or reduced, mention
The durability of high material not only can be improved plasticizer durability, but also can improve its mechanical property.Fourth is introduced in the material
Nitrile rubber, the performances such as tensile strength increase with dosage and are in the gesture of rising, and wearability further increases, and can also reduce material
Compression set improves its elasticity, can also improve the resistance to deflection of material.And the present invention has found in practice process, adds
Epoxy-modified hydrogeneous silicone resin and buttress rubber are added, good coordination plasticizing effect can be formed, has made effect compatible with PVC itself
The bad buttress rubber of fruit, can also play the effect of toughening, and enhance anti-slipping property, improve processing performance and reduce at
This, is additionally added illite powder geopolymer, with improve wearability and tensile strength, if coupling agent is used in sizing material, into one
Step reduces material cost.
The present invention has the advantage that compared with prior art
The wear-resisting resistance to migration high resiliency foot pad material of one kind disclosed by the invention can not only save rubber sources, reduce cost, change
The physical property and processing performance of kind foot pad, can also increase foot pad kind, light and beautiful, flexible high-performance foot pad,
Oil resistant foot pad with chemical proof and cold resistance and the ozone aging resistance of the diaphragm, and surface property itself is good, resistant slide, without carrying on the back
The processing such as painting, fabric reinforcement, just there is good resistant slide effect；The wear-resisting resistance to migration high resiliency foot pad material of one kind disclosed by the invention
Material, reduce migration of plasticizer, be exactly like corium foot pad in appearance, wearability and waterproofness are superior to corium foot pad, have it is light,
Easy cleaning, clean surface, comfort level are high, low in cost, wear-resisting antiskid, fire retardant elastic is excellent, prevent the foot pad material of old resistance to migration.
Specific embodiment
Illustrate the present invention with specific embodiment below, but is not limitation of the present invention.
Embodiment 1
A kind of wear-resisting resistance to migration high resiliency foot pad material, is made: 119 parts of polyvinyl chloride, methyl of the raw material of following parts by weight
45 parts of hydrogeneous silicone resin, 47 parts of allyl glycidyl ether, 47 parts of vinyl ester resin, 64 parts of toluene, 13 parts of nitrile rubber, chlorine
21 parts of ethylene-butyl acrylate copolymer, 7 parts of buttress rubber, 33 parts of plasticizer, 1.5 parts of anti-aging agent, 3 parts of stabilizer, promotor
0.7 part, 2 parts of crosslinking agent, 34 parts of carbon black, 21 parts of snake mountain flour, 26 parts of illite powder, 1.5 parts of sorbierite, 0.1 part of chloroplatinic acid, second
5 parts of alcohol.
A kind of preparation method of wear-resisting resistance to migration high resiliency foot pad material, includes the following steps: each original of (1) precise
Material, in a kettle, be added methyl hydrogen silicone resin, the allyl glycidyl ether of total amount half, total amount half toluene, stir
It mixes down and is heated to 65 DEG C, keep 15min, after being cooled to 45 DEG C, chloroplatinic acid is dissolved in the solution formed after ethyl alcohol, be added dropwise anti-
It answers in kettle, is heated to 115 DEG C, after being stirred to react 30min, add remaining allyl glycidyl ether, residual toluene, vinyl
Ester resin stirs 30 ~ 40min of lower heating, then is warming up to 120 DEG C and continues after stirring 1h, and 100 DEG C of dry 1h obtain epoxy-modified contain
Hydrogen silicone resin；(2) by epoxy-modified hydrogeneous silicone resin, n-butyl cholroacetate, nitrile rubber, buttress rubber point
It does not plasticate and puts into mixer mixing 7min after 10min, put into anti-aging agent, obtain just refining glue；(3) by load weighted polyvinyl chloride, steady
Determine agent, sorbierite after mixing and temperature reach 65 DEG C after be added plasticizer, stirring to powder is smooth, after not viscous group, then plus
Enter carbon black, snake mountain flour, illite powder row to be sufficiently mixed, obtains mixture；(4) mixture and first refining glue are put into mixer
Pressurize mixing 5min at 130 DEG C, and pressure is cooled at 80 DEG C, and promotor and crosslinking agent is added, after turning refining uniformly, slice；(5) will
The sheet material being kneaded is hot-forming in compression molding agent, and molding temperature is set as 165 DEG C, molding pressure 25MPa；(6) it cuts
After foot pad after vulcanization, to after vulcanization foot pad carry out surface silk-screen, stamp, spraying, wire drawing process to get.
Further, the promotor is the di n butyl xanthogen disulfide, butyl dithiocarbonic acids zinc, two sulphur
Change the combination of bisbenzimidazole.
Further, the n-butyl cholroacetate, butyl acrylate content accounting are that 12 ~ 14%, K value is
60 ~ 65, the polyvinyl chloride is SG-3 resin-oatmeal, and the vinyl ester resin is acrylic modified bisphenol type epoxy tree
Epoxy-type vinyl ester resin, viscosity 600mpas at 25 DEG C, the hydrogeneous rate of methyl hydrogen silicone resin are 1%.
Further, the stabilizer is the group of poly- tin glycol lauric acid-maleate, calcium benzoate, zinc ricinate
It closes.
Further, the plasticizer is the combination of triacetyl glycerine, glyceryl laurate ester, cyclohexane carboxylate.
Further, the illite powder is illite geopolymer powder.
Further, the anti-aging agent is 1,4 Er Benzyl base benzene, Pyrogentisinic Acid's list benzyl oxide and 2- thionaphthol according to mass fraction ratio
For complex antiager made of 1:2:2 compounding.
Embodiment 2
A kind of wear-resisting resistance to migration high resiliency foot pad material, is made: 116 parts of polyvinyl chloride, methyl of the raw material of following parts by weight
37 parts of hydrogeneous silicone resin, 33 parts of allyl glycidyl ether, 33 parts of vinyl ester resin, 43 parts of toluene, 7 parts of nitrile rubber, chlorine
13 parts of ethylene-butyl acrylate copolymer, 5 parts of buttress rubber, 19 parts of plasticizer, 0.5 part of anti-aging agent, 1 part of stabilizer, promotor
0.4 part, 1 part of crosslinking agent, 27 parts of carbon black, 18 parts of snake mountain flour, 17 parts of illite powder, 1 part of sorbierite, 0.06 part of chloroplatinic acid, second
4 parts of alcohol.
A kind of preparation method of wear-resisting resistance to migration high resiliency foot pad material, includes the following steps: each original of (1) precise
Material, in a kettle, be added methyl hydrogen silicone resin, the allyl glycidyl ether of total amount half, total amount half toluene, stir
It mixes down and is heated to 65 DEG C, keep 10min, after being cooled to 45 DEG C, chloroplatinic acid is dissolved in the solution formed after ethyl alcohol, be added dropwise anti-
It answers in kettle, is heated to 110 DEG C, after being stirred to react 20min, add remaining allyl glycidyl ether, residual toluene, vinyl
Ester resin stirs lower heating 30min, then is warming up to 115 DEG C and continues after stirring 1h, and 100 DEG C of dry 1h obtain epoxy-modified Silicon Containing Hydrogen
Resin；(2) epoxy-modified hydrogeneous silicone resin, n-butyl cholroacetate, nitrile rubber, buttress rubber are moulded respectively
Mixer mixing 3min is put into after refining 5min, puts into anti-aging agent, obtains just refining glue；(3) by load weighted polyvinyl chloride, stabilizer,
Sorbierite after mixing and temperature reach 60 DEG C after be added plasticizer, stirring is to powder is smooth, after not viscous group, adds charcoal
Black, snake mountain flour, illite powder row are sufficiently mixed, and obtain mixture；(4) mixture and first refining glue are put into 120 in mixer
Pressurize 3 ~ 5min of mixing at DEG C, and pressure is cooled at 80 DEG C, and promotor and crosslinking agent is added, after turning refining uniformly, slice；(5) will
The sheet material being kneaded is hot-forming in compression molding agent, and molding temperature is set as 150 DEG C ~ 165 DEG C, molding pressure 20MPa；
(6) cut vulcanization after foot pad after, to after vulcanization foot pad carry out surface silk-screen, stamp, spraying, wire drawing process to get.
Further, the promotor is the di n butyl xanthogen disulfide, butyl dithiocarbonic acids zinc, two sulphur
Change one of or several combination of bisbenzimidazole.
Further, the n-butyl cholroacetate, butyl acrylate content accounting are that 12 ~ 14%, K value is
60 ~ 65, the polyvinyl chloride is SG-3 resin-oatmeal, and the vinyl ester resin is acrylic modified bisphenol type epoxy tree
Epoxy-type vinyl ester resin, viscosity 650mpas at 25 DEG C, the hydrogeneous rate of methyl hydrogen silicone resin are 0.8%.
Further, the stabilizer be poly- tin glycol lauric acid-maleate, calcium benzoate, zinc ricinate its
Middle one or more combination.
Further, the plasticizer is the one of which of triacetyl glycerine, glyceryl laurate ester, cyclohexane carboxylate
Or several combinations.
Further, the illite powder is illite geopolymer powder.
Further, the anti-aging agent is 1,4 Er Benzyl base benzene, Pyrogentisinic Acid's list benzyl oxide and 2- thionaphthol according to mass fraction ratio
For complex antiager made of 1:3:1 compounding.
Comparative example 1
This comparative example compared with Example 2, weighs in step in raw material, saves n-butyl cholroacetate ingredient, removes
Furthermore method and step is all the same.
Comparative example 2
This comparative example compared with Example 2, is saved step (1), and remaining step is also free of the modified hydrogeneous silicone resin of modified epoxy, is removed
Furthermore method and step is all the same.
Comparative example 3
This comparative example compared with Example 2, weighs in step in raw material, saves vinyl ester resin ingredient, method in addition to this
Step is all the same.
Comparative example 4
This comparative example compared with Example 2, weighs in step in raw material, saves buttress rubber ingredient, method and step in addition to this
It is all the same.
Comparative example 5
This comparative example compared with Example 2, weighs in step in raw material, saves snake mountain flour and illite powder ingredient, in addition to this
Method and step it is all the same.
The performance test conditions and method of each embodiment and comparative example material of table 1
The performance test results of each embodiment and comparative example foot pad material of table 2
The wear-resisting resistance to migration high resiliency foot pad material of one kind disclosed by the invention is not only wear-resisting it can be seen from the test result of table 1
Property it is good, shrinkage is small, heat-resist, cold cycling resistance capacity is strong, good flame resistance, water resistant mark and surface damage, salt erosion and takes off
Color, spatter property be good, mould proof, odorlessness, skid resistance and resistance to migration are excellent, can be widely applied to automatic foot-mat, bath mat,
The preparation and production of the products such as bed steps foot pad, floor foot pad.
Claims (8)
1. a kind of wear-resisting resistance to migration high resiliency foot pad material, which is characterized in that be made of the raw material of following parts by weight: polychlorostyrene second
116 ~ 119 parts of alkene, 37 ~ 45 parts of methyl hydrogen silicone resin, 33 ~ 47 parts of allyl glycidyl ether, vinyl ester resin 33 ~ 47
Part, increases 43 ~ 64 parts of toluene, 7 ~ 13 parts of nitrile rubber, 13 ~ 21 parts of n-butyl cholroacetate, 5 ~ 7 parts of buttress rubber
Mould 19 ~ 33 parts of agent, 0.5 ~ 1.5 part of anti-aging agent, 1 ~ 3 part of stabilizer, 0.4 ~ 0.7 part of promotor, 0.5 ~ 2 part of crosslinking agent, carbon black 23 ~
34 parts, 13 ~ 21 parts of snake mountain flour, 13 ~ 26 parts of illite powder, 0.3 ~ 1.5 part of sorbierite, 0.01 ~ 0.1 part of chloroplatinic acid, ethyl alcohol 2 ~ 5
Part.
2. the wear-resisting resistance to migration high resiliency foot pad material of one kind as described in wooden fork benefit requires 1, which is characterized in that the promotor is institute
State di n butyl xanthogen disulfide, butyl dithiocarbonic acids zinc, one of or several group of dibenzimidazole disulfide
It closes.
3. a kind of wear-resisting resistance to migration high resiliency foot pad material as described in claim 1, which is characterized in that the vinyl chloride-the third
Olefin(e) acid acrylate copolymer, butyl acrylate content accounting are that 12 ~ 14%, K value is 60 ~ 65, and the polyvinyl chloride is SG-3 resin
Powder, the vinyl ester resin are acrylic modified bisphenol A type epoxy resin type vinyl ester resin, viscosity at 25 DEG C
500 ~ 650mpas, the hydrogeneous rate of methyl hydrogen silicone resin are 0.7-1%.
4. a kind of wear-resisting resistance to migration high resiliency foot pad material as described in claim 1, which is characterized in that the stabilizer is poly-
One of or several combination of tin glycol lauric acid-maleate, calcium benzoate, zinc ricinate.
5. a kind of wear-resisting resistance to migration high resiliency foot pad material as described in claim 1, which is characterized in that the plasticizer three
One of or several combination of acetoglyceride, glyceryl laurate ester, cyclohexane carboxylate.
6. wear-resisting resistance to migration high resiliency foot pad material as described in claim 1 a kind of, which is characterized in that the illite powder is
Illite geopolymer powder.
7. a kind of wear-resisting resistance to migration high resiliency foot pad material as described in claim 1, which is characterized in that the anti-aging agent is 1,
4 Er Benzyl base benzene, Pyrogentisinic Acid's list benzyl oxide and 2- thionaphthol are compound anti-old made of compounding according to mass fraction ratio for 1 ~ 3:2 ~ 3:1 ~ 2
Agent.
8. a kind of preparation method of wear-resisting resistance to migration high resiliency foot pad material as described in claim 1, which is characterized in that including
Following steps: (1) allyl glycidyl of methyl hydrogen silicone resin, total amount half is added in a kettle in each raw material of precise
The toluene of glycerin ether, total amount half is heated to 65 DEG C under stirring, 10 ~ 15min is kept to be dissolved in chloroplatinic acid after being cooled to 45 DEG C
The solution formed after ethyl alcohol, is added dropwise in reaction kettle, is heated to 110 ~ 115 DEG C, after being stirred to react 20 ~ 30min, adds surplus
Remaining allyl glycidyl ether, residual toluene, vinyl ester resin stir 30 ~ 40min of lower heating, then are warming up to 115 ~ 120 DEG C
Continue after stirring 1h, 100 DEG C of dry 1h obtain epoxy-modified hydrogeneous silicone resin；(2) by epoxy-modified hydrogeneous silicone resin, vinyl chloride-
Butyl acrylate copolymer, nitrile rubber, buttress rubber plasticate put into 3 ~ 7min of mixer mixing after 5 ~ 10min respectively, investment
Anti-aging agent obtains just refining glue；(3) by load weighted polyvinyl chloride, stabilizer, sorbierite after mixing and temperature reach 60 ~ 65
It is added plasticizer after DEG C, stirring is to powder is smooth, after not viscous group, it is sufficiently mixed to add carbon black, snake mountain flour, illite powder row
It closes, obtains mixture；(4) mixture and first refining glue are put into the 3 ~ 5min of mixing that pressurizes at 115 ~ 130 DEG C in mixer, forced cold
But at 80 DEG C, promotor and crosslinking agent is added, after turning refining uniformly, slice；(5) by the sheet material being kneaded in compression molding agent
Hot-forming, molding temperature is set as 150 DEG C ~ 165 DEG C, and molding pressure is 16 ~ 25MPa；(6) right after the foot pad after cutting vulcanization
Foot pad after vulcanization carry out surface silk-screen, stamp, spraying, wire drawing process to get.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811298417.5A CN109467846A (en) | 2018-11-02 | 2018-11-02 | A kind of wear-resisting resistance to migration high resiliency foot pad material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811298417.5A CN109467846A (en) | 2018-11-02 | 2018-11-02 | A kind of wear-resisting resistance to migration high resiliency foot pad material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN109467846A true CN109467846A (en) | 2019-03-15 |
Family
ID=65666917
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811298417.5A Pending CN109467846A (en) | 2018-11-02 | 2018-11-02 | A kind of wear-resisting resistance to migration high resiliency foot pad material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN109467846A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110938264A (en) * | 2019-10-23 | 2020-03-31 | 清远高新华园科技协同创新研究院有限公司 | High-molecular fluorescent beautifying colloid film for automobile, preparation method and production equipment |
Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589086A (en) * | 2013-08-30 | 2014-02-19 | 南通市东风特种电线有限公司 | Flexible polyvinyl chloride cable material and preparation method thereof |
| CN103756187A (en) * | 2014-01-02 | 2014-04-30 | 浙江鸿盛原汽车用品有限公司 | PVC (Polyvinyl Chloride) elastomer foot pad and preparation method thereof |
| CN104710701A (en) * | 2013-12-11 | 2015-06-17 | 天津德昊超微新材料有限公司 | Special material of turnover box non-slip mat |
| CN104817791A (en) * | 2015-05-11 | 2015-08-05 | 湖州福泽鞋业有限公司 | Environment-friendly stable-light-emission polyvinyl chloride shoe sole material and preparation method thereof |
| CN106700322A (en) * | 2016-11-21 | 2017-05-24 | 桐乡市同益塑业有限公司 | Automobile foot mat silk-fabric material and preparation method thereof |
| CN108047592A (en) * | 2017-12-04 | 2018-05-18 | 安徽精致汽车饰件有限公司 | A kind of automobile flame-proof Slippery proof foot pad |
| CN108707297A (en) * | 2018-06-15 | 2018-10-26 | 浙江威思康塑胶有限公司 | A kind of heat-proof combustion-resistant PVC injection molding materials |
-
2018
- 2018-11-02 CN CN201811298417.5A patent/CN109467846A/en active Pending
Patent Citations (7)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103589086A (en) * | 2013-08-30 | 2014-02-19 | 南通市东风特种电线有限公司 | Flexible polyvinyl chloride cable material and preparation method thereof |
| CN104710701A (en) * | 2013-12-11 | 2015-06-17 | 天津德昊超微新材料有限公司 | Special material of turnover box non-slip mat |
| CN103756187A (en) * | 2014-01-02 | 2014-04-30 | 浙江鸿盛原汽车用品有限公司 | PVC (Polyvinyl Chloride) elastomer foot pad and preparation method thereof |
| CN104817791A (en) * | 2015-05-11 | 2015-08-05 | 湖州福泽鞋业有限公司 | Environment-friendly stable-light-emission polyvinyl chloride shoe sole material and preparation method thereof |
| CN106700322A (en) * | 2016-11-21 | 2017-05-24 | 桐乡市同益塑业有限公司 | Automobile foot mat silk-fabric material and preparation method thereof |
| CN108047592A (en) * | 2017-12-04 | 2018-05-18 | 安徽精致汽车饰件有限公司 | A kind of automobile flame-proof Slippery proof foot pad |
| CN108707297A (en) * | 2018-06-15 | 2018-10-26 | 浙江威思康塑胶有限公司 | A kind of heat-proof combustion-resistant PVC injection molding materials |
Non-Patent Citations (5)
| Title |
|---|
| 华丽，徐红，郑凤梅: "改性有机硅涂料综述", 《化工科技》 * |
| 张旭之等: "《乙烯衍生物工学》", 31 July 1995, 化学工业出版社 * |
| 潘祖仁等: "《塑料工业手册 聚氯乙烯》", 31 August 1999, 化学工业出版社 * |
| 邓本诚等: "《橡胶并用与橡塑共混技术 性能、工艺与配方》", 30 June 1998, 化学工业出版社 * |
| 黄文润: "《硅油及其应用》", 31 July 2018, 四川科学技术出版社 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110938264A (en) * | 2019-10-23 | 2020-03-31 | 清远高新华园科技协同创新研究院有限公司 | High-molecular fluorescent beautifying colloid film for automobile, preparation method and production equipment |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| DE112011100254T5 (en) | Method for producing a Sillcontrol | |
| US11760835B2 (en) | Curative and method | |
| CN106279860A (en) | A kind of foamed shoe sole and preparation method thereof and shoes | |
| CN106367982B (en) | A kind of automotive seat PVC imitation leather materials and preparation method thereof | |
| AU2012288402A1 (en) | Support for human body parts | |
| US11396578B2 (en) | Curative | |
| CN107200911A (en) | A kind of ultralight high-elastic environment protection sole and preparation method thereof | |
| AU2022279422A1 (en) | Curative | |
| CN108049198A (en) | Artificial leather inorganic agent, artificial leather and preparation method thereof, the vehicle with artificial leather | |
| CN111086313A (en) | Polyurethane elastomer modified PVC synthetic leather and preparation method thereof | |
| CN105602444A (en) | Yoga mat and preparation method | |
| CN109467846A (en) | A kind of wear-resisting resistance to migration high resiliency foot pad material | |
| CN104494256B (en) | A kind of elastomer foamed matting materials of environment-friendly thermoplastic and preparation method thereof | |
| CN109265815B (en) | Modified EVA (ethylene-vinyl acetate) foam material and preparation method thereof | |
| CN108642895A (en) | A kind of aqueous coating automobile artificial leather and preparation method thereof | |
| CN108547158A (en) | A kind of aqueous coating sofa artificial leather and preparation method thereof | |
| CN106811986B (en) | A kind of clean preparation method of TPO modified TPU superfine fiber chemical leather | |
| CN102898698A (en) | Synthetic non-slip rubber for soles and preparation method for synthetic non-slip rubber | |
| CN108001013A (en) | A kind of preparation method of the elastic TPU coiled material floors of environment-protecting and non-poisonous evil | |
| CN109233005A (en) | A kind of Light rubber and preparation method thereof for sole | |
| CN109651834A (en) | A kind of environmentally friendly vehicle foot pad material and preparation method thereof | |
| CN103497413A (en) | Lightweight anti-skid high-wear-resistant rubber material for soles, and preparation method thereof | |
| CN109552468A (en) | A kind of saddle and its production technology | |
| CN104404775A (en) | Production technology for backing-free leather for automobile | |
| CN109337169B (en) | High-elasticity wear-resistant composite foam material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20190315 |