CN108049198A - Artificial leather inorganic agent, artificial leather and preparation method thereof, the vehicle with artificial leather - Google Patents
Artificial leather inorganic agent, artificial leather and preparation method thereof, the vehicle with artificial leather Download PDFInfo
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- CN108049198A CN108049198A CN201810039352.6A CN201810039352A CN108049198A CN 108049198 A CN108049198 A CN 108049198A CN 201810039352 A CN201810039352 A CN 201810039352A CN 108049198 A CN108049198 A CN 108049198A
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0043—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers
- D06N3/0045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by their foraminous structure; Characteristics of the foamed layer or of cellular layers obtained by applying a ready-made foam layer; obtained by compressing, crinkling or crushing a foam layer, e.g. Kaschierverfahren für Schaumschicht
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D169/00—Coating compositions based on polycarbonates; Coating compositions based on derivatives of polycarbonates
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2211/00—Specially adapted uses
- D06N2211/12—Decorative or sun protection articles
- D06N2211/28—Artificial leather
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- Engineering & Computer Science (AREA)
- Chemical & Material Sciences (AREA)
- Textile Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Synthetic Leather, Interior Materials Or Flexible Sheet Materials (AREA)
Abstract
Present invention offer artificial leather inorganic agent, artificial leather and preparation method thereof, the vehicle with artificial leather, the artificial leather inorganic agent, including：The polycarbonate resin fat liquor of 90 110 parts by weight and the auxiliary agent of 89 parts by weight, wherein, the auxiliary agent includes：Curing agent：46 parts by weight；Antifoaming agent：0.05 0.15 parts by weight；Levelling agent：12 parts by weight；Hand feeling agent：13 parts by weight.Artificial leather inorganic agent according to embodiments of the present invention has the characteristics that light shine, low fogging, low smell and low temperature resistant complications are had excellent performance, the artificial leather prepared by the artificial leather inorganic agent has high-wearing feature, meet the requirement of automobile interior product abrasion performance, the preparation method of the artificial leather is simple, easily controllable, suit large area to popularize application.
Description
Technical field
The present invention relates to vehicle accessory manufacturing technology fields, more particularly, to a kind of artificial leather inorganic agent, pass through the people
Artificial leather and prepare the method for the artificial leather and the vehicle with the artificial leather prepared by fabricate-leather inorganic agent.
Background technology
In recent years, with the raising of China's level of consumption, the demand of automobile is also skyrocketed through, with auto output
Increase, automotive interior material is also developing rapidly.Consumer be merely not only when purchasing vehicle value automobile function, security,
External styling etc., more and more consumers are also higher and higher to the durability requirements of interior trim.Therefore, now in interior trim
Design field proposes new requirement to the durability of interior products.
Artificial polyvinyl chloride leather, i.e. PVC artificial leather are the plastics that a kind of appearance, feel can simultaneously replace that it is used like leather
Product.Usually using fabric as base, coat synthetic resin and the addition of various plastics is made.Its substitute as natural leather,
Solve the problems, such as corium resource anxiety and its in process pollution on the environment.PVC artificial leather is because soft with feel
The advantages that soft, lines is clear, finished product good color fastness, wearability, good flame resistance and be widely used in automotive trim field, with
The continuous improvement of auto output, the dosage of automobile using PVC artificial leather are also increasing substantially.
But due to the limitation of common coating PVC artificial leather nature, there are abrasion resistant effect it is bad the problem of, it is long
The phenomenon that time friction is susceptible to coating shedding.
The content of the invention
In view of this, the present invention a kind of artificial leather inorganic agent is provided and the artificial leather that is prepared by the artificial leather inorganic agent and
The method for preparing the artificial leather.
The present invention also provides a kind of vehicles with the artificial leather..
In order to solve the above technical problems, the present invention uses following technical scheme：
The artificial leather inorganic agent of embodiment according to a first aspect of the present invention, including：The polycarbonate resin of 90-110 parts by weight
The auxiliary agent of fat liquor and 8-9 parts by weight, wherein, the auxiliary agent includes：
Curing agent：4-6 parts by weight；
Antifoaming agent：0.05-0.15 parts by weight；
Levelling agent：1-2 parts by weight；
Hand feeling agent：1-3 parts by weight.
Further, the curing agent is polycarbodiimide curing agent, and the antifoaming agent is organic silicon defoamer, described
Levelling agent is makrolon levelling agent, and the hand feeling agent is silicon class hand feeling agent.
Further, further include to adjust the viscosity modifier of viscosity, the viscosity modifier is thickener or viscosity reduction
Agent.
The artificial leather of embodiment according to a second aspect of the present invention, including：
Basal layer；
According to the artificial leather inorganic agent described in above-described embodiment, the artificial leather inorganic agent is coated on the basal layer
Surface, the coated weight of the artificial leather inorganic agent is 40-50g/ ㎡.
Further, the basal layer includes the polyvinyl chloride nonfoamed layer, polyvinyl chloride foam layer and the back of the body that set gradually
Serve as a contrast fabric.
Further, the polyvinyl chloride nonfoamed layer is made of following component：
Corvic：90-110 parts by weight；
Plasticizer：80-90 parts by weight；
Heat stabilizer：4-6 parts by weight；
Colorant：9-11 parts by weight.
Further, the polyvinyl chloride foam layer is made of following component：
Corvic：90-110 parts by weight；
Plasticizer：80-90 parts by weight；
Heat stabilizer：3-5 parts by weight；
Foaming agent：4-5 parts by weight；
Colorant：9-11 parts by weight.
Further, the plasticizer is low volatility linear polymeric plasticizer, synthesis vegetable esters or polyesters are plasticized
One kind in agent, the heat stabilizer are composite epoxy zinc class stabilizer, and the colorant is carbon black, nickel titanium yellow, iron oxide red, dioxy
Change the one or more in titanium, the foaming agent is azodicarbonamide.
The preparation method of the artificial leather of embodiment according to a third aspect of the present invention, comprises the following steps：
Step S1, polyvinyl chloride nonfoamed layer mixture and polyvinyl chloride foam layer mixture are prepared respectively；
Step S2, by the polyvinyl chloride foam layer mixture prepared and the polyvinyl chloride nonfoamed layer mixture
It is sequentially placed into fabric backed upper and carries out calender lamination, obtain semi-finished product；
Step S3, artificial leather inorganic agent according to any one of claim 1-3, shape are coated on the semi-finished product
Into process layer；
Step S4, the semi-finished product after the process layer will be formed to be foamed and be embossed, obtains artificial leather.
The vehicle of embodiment according to a fourth aspect of the present invention, including according to the artificial leather described in above-described embodiment.
The above-mentioned technical proposal of the present invention has the beneficial effect that：
Artificial leather inorganic agent according to embodiments of the present invention has light shine, low fogging, low smell and low temperature resistant tortuosity
Can be excellent the characteristics of, the artificial leather prepared by the artificial leather inorganic agent have high-wearing feature, it is resistance to meet automobile interior product
The requirement of abrasion, the preparation method of the artificial leather is simple, easily controllable, and suit large area to popularize application.
Description of the drawings
Fig. 1 is the structure diagram of the artificial leather of the embodiment of the present invention；
Reference numeral：
Artificial leather 100；
Fabric backed 10；
Polyvinyl chloride foam layer 20；
Polyvinyl chloride nonfoamed layer 30；
Process layer 40.
Specific embodiment
To make the purpose, technical scheme and advantage of the embodiment of the present invention clearer, below in conjunction with the embodiment of the present invention
Attached drawing, the technical solution of the embodiment of the present invention is clearly and completely described.Obviously, described embodiment is this hair
Bright part of the embodiment, instead of all the embodiments.Based on described the embodiment of the present invention, ordinary skill
Personnel's all other embodiments obtained, belong to the scope of protection of the invention.
Artificial leather inorganic agent according to embodiments of the present invention is detailed below.
Artificial leather inorganic agent according to embodiments of the present invention, including：The polycarbonate resin fat liquor of 90-110 parts by weight and
The auxiliary agent of 8-9 parts by weight, wherein, auxiliary agent includes：
Curing agent：4-6 parts by weight；
Antifoaming agent：0.05-0.15 parts by weight；
Levelling agent：1-2 parts by weight；
Hand feeling agent：1-3 parts by weight.
According to one embodiment of present invention, curing agent is polycarbodiimide curing agent, and antifoaming agent defoams for organosilicon
Agent, levelling agent are makrolon levelling agent, and hand feeling agent is silicon class hand feeling agent.
Preferably, in certain specific embodiments of the invention, further include to adjust the viscosity modifier of viscosity, glue
It is thickener or thinner to spend conditioning agent.Wherein, the viscosity of artificial leather inorganic agent is：The artificial leather inorganic agent is through No. 3 Ford cups
The time of base apertures outflow is 30-40 seconds.
Artificial leather inorganic agent according to embodiments of the present invention is especially suitable for PVC artificial leather 100, and the artificial leather inorganic agent is also
There is light shine, low temperature resistant tortuous excellent performance, low fogging and low smell.Wherein, polycarbonate resin emulsion components can
With in the gap of partial penetration to PVC, silicon class hand feeling agent, polycarbodiimide curing agent, machine silicon defoaming agent in auxiliary agent can be with
Increase PVC surface and slide sense, the two mutual cooperation effect can make PVC artificial leather 100 achieve the effect that high abrasion.
As shown in Figure 1, the artificial leather 100 of embodiment according to a second aspect of the present invention, including：
Basal layer；
According to the artificial leather inorganic agent of above-described embodiment, artificial leather inorganic agent is coated on the surface of basal layer, at artificial leather
The coated weight for managing agent is 40-50g/m2。
In other words, surface artificial leather inorganic agent of the artificial leather 100 mainly by basal layer and coated in basal layer forms, people
Coated weight of the fabricate-leather inorganic agent on the surface of basal layer can be 40-50g/m2.By coating above-mentioned reality on the surface of basal layer
The artificial leather inorganic agent of example is applied, can effectively promote the wear-resisting property of artificial leather 100, prevents artificial leather 100 from rubbing because of long-time
The phenomenon that being susceptible to coating shedding.
According to one embodiment of present invention, basal layer includes the polyvinyl chloride nonfoamed layer 30 set gradually, polychlorostyrene second
Alkene foaming layer 20 and fabric backed 10.
That is, basal layer is mainly by polyvinyl chloride nonfoamed layer 30, polyvinyl chloride foam layer 20 and fabric backed 10
Composition, wherein, fitting is set successively from top to down for polyvinyl chloride nonfoamed layer 30, polyvinyl chloride foam layer 20 and fabric backed 10
It puts.
According to one embodiment of present invention, polyvinyl chloride nonfoamed layer 30 is made of following component：
Corvic：90-110 parts by weight；
Plasticizer：80-90 parts by weight；
Heat stabilizer：4-6 parts by weight；
Colorant：9-11 parts by weight.
In certain specific embodiments of the invention, polyvinyl chloride foam layer 20 is made of following component：
Corvic：90-110 parts by weight；
Plasticizer：80-90 parts by weight；
Heat stabilizer：3-5 parts by weight；
Foaming agent：4-5 parts by weight；
Colorant：9-11 parts by weight.
According to one embodiment of present invention, plasticizer for low volatility linear polymeric plasticizer, synthesis vegetable esters or
One kind in polyesters plasticizer, heat stabilizer are composite epoxy zinc class stabilizer, and colorant is carbon black, nickel titanium yellow, iron oxide red, two
One or more in titanium oxide, foaming agent are azodicarbonamide.
As shown in Figure 1, the preparation method of the artificial leather of embodiment according to a third aspect of the present invention, comprises the following steps：
Step S1, polyvinyl chloride nonfoamed layer mixture and polyvinyl chloride foam layer mixture are prepared respectively；
Step S2, the polyvinyl chloride foam layer mixture prepared and polyvinyl chloride nonfoamed layer mixture are sequentially placed into
On fabric backed 10 and calender lamination is carried out, obtains semi-finished product；
Step S3, artificial leather inorganic agent as claimed in one of claims 1-3 is coated on semi-finished product, forms process layer
40；
Step S4, the semi-finished product after formation process layer 40 are foamed and are embossed, obtain artificial leather 100.
That is, the preparation method of the artificial leather of the embodiment of the present invention, it is possible, firstly, to prepare the non-hair of polyvinyl chloride respectively
Alveolar layer mixture and polyvinyl chloride foam layer mixture.Then, by the polyvinyl chloride foam layer mixture prepared and polychlorostyrene second
Alkene nonfoamed layer mixture is sequentially placed on fabric backed 10, and carries out calender lamination, obtains semi-finished product.Secondly, half into
The artificial leather inorganic agent in above-described embodiment is coated on product, forms process layer 40.Finally, by the semi-finished product after formation process layer 40
It is foamed and is embossed, obtain the artificial leather 100 of the embodiment of the present invention.
Artificial leather 100 prepared by the preparation method of artificial leather according to embodiments of the present invention has high-wearing feature, meets vehicle
The requirement of interior products abrasion performance, the preparation method of the artificial leather is simple, easily controllable, and suit large area to popularize application.
The vehicle of embodiment includes the artificial leather 100 prepared in above-described embodiment according to a fourth aspect of the present invention.Due to root
There is above-mentioned technical characteristic according to the artificial leather 100 of the embodiment of the present invention, therefore, vehicle according to embodiments of the present invention also has phase
The technical characteristic answered that is, with high-wearing feature, meets the requirement of automobile interior product abrasion performance.
The other structures of vehicle according to embodiments of the present invention and operation are all to those skilled in the art can be with
Understand and easy to implement, therefore be not described in detail.
The preparation method of the artificial leather of the present invention is described with reference to the accompanying drawings and in conjunction with specific embodiments.
Embodiment 1
As shown in Figure 1, first, by 5 parts by weight curing agent, 0.1 parts by weight antifoaming agent, 1.5 parts by weight levelling agents and 2 weight
Part hand feeling agent is mixed, it is to be mixed uniformly after obtain auxiliary agent.Then, the auxiliary agent of 8.6 parts by weight and the poly- carbon of 100 parts by weight are taken
Acid ester resin lotion is mixed, and adjusts viscosity to the time through No. 3 Ford cup base apertures outflows using viscosity modifier
For 30 seconds, artificial leather inorganic agent is obtained.
Then, by the Corvic of 100 parts by weight, the plasticizer of 85 parts by weight, the heat stabilizer of 5 parts by weight and 10
Weight part of pigment is mixed, and stirring at low speed is carried out under conditions of 1500 revs/min, after stirring at low speed is uniform, then 2600
High-speed stirred is carried out under conditions of rev/min, just batch mixing is obtained after high-speed stirred is uniform.Then, obtained first batch mixing is existed
Mixing is carried out in ten thousand horsepowers of machines, after mixing, then is kneaded in mill agent, it is polychlorostyrene second to be kneaded uniform mixture
Alkene nonfoamed layer mixture.
Secondly, by the Corvic of 100 parts by weight, the plasticizer of 85 parts by weight, the heat stabilizer of 4 parts by weight, 4.2
In the foaming agent of parts by weight and the colorant of 8 parts by weight input mixer, stirring at low speed is carried out under conditions of 1500 revs/min,
Stirring at low speed and then high-speed stirred is carried out under conditions of 2600 revs/min, after the completion for the treatment of high-speed stirred, obtain just batch mixing.
Then, first batch mixing in ten thousand horsepowers of machines is subjected to mixing, after mixing, then is kneaded in mill agent, is kneaded uniform
Mixture is polyvinyl chloride foam layer mixture.
Furthermore polyvinyl chloride nonfoamed layer mixture obtained above and polyvinyl chloride foam layer mixture are knitted with backing
Object 10 is put into togerther in calender, and polyvinyl chloride foam layer mixture and polyvinyl chloride nonfoamed layer mixture are sequentially placed into
Calender lamination is carried out on fabric backed 10, obtains semi-finished product.
Finally, the artificial leather inorganic agent of 45/ ㎡ is coated on the surface of obtained semi-finished product, forms process layer 40.And by shape
It is foamed and is embossed into the semi-finished product after process layer 40 so that the epidermis of artificial leather 100 has more flexibility, also makes artificial leather
100 surfaces print appearance decorative pattern in need, obtain artificial leather 100.
Embodiment 2
As shown in Figure 1, first, by 4 parts by weight curing agent, 0.15 parts by weight antifoaming agent, 1 parts by weight levelling agent and 3 weight
Part hand feeling agent is mixed, it is to be mixed uniformly after obtain auxiliary agent.Then, the auxiliary agent of 9 parts by weight and the poly- carbonic acid of 90 parts by weight are taken
Ester resin emulsion is mixed, and is to the time through No. 3 Ford cup base apertures outflows using viscosity modifier adjusting viscosity
35 seconds, obtain artificial leather inorganic agent.
Then, by the Corvic of 110 parts by weight, the plasticizer of 80 parts by weight, the heat stabilizer of 6 parts by weight and 11
Weight part of pigment is mixed, and stirring at low speed is carried out under conditions of 1100 revs/min, after stirring at low speed is uniform, then 2300
High-speed stirred is carried out under conditions of rev/min, just batch mixing is obtained after high-speed stirred is uniform.Then, obtained first batch mixing is existed
Mixing is carried out in ten thousand horsepowers of machines, after mixing, then is kneaded in mill agent, it is polychlorostyrene second to be kneaded uniform mixture
Alkene nonfoamed layer mixture.
Secondly, by the Corvic of 90 parts by weight, the plasticizer of 90 parts by weight, the heat stabilizer of 3 parts by weight, 5 weights
It measures in the foaming agent of part and the colorant input mixer of 11 parts by weight, stirring at low speed is carried out under conditions of 1100 revs/min, it is low
Speed stirs and then high-speed stirred is carried out under conditions of 2300 revs/min, after the completion for the treatment of high-speed stirred, obtains just batch mixing.So
Afterwards, first batch mixing in ten thousand horsepowers of machines is subjected to mixing, after mixing, then is kneaded in mill agent, is kneaded uniform mixed
It is polyvinyl chloride foam layer mixture to close material.
Furthermore polyvinyl chloride nonfoamed layer mixture obtained above and polyvinyl chloride foam layer mixture are knitted with backing
Object 10 is put into togerther in calender, and polyvinyl chloride foam layer mixture and polyvinyl chloride nonfoamed layer mixture are sequentially placed into
Calender lamination is carried out on fabric backed 10, obtains semi-finished product.
Finally, 50/m is coated on the surface of obtained semi-finished product2Artificial leather inorganic agent, formed process layer 40.And by shape
It is foamed and is embossed into the semi-finished product after process layer 40 so that the epidermis of artificial leather 100 has more flexibility, also makes artificial leather
100 surfaces print appearance decorative pattern in need, obtain artificial leather 100.
Embodiment 3
As shown in Figure 1, first, by 6 parts by weight curing agent, 0.05 parts by weight antifoaming agent, 2 parts by weight levelling agents and 1 weight
Part hand feeling agent is mixed, it is to be mixed uniformly after obtain auxiliary agent.Then, the auxiliary agent of 8 parts by weight and the poly- carbonic acid of 110 parts by weight are taken
Ester resin emulsion is mixed, and is to the time through No. 3 Ford cup base apertures outflows using viscosity modifier adjusting viscosity
40 seconds, obtain artificial leather inorganic agent.
Then, by the Corvic of 90 parts by weight, the plasticizer of 90 parts by weight, the heat stabilizer of 4 parts by weight and 9 weights
Amount part colorant mixed, stirring at low speed is carried out under conditions of 1300 revs/min, after stirring at low speed is uniform, then 2500 turns/
High-speed stirred is carried out under conditions of minute, just batch mixing is obtained after high-speed stirred is uniform.Then, by obtained first batch mixing in ten thousand horses
Mixing is carried out in power machine, after mixing, then is kneaded in mill agent, it is that polyvinyl chloride is non-to be kneaded uniform mixture
Foaming layer mixture.
Secondly, by the Corvic of 110 parts by weight, the plasticizer of 80 parts by weight, the heat stabilizer of 5 parts by weight, 4 weights
It measures in the foaming agent of part and the colorant input mixer of 9 parts by weight, stirring at low speed is carried out under conditions of 1300 revs/min, it is low
Speed stirs and then high-speed stirred is carried out under conditions of 2500 revs/min, after the completion for the treatment of high-speed stirred, obtains just batch mixing.So
Afterwards, first batch mixing in ten thousand horsepowers of machines is subjected to mixing, after mixing, then is kneaded in mill agent, is kneaded uniform mixed
It is polyvinyl chloride foam layer mixture to close material.
Furthermore polyvinyl chloride nonfoamed layer mixture obtained above and polyvinyl chloride foam layer mixture are knitted with backing
Object 10 is put into togerther in calender, and polyvinyl chloride foam layer mixture and polyvinyl chloride nonfoamed layer mixture are sequentially placed into
Calender lamination is carried out on fabric backed 10, obtains semi-finished product.
Finally, the artificial leather inorganic agent of 40/ ㎡ is coated on the surface of obtained semi-finished product, forms process layer 40.And by shape
It is foamed and is embossed into the semi-finished product after process layer 40 so that the epidermis of artificial leather 100 has more flexibility, also makes artificial leather
100 surfaces print appearance decorative pattern in need, obtain artificial leather 100.
The performance detection of the artificial leather 100 prepared according to embodiments of the present invention is as shown in table 1；
Table 1
It should be noted that comparative example 1 is the artificial leather 100 prepared according to existing preparation method, as shown in Table 1, this
The Martindale's wear-resisting test for inventing the artificial leather 100 prepared is maintained at 50000 times without breakage, as a result than existing artificial leather
Wearability improves one times.
The above is the preferred embodiment of the present invention, it is noted that for those skilled in the art
For, without departing from the principles of the present invention, several improvements and modifications can also be made, these improvements and modifications
It should be regarded as protection scope of the present invention.
Claims (10)
1. a kind of artificial leather inorganic agent, which is characterized in that including：Polycarbonate resin fat liquor and the 8-9 weight of 90-110 parts by weight
The auxiliary agent of part is measured, wherein, the auxiliary agent includes：
Curing agent：4-6 parts by weight；
Antifoaming agent：0.05-0.15 parts by weight；
Levelling agent：1-2 parts by weight；
Hand feeling agent：1-3 parts by weight.
2. artificial leather inorganic agent according to claim 1, which is characterized in that the curing agent cures for polycarbodiimide
Agent, the antifoaming agent are organic silicon defoamer, and the levelling agent is makrolon levelling agent, and the hand feeling agent is silicon class feel
Agent.
3. artificial leather inorganic agent according to claim 1, which is characterized in that further include to adjust the viscosity-adjusting agent of viscosity
Agent, the viscosity modifier are thickener or thinner.
4. a kind of artificial leather, which is characterized in that including：
Basal layer；
Artificial leather inorganic agent according to any one of claim 1-3, the artificial leather inorganic agent are coated on the basis
The surface of layer, the coated weight of the artificial leather inorganic agent is 40-50g/ ㎡.
5. artificial leather according to claim 4, which is characterized in that it is non-that the basal layer includes the polyvinyl chloride set gradually
Foaming layer, polyvinyl chloride foam layer and fabric backed.
6. artificial leather according to claim 5, which is characterized in that the polyvinyl chloride nonfoamed layer is by following component system
Into：
Corvic：90-110 parts by weight；
Plasticizer：80-90 parts by weight；
Heat stabilizer：4-6 parts by weight；
Colorant：9-11 parts by weight.
7. artificial leather according to claim 4, which is characterized in that the polyvinyl chloride foam layer is by following component system
Into：
Corvic：90-110 parts by weight；
Plasticizer：80-90 parts by weight；
Heat stabilizer：3-5 parts by weight；
Foaming agent：4-5 parts by weight；
Colorant：9-11 parts by weight.
8. the artificial leather according to claim 6 or 7, which is characterized in that the plasticizer is low volatility linear polymeric
Plasticizer, synthesis vegetable esters or polyesters plasticizer in one kind, the heat stabilizer be composite epoxy zinc class stabilizer, institute
Colorant is stated as the one or more in carbon black, nickel titanium yellow, iron oxide red, titanium dioxide, the foaming agent is azodicarbonamide.
9. a kind of preparation method of artificial leather, which is characterized in that comprise the following steps：
Step S1, polyvinyl chloride nonfoamed layer mixture and polyvinyl chloride foam layer mixture are prepared respectively；
Step S2, by the polyvinyl chloride foam layer mixture prepared and the polyvinyl chloride nonfoamed layer mixture successively
It is placed in fabric backed upper and carries out calender lamination, obtain semi-finished product；
Step S3, artificial leather inorganic agent according to any one of claim 1-3 is coated on the semi-finished product, at formation
Manage layer；
Step S4, the semi-finished product after the process layer will be formed to be foamed and be embossed, obtains artificial leather.
10. a kind of vehicle, which is characterized in that including the artificial leather any one of claim 4-8.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108823995A (en) * | 2018-07-04 | 2018-11-16 | 北京汽车研究总院有限公司 | Artificial leather inorganic agent, artificial polyvinyl chloride leather, preparation method and the usage |
| CN111434738A (en) * | 2019-01-11 | 2020-07-21 | 上海意缂姆化工科技有限公司 | Water-based polycarbonate rain boot gloss oil, preparation method and use method thereof |
| CN112080948A (en) * | 2020-09-10 | 2020-12-15 | 北京汽车集团越野车有限公司 | Polyvinyl chloride artificial leather, preparation method and vehicle |
| CN112431036A (en) * | 2020-11-19 | 2021-03-02 | 苏州贝斯特装饰新材料有限公司 | High-wear-resistance PVC artificial leather post-treatment method and PVC artificial leather |
| CN114536914A (en) * | 2022-03-07 | 2022-05-27 | 北京汽车集团越野车有限公司 | Polyvinyl chloride artificial leather and preparation method thereof |
| CN114713480A (en) * | 2022-04-14 | 2022-07-08 | 无锡市曼优丽新型复合材料有限公司 | Artificial leather for automotive interior and preparation method thereof |
| CN115726198A (en) * | 2022-12-16 | 2023-03-03 | 昆山阿基里斯新材料科技有限公司 | Artificial leather with excellent durability and preparation method thereof |
| CN115807344A (en) * | 2021-09-14 | 2023-03-17 | 南亚塑胶工业股份有限公司 | Polyvinyl chloride artificial leather without foaming structure |
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| CN114713480A (en) * | 2022-04-14 | 2022-07-08 | 无锡市曼优丽新型复合材料有限公司 | Artificial leather for automotive interior and preparation method thereof |
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