CN109467338A - A kind of abrasion-resistance glass stone and preparation method thereof - Google Patents
A kind of abrasion-resistance glass stone and preparation method thereof Download PDFInfo
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- CN109467338A CN109467338A CN201811529231.6A CN201811529231A CN109467338A CN 109467338 A CN109467338 A CN 109467338A CN 201811529231 A CN201811529231 A CN 201811529231A CN 109467338 A CN109467338 A CN 109467338A
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- parts
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- abrasion
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/18—Polyesters; Polycarbonates
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Macromonomer-Based Addition Polymer (AREA)
Abstract
The invention discloses a kind of abrasion-resistance glass stone and preparation method thereof, which includes the raw material of following mass fraction: 60-120 parts of glass particle, 110-130 parts of glass powder, 0.3-0.7 parts of coupling agent, 0.1-0.5 parts of curing agent, 0.2-0.6 parts of promotor, 1-5 parts of mill base and 40-80 parts of unsaturated polyester resin；By above-mentioned raw materials by stirring, compacting and solidification and etc. carry out preparing glass stone.The present invention uses three step curing schedules by adding glass particle in raw material in glass made of stones make in curing process, realizes the bending strength and wearability for improving glass stone slab, so that glass stone slab is suitable for reality requirement wear-resisting to plate and intensity.
Description
Technical field
The present invention relates to glass stone manufacturing field, specifically a kind of abrasion-resistance glass stone and preparation method thereof.
Background technique
Glass stone, usually our the glass stones said be it is a kind of by 90% or more glass crystal is plus resin and other are micro
A kind of artificial synthesized Novel stone of element, it is suppressed under certain physics, electrochemical conditions by special machine
Large-sized plates material, its main material is glass.Glass is that a kind of heated or pressure is easy for becoming liquid mineral,
It is fairly common rock-forming mineral, all has it in three categories rock.Because it is crystallized the latest in igneous rock, usually lack
Few complete crystal face, is filled in mostly among the rock-forming mineral that other are first crystallized.
Glass stone has a wide range of applications in building materials field, such as external wall, windowsill or ground foundation stone, kitchen and bathroom countertop
Deng, it is in great demand, and scrap glass substantial amounts are lived in, environment and personal safety is endangered, if can be by post-consumer glass
Recycling, by special processing technology enable post-consumer glass become production abrasion-resistance glass stone raw material, produce have compared with
The glass stone of good wearability and aesthetics, this is of great advantage to environmental protection.
Summary of the invention
The purpose of the present invention is to provide a kind of abrasion-resistance glass stones, to solve the problems mentioned in the above background technology.
To achieve the above object, the invention provides the following technical scheme:
A kind of abrasion-resistance glass stone, the raw material including following mass fraction: 60-120 parts of glass particle, glass powder 110-130
Part, 0.3-0.7 parts of coupling agent, 0.1-0.5 parts of curing agent, 0.2-0.6 parts of promotor, 1-5 parts of mill base and unsaturated polyester resin
40-80 parts.
A kind of abrasion-resistance glass stone, the raw material including following mass fraction: 80-100 parts of glass particle, glass powder 115-125
Part, 0.4-0.6 parts of coupling agent, 0.2-0.4 parts of curing agent, 0.3-0.5 parts of promotor, 2-4 parts of mill base and unsaturated polyester resin
50-70 parts.
A kind of abrasion-resistance glass stone, the raw material including following mass fraction: 90 parts of glass particle, 120 parts of glass powder, coupling agent
0.5 part, 0.3 part of curing agent, 0.4 part of promotor, 3 parts of mill base and 60 parts of unsaturated polyester resin.
As a further solution of the present invention: the mill base is resin mill base.
As a further solution of the present invention: the specification of the glass particle is 40-70 mesh.
As a further solution of the present invention: the coupling agent is titanate coupling agent.
As a further solution of the present invention: the curing agent is diethylenetriamine.
As a further solution of the present invention: the promotor is cobalt iso-octoate.
A kind of preparation method such as abrasion-resistance glass stone the following steps are included:
Step 1: preparing binder, and coupling agent, curing agent, promotor, mill base and unsaturated polyester resin are put into stirring
It is stirred in machine, stirs evenly to obtain binder A；
Step 2: glass particle, glass powder and binder A are put into blender and are stirred mixing again, is stirred evenly
After discharge, obtain mixture B；
Step 3: it the smooth cloth of mixture B is entered into well press exhausts vacuum and suppress, obtain pressboard C；
Step 4: being distributed into curing oven for pressboard C, point three steps solidification, total curing time 300min；
First step solidification temperature is 60-80 DEG C, curing time 100min；
Second step；Solidification temperature is 80-100 DEG C, curing time 100min；
Third step solidification temperature is 80-100 DEG C, curing time 100min.
Step 5: after ejecting plate, plate is put after fixed frame fixes 8 hours in parallel, then carry out rubbing down.
As a further solution of the present invention: first step solidification temperature is 70 to set DEG C in the step 4；Second step solidification
Temperature is 90 DEG C；Third step solidification temperature is 90 DEG C.
Compared with prior art, the beneficial effects of the present invention are: the present invention is by adding glass in glass made of stones make in raw material
Glass particle, and three step curing schedules are used in curing process, realize the bending strength and wearability for improving glass stone slab,
So that glass stone slab is suitable for reality requirement wear-resisting to plate and intensity.
Specific embodiment
The technical solution of the patent is explained in further detail With reference to embodiment.
Embodiment 1
A kind of abrasion-resistance glass stone, the raw material including following quality: glass particle 60ka, glass powder 110kg, coupling agent
0.3kg, curing agent 0.1kg, promotor 0.2kg, mill base 1kg and unsaturated polyester resin 40kg.
A kind of preparation method of abrasion-resistance glass stone, comprising the following steps:
Step 1: preparing binder, by the coupling agent of above-mentioned quality, curing agent, promotor, mill base and unsaturated polyester (UP) tree
Rouge is put into blender and is stirred, and stirs evenly to obtain binder A；
Step 2: glass particle, glass powder and binder A are put into blender and are stirred mixing again, is stirred evenly
After discharge, obtain mixture B；
Step 3: it the smooth cloth of mixture B is entered into well press exhausts vacuum and suppress, obtain pressboard C；
Step 4: being distributed into curing oven for pressboard C, point three steps solidification, total curing time 300min；First step solidification temperature
Degree is 60 DEG C, curing time 100min；Second step；Solidification temperature is 80 DEG C, curing time 100min；Third step solidification temperature is
80-100 DEG C, curing time 100min.
Step 5: after ejecting plate, plate is put after fixed frame fixes 8 hours in parallel, then carry out rubbing down.
Embodiment 2
A kind of abrasion-resistance glass stone, the raw material including following quality: glass particle 120kg, glass powder 130kg, coupling agent
0.7kg, curing agent 0.5kg, promotor 0.6kg, mill base 5kg and unsaturated polyester resin 80kg.
A kind of preparation method of abrasion-resistance glass stone, comprising the following steps:
Step 1: preparing binder, by the coupling agent of above-mentioned quality, curing agent, promotor, mill base and unsaturated polyester (UP) tree
Rouge is put into blender and is stirred, and stirs evenly to obtain binder A；
Step 2: glass particle, glass powder and binder A are put into blender and are stirred mixing again, is stirred evenly
After discharge, obtain mixture B；
Step 3: it the smooth cloth of mixture B is entered into well press exhausts vacuum and suppress, obtain pressboard C；
Step 4: being distributed into curing oven for pressboard C, point three steps solidification, total curing time 300min；First step solidification temperature
Degree is 80 DEG C, curing time 100min；Second step；Solidification temperature is 100 DEG C, curing time 100min；Third step solidification temperature
It is 100 DEG C, curing time 100min.
Step 5: after ejecting plate, plate is put after fixed frame fixes 8 hours in parallel, then carry out rubbing down.
Embodiment 3
A kind of abrasion-resistance glass stone, the raw material including following quality: glass particle 80kg, glass powder 115kg, coupling agent
0.4kg, curing agent 0.2kg, promotor 0.3kg, mill base 2kg and unsaturated polyester resin 50kg.
A kind of preparation method of abrasion-resistance glass stone, comprising the following steps:
Step 1: preparing binder, by the coupling agent of above-mentioned quality, curing agent, promotor, mill base and unsaturated polyester (UP) tree
Rouge is put into blender and is stirred, and stirs evenly to obtain binder A；
Step 2: glass particle, glass powder and binder A are put into blender and are stirred mixing again, is stirred evenly
After discharge, obtain mixture B；
Step 3: it the smooth cloth of mixture B is entered into well press exhausts vacuum and suppress, obtain pressboard C；
Step 4: being distributed into curing oven for pressboard C, point three steps solidification, total curing time 300min；First step solidification temperature
Degree is 60 DEG C, curing time 100min；Second step；Solidification temperature is 80 DEG C, curing time 100min；Third step solidification temperature is
80-100 DEG C, curing time 100min.
Step 5: after ejecting plate, plate is put after fixed frame fixes 8 hours in parallel, then carry out rubbing down.
Embodiment 4
A kind of abrasion-resistance glass stone, the raw material including following quality: glass particle 100kg, glass powder 125kg, coupling agent
0.6kg, curing agent 0.4kg, promotor 0.5kg, mill base 4kg and unsaturated polyester resin 70kg.
A kind of preparation method of abrasion-resistance glass stone, comprising the following steps:
Step 1: preparing binder, by the coupling agent of above-mentioned quality, curing agent, promotor, mill base and unsaturated polyester (UP) tree
Rouge is put into blender and is stirred, and stirs evenly to obtain binder A；
Step 2: glass particle, glass powder and binder A are put into blender and are stirred mixing again, is stirred evenly
After discharge, obtain mixture B；
Step 3: it the smooth cloth of mixture B is entered into well press exhausts vacuum and suppress, obtain pressboard C；
Step 4: being distributed into curing oven for pressboard C, point three steps solidification, total curing time 300min；First step solidification temperature
Degree is 80 DEG C, curing time 100min；Second step；Solidification temperature is 100 DEG C, curing time 100min；Third step solidification temperature
It is 100 DEG C, curing time 100min.
Step 5: after ejecting plate, plate is put after fixed frame fixes 8 hours in parallel, then carry out rubbing down.
Embodiment 5
A kind of abrasion-resistance glass stone, the raw material including following quality: glass particle 90kg, glass powder 120kg, coupling agent
0.5kg, curing agent 0.3kg, promotor 0.4kg, mill base 3kg and unsaturated polyester resin 60kg.
A kind of preparation method of abrasion-resistance glass stone, comprising the following steps:
Step 1: preparing binder, by the coupling agent of above-mentioned quality, curing agent, promotor, mill base and unsaturated polyester (UP) tree
Rouge is put into blender and is stirred, and stirs evenly to obtain binder A；
Step 2: glass particle, glass powder and binder A are put into blender and are stirred mixing again, is stirred evenly
After discharge, obtain mixture B；
Step 3: it the smooth cloth of mixture B is entered into well press exhausts vacuum and suppress, obtain pressboard C；
Step 4: being distributed into curing oven for pressboard C, point three steps solidification, total curing time 300min；First step solidification temperature
Degree is 70 DEG C, curing time 100min；Second step；Solidification temperature is 90 DEG C, curing time 100min；Third step solidification temperature is
90 DEG C, curing time 100min.
Step 5: after ejecting plate, plate is put after fixed frame fixes 8 hours in parallel, then carry out rubbing down.
Comparative example, as a comparison case using commercially available glass slabstone.
Performance test
Glass slabstone number consecutively 1-6 is made in glass slabstone and comparative example prepared by embodiment 1-5, carries out bending resistance respectively
The test of intensity and wear intensity test, standard testing of the wear intensity test according to SN/T 0308-93.Test result obtains table one.
Table one
| Number | Bending strength (MPa) | Wear intensity (g/cm3) |
| 1 | 246.7 | 2.98×10-5 |
| 2 | 248.5 | 3.14×10-5 |
| 3 | 252.9 | 2.70×10-5 |
| 4 | 248.4 | 2.64×10-5 |
| 5 | 256.7 | 2.16×10-5 |
| 6 | 198.5 | 9.74×10-4 |
It could be aware that from the data of the performance test in table one, be added to glass particle and produced by three step curing process
Glass stone slab bending strength significantly improve, while wear intensity substantially reduces, that is, possesses better wear-resisting property.
It is obvious to a person skilled in the art that invention is not limited to the details of the above exemplary embodiments, Er Qie
In the case where without departing substantially from spirit or essential attributes of the invention, the present invention can be realized in other specific forms.Therefore, no matter
From the point of view of which point, the present embodiments are to be considered as illustrative and not restrictive, and the scope of the present invention is by appended power
Benefit requires rather than above description limits, it is intended that all by what is fallen within the meaning and scope of the equivalent elements of the claims
Variation is included within the present invention.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiments being understood that.
Claims (7)
1. a kind of abrasion-resistance glass stone, which is characterized in that the raw material including following mass fraction: 60-120 parts of glass particle, glass
110-130 parts of powder, 0.3-0.7 parts of coupling agent, 0.1-0.5 parts of curing agent, 0.2-0.6 parts of promotor, 1-5 parts of mill base and unsaturation
40-80 parts of polyester resin.
2. a kind of abrasion-resistance glass stone, which is characterized in that the raw material including following mass fraction: 80-100 parts of glass particle, glass
115-125 parts of powder, 0.4-0.6 parts of coupling agent, 0.2-0.4 parts of curing agent, 0.3-0.5 parts of promotor, 2-4 parts of mill base and unsaturation
50-70 parts of polyester resin.
3. a kind of abrasion-resistance glass stone, which is characterized in that the raw material including following mass fraction: 90 parts of glass particle, glass powder 120
Part, 0.5 part of coupling agent, 0.3 part of curing agent, 0.4 part of promotor, 3 parts of mill base and 60 parts of unsaturated polyester resin.
4. -3 any a kind of abrasion-resistance glass stone according to claim 1, which is characterized in that the mill base is resin mill base.
5. -3 a kind of abrasion-resistance glass stone according to claim 1, which is characterized in that the specification of the glass particle is
40-70 mesh.
6. a kind of preparation method of abrasion-resistance glass stone a method according to any one of claims 1-3, which is characterized in that including following step
Rapid: step 1: preparing binder, and coupling agent, curing agent, promotor, mill base and unsaturated polyester resin are put into blender
It is stirred, stirs evenly to obtain binder A；Step 2: by glass particle, glass powder and binder A be put into blender again into
Row is stirred, and is discharged after mixing evenly, is obtained mixture B；Step 3: the smooth cloth of mixture B is entered into press well and exhausts vacuum
It is suppressed, obtains pressboard C；Step 4: being distributed into curing oven for pressboard C, point three steps solidification, total curing time 300min；
First step solidification temperature is 60-80 DEG C, curing time 100min；Second step；Solidification temperature is 80-100 DEG C, curing time
100min；Third step solidification temperature is 80-100 DEG C, curing time 100min；Step 5: after ejecting plate, it is parallel that plate is put into fixed frame
After fixing 8 hours, then carry out rubbing down.
7. a kind of abrasion-resistance glass Preparation Method made of stones according to claim 4, which is characterized in that the first step in the step 4
Solidification temperature is 70 to set DEG C；Second step solidification temperature is 90 DEG C；Third step solidification temperature is 90 DEG C.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811529231.6A CN109467338A (en) | 2018-12-14 | 2018-12-14 | A kind of abrasion-resistance glass stone and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201811529231.6A CN109467338A (en) | 2018-12-14 | 2018-12-14 | A kind of abrasion-resistance glass stone and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
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| CN109467338A true CN109467338A (en) | 2019-03-15 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201811529231.6A Withdrawn CN109467338A (en) | 2018-12-14 | 2018-12-14 | A kind of abrasion-resistance glass stone and preparation method thereof |
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| Country | Link |
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| CN (1) | CN109467338A (en) |
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2018
- 2018-12-14 CN CN201811529231.6A patent/CN109467338A/en not_active Withdrawn
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Application publication date: 20190315 |