CN109461511A - A kind of X-ray protection cloth and X-ray protection clothes - Google Patents

A kind of X-ray protection cloth and X-ray protection clothes Download PDF

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Publication number
CN109461511A
CN109461511A CN201811242510.4A CN201811242510A CN109461511A CN 109461511 A CN109461511 A CN 109461511A CN 201811242510 A CN201811242510 A CN 201811242510A CN 109461511 A CN109461511 A CN 109461511A
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China
Prior art keywords
ray protection
nanometer
protection cloth
silk thread
cloth
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Granted
Application number
CN201811242510.4A
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Chinese (zh)
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CN109461511B (en
Inventor
梁丹峰
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Shanghai Best Textile Co Ltd
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Shanghai Best Textile Co Ltd
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Priority to CN201811242510.4A priority Critical patent/CN109461511B/en
Publication of CN109461511A publication Critical patent/CN109461511A/en
Priority to PCT/CN2019/079243 priority patent/WO2020082684A1/en
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Publication of CN109461511B publication Critical patent/CN109461511B/en
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    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21FPROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F3/00Shielding characterised by its physical form, e.g. granules, or shape of the material
    • G21F3/02Clothing
    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21FPROTECTION AGAINST X-RADIATION, GAMMA RADIATION, CORPUSCULAR RADIATION OR PARTICLE BOMBARDMENT; TREATING RADIOACTIVELY CONTAMINATED MATERIAL; DECONTAMINATION ARRANGEMENTS THEREFOR
    • G21F1/00Shielding characterised by the composition of the materials
    • G21F1/12Laminated shielding materials

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
  • Chemical Or Physical Treatment Of Fibers (AREA)
  • Professional, Industrial, Or Sporting Protective Garments (AREA)

Abstract

The present invention discloses a kind of X-ray protection cloth, it includes the protective coating of base and at least one side being arranged in base's tow sides, the base is that the silk thread of adhesion metal oxide particle is formed by weaving, the protective coating is the resinous coat with the metal oxide particle, the metal oxide particle includes nanometer tantalum pentoxide particle and nanometer tungsten oxide particle, since the present invention is by nanometer tantalum, tungsten oxide particle is attached on silk thread, and it is provided on the cloth surface that silk thread is woven into nanometer tantalum, the coating of tungsten oxide, so that cloth has preferable X-ray-preventing ability.Simultaneously as coating layer thickness is relatively thin, so that cloth has many advantages, such as the performance of slim and graceful softness, there is easy cleaning, comfortable and easy to wear, ventilative, waterproof, antibacterial after cloth, which is made into, to be taken for X-ray protection.

Description

A kind of X-ray protection cloth and X-ray protection clothes
Technical field
The present invention relates to field of medical products, especially a kind of X-ray protection cloth and X-ray protection clothes.
Background technique
X-ray protection clothes are necessity equipment of the hospital in X-ray menisectomy, can largely protect medical matters people The significant points of member and patient.
Usual X-ray protection clothes are made of lead glue skin, the usual thickness of cloth in 5mm or more, weight is larger, quality compared with It is firmly and airtight, it can only generally be made into vest as a result, the position of protection is limited.It is sultry after dress, and due to weight Relationship to a certain extent can impact doctor's operation.Further, since it is thick and heavy and can not fold, it cannot be using common Mode clean, cleaning and sterilizing is more troublesome, and collection is also more inconvenient when impracticable, the bending part appearance after using 1-2 It is easy to damage, cause it can not normal use.
Therefore, a kind of slim and graceful softness X-ray protection cloth easy to use is needed at present.
Summary of the invention
The object of the present invention is to provide a kind of slim and graceful softness X-ray protection cloth easy to use and X-ray protection clothes.
In order to achieve the above objectives, the technical solution adopted by the present invention is that: a kind of X-ray protection cloth comprising base and The protective coating of at least one side in base's tow sides is set, and the base is the silk of adhesion metal oxide particle Line is formed by weaving, and the protective coating is the resinous coat with the metal oxide particle, the metal oxide particle Including nanometer tantalum pentoxide particle and nanometer tungsten oxide particle.
Preferably, the X-ray protection cloth uses following production stage:
1) silk thread is impregnated in metal soak, which includes following components by weight percentage: 2-5% nanometers Tantalum pentoxide, 2-5% nanometer tungsten oxide and 90-96% assist liquid;
2) silk thread after immersion is air-dried, and be wound into a roll;
3) cloth is woven into using the silk thread after drying, and carries out antibacterial and dyeing processing;
4) gelatinous protective coating is coated in design on fabric surface, which includes following components by weight percentage: 5-15% nanometers of tantalums Oxide, 5-15% nanometer tungsten oxide and 70-90% resin;
5) protective coating of design on fabric surface is dried, and is wound into a roll.
It is further preferred that metal soak includes following components by weight percentage in step 1): 3% nanometer of tantalum oxidation Object, 3% nanometer of tungsten oxide and 94% auxiliary liquid.
It is further preferred that impregnating silk thread in step 1) in such a way that single wire is by fermentation vat, soaking temperature is 220-240 DEG C, be 20-30h when immersion.
It is further preferred that the air-dried mode in step 2 is natural air drying at normal temperature.
It is further preferred that metal soak includes following components by weight percentage in step 5): 10% nanometer of tantalum oxidation Object, 10% nanometer of tungsten oxide and 80% resin.
It is further preferred that the drying temperature in step 5) is 150-250 DEG C, drying time 8-15s.
Preferably, the protective coating with a thickness of 0.2-1mm.
Preferably, the weaving mode of base is to interweave.
A kind of X-ray protection clothes, use above-mentioned X-ray protection cloth to be made.
Due to the above technical solutions, the present invention has the following advantages over the prior art:
Since nanometer tantalum, tungsten oxide particle are attached on silk thread by the present invention, and the cloth surface being woven into silk thread is provided with Coating with nanometer tantalum, tungsten oxide, so that cloth has preferable X-ray-preventing ability.Simultaneously as coating layer thickness compared with It is thin, so that cloth has slim and graceful soft performance, there is easy cleaning, dress to relax after cloth, which is made into, to be taken for X-ray protection The advantages that suitable, ventilative, waterproof, antibacterial.
Specific embodiment
The invention will be further described for the following examples:
Embodiment one: a kind of X-ray protection cloth comprising base is anti-with the one side being arranged in base's tow sides Coating is protected, the base is that the silk thread of adhesion metal oxide particle is interwoven (the low bullet that silk thread is 300D in the present embodiment Silk, the thickness after being woven into cloth is about 0.3mm), the protective coating is the resinous coat with the metal oxide particle, The metal oxide particle includes nanometer tantalum pentoxide particle and nanometer tungsten oxide particle.
Above-mentioned X-ray protection cloth uses following production stage:
1) by silk thread with single wire by being impregnated in leaching metal soak, soaking temperature is 220-240 DEG C, and when immersion is 20-30h, which includes following components by weight percentage: 2% nanometer of tantalum pentoxide, 2% nanometer of tungsten oxide and 96% auxiliary liquid (stabilizer for assisting liquid to use alcohols solvent and add a certain amount of pu polyurethane, organosilicon etc in the application with Reduce precipitating);2) it by the natural air drying at normal temperature of the silk thread after immersion, and is wound into a roll;
3) cloth is woven into using the silk thread after drying, and carries out antibacterial and dyeing processing;
4) gelatinous protective coating is coated in design on fabric surface, which includes following components by weight percentage: 5% nanometer of tantalum oxygen Compound, 5% nanometer of tungsten oxide and 90% resin;
5) protective coating of design on fabric surface is dried, drying temperature is 150-250 DEG C, drying time 8-15s, and is wound into a roll, Placement naturally cools to room temperature.
The cloth lead equivalent testing result of the present embodiment is as follows:
Coating layer thickness (mm) 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Lead equivalent (mmPb) 0.16 0.19 0.21 0.24 0.27 0.30 0.32 0.34 0.36
Embodiment two: a kind of X-ray protection cloth comprising base is anti-with the one side being arranged in base's tow sides Coating is protected, the base is that the silk thread of adhesion metal oxide particle is interwoven (the low bullet that silk thread is 300D in the present embodiment Silk, the thickness after being woven into cloth is about 0.3mm), the protective coating is the resinous coat with the metal oxide particle, The metal oxide particle includes nanometer tantalum pentoxide particle and nanometer tungsten oxide particle.
Above-mentioned X-ray protection cloth uses following production stage:
1) by silk thread with single wire by being impregnated in leaching metal soak, soaking temperature is 220-240 DEG C, and when immersion is 20-30h, which includes following components by weight percentage: 3% nanometer of tantalum pentoxide, 3% nanometer of tungsten oxide and 94% auxiliary liquid;
2) it by the natural air drying at normal temperature of the silk thread after immersion, and is wound into a roll;
3) cloth is woven into using the silk thread after drying, and carries out antibacterial and dyeing processing;
4) gelatinous protective coating is coated in design on fabric surface, which includes following components by weight percentage: 10% nanometer of tantalum oxygen Compound, 10% nanometer of tungsten oxide and 80% resin;
5) protective coating of design on fabric surface is dried, drying temperature is 150-250 DEG C, drying time 8-15s, and is wound into a roll, Placement naturally cools to room temperature.
The cloth lead equivalent testing result of the present embodiment is as follows:
Coating layer thickness (mm) 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Lead equivalent (mmPb) 0.18 0.22 0.27 0.32 0.36 0.38 0.40 0.42 0.43
Embodiment three: a kind of X-ray protection cloth comprising base is anti-with the one side being arranged in base's tow sides Coating is protected, the base is that the silk thread of adhesion metal oxide particle is interwoven (the low bullet that silk thread is 300D in the present embodiment Silk, the thickness after being woven into cloth is about 0.3mm), the protective coating is the resinous coat with the metal oxide particle, The metal oxide particle includes nanometer tantalum pentoxide particle and nanometer tungsten oxide particle.
Above-mentioned X-ray protection cloth uses following production stage:
1) by silk thread with single wire by being impregnated in leaching metal soak, soaking temperature is 220-240 DEG C, and when immersion is 20-30h, which includes following components by weight percentage: 5% nanometer of tantalum pentoxide, 5% nanometer of tungsten oxide and 90% auxiliary liquid;
2) it by the natural air drying at normal temperature of the silk thread after immersion, and is wound into a roll;
3) cloth is woven into using the silk thread after drying, and carries out antibacterial and dyeing processing;
4) gelatinous protective coating is coated in design on fabric surface, which includes following components by weight percentage: 15% nanometer of tantalum oxygen Compound, 15% nanometer of tungsten oxide and 70% resin;
5) protective coating of design on fabric surface is dried, drying temperature is 150-250 DEG C, drying time 8-15s, and is wound into a roll, Placement naturally cools to room temperature.
The cloth lead equivalent testing result of the present embodiment is as follows:
Coating layer thickness (mm) 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1.0
Lead equivalent (mmPb) 0.19 0.23 0.25 0.29 0.37 0.39 0.40 0.42 0.44
Compared with prior art, there are the above advantages for above-described embodiment:
1. fabric has preferable X-ray-preventing, the anti-blood of waterproof, air-moisture-permeable, antibacterium, antistatic, soft characteristic.
2. it is slim and graceful soft after the clothes of X-ray protection made of fabric, there is preferable ventilative, waterproof performance, it is comfortable and easy to wear.
3. the clothes of X-ray protection made of fabric can be washed by the way of common, be sterilized, and convenient for folding can be received Hiding.
4. the clothes of X-ray protection made of fabric have longer service life, it is not easy to damage.
The above embodiments merely illustrate the technical concept and features of the present invention, and its object is to allow person skilled in the art Scholar cans understand the content of the present invention and implement it accordingly, and it is not intended to limit the scope of the present invention.It is all according to the present invention Equivalent change or modification made by Spirit Essence, should be covered by the protection scope of the present invention.

Claims (10)

1. a kind of X-ray protection cloth comprising the protection of base and at least one side being arranged in base's tow sides Coating, it is characterised in that: the base be adhesion metal oxide particle silk thread be formed by weaving, the protective coating be with The resinous coat of the metal oxide particle, the metal oxide particle include nanometer tantalum pentoxide particle and nanometer tungsten oxygen Compound particle.
2. a kind of X-ray protection cloth according to claim 1, it is characterised in that: the X-ray protection cloth use with Lower production stage:
1) silk thread is impregnated in metal soak, which includes following components by weight percentage: 2-5% nanometers Tantalum pentoxide, 2-5% nanometer tungsten oxide and 90-96% assist liquid;
2) silk thread after immersion is air-dried, and be wound into a roll;
3) cloth is woven into using the silk thread after drying, and carries out antibacterial and dyeing processing;
4) gelatinous protective coating is coated in design on fabric surface, which includes following components by weight percentage: 5-15% nanometers of tantalums Oxide, 5-15% nanometer tungsten oxide and 70-90% resin;
5) protective coating of design on fabric surface is dried, and is wound into a roll.
3. a kind of X-ray protection cloth according to claim 2, it is characterised in that: metal soak is by weight in step 1) Measuring percentage includes following components: 3% nanometer of tantalum pentoxide, 3% nanometer of tungsten oxide and 94% auxiliary liquid.
4. a kind of X-ray protection cloth according to claim 2, it is characterised in that: passed through in step 1) with single wire The mode of fermentation vat impregnates silk thread, and soaking temperature is 220-240 DEG C, and when immersion is 20-30h.
5. a kind of X-ray protection cloth according to claim 2, it is characterised in that: air-dried mode in step 2 be Natural air drying under room temperature.
6. a kind of X-ray protection cloth according to claim 2, it is characterised in that: metal soak is by weight in step 5) Measuring percentage includes following components: 10% nanometer of tantalum pentoxide, 10% nanometer of tungsten oxide and 80% resin.
7. a kind of X-ray protection cloth according to claim 2, it is characterised in that: the drying temperature in step 5) is 150-250 DEG C, drying time 8-15s.
8. a kind of X-ray protection cloth according to claim 1, it is characterised in that: the protective coating with a thickness of 0.2-1mm。
9. a kind of X-ray protection cloth according to claim 1, it is characterised in that: the weaving mode of base is to interweave.
10. a kind of X-ray protection clothes, it is characterised in that: it uses the X-ray protection cloth of claim 1-9 to be made.
CN201811242510.4A 2018-10-24 2018-10-24 X-ray protective cloth and X-ray protective clothing Active CN109461511B (en)

Priority Applications (2)

Application Number Priority Date Filing Date Title
CN201811242510.4A CN109461511B (en) 2018-10-24 2018-10-24 X-ray protective cloth and X-ray protective clothing
PCT/CN2019/079243 WO2020082684A1 (en) 2018-10-24 2019-03-22 X-ray protective cloth and x ray protective suit

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Application Number Priority Date Filing Date Title
CN201811242510.4A CN109461511B (en) 2018-10-24 2018-10-24 X-ray protective cloth and X-ray protective clothing

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CN109461511B CN109461511B (en) 2020-03-20

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Cited By (5)

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WO2020082684A1 (en) * 2018-10-24 2020-04-30 上海都浩纺织品有限公司 X-ray protective cloth and x ray protective suit
CN111933324A (en) * 2020-08-20 2020-11-13 山东杰创安全检测有限公司 X-ray protective cloth and X-ray protective clothing
WO2020252861A1 (en) * 2019-06-21 2020-12-24 四川大学 High-z-element-natural leather composite x-ray shielding material and preparation method therefor
CN113650362A (en) * 2021-08-11 2021-11-16 四川大学 Preparation method of X-ray protection material based on superfine fiber membrane
CN116356572A (en) * 2023-05-11 2023-06-30 东华大学 X-ray irradiation preventing fiber and preparation method and application thereof

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WO2020082684A1 (en) * 2018-10-24 2020-04-30 上海都浩纺织品有限公司 X-ray protective cloth and x ray protective suit
WO2020252861A1 (en) * 2019-06-21 2020-12-24 四川大学 High-z-element-natural leather composite x-ray shielding material and preparation method therefor
CN111933324A (en) * 2020-08-20 2020-11-13 山东杰创安全检测有限公司 X-ray protective cloth and X-ray protective clothing
CN113650362A (en) * 2021-08-11 2021-11-16 四川大学 Preparation method of X-ray protection material based on superfine fiber membrane
CN116356572A (en) * 2023-05-11 2023-06-30 东华大学 X-ray irradiation preventing fiber and preparation method and application thereof

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