CN109458620A - Reduce the compound additive and its application method of sludge incineration fine particle production quantity - Google Patents

Reduce the compound additive and its application method of sludge incineration fine particle production quantity Download PDF

Info

Publication number
CN109458620A
CN109458620A CN201811366266.2A CN201811366266A CN109458620A CN 109458620 A CN109458620 A CN 109458620A CN 201811366266 A CN201811366266 A CN 201811366266A CN 109458620 A CN109458620 A CN 109458620A
Authority
CN
China
Prior art keywords
sludge
fine particle
diatomite
compound additive
quick lime
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201811366266.2A
Other languages
Chinese (zh)
Inventor
李彦龙
赵云斌
李润东
满佳琪
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Shenyang Aerospace University
Original Assignee
Shenyang Aerospace University
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Shenyang Aerospace University filed Critical Shenyang Aerospace University
Priority to CN201811366266.2A priority Critical patent/CN109458620A/en
Publication of CN109458620A publication Critical patent/CN109458620A/en
Pending legal-status Critical Current

Links

Classifications

    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • F23G7/001Incinerators or other apparatus for consuming industrial waste, e.g. chemicals for sludges or waste products from water treatment installations
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/033Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment comminuting or crushing
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/04Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment drying
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/30Incineration of waste; Incinerator constructions; Details, accessories or control therefor having a fluidised bed
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G2209/00Specific waste
    • F23G2209/12Sludge, slurries or mixtures of liquids

Abstract

A kind of compound additive and its application method reducing sludge incineration fine particle production quantity, belongs to sludge incineration processing technology field.The compound additive of the reduction sludge incineration fine particle production quantity is the mixture of quick lime and diatomite, in mass ratio, quick lime: diatomite=(0.25~1): 1.Its application method are as follows: mix quick lime and diatomite, in the sludge powder that partial size after drying is added is 150 μm~500 μm, it is burned together, incineration temperature is 750~950 DEG C, obtained fine particle production quantity is decreased obviously, and under the high temperature conditions, quick lime can react with diatomite, form the calcium silicates with absorption property.In addition, the rich reserves of quick lime and diatomite, cheap, transport and storage are convenient, can effectively reduce the cost to the control of sludge incineration fine particle.

Description

Reduce the compound additive and its application method of sludge incineration fine particle production quantity
Technical field
The present invention relates to sludge incineration processing technology fields, and in particular to a kind of reduction sludge incineration fine particle production quantity Compound additive and its application method.
Background technique
With the quickening of China's urbanization step, the yield and treating capacity of municipal sewage increase sharply, but following Sludge bring secondary pollution again.Treatment of Sludge and the purpose of disposition with minimizing, recycling, it is harmless turn to principle, mainly Method of disposal has Sludge landfill method, sludge composting method and sludge incineration method.Wherein, Sludge landfill method needs to occupy a large amount of soils, And deal with the pollution that may cause soil and groundwater improperly.Sludge composting method is with low energy consumption, supports in recoverable sludge The advantages that dividing, but there are the danger of pathogen diffusion and heavy metal pollution.Compared to compost and landfill, the processing of sludge incineration method is not The minimizing of sludge and innoxious can be only realized to the maximum extent, and auxiliary product can also be made in incineration residue, be one The effective sludge treating method of kind.Sludge incineration method has processing speed fast, and treating capacity is big, and occupied area is small, does not need long-term Storage, can on-site incineration, the features such as not needing long-distance transportation, can recover energy for heat supply or power generation.Flying dust is to burn The pollutant generated in the process, yield are about the 0.5~3% of burning amount.Contain high concentration and height in flying ash particulate matter The harmful substances such as the heavy metal of leaching concentration and highly toxic dioxin, if imappropriate processing or method of disposal, have Evil substance will in the ecosystem Transport And Transformation, and then polluted underground water, soil and air, finally endanger human health.Due to The partial size very little of fine particle, the residence time in atmospheric environment is long, and about 7~30 days, and also it is more liquid, hold It is easily inhaled into and is deposited inside mankind's alveolar and be difficult to be breathed out.Along with fine particle has biggish specific surface area, it is easy The heavy metal generated during sludge incineration is adsorbed, human body is caused greatly to injure.
Currently, coal-fired, biomass-burning is largely focused on to the fine particle research that burning generates both at home and abroad, and to sludge The research of fine particle caused by burning is less.Traditional dust removal method has the cleaners such as bag-type dust and electric precipitation, but It is lower to the removal efficiency of fine particle and superfine particulate matter and higher cost.
Such as CN106281564A, by the way that diatomite modified is modified as hydrochloric Acid Modification diatomite powder and poly- hydroxy Al Diatomite powder, reduces the production quantity of fine particle by certain physically or chemically effect, but hydrochloric acid and poly- hydroxy Al Preparation cost is higher, is unsuitable for large-scale use.
Summary of the invention
In view of the drawbacks of the prior art, the present invention provides a kind of compound adding for reducing sludge incineration fine particle production quantity Add agent and its application method, the compound additive of the reduction sludge incineration fine particle production quantity be by quick lime and diatomite by According to predetermined ratio mixing be used as additive, using the compound additive reduce sludge incineration fine particle generate method, be by After compound additive and sludge are mixed according to scheduled mass ratio, it is added in fluidized bed burns together, in combustion process, addition Quick lime (CaO) can not only reduce the production quantity of fine particle, but also under the high temperature conditions, quick lime can be sent out with diatomite Raw reaction, forms the calcium silicates with absorption property.In addition, the rich reserves of quick lime and diatomite, cheap, transport and Storage is convenient, can effectively reduce the cost to the control of sludge incineration fine particle.
A kind of compound additive of reduction sludge incineration fine particle production quantity of the invention is quick lime and diatomite Mixture, in mass ratio, quick lime: diatomite=(0.25~1): 1, preferably 0.75:1.
A kind of application method of the compound additive of reduction sludge incineration fine particle production quantity of the invention, including it is following Step:
Step 1: preparing compound additive
By quality proportioning, quick lime and diatomite are mixed, obtain the diatomite for being mixed with quick lime;
Step 2: sludge pre-treatment
Sludge is dried, grind, is sieved, the sludge powder that partial size is 150 μm~500 μm is obtained;
Step 3: compound additive and sludge mixing
The diatomite for being mixed with quick lime and sludge powder are sufficiently mixed, the sludge powder for being mixed with additive is obtained;Wherein, it is mixed with The mass percent that the diatomite of quick lime accounts for sludge silty amount is 3%~9%;
Step 4: burning
Will be mixed with compound additive sludge powder be added sludge incinerator in, burned, incineration temperature be 750~ 950 DEG C, burning atmosphere is air atmosphere, the fine particle after being burned.
In the step 2, the drying, drying temperature is 105 DEG C~200 DEG C.
In the step 4, the sludge incinerator is one of sludge incinerator, fluidized bed, is preferably flowed Change bed.
It is thin that reduction sludge incineration is carried out using the compound additive of reduction sludge incineration fine particle production quantity of the invention Particulate matter generates, analytic process are as follows:
Fine particle after burning is entered into cyclone separator with flue gas, separation diameter is greater than 10 μm of particulate matter, remaining Fine particle and superfine particulate matter enter in the charged ram of low pressure (ELPI) with flue gas, to the fine particle of different-diameter into Row classification is collected, then analysis statistics, is reduced the function and effect of the additive of sludge incineration fine particle generation.
The compound additive and its application method of a kind of reduction sludge incineration fine particle production quantity of the invention are beneficial Effect are as follows:
1, the present invention is by being added the compound additive for being mixed with the diatomite of quick lime, in turn during sludge incineration Sludge incineration fine particle production quantity is reduced, during the mechanism of action is sludge incineration, addition quick lime (CaO) not only can be with The production quantity of fine particle is reduced, and under the high temperature conditions, quick lime can react with diatomite, being formed has absorption The calcium silicates of performance.
2, the rich reserves of quick lime and diatomite, cheap, transport and storage are convenient, can effectively reduce to dirt Mud burns the cost of fine particle control.
Detailed description of the invention
Fig. 1 is that the compound additive of quick lime and diatomite different ratio generates fine graineds to 250~500 μm of sludge incinerations The impact effect figure of object.
Fig. 2 is that the compound additive of quick lime and diatomite different ratio generates thin to 187.5~250 μm of sludge incinerations The impact effect figure of grain object.
Specific embodiment
Below with reference to embodiment, the present invention is described in further detail.
Embodiment 1
A kind of compound additive reducing sludge incineration fine particle production quantity is the mixture of quick lime and diatomite, In mass ratio, quick lime: diatomite=0.25:1.
A kind of application method for the compound additive reducing sludge incineration fine particle production quantity, comprising the following steps:
Step 1: preparing compound additive
By quality proportioning, quick lime and diatomite are mixed, obtain the diatomite for being mixed with quick lime;
Step 2: sludge pre-treatment
Sludge is placed in 105 DEG C of baking ovens after drying, is ground dry sludge using grinder, and crosses 30 meshes Son is sieved, and the sludge powder that partial size is 250 μm~500 μm is obtained;
Step 3: compound additive and sludge mixing
The sludge powder that the diatomite for being mixed with quick lime and partial size are 250 μm~500 μm is sufficiently mixed, obtains being mixed with addition The sludge powder of agent;Wherein, it is 6% that the diatomite for being mixed with quick lime, which accounts for the mass percent of sludge silty amount,;
Step 4: burning
It will be mixed with the sludge powder of compound additive, is added in fluidized bed with the feed rate of 20g/min, is burned, burnt Burning temperature is 850 DEG C, and burning atmosphere is air atmosphere, the fine particle after being burned.
Step 5: analysis
Fine particle after burning is flowed through into cyclone separator with flue gas, kinetic diameter in flue gas is filtered out and is greater than 10 μm Particulate matter, remaining fine particle and superfine particulate matter enter the charged ram of low pressure (ELPI) with flue gas, by fine particle Be divided into 14 grades be respectively as follows: 6~16.7nm, 16.7~27.5nm, 27.5~56nm, 56~94.2nm, 94.2~156nm, 156~ 261nm, 261~382nm, 382~613nm, 613~948nm, 948~1600nm, 1.6~2.39 μm, 2.39~3.99 μm, 3.99~6.68 μm, 6.68~9.91 μm, acquisition time 30min.
Embodiment 2
A kind of compound additive reducing sludge incineration fine particle production quantity is the mixture of quick lime and diatomite, In mass ratio, quick lime: diatomite=0.5:1.
A kind of application method for the compound additive reducing sludge incineration fine particle production quantity, with embodiment 1, difference Be in, in mass ratio, quick lime: diatomite=0.5:1.
Embodiment 3
A kind of compound additive reducing sludge incineration fine particle production quantity is the mixture of quick lime and diatomite, In mass ratio, quick lime: diatomite=0.75:1.
A kind of application method for the compound additive reducing sludge incineration fine particle production quantity, with embodiment 1, difference Be in, in mass ratio, quick lime: diatomite=0.75:1.
Embodiment 4
A kind of compound additive reducing sludge incineration fine particle production quantity is the mixture of quick lime and diatomite, In mass ratio, quick lime: diatomite=1:1.
A kind of application method for the compound additive reducing sludge incineration fine particle production quantity, with embodiment 1, difference Be in, in mass ratio, quick lime: diatomite=1:1.
According in embodiment 1, embodiment 2, embodiment 3, embodiment 4, the quality proportioning system of different quick limes and diatomite The impact effect that standby compound additive generates fine particle to 250~500 μm of sludge incinerations is analyzed, obtained impact effect figure Fig. 1 is seen, from Fig. 1, it can be seen that in the content range studied, with the increase of compound additive ratio, fine particle Production quantity be also reduce, when the ratio of compound additive be 0.75:1 when, the production quantity of fine particle is the smallest.
Comparative example 1
A kind of processing method of sludge, comprising the following steps:
Step 1: sludge pre-treatment
Sludge is placed in 105 DEG C of baking ovens after drying, is ground dry sludge using grinder, and crosses 30 meshes Son is sieved, and the sludge powder that partial size is 250 μm~500 μm is obtained;
Step 2: burning
The sludge powder for being 250 μm~500 μm by partial size is added in fluidized bed with the feed rate of 20g/min, is burnt It burns, incineration temperature is 850 DEG C, and burning atmosphere is air atmosphere, the fine particle after being burned.
Step 3: analysis
Fine particle after burning is flowed through into cyclone separator with flue gas, kinetic diameter in flue gas is filtered out and is greater than 10 μm Particulate matter, remaining fine particle and superfine particulate matter enter the charged ram of low pressure (ELPI) with flue gas, by fine particle Be divided into 14 grades be respectively as follows: 6~16.7nm, 16.7~27.5nm, 27.5~56nm, 56~94.2nm, 94.2~156nm, 156~ 261nm, 261~382nm, 382~613nm, 613~948nm, 948~1600nm, 1.6~2.39 μm, 2.39~3.99 μm, 3.99~6.68 μm, 6.68~9.91 μm, acquisition time 30min.
The fine particle that embodiment 1, embodiment 2, embodiment 3, embodiment 4 and comparative example obtain is collected and is counted Analysis, as a result:
It measures under experimental conditions, is not added with the sludge (comparative example 1) of additive, burns the PM of generation0.1、PM1、PM2.5、 PM10Particle diameter distribution (1/cm3) it is respectively 152212.04,11306.52,11128.85,7577.75;
The sludge (embodiment 1) that quick lime and diatomite mixing ratio are 0.25:1, burns the PM of generation0.1、PM1、PM2.5、 PM10Particle diameter distribution (1/cm3) it is respectively 13009.08,6043.70,1404.61,1327.97;
The sludge (embodiment 2) that quick lime and diatomite mixing ratio are 0.5:1, burns the PM of generation0.1、PM1、PM2.5、 PM10Particle diameter distribution (1/cm3) it is respectively 11513.79,4703.07,1320,1021;
The sludge (embodiment 3) that quick lime and diatomite mixing ratio are 0.75:1, burns the PM of generation0.1、PM1、PM2.5、 PM10Particle diameter distribution (1/cm3) it is respectively 5612.35,2204,1069.59,916.99;
The sludge (embodiment 4) that quick lime and diatomite mixing ratio are 1:1, burns the PM of generation0.1、PM1、PM2.5、PM10 Particle diameter distribution (1/cm3) it is respectively 7256.16,3597.12,1235.76,1005.70.
It is by this as a result, available, it, can after the compound additive for reducing sludge incineration fine particle production quantity is added The effective production quantity for inhibiting fine particulates.
Embodiment 5
A kind of compound additive reducing sludge incineration fine particle production quantity is the mixture of quick lime and diatomite, In mass ratio, quick lime: diatomite=0.25:1.
A kind of application method for the compound additive reducing sludge incineration fine particle production quantity, comprising the following steps:
Step 1: preparing compound additive
By quality proportioning, quick lime and diatomite are mixed, obtain the diatomite for being mixed with quick lime;
Step 2: sludge pre-treatment
Sludge is placed in 105 DEG C of baking ovens after drying, is ground dry sludge using grinder, and crosses 60 meshes Son is sieved, and the sludge powder that partial size is 187.5 μm~250 μm is obtained;
Step 3: compound additive and sludge mixing
The sludge powder that the diatomite for being mixed with quick lime and partial size are 187.5 μm~250 μm is sufficiently mixed, obtains being mixed with and adds Add the sludge powder of agent;Wherein, it is 6% that the diatomite for being mixed with quick lime, which accounts for the mass percent of sludge silty amount,;
Step 4: burning
It will be mixed with the sludge powder of compound additive, is added in fluidized bed with the feed rate of 20g/min, is burned, burnt Burning temperature is 850 DEG C, and burning atmosphere is air atmosphere, the fine particle after being burned.
Step 5: analysis
Fine particle after burning is flowed through into cyclone separator with flue gas, kinetic diameter in flue gas is filtered out and is greater than 10 μm Particulate matter, remaining fine particle and superfine particulate matter enter the charged ram of low pressure (ELPI) with flue gas, by fine particle It is divided into 14 grades, is respectively as follows: 6~16.7nm, 16.7~27.5nm, 27.5~56nm, 56~94.2nm, 94.2~156nm, 156 ~261nm, 261~382nm, 382~613nm, 613~948nm, 948~1600nm, 1.6~2.39 μm, 2.39~3.99 μ M, 3.99~6.68 μm, 6.68~9.91 μm, acquisition time 30min.
Embodiment 6
A kind of compound additive reducing sludge incineration fine particle production quantity is the mixture of quick lime and diatomite, In mass ratio, quick lime: diatomite=0.5:1.
A kind of application method for the compound additive reducing sludge incineration fine particle production quantity, with embodiment 4, difference Be in, in mass ratio, quick lime: diatomite=0.5:1.
Embodiment 7
A kind of compound additive reducing sludge incineration fine particle production quantity is the mixture of quick lime and diatomite, In mass ratio, quick lime: diatomite=0.75:1.
A kind of application method for the compound additive reducing sludge incineration fine particle production quantity, with embodiment 4, difference Be in, in mass ratio, quick lime: diatomite=0.75:1.
Embodiment 8
A kind of compound additive reducing sludge incineration fine particle production quantity is the mixture of quick lime and diatomite, In mass ratio, quick lime: diatomite=1:1.
A kind of application method for the compound additive reducing sludge incineration fine particle production quantity, with embodiment 4, difference Be in, in mass ratio, quick lime: diatomite=1:1.
According in embodiment 5, embodiment 6, embodiment 7, embodiment 8, the quality proportioning system of different quick limes and diatomite The impact effect that standby compound additive generates fine particle to 187.5 μm~250 μm sludge incinerations is analyzed, obtained influence effect Fruit figure is shown in Fig. 2, from Fig. 2, it can be seen that in the content range studied, with the increase of compound additive ratio, and thin The production quantity of grain object is also to reduce, and when the ratio of compound additive is 0.75:1, the production quantity of fine particle is the smallest.
Comparative example 2
A kind of processing method of sludge, comprising the following steps:
Step 1: sludge pre-treatment
Sludge is placed in 105 DEG C of baking ovens after drying, is ground dry sludge using grinder, and crosses 60 meshes Son is sieved, and the sludge powder that partial size is 187.5 μm~250 μm is obtained;
Step 2: burning
The sludge powder for being 187.5 μm~250 μm by partial size is added in fluidized bed with the feed rate of 20g/min, is burnt It burns, incineration temperature is 850 DEG C, and burning atmosphere is air atmosphere, the fine particle after being burned.
Step 3: analysis
Fine particle after burning is flowed through into cyclone separator with flue gas, kinetic diameter in flue gas is filtered out and is greater than 10 μm Particulate matter, remaining fine particle and superfine particulate matter enter the charged ram of low pressure (ELPI) with flue gas, by fine particle Be divided into 14 grades be respectively as follows: 6~16.7nm, 16.7~27.5nm, 27.5~56nm, 56~94.2nm, 94.2~156nm, 156~ 261nm, 261~382nm, 382~613nm, 613~948nm, 948~1600nm, 1.6~2.39 μm, 2.39~3.99 μm, 3.99~6.68 μm, 6.68~9.91 μm, acquisition time 30min.
The fine particle that embodiment 5, embodiment 6, embodiment 7, embodiment 8 and comparative example 2 obtain is collected and is united Meter analysis, as a result:
It measures under experimental conditions, is not added with the sludge (comparative example 2) of additive, burns the PM of generation0.1、PM1、PM2.5、 PM10Particle diameter distribution (1/cm3) it is respectively 62712.76,32686.41,8069.61,6191.16;
The sludge (embodiment 5) that quick lime and diatomite mixing ratio are 0.25:1, burns the PM of generation0.1、PM1、PM2.5、 PM10Particle diameter distribution (1/cm3) it is respectively 1895.73,9250.21,1420.81,815.51;
The sludge (embodiment 6) that quick lime and diatomite mixing ratio are 0.5:1, burns the PM of generation0.1、PM1、PM2.5、 PM10Particle diameter distribution (1/cm3) it is respectively 8116.47,2080.42,1235.06,375.74;
The sludge (embodiment 7) that quick lime and diatomite mixing ratio are 0.75:1, burns the PM of generation0.1、PM1、PM2.5、 PM10Particle diameter distribution (1/cm3) it is respectively 5788.79,1546.98,284.94,99.64;
The sludge (embodiment 8) that quick lime and diatomite mixing ratio are 1:1, burns the PM of generation0.1、PM1、PM2.5、PM10 Particle diameter distribution (1/cm3) it is respectively 7632.59,1759.64,798.26,201.35.
By comparing to embodiment 1 and embodiment 4, discovery sludge partial size is smaller, and treatment effect is better, this be because For, the smaller mixing of partial size is more uniform, it is contemplated that the practical application that sludge burns in a fluidized bed, if partial size is too small, rigid It when into fluidized bed, is easy to be run by wind, if partial size is too big, wind-force is not enough to that sludge is supported to realize fluidized state.
Embodiment 9
A kind of compound additive reducing sludge incineration fine particle production quantity is the mixture of quick lime and diatomite, In mass ratio, quick lime: diatomite=0.4:1.
A kind of application method for the compound additive reducing sludge incineration fine particle production quantity, comprising the following steps:
Step 1: preparing compound additive
By quality proportioning, quick lime and diatomite are mixed, obtain the diatomite for being mixed with quick lime;
Step 2: sludge pre-treatment
Sludge is placed in 200 DEG C of baking ovens after drying, dry sludge is ground using grinder, and is sieved, is obtained The sludge powder for being 150 μm~200 μm to partial size;
Step 3: compound additive and sludge mixing
The diatomite for being mixed with quick lime and sludge powder are sufficiently mixed, the sludge powder for being mixed with additive is obtained;Wherein, it is mixed with The mass percent that the diatomite of quick lime accounts for sludge silty amount is 3%;
Step 4: burning
The sludge powder for being mixed with compound additive is added in fluidized bed, is burned, incineration temperature is 750 DEG C, burns gas Atmosphere is air atmosphere, the fine particle after being burned.
Embodiment 10
A kind of compound additive reducing sludge incineration fine particle production quantity is the mixture of quick lime and diatomite, In mass ratio, quick lime: diatomite=0.7:1.
A kind of application method for the compound additive reducing sludge incineration fine particle production quantity, comprising the following steps:
Step 1: preparing compound additive
By quality proportioning, quick lime and diatomite are mixed, obtain the diatomite for being mixed with quick lime;
Step 2: sludge pre-treatment
Sludge is placed in 150 DEG C of baking ovens after drying, dry sludge is ground using grinder, and is sieved, is obtained The sludge powder for being 200 μm~300 μm to partial size;
Step 3: compound additive and sludge mixing
The diatomite for being mixed with quick lime and sludge powder are sufficiently mixed, the sludge powder for being mixed with additive is obtained;Wherein, it is mixed with The mass percent that the diatomite of quick lime accounts for sludge silty amount is 9%;
Step 4: burning
The sludge powder for being mixed with compound additive is added in fluidized bed, is burned, incineration temperature is 950 DEG C, burns gas Atmosphere is air atmosphere, the fine particle after being burned.

Claims (6)

1. a kind of compound additive for reducing sludge incineration fine particle production quantity, which is characterized in that the reduction sludge incineration is thin The compound additive of particulate matter production quantity is the mixture of quick lime and diatomite, in mass ratio, quick lime: diatomite= (0.25~1): 1.
2. reducing the compound additive of sludge incineration fine particle production quantity as described in claim 1, which is characterized in that the drop The compound additive of low sludge incineration fine particle production quantity is the mixture of quick lime and diatomite, in mass ratio, quick lime: Diatomite=0.75:1.
3. the application method of the compound additive described in claim 1 for reducing sludge incineration fine particle production quantity, feature It is, comprising the following steps:
Step 1: preparing compound additive
By quality proportioning, quick lime and diatomite are mixed, obtain the diatomite for being mixed with quick lime;
Step 2: sludge pre-treatment
Sludge is dried, grind, is sieved, the sludge powder that partial size is 150 μm~500 μm is obtained;
Step 3: compound additive and sludge mixing
The diatomite for being mixed with quick lime and sludge powder are sufficiently mixed, the sludge powder for being mixed with additive is obtained;Wherein, it is mixed with raw stone The mass percent that the diatomite of ash accounts for sludge silty amount is 3%~9%;
Step 4: burning
The sludge powder for being mixed with compound additive is added in sludge incinerator, is burned, incineration temperature is 750~950 DEG C, Burning atmosphere is air atmosphere, the fine particle after being burned.
4. the application method of the compound additive of sludge incineration fine particle production quantity is reduced as claimed in claim 3, it is special Sign is, in the step 2, the drying, drying temperature is 105 DEG C~200 DEG C.
5. the application method of the compound additive of sludge incineration fine particle production quantity is reduced as claimed in claim 3, it is special Sign is, in the step 4, the sludge incinerator is one of sludge incinerator, fluidized bed.
6. the application method of the compound additive of sludge incineration fine particle production quantity is reduced as claimed in claim 3, it is special Sign is, carries out reducing sludge incineration thin using the compound additive of reduction sludge incineration fine particle production quantity of the invention Grain object generates, analytic process are as follows:
Fine particle after burning is entered into cyclone separator with flue gas, separation diameter is greater than 10 μm of particulate matter, remaining thin Particulate matter and superfine particulate matter enter in the charged ram of low pressure with flue gas, carry out classification receipts to the fine particle of different-diameter Collection, then analysis statistics, is reduced the function and effect of the additive of sludge incineration fine particle generation.
CN201811366266.2A 2018-11-16 2018-11-16 Reduce the compound additive and its application method of sludge incineration fine particle production quantity Pending CN109458620A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201811366266.2A CN109458620A (en) 2018-11-16 2018-11-16 Reduce the compound additive and its application method of sludge incineration fine particle production quantity

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201811366266.2A CN109458620A (en) 2018-11-16 2018-11-16 Reduce the compound additive and its application method of sludge incineration fine particle production quantity

Publications (1)

Publication Number Publication Date
CN109458620A true CN109458620A (en) 2019-03-12

Family

ID=65610721

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201811366266.2A Pending CN109458620A (en) 2018-11-16 2018-11-16 Reduce the compound additive and its application method of sludge incineration fine particle production quantity

Country Status (1)

Country Link
CN (1) CN109458620A (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110180487A (en) * 2019-06-11 2019-08-30 沈阳航空航天大学 A kind of method and device using boron nitride control sludge incineration fine particle

Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1421515A (en) * 2001-11-23 2003-06-04 朱珍锦 Method of reducing the exhausted toxic heavy metal pollutent in fume of coal-burning boiler
ES2338199A1 (en) * 2008-07-28 2010-05-04 Ibs Business Services Ltd Additive to improve the combustión in industrial combustión apparatus, procedure to manufacture it and mode of utilization. (Machine-translation by Google Translate, not legally binding)
CN101987984A (en) * 2010-08-27 2011-03-23 天津百利阳光环保设备有限公司 Method for making compound solid waste derived fuel
CN102491607A (en) * 2011-11-23 2012-06-13 彭尹华 Technology for producing sewage adsorbing stones by using sewage processing plant sludge
CN103540382A (en) * 2013-09-13 2014-01-29 华中科技大学 Coal-burning additive for reducing emission of fine particles and heavy metals and preparation method thereof
CN104891769A (en) * 2015-05-29 2015-09-09 常州振业机械设备有限公司 Sludge drying incineration system and method
CN105112122A (en) * 2015-09-24 2015-12-02 东南大学 Biomass combustion coal additive effective in controlling release of alkali metals
CN106590811A (en) * 2016-11-22 2017-04-26 中冶节能环保有限责任公司 Method for significantly reducing discharge of sintering flue gas inhalable particles and fine particles

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1421515A (en) * 2001-11-23 2003-06-04 朱珍锦 Method of reducing the exhausted toxic heavy metal pollutent in fume of coal-burning boiler
ES2338199A1 (en) * 2008-07-28 2010-05-04 Ibs Business Services Ltd Additive to improve the combustión in industrial combustión apparatus, procedure to manufacture it and mode of utilization. (Machine-translation by Google Translate, not legally binding)
CN101987984A (en) * 2010-08-27 2011-03-23 天津百利阳光环保设备有限公司 Method for making compound solid waste derived fuel
CN102491607A (en) * 2011-11-23 2012-06-13 彭尹华 Technology for producing sewage adsorbing stones by using sewage processing plant sludge
CN103540382A (en) * 2013-09-13 2014-01-29 华中科技大学 Coal-burning additive for reducing emission of fine particles and heavy metals and preparation method thereof
CN104891769A (en) * 2015-05-29 2015-09-09 常州振业机械设备有限公司 Sludge drying incineration system and method
CN105112122A (en) * 2015-09-24 2015-12-02 东南大学 Biomass combustion coal additive effective in controlling release of alkali metals
CN106590811A (en) * 2016-11-22 2017-04-26 中冶节能环保有限责任公司 Method for significantly reducing discharge of sintering flue gas inhalable particles and fine particles

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110180487A (en) * 2019-06-11 2019-08-30 沈阳航空航天大学 A kind of method and device using boron nitride control sludge incineration fine particle
CN110180487B (en) * 2019-06-11 2022-08-02 沈阳航空航天大学 Method and device for controlling sludge incineration fine particulate matter by using boron nitride

Similar Documents

Publication Publication Date Title
CN108480360B (en) Method for recycling fly ash resources and discharging tail gas in ultra-clean mode by melting method of rotary kiln
WO2019095964A1 (en) Treatment method and device for cooperatively burning garbage and semi-dry sludge
CN110560019A (en) efficient, energy-saving and environment-friendly waste activated carbon regeneration method
CN1270988C (en) Sludge burning treatment method and system
CN111068612B (en) Method for preparing zeolite-like porous material by using solid waste, zeolite-like porous material and application thereof
CN203886406U (en) Tail gas purification device of circulating fluid bed garbage incinerator
CN101786786A (en) Sewage treatment and utilization method of municipal sewage treatment plant
CN106424110A (en) Low-temperature thermal desorption and efficient mercury recovery method of mercury-polluted soil
CN101357290A (en) Method and system of controlling dioxin discharge in flue gas by duty-cycle operation of sulphur-containing inhibitor
CN109945211B (en) Burning treatment method and system for semi-coke pyrolysis waste gas and waste liquid
CN104147890A (en) Method for trapping coal-fired PM2.5 by using agglomeration of attapulgite turbid liquid
CN101700524B (en) Fixing agent and method for safely disposing heavy metal polluted soil repairing plant
CN104326498B (en) Device utilizing high-temperature flue gas with high CO2 content to produce ultrafine active calcium powder and production method thereof
CN106238442A (en) Soil-repairing agent preparation system
CN109458620A (en) Reduce the compound additive and its application method of sludge incineration fine particle production quantity
CN103435243B (en) Parallel sludge low-temperature drying system utilizing waste heat of flue gas
CN105349222A (en) Preparation method of modified kaolin for trapping semi-volatile heavy metals
CN108862974B (en) Oil sludge treatment system and method
CN106482120A (en) The method and apparatus for organic solid waste process being carried out using recirculating fluidized bed
CN103104920B (en) The capture method of solid waste burning heavy metals in process and superfine particulate matter
CN102631886B (en) Waste incineration additive with function of capturing heavy metals and preparation method thereof
CN109500049A (en) A kind of daily-life garbage without environmental pollution recycling processing method utilized with effluent cycle
CN106893614B (en) A kind of method that Combustion Source particulate matter is reduced using flyash
CN106861606A (en) A kind of preparation method of nano titanium oxide/fly ash composite material
CN214635210U (en) Garbage disposal equipment based on magnetic separation and microwave regeneration

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
RJ01 Rejection of invention patent application after publication
RJ01 Rejection of invention patent application after publication

Application publication date: 20190312