CN101357290A - Method and system of controlling dioxin discharge in flue gas by duty-cycle operation of sulphur-containing inhibitor - Google Patents
Method and system of controlling dioxin discharge in flue gas by duty-cycle operation of sulphur-containing inhibitor Download PDFInfo
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- CN101357290A CN101357290A CNA2008101212859A CN200810121285A CN101357290A CN 101357290 A CN101357290 A CN 101357290A CN A2008101212859 A CNA2008101212859 A CN A2008101212859A CN 200810121285 A CN200810121285 A CN 200810121285A CN 101357290 A CN101357290 A CN 101357290A
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- Prior art keywords
- dioxin
- sulphur
- incinerator
- flue gas
- containing inhibitor
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- HGUFODBRKLSHSI-UHFFFAOYSA-N 2,3,7,8-tetrachloro-dibenzo-p-dioxin Chemical compound O1C2=CC(Cl)=C(Cl)C=C2OC2=C1C=C(Cl)C(Cl)=C2 HGUFODBRKLSHSI-UHFFFAOYSA-N 0.000 title claims abstract description 62
- 238000000034 method Methods 0.000 title claims abstract description 44
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 title claims abstract description 38
- 239000003112 inhibitor Substances 0.000 title claims abstract description 35
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 title claims abstract description 23
- 239000003546 flue gas Substances 0.000 title claims abstract description 23
- 239000005864 Sulphur Substances 0.000 title claims description 31
- RAHZWNYVWXNFOC-UHFFFAOYSA-N Sulphur dioxide Chemical compound O=S=O RAHZWNYVWXNFOC-UHFFFAOYSA-N 0.000 claims abstract description 46
- 238000003795 desorption Methods 0.000 claims abstract description 30
- 239000000428 dust Substances 0.000 claims abstract description 26
- 239000007789 gas Substances 0.000 claims abstract description 17
- 230000008569 process Effects 0.000 claims abstract description 14
- 238000010521 absorption reaction Methods 0.000 claims abstract description 9
- 239000010813 municipal solid waste Substances 0.000 claims abstract description 8
- 239000012299 nitrogen atmosphere Substances 0.000 claims abstract description 7
- 229910052717 sulfur Inorganic materials 0.000 claims abstract description 7
- 239000011593 sulfur Substances 0.000 claims abstract description 7
- 239000000203 mixture Substances 0.000 claims abstract description 4
- 239000003463 adsorbent Substances 0.000 claims description 20
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims description 14
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 14
- 229910052799 carbon Inorganic materials 0.000 claims description 14
- 238000007599 discharging Methods 0.000 claims description 9
- 229910052757 nitrogen Inorganic materials 0.000 claims description 7
- 238000013019 agitation Methods 0.000 claims description 6
- 239000000779 smoke Substances 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 5
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 claims description 4
- 239000004202 carbamide Substances 0.000 claims description 4
- 238000000746 purification Methods 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- 229910000278 bentonite Inorganic materials 0.000 claims description 3
- 239000000440 bentonite Substances 0.000 claims description 3
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 claims description 3
- 230000005540 biological transmission Effects 0.000 claims description 3
- 230000007246 mechanism Effects 0.000 claims description 3
- 238000002156 mixing Methods 0.000 claims description 3
- 238000005516 engineering process Methods 0.000 abstract description 6
- 239000010881 fly ash Substances 0.000 abstract description 3
- 230000008859 change Effects 0.000 abstract description 2
- 239000002910 solid waste Substances 0.000 abstract description 2
- 230000002745 absorbent Effects 0.000 abstract 2
- 239000002250 absorbent Substances 0.000 abstract 2
- 230000000694 effects Effects 0.000 abstract 1
- 230000005764 inhibitory process Effects 0.000 abstract 1
- 231100000770 Toxic Equivalency Factor Toxicity 0.000 description 5
- 239000003245 coal Substances 0.000 description 5
- 230000006872 improvement Effects 0.000 description 4
- 238000010438 heat treatment Methods 0.000 description 3
- QGZKDVFQNNGYKY-UHFFFAOYSA-N Ammonia Chemical compound N QGZKDVFQNNGYKY-UHFFFAOYSA-N 0.000 description 2
- 239000003610 charcoal Substances 0.000 description 2
- 238000002485 combustion reaction Methods 0.000 description 2
- 239000010791 domestic waste Substances 0.000 description 2
- 239000000446 fuel Substances 0.000 description 2
- 239000012071 phase Substances 0.000 description 2
- 230000000452 restraining effect Effects 0.000 description 2
- 238000003756 stirring Methods 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 229910021529 ammonia Inorganic materials 0.000 description 1
- 239000002956 ash Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 239000010782 bulky waste Substances 0.000 description 1
- 238000012512 characterization method Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000001351 cycling effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000002950 deficient Effects 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000005012 migration Effects 0.000 description 1
- 238000013508 migration Methods 0.000 description 1
- 230000001473 noxious effect Effects 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 238000012545 processing Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007790 solid phase Substances 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 238000004174 sulfur cycle Methods 0.000 description 1
- 230000002194 synthesizing effect Effects 0.000 description 1
- 238000012360 testing method Methods 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 238000004056 waste incineration Methods 0.000 description 1
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Abstract
The invention relates to a technology for controlling dioxin discharge in the process of treating solid wastes by an incineration method, and aims at providing a method for controlling the dioxin discharge in flue gas by reusing a sulfur-containing inhibitor and a system thereof. The method comprises the following steps: the sulfur-containing inhibitor and garbage are mixed and put into an incinerator; an absorbent is put in a flue to absorb sulfur dioxide and the dioxin; fly ash produced in the incineration process and on the absorption are collected by a dust collector; the mixture of the absorbent and the fly ash is sent to a thermal desorption device, heated and stirred under the protection of nitrogen atmosphere, and then the sulfur dioxide and the dioxin are desorbed in a gaseous form; the gas containing the sulfur dioxide and the dioxin is sent back to the incinerator, the dioxin is decomposed in the incinerator and the sulfur dioxide is reused as an inhibitor. The technology has the advantages of simple process, no large change on an original flue gas treatment system of the incinerator, obvious inhibition effect on the dioxin, and having significant application value for solving the problem of dioxin discharge in the garbage incineration process.
Description
Technical field
The present invention relates to the technology of dioxin emission control in the burning method disposal of solid discarded object process, particularly relate to a kind of method and system that recycle dioxin discharging in the sulphur-containing inhibitor control flue gas.
Background technology
Along with China's economy development and quickening of urbanization process at a high speed, the generation of domestic waste and trade waste increases rapidly.Burning method is processed solid waste because treating capacity is big, and it is good to subtract capacitive, and is innoxious thorough, and can reclaim heat, therefore at home and abroad obtains using more and more widely.China's recent years successively builds up the bulky refuse incineration plant in most of city.Yet can produce the noxious materials such as dioxin in the Refuse Incineration Process.Dioxin toxicity is very big, and is difficult to obtain degraded at nature, such as strictly control, will bring serious harm to natural environment and people healthy.Therefore, generation and discharging how to control dioxin have become extremely urgent, anxious to be resolved problem.
To the control of the dioxin in domestic waste and the danger wastes burning process, method commonly used has both at home and abroad: sack cleaner contains ammonia inhibitor etc. in conjunction with charcoal absorption, interpolation sulfur-bearing.Sack cleaner in conjunction with charcoal absorption be at present domestic and international many incinerators generally adopt the dioxin control method.This method is by pulverous active carbon being spurted into the dioxin that adsorbs in the flue in the gas phase, filter lower flying dust and active carbon with deduster then, thereby minimizing being by the dioxin amount of smoke stack emission.But there are two main defectives in this method: the one, and itself can not reduce the total amount of dioxin this method, just the dioxin in the gas phase is collected in solid phase then by the absorption migration of active carbon, the flying dust enrichment that is mixed with active carbon that produces the dioxin of high concentration, harm to environment is very big, the at present disposal for the castoff burning flying dust does not have good way yet, the method of domestic main landfill is disposed this class flying dust, and is very big to the potential hazard of environment; The 2nd, this method need to consume a large amount of active carbons, and operating cost is comparatively outstanding.
Adding the sulphur inhibitor is proved to be and can reduces synthesizing of dioxin in the source, main application form is rubbish and coal multifuel combustion at present, but the main purpose of coal multifuel combustion is because the calorific value of rubbish own is lower, need auxiliary fuel could burn thoroughly, relative higher sulfur content has also played the inhibitory action of dioxin in the coal.But along with the raising of economic level, the calorific value in the rubbish also increases gradually now, and will not need coal as auxiliary fuel future.And for the disposable small incinerator of some heats, coal is uneconomic especially.Can predict the inhibitor such as following separately interpolation sulphur, urea will be the principal mode of commercial Application.
Sulphur inhibitor such as sulfur dioxide itself commonly used are exactly pollutant, need special purifier to prevent from emitting environment to be worked the mischief, and substantially can not reuse after the purification, and operating cost is higher.
Summary of the invention
The objective of the invention is to overcome deficiency of the prior art, a kind of method that recycles dioxin discharging in the sulphur-containing inhibitor control flue gas is provided, and another object of the present invention provides a kind of system that recycles dioxin discharging in the sulphur-containing inhibitor control flue gas.
In order to solve the problems of the technologies described above, the present invention is achieved by the following technical solutions:
The invention provides a kind of method that recycles dioxin discharging in the sulphur-containing inhibitor control flue gas, may further comprise the steps:
(1) sulphur-containing inhibitor and rubbish mixing are put in the incinerator, the addition of control sulphur-containing inhibitor is so that the sulfur dioxide in flue gas concentration of incinerator burner hearth remains on 200～400mg/Nm
3
(2) adsorbent is put into absorption sulfur in smoke and dioxin in the flue, the temperature of adsorbent input point is lower than 200 ℃;
(3) flying dust that produces with deduster collection adsorbent and burning process;
(4) adsorbent collected and the mixture of flying dust are sent in the thermal desorption device, under the nitrogen atmosphere protection, added thermal agitation, sulfur dioxide and dioxin are come out with the gas form desorption;
(5) gas that will contain sulfur dioxide and dioxin is sent incinerator back to, and dioxin decomposes in incinerator, and sulfur dioxide then recycles as inhibitor.
As a kind of improvement, described sulphur-containing inhibitor be sulphur, urea or sulfur dioxide wherein any one.
As a kind of improvement, described adsorbent be active carbon, diatomite or bentonite wherein any one.
As a kind of improvement, the addition of described adsorbent is 150～300mg/Nm
3
As a kind of improvement, when adding thermal agitation under the nitrogen atmosphere protection, the temperature in the control thermal desorption device is 250～320 ℃.
The present invention also provides a kind of system of controlling dioxin discharge in flue gas by duty-cycle operation of sulphur-containing inhibitor method, comprise incinerator, adsorbent dispensing port and deduster are set in the flue gas purification system of incinerator, and the outlet of deduster is connected to a thermal desorption device by the ash material conveyance conduit; Described thermal desorption device comprises the housing of internal heater, and its inner axle that connection for transmission mechanism is installed arranges some inclinations and is installed on wedge shape blade on the axle on the axle; A helixes feed equipment is established on the top of housing one end, and a spiral discharge device is established in other end bottom; Establish a nitrogen inlet at housing one end in addition, establish thermal desorption gas outlet at the other end; The outlet of thermal desorption gas connects the incinerator burner hearth by pipeline.
Compared with prior art, the invention has the beneficial effects as follows:
Dioxin restraining method technology of the present invention is simple, does not need the original smoke processing system of incinerator is carried out big change, and the dioxin restraining effect is obvious, has important use for the emission problem that solves dioxin in the waste incineration process and is worth.
Description of drawings
Fig. 1 is a process chart of the present invention;
Fig. 2 is the structural representation of thermal desorption device among the present invention.
The specific embodiment
With reference to the accompanying drawings, will describe the present invention below.
The method of the controlling dioxin discharge in flue gas by duty-cycle operation of sulphur-containing inhibitor in the present embodiment may further comprise the steps:
(1) sulphur-containing inhibitor and rubbish mixing are put in the incinerator, the addition of control sulphur-containing inhibitor is so that the sulfur dioxide in flue gas concentration of incinerator burner hearth remains on 200～400mg/Nm
3
(2) adsorbent is put into absorption sulfur in smoke and dioxin in the flue, the temperature of adsorbent input point is lower than 200 ℃;
(3) flying dust that produces with deduster collection adsorbent and burning process;
(4) adsorbent collected and the mixture of flying dust are sent in the thermal desorption device, under the nitrogen atmosphere protection, added thermal agitation, sulfur dioxide and dioxin are come out with the gas form desorption; In flying dust thermal desorption process, feed nitrogen and make flying dust thermal desorption device inside be in the state of anaerobic, prevent the synthetic again of dioxin.
(5) gas that will contain sulfur dioxide and dioxin is sent incinerator back to, and dioxin decomposes in incinerator, and sulfur dioxide then recycles as inhibitor.
Sulphur-containing inhibitor can select sulphur, urea or sulfur dioxide wherein any one, be sulphur in the present embodiment.
Adsorbent can select active carbon, diatomite or bentonite wherein any one, be active carbon in the present embodiment.Active carbon not only can adsorb dioxin can also adsorb gas molecules such as sulfur dioxide.Active carbon also often is applied to desulfurization.And active carbon is after being heated, and the material of absorption can discharge with gas form.Utilizing this characterization of adsorption of active carbon, can be used for realizing recycling of inhibitor, can dispose the flying dust that contains the high concentration dioxin simultaneously, will be a up-and-coming dioxin emission control technique.
The addition of active carbon is 100～300mg/Nm
3
When adding thermal agitation under the nitrogen atmosphere protection, the temperature in the control thermal desorption device is 250～320 ℃.
The system that recycles dioxin discharge method in the sulphur-containing inhibitor control flue gas in the present embodiment, comprise incinerator, adsorbent dispensing port and deduster are set in the flue gas purification system of incinerator, and the outlet of deduster is connected to a thermal desorption device by grey material conveying tube road.
The thermal desorption apparatus structure as shown in Figure 2.
The thermal desorption device comprises the housing 3 of the built-in resistance wire that is used for heating, its inner axle 5 that connection for transmission mechanism is installed, and motor 1 rotates by bearing 4 band moving axis 5.Some inclinations are set on the axle 5 are installed on wedge shape blade 6 on the axle, be used for stirring flying dust so that the flying dust thermally equivalent. The top of housing 3 one ends is established a helixes feed equipment 2 and is used for adding flying dust, and other end bottom is established a spiral discharge device 7 flying dust of handling well is discharged; Establish a nitrogen inlet at housing 3 one ends in addition, establish thermal desorption gas outlet at the other end; The outlet of thermal desorption gas connects the incinerator burner hearth by pipeline.
The method of operation of thermal desorption device is as follows: shell 3 is by internal resistance silk heating inner bin to 300 ℃.Pass into nitrogen so that the inner state that is in anaerobic.The flying dust of collecting from sack cleaner feeds from helixes feed equipment 2.Start motor 1 so that axle 5 drives wedge shape blades 6 rotates, flying dust stirs under wedge shape blade 6 drives, and fully is heated, so that the sulfur dioxide of absorption and dioxin desorption and taken out of by nitrogen.After pending a period of time, close heating, flying dust is naturally cooled to below 200 ℃, close nitrogen stream.Flying dust is discharged the thermal desorption device by spiral discharge device 7.
Compare with the comparative test of not adopting sulfur cycle control dioxin method, dioxin toxic equivalent concentration before active carbon drops into point has descended 90.4%, dioxin toxic equivalent concentration in the flying dust that sack cleaner is collected has descended 93.3%, and the dioxin toxic equivalent concentration of smoke stack emission has descended 94.1%.After flying dust is disposed through flying dust thermal desorption device, there is approximately 37% sulfur dioxide to obtain cycling and reutilization.Dioxin total amount in the flying dust and toxic equivalent concentration have all descended more than 95%, and wherein toxic equivalent concentration is 0.043ng/g, far below the national standard of present incineration of refuse flyash dioxin.
At last, it is also to be noted that what more than enumerate only is specific embodiments of the invention.Obviously, the invention is not restricted to above embodiment, many distortion can also be arranged.All distortion that those of ordinary skill in the art can directly derive or associate from content disclosed by the invention all should be thought protection scope of the present invention.
Claims (6)
1, a kind of method that recycles dioxin discharging in the sulphur-containing inhibitor control flue gas may further comprise the steps:
(1) sulphur-containing inhibitor and rubbish mixing are put in the incinerator, the addition of control sulphur-containing inhibitor is so that the sulfur dioxide in flue gas concentration of incinerator furnace outlet remains on 200～400mg/Nm
3
(2) adsorbent is put into absorption sulfur in smoke and dioxin in the flue, the temperature of adsorbent input point is lower than 200 ℃;
(3) flying dust that produces with deduster collection adsorbent and burning process;
(4) adsorbent collected and the mixture of flying dust are sent in the thermal desorption device, under the nitrogen atmosphere protection, added thermal agitation, sulfur dioxide and dioxin are come out with the gas form desorption;
(5) gas that will contain sulfur dioxide and dioxin is sent incinerator back to, and dioxin decomposes in incinerator, and sulfur dioxide then recycles as inhibitor.
2, the method that recycles dioxin discharging in the sulphur-containing inhibitor control flue gas according to claim 1 is characterized in that, described sulphur-containing inhibitor be sulphur, urea or sulfur dioxide wherein any one.
3, the method that recycles dioxin discharging in the sulphur-containing inhibitor control flue gas according to claim 1 is characterized in that, described adsorbent be active carbon, diatomite or bentonite wherein any one.
4, the method for controlling dioxin discharge in flue gas by duty-cycle operation of sulphur-containing inhibitor according to claim 1 is characterized in that, the addition of described adsorbent is 100～300mg/Nm
3
5, the method that recycles dioxin discharging in the sulphur-containing inhibitor control flue gas according to claim 1 is characterized in that, when adding thermal agitation under the nitrogen atmosphere protection, the temperature in the control thermal desorption device is 250～320 ℃.
6, a kind of system for the described controlling dioxin discharge in flue gas by duty-cycle operation of sulphur-containing inhibitor method of claim 1, comprise incinerator, adsorbent dispensing port and deduster are set in the flue gas purification system of incinerator, it is characterized in that the outlet of deduster is connected to a thermal desorption device by the ash material conveyance conduit; Described thermal desorption device comprises the housing of internal heater, and its inner axle that connection for transmission mechanism is installed arranges some inclinations and is installed on wedge shape blade on the axle on the axle; A helixes feed equipment is established on the top of housing one end, and a spiral discharge device is established in other end bottom; Establish a nitrogen inlet at housing one end in addition, establish thermal desorption gas outlet at the other end; The outlet of thermal desorption gas connects the incinerator burner hearth by pipeline.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008101212859A CN101357290A (en) | 2008-09-25 | 2008-09-25 | Method and system of controlling dioxin discharge in flue gas by duty-cycle operation of sulphur-containing inhibitor |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CNA2008101212859A CN101357290A (en) | 2008-09-25 | 2008-09-25 | Method and system of controlling dioxin discharge in flue gas by duty-cycle operation of sulphur-containing inhibitor |
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| CN101357290A true CN101357290A (en) | 2009-02-04 |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102000443A (en) * | 2010-11-05 | 2011-04-06 | 天津大学 | Method for collecting dioxin from incineration flue gas of household garbage |
| CN102266712A (en) * | 2010-03-01 | 2011-12-07 | 中国科学院生态环境研究中心 | Method for inhibiting generation of dioxins |
| CN101725989B (en) * | 2009-12-31 | 2012-08-22 | 北京中科通用能源环保有限责任公司 | Retardant adding system for retarding generation of dioxins |
| CN103292339A (en) * | 2013-06-24 | 2013-09-11 | 湖南科技大学 | Comprehensive processing recycling process and device of bromine-contained high temperature flue gas |
| CN105080325A (en) * | 2015-09-01 | 2015-11-25 | 同济大学 | Method of inhibiting generation of dioxins in solid waste incineration flue gas |
| CN107894000A (en) * | 2017-12-19 | 2018-04-10 | 北京中洁蓝环保科技有限公司 | A kind of thermal desorption system of domestic garbage incineration flyash |
| CN108500046A (en) * | 2018-05-09 | 2018-09-07 | 中国联合工程有限公司 | Contaminated soil thermal desorption device and its method for reducing dioxin generation |
| CN110398140A (en) * | 2019-09-02 | 2019-11-01 | 洛阳炬星窑炉有限公司 | A kind of water removal of material and remove organic matter device |
| CN110479078A (en) * | 2019-09-09 | 2019-11-22 | 广州派安环保科技有限公司 | A kind of production of dioxin restraining agent and technique for applying |
| CN111069226A (en) * | 2019-10-31 | 2020-04-28 | 浙江大学台州研究院 | Novel S-N-P inhibitor coupled mechanochemical method for degrading waste incineration fly ash |
| CN115329659A (en) * | 2022-07-18 | 2022-11-11 | 浙江大学 | Method and system for real-time early warning and intelligent control of dioxin emission in waste incinerator |
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2008
- 2008-09-25 CN CNA2008101212859A patent/CN101357290A/en active Pending
Cited By (16)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101725989B (en) * | 2009-12-31 | 2012-08-22 | 北京中科通用能源环保有限责任公司 | Retardant adding system for retarding generation of dioxins |
| CN102266712A (en) * | 2010-03-01 | 2011-12-07 | 中国科学院生态环境研究中心 | Method for inhibiting generation of dioxins |
| CN102000443A (en) * | 2010-11-05 | 2011-04-06 | 天津大学 | Method for collecting dioxin from incineration flue gas of household garbage |
| CN102000443B (en) * | 2010-11-05 | 2012-10-03 | 天津大学 | Method for collecting dioxin from incineration flue gas of household garbage |
| CN103292339A (en) * | 2013-06-24 | 2013-09-11 | 湖南科技大学 | Comprehensive processing recycling process and device of bromine-contained high temperature flue gas |
| CN103292339B (en) * | 2013-06-24 | 2015-06-17 | 湖南科技大学 | Comprehensive processing recycling process and device of bromine-contained high temperature flue gas |
| CN105080325A (en) * | 2015-09-01 | 2015-11-25 | 同济大学 | Method of inhibiting generation of dioxins in solid waste incineration flue gas |
| CN105080325B (en) * | 2015-09-01 | 2017-06-13 | 同济大学 | A kind of method for suppressing the generation of solid waste incineration fume dioxins materials |
| CN107894000A (en) * | 2017-12-19 | 2018-04-10 | 北京中洁蓝环保科技有限公司 | A kind of thermal desorption system of domestic garbage incineration flyash |
| CN108500046A (en) * | 2018-05-09 | 2018-09-07 | 中国联合工程有限公司 | Contaminated soil thermal desorption device and its method for reducing dioxin generation |
| CN110398140A (en) * | 2019-09-02 | 2019-11-01 | 洛阳炬星窑炉有限公司 | A kind of water removal of material and remove organic matter device |
| CN110398140B (en) * | 2019-09-02 | 2024-05-07 | 洛阳炬星窑炉有限公司 | Device for removing water and organic matters from materials |
| CN110479078A (en) * | 2019-09-09 | 2019-11-22 | 广州派安环保科技有限公司 | A kind of production of dioxin restraining agent and technique for applying |
| CN111069226A (en) * | 2019-10-31 | 2020-04-28 | 浙江大学台州研究院 | Novel S-N-P inhibitor coupled mechanochemical method for degrading waste incineration fly ash |
| CN115329659A (en) * | 2022-07-18 | 2022-11-11 | 浙江大学 | Method and system for real-time early warning and intelligent control of dioxin emission in waste incinerator |
| CN115329659B (en) * | 2022-07-18 | 2023-07-14 | 浙江大学 | Method and system for real-time early warning and intelligent control of dioxin emission of waste incinerator |
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Application publication date: 20090204 |