CN109457478A - A kind of terylene substrate fabric finishing technique that can stablize bonding with solar energy substrate - Google Patents
A kind of terylene substrate fabric finishing technique that can stablize bonding with solar energy substrate Download PDFInfo
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- CN109457478A CN109457478A CN201811263182.6A CN201811263182A CN109457478A CN 109457478 A CN109457478 A CN 109457478A CN 201811263182 A CN201811263182 A CN 201811263182A CN 109457478 A CN109457478 A CN 109457478A
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- substrate
- solar energy
- desizing
- temperature
- terylene
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- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M15/00—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment
- D06M15/19—Treating fibres, threads, yarns, fabrics, or fibrous goods made from such materials, with macromolecular compounds; Such treatment combined with mechanical treatment with synthetic macromolecular compounds
- D06M15/21—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06M15/227—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds of hydrocarbons, or reaction products thereof, e.g. afterhalogenated or sulfochlorinated
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C23/00—Making patterns or designs on fabrics
- D06C23/04—Making patterns or designs on fabrics by shrinking, embossing, moiréing, or crêping
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06C—FINISHING, DRESSING, TENTERING OR STRETCHING TEXTILE FABRICS
- D06C7/00—Heating or cooling textile fabrics
- D06C7/02—Setting
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06L—DRY-CLEANING, WASHING OR BLEACHING FIBRES, FILAMENTS, THREADS, YARNS, FABRICS, FEATHERS OR MADE-UP FIBROUS GOODS; BLEACHING LEATHER OR FURS
- D06L1/00—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods
- D06L1/12—Dry-cleaning or washing fibres, filaments, threads, yarns, fabrics, feathers or made-up fibrous goods using aqueous solvents
- D06L1/14—De-sizing
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0006—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using woven fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/0002—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate
- D06N3/0015—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof characterised by the substrate using fibres of specified chemical or physical nature, e.g. natural silk
- D06N3/0036—Polyester fibres
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N3/00—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
- D06N3/04—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- D06N3/045—Artificial leather, oilcloth or other material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof with macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds with polyolefin or polystyrene (co-)polymers
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N7/00—Flexible sheet materials not otherwise provided for, e.g. textile threads, filaments, yarns or tow, glued on macromolecular material
- D06N7/0092—Non-continuous polymer coating on the fibrous substrate, e.g. plastic dots on fabrics
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06M—TREATMENT, NOT PROVIDED FOR ELSEWHERE IN CLASS D06, OF FIBRES, THREADS, YARNS, FABRICS, FEATHERS OR FIBROUS GOODS MADE FROM SUCH MATERIALS
- D06M2101/00—Chemical constitution of the fibres, threads, yarns, fabrics or fibrous goods made from such materials, to be treated
- D06M2101/16—Synthetic fibres, other than mineral fibres
- D06M2101/30—Synthetic polymers consisting of macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- D06M2101/32—Polyesters
-
- D—TEXTILES; PAPER
- D06—TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
- D06N—WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
- D06N2209/00—Properties of the materials
- D06N2209/16—Properties of the materials having other properties
- D06N2209/1664—Releasability
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- Engineering & Computer Science (AREA)
- Textile Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Treatments For Attaching Organic Compounds To Fibrous Goods (AREA)
- Laminated Bodies (AREA)
Abstract
The invention discloses a kind of terylene substrate fabric finishing techniques that can stablize bonding with solar energy substrate, comprising the following steps: desizing pretreatment;The further provided for contouring processing of cloth cover can increase the contact specific surface area of cloth cover, and follow-up coating and adhesion technique is enable to have better removing fastness;Drying and shaping;Top finish.Existing polyester fabric can be enabled to cross to use as the flexible substrates of solar energy substrate.Existing solar energy substrate package machine can be used by the finishing technique of the invention, without improving existing encapsulation technology parameter, directly industrialization can use the fabric.
Description
Technical field
The present invention relates to a kind of terylene substrate fabrics, and in particular to a kind of terylene base that can stablize bonding with solar energy substrate
Expect finishing technique in bottom surface.
Background technique
Flexible amorphous silicon solar battery complete industrialized production at present can be encapsulated using high molecular polymer glue film,
Keep product more flexible durable, and can any bending fold (conventional solar cell is with glass-encapsulated, fragile rapid wear), very
Any moulding can be extremely fabricated to according to different equipment Requirements, it is easy to carry after folding.It, only need to be by solar-electricity when field work
Pond plate is arbitrarily sprawled or is hung, and can be powered to load, and can bear use when walking.Flexible amorphous silicon solar-electricity
The polymeric laminate of pool surface encapsulation has carried out scientific design, and the lines on surface handles the absorbable light from all angles
Line effectively prevents daylight and loses.Even if can also generate 30% or so power, overall efficiency in the rainy days of not sunlight
20% is promoted than conventional solar cell.Moreover, also there is non-maintaining, waterproof after flexible thin-film solar cell is encapsulated, prevent
The advantages of traditional solar energy such as rotten, antifouling, shock resistance, anti-weight, heatproof insulation can not have.
But there is no consider and existing textile product completely for flexible amorphous silicon solar battery packaged at present
Depth integration, for Related product only be simply superimposed, no organic combination is integrated.For some high-end products
In, fabric and solar cell substrates are combined using integrated pressure-bearing technology, but the fabric type used is limited, often
With non-woven cloth or military camouflage fabric.Main cause is in fabric collapsing performance, anti-perspective performance, waterproof performance, fabric
Still there are some problems on substrate stripping performance.In existing three junction amorphous silicons thin-film solar cells substrate, use is soft
Base material of the property stainless steel film as solar battery, and for really using fabric to rarely have report as the research of substrate
Road, therefore, the research in flexible fabric substrate are still in infancy.
Summary of the invention
In order to solve the above technical problems, raising flexible amorphous silicon solar battery and the depth of existing textile product are melted
It closes, the present invention provides a kind of terylene substrate fabric finishing technique that can stablize bonding with solar energy substrate.
The technical solution adopted by the present invention:
One kind provided by the invention can stablize the terylene substrate fabric finishing technique of bonding, including following step with solar energy substrate
It is rapid:
(1) desizing pre-processes:
Desizing after cloth feeding, 90-95 DEG C of desizing temperature, desizing time 0.5-1h, then soap, 85-95 DEG C of temperature of soaping is soaped the time
0.5-1h uses hot water wash after soaping, 90-100 DEG C of hot water wash temperature, hot water wash time 0.5-1h, last cold water washes.Desizing is pre-
In treatment process, using desizing refining agent 4-6g/L, bleeding agent 1-3g/L, alkaline reagent.
(2) the further provided for contouring processing of cloth cover:
Wire mesh presses after cloth feeding, and wire mesh uses 200-300 mesh, then brush silane coupling agent, controls 25-35 DEG C of temperature,
0.5-1h is brushed, is finally soaped, 85-95 DEG C of temperature of soaping, soap time 0.5-1h.
(3) drying and shaping:
It is spraying using waterproof agent after cloth feeding, then the shrinkproof drying of pressure point formula pressing, stentering forming temperature: 155- are carried out to fabric
165 DEG C, control tentering speed: 36-40 m/min, cooling, last clot cloth outputting.
(4) top finish:
After cloth feeding, using paste point coating, adhesive carries out adhesive coatings using high-temperature-resistance polyolefin class adhesive, dries, is cold
But clot again.
Further, in desizing preprocessing process, using desizing refining agent 4-6g/L, bleeding agent 1-3g/L, alkaline reagent.
Further, in paste point coating, adhesive carries out adhesive coatings using high-temperature-resistance polyolefin class adhesive.
Further, the fabric uses the highly dense dacron of 220T or more terylene plain weave, and finished product grammes per square metre is controlled at 70 grams
More than.
Compared with prior art, beneficial effects of the present invention: the finishing technique of the terylene substrate fabric the following steps are included:
Desizing pretreatment;The further provided for contouring processing of cloth cover can increase the contact specific surface area of cloth cover, enable follow-up coating and adhesion technique
Enough there is better removing fastness;Drying and shaping;Top finish.Existing polyester fabric can be enabled to cross as solar energy substrate
Flexible substrates use.
Detailed description of the invention
Fig. 1 is the further provided for contouring mechanism principle figure of cloth cover.
Fig. 2 is fabric surface pit scanning electron microscope diagram.
1, wire mesh, 2, fabric, 3, straining pulley, 4, reagent trough.
Specific embodiment
In order to deepen the understanding of the present invention, it is described in detail, is retouched in this specification With reference to embodiment
It states that the examples are only for explaining the invention, is not used to limit the present invention.
Embodiment 1
A kind of terylene substrate fabric finishing technique that can stablize bonding with solar energy substrate of the invention, comprising the following steps:
(1) desizing pre-processes:
Desizing after cloth feeding, 90 DEG C of desizing temperature, desizing time 0.5h, then soap, 85 DEG C of temperature of soaping, soap time 0.5h, soap
Hot water wash is used after washing, 90 DEG C of hot water wash temperature, hot water wash time 0.5h, last cold water is washed.In desizing preprocessing process, use
Desizing refining agent 4g/L, bleeding agent 1g/L, alkaline reagent.
(2) the further provided for contouring processing of cloth cover:
Wire mesh presses after cloth feeding, and wire mesh uses 200 mesh, then brush silane coupling agent, controls 25 DEG C of temperature, brushes
0.5h finally soaps, and 85 DEG C of temperature of soaping, soap time 0.5h.
(3) drying and shaping (adding water-proof finish):
It is spraying using waterproof agent after cloth feeding, then the shrinkproof drying of pressure point formula pressing, stentering forming temperature: 155 are carried out to fabric
DEG C, control tentering speed: 36 m/min, cooling, last clot cloth outputting.
(4) top finish:
After cloth feeding, using paste point coating, adhesive carries out adhesive coatings using high-temperature-resistance polyolefin class adhesive, dries, is cold
But clot again.
Embodiment 2
A kind of terylene substrate fabric finishing technique that can stablize bonding with solar energy substrate of the invention, comprising the following steps:
(1) desizing pre-processes:
Desizing after cloth feeding, 92 DEG C of desizing temperature, desizing time 0.7h, then soap, 90 DEG C of temperature of soaping, soap time 0.7h, soap
Hot water wash is used after washing, 95 DEG C of hot water wash temperature, hot water wash time 0.7h, last cold water is washed.In desizing preprocessing process, use
Desizing refining agent 5g/L, bleeding agent 2g/L, alkaline reagent.
(2) the further provided for contouring processing of cloth cover:
Wire mesh presses after cloth feeding, and wire mesh uses 250 mesh, then brush silane coupling agent, controls 30 DEG C of temperature, brushes
0.7h finally soaps, and 90 DEG C of temperature of soaping, soap time 0.7h.
(3) drying and shaping (adding water-proof finish):
It is spraying using waterproof agent after cloth feeding, then the shrinkproof drying of pressure point formula pressing, stentering forming temperature: 160 are carried out to fabric
DEG C, control tentering speed: 38 m/min, cooling, last clot cloth outputting.
(4) top finish:
After cloth feeding, using paste point coating, adhesive carries out adhesive coatings using high-temperature-resistance polyolefin class adhesive, dries, is cold
But clot again.
Embodiment 3
A kind of terylene substrate fabric finishing technique that can stablize bonding with solar energy substrate of the invention, comprising the following steps:
(1) desizing pre-processes:
Desizing after cloth feeding, 95 DEG C of desizing temperature, desizing time 1h, then soap, 95 DEG C of temperature of soaping, soap time 1h, after soaping
Using hot water wash, 100 DEG C of hot water wash temperature, hot water wash time 1h, last cold water is washed.In desizing preprocessing process, using desizing
Refining agent 6g/L, bleeding agent 3g/L, alkaline reagent.
(2) the further provided for contouring processing of cloth cover:
Wire mesh presses after cloth feeding, and wire mesh uses 300 mesh, then brush silane coupling agent, controls 35 DEG C of temperature, brushes 1h,
It finally soaps, 95 DEG C of temperature of soaping, soap time 1h.
(3) drying and shaping (adding water-proof finish):
It is spraying using waterproof agent after cloth feeding, then the shrinkproof drying of pressure point formula pressing, stentering forming temperature: 165 are carried out to fabric
DEG C, control tentering speed: 40 m/min, cooling, last clot cloth outputting.
(4) top finish:
After cloth feeding, using paste point coating, adhesive carries out adhesive coatings using high-temperature-resistance polyolefin class adhesive, dries, is cold
But clot again.
Fabric used in above-described embodiment 1-3 uses the highly dense dacron of 220T or more terylene plain weave, the control of finished product grammes per square metre
At 70 grams or more.
Finishing technique of the invention can be such that terylene substrate fabric and solar energy substrate stablizes and bond, mainly include desizing
Pretreatment, the further provided for contouring processing of cloth cover, drying and shaping, top finish this four steps:
(1) in order to increase the contact specific surface area of cloth cover, follow-up coating and adhesion technique is enable to have better removing jail
Degree needs to carry out the processing of cloth cover bumps to woven surface.
In order to guarantee treatment effeciency and guarantee that coupling agent can form tiny pit in cloth cover, thus it is even using silk screen brush
Join the method for agent.It is combined closely between the surface and wire mesh 1 of fabric 2 by straining pulley 3, is transported in the mode that clearance-type is reciprocal
Row (such as Fig. 1).Ensure that fabric surface has tiny pit, such as Fig. 2.
(2) drying and shaping (adding water-proof finish), makes ironing shrinkage less than 1.5% mainly for guaranteeing dimensional stability.
(3) top finish
In order to make fabric hydrostatic pressing reach 800kPa, while in order to increase the adhesive strength of solar energy substrate and substrate, that is, remove
Fastness >=15N, it is necessary to which coating treatment is carried out to fabric.Using paste point coating, this method without reverse osmosis material phenomenon, coating uniform,
Peel strength fluctuating range is small after bonding, and adhesive strength is uniform.
Since solar energy substrate and substrate encapsulation need more than 1 atmospheric pressure, encapsulation being spent 100, conventional fabric cannot more
Meet above-mentioned requirements, and requires removing fastness (fabric and solar energy substrate) >=15N, light transmittance≤15%, ironing relaxation shrinkage≤
1.5%, hydrostatic pressing >=800(solar energy substrate needs waterproof, and is unable to leak adhesive when bonding).One kind through the invention can be with the sun
Energy substrate stablizes the terylene substrate fabric finishing technique of bonding, and existing polyester fabric can be enabled to cross as solar energy substrate
Flexible substrates use.Existing solar energy substrate package machine can be used by the finishing technique of the invention, it is existing without improving
There is encapsulation technology parameter, directly industrialization can use the fabric.
Claims (4)
1. the terylene substrate fabric finishing technique that one kind can stablize bonding with solar energy substrate, it is characterised in that: including following step
It is rapid:
(1) desizing pre-processes:
Desizing after cloth feeding, 90-95 DEG C of desizing temperature, desizing time 0.5-1h, then soap, 85-95 DEG C of temperature of soaping is soaped the time
0.5-1h uses hot water wash after soaping, 90-100 DEG C of hot water wash temperature, hot water wash time 0.5-1h, last cold water washes;
(2) the further provided for contouring processing of cloth cover:
Wire mesh presses after cloth feeding, and wire mesh uses 200-300 mesh, then brush silane coupling agent, controls 25-35 DEG C of temperature,
0.5-1h is brushed, is finally soaped, 85-95 DEG C of temperature of soaping, soap time 0.5-1h;
(3) drying and shaping:
It is spraying using waterproof agent after cloth feeding, then the shrinkproof drying of pressure point formula pressing, stentering forming temperature: 155- are carried out to fabric
165 DEG C, control tentering speed: 36-40 m/min, cooling, last clot cloth outputting;
(4) top finish:
After cloth feeding, using paste point coating, drying, cooling clot again.
2. one kind according to claim 1 can stablize the terylene substrate fabric finishing technique of bonding with solar energy substrate,
It is characterized in that: in desizing preprocessing process, using desizing refining agent 4-6g/L, bleeding agent 1-3g/L, alkaline reagent.
3. one kind according to claim 1 can stablize the terylene substrate fabric finishing technique of bonding with solar energy substrate,
Be characterized in that: in paste point coating, adhesive carries out adhesive coatings using high-temperature-resistance polyolefin class adhesive.
4. one kind according to claim 1 can stablize the terylene substrate fabric finishing technique of bonding with solar energy substrate,
Be characterized in that: the fabric uses the highly dense dacron of 220T or more terylene plain weave, and finished product grammes per square metre is controlled at 70 grams or more.
Priority Applications (1)
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CN201811263182.6A CN109457478B (en) | 2018-10-28 | 2018-10-28 | Finishing process of polyester base fabric capable of being stably bonded with solar substrate |
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CN201811263182.6A CN109457478B (en) | 2018-10-28 | 2018-10-28 | Finishing process of polyester base fabric capable of being stably bonded with solar substrate |
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CN109457478A true CN109457478A (en) | 2019-03-12 |
CN109457478B CN109457478B (en) | 2021-11-09 |
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Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007191825A (en) * | 2006-01-20 | 2007-08-02 | Singtex Industrial Co Ltd | Method for producing knitted fabric capable of breaking wind and preventing water |
CN103767201A (en) * | 2014-01-06 | 2014-05-07 | 浙江金三发粘合衬有限公司 | Process for preparing anti-static adhesive interlining of all-wool fabric |
WO2018003459A1 (en) * | 2016-06-28 | 2018-01-04 | 東レ株式会社 | Composite sheet product and method for manufacturing same |
-
2018
- 2018-10-28 CN CN201811263182.6A patent/CN109457478B/en active Active
Patent Citations (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JP2007191825A (en) * | 2006-01-20 | 2007-08-02 | Singtex Industrial Co Ltd | Method for producing knitted fabric capable of breaking wind and preventing water |
CN103767201A (en) * | 2014-01-06 | 2014-05-07 | 浙江金三发粘合衬有限公司 | Process for preparing anti-static adhesive interlining of all-wool fabric |
WO2018003459A1 (en) * | 2016-06-28 | 2018-01-04 | 東レ株式会社 | Composite sheet product and method for manufacturing same |
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